• Journal of the Korean Society for Nondestructive Testing
• /
• v.35 no.6
• /
• pp.414-420
• /
• 2015

Concrete undergoes significant phase changes from liquid to solid states as hydration progresses. These phase changes are known as the setting process. A liquid state concrete is electrically conductive because of the presence of water and ions. However, since the conductive elements in the liquid state of concrete are consumed to produce non-conductive hydration products, the electrical conductivity of hydrating concrete decreases during the setting process. Therefore, the electrical properties of hydrating concrete can be used to monitor the setting process of concrete. In this study, a parameter identification method to estimate electrical parameters such as ohmic resistance of concrete is proposed. The effectiveness of the proposed method for monitoring the setting process of concrete is experimentally validated.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2000.10b
• /
• pp.983-988
• /
• 2000

Anchoring systems with structural stability and endurance have been one of the most important elements for PSC structures, especially for the structures using non-corrosive FRP tendons. FRP tendons are in increasing use for underground and coastal structures constantly contacted with fresh water or sea water because of their superiority to metallic ones in corrosion-resistance. In this study new non-metallic anchoring system for FRP tendons has been tested and investigated. The newly developed anchoring system utilizes FRP pipes and HEM (Highly Expansive Mortar). The major factors considered in this experiment were expansive pressure of HEM during its hydration and the strength of GFRP(Glass Fiber Reinforced Plastic) Pipe. Anchoring forces of the new anchoring system were investigated from the pull-out testes. The authors analyzed pull-out procedures of the FRP tendons in the various pipe filled with HEM and suggested an improved idea to develop novel non-metallic anchoring system for FRP tendons

• Journal of the Korea Concrete Institute
• /
• v.18 no.2 s.92
• /
• pp.267-274
• /
• 2006

Greenhouse gas reduction will be highlighted as the most pending question in the cement industry in future because the production of Portland cement not only consumes limestone, clay, coal, and electricity, but also release waste gases such as $CO_2,\;SO_3$, and NOX, which can contribute to the greenhouse effect and acid rain. To meet the increase of cement demand and simultaneously comply with the Kyoto Protocol, cement that gives less $CO_2$ discharge should be urgently developed. This study aims to manufacture non-sintering cement(NSC) by adding phosphogypsum(PG) and waste lime(WL) to granulated blast furnace slag(GBFS) as sulfate and alkali activators. This study also Investigates the hydration reaction of NSC through analysis of scanning electron microscopy(SEM), X-ray diffraction(XRD), differential thermal analysis(DTA), and pH. Results obtained from analysis of the hydrate have shown that the glassy films of GBFS are destroyed by the activation of alkali and sulfate, ions eluted from the inside of GBFS react with PG and produce ettringite, and consequently the remaining component in GBFS slowly produced C-5-H(I) gel. Here, PG is considered not only to play the role of simple activator, but also to work as a binder reacting with GBFS.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2003.05a
• /
• pp.763-768
• /
• 2003

This study is to specify the properties of solidification/stabilization of heavy metals in connection with looking over the hydration features of non-sintering cement using industrial by-products. In this study, we added Cr and Pb to non-sintering cement(NSC), ordinary portland cement (OPC), and Blast-furnace slag cement(BSC) to specify the solidification process. Heavy metal leaching test was carried out to evaluate solidification degree of various cement. Follow result, marking no higher than 0.7% of un-solidified ratio of BSC was the most predominant result when we mixed the materials with Cr. 5.8% for NSCI and 6.2% for NSC2. On the contrary, in case of adding Pb, NSCl and NSC2 made better solidification results than those of OPC(below 0.2%) and BSC(below 0.05%), marking nearly 0%.

• Journal of the Korean Ceramic Society
• /
• v.41 no.10 s.269
• /
• pp.749-755
• /
• 2004

Fluosilicic acid ($H_2SiF_6$) is recovered as aqueous solution which absorbs $SiF_4$ produced from the manufacturing of industrial-graded $H_3PO_4$ or HF. Generally, fluosilicate salts prepared by the reaction between $H_2SiF_6$ and metal salts. Addition of fluosilicate salts to cement endows odd properties through unique chemical reaction with the fresh and hardened cement. In this study, two-component fluosilicate salt based chemical admixtures (MZ) of $4\%,\;6\%$, and $8\%$ concentration were prepared by the reaction of $H_2SiF_6$ ($25\pm2\%$) and metal salts. The effect of concentration of MZ at a constant adding ratio on the hydration and watertightness of cement were investigated respectively. In a cement containing MZ, metal fluorides such as $CaF_2$ and soluble silica by hydrolysis were newly formed during hydration. The total porosity of the hardened cement was lower in the presence of U because of packing role of metal fluoride and pozzolanic reaction of soluble $SiO_2$. Consequently, the watertightness of the hardened paste containing MZ was more improved than non-added (plain) due to an odd hydration between cement and MZ.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2002.10a
• /
• pp.655-660
• /
• 2002

Major deterioration in concrete structures are salt attack and carbonation. Especially severe problems due to carbonation occur in tile concrete structures of city, tunnel, underground structures. Cracks in concrete during service life including early age due to hydration heat and/or shrinkage accelerate the diffusion of concrete so that the deterioration is also accelerated. In this study, carbonation depths of both non-cracked concrete and cracked concrete are evaluated and weight change test and TGA are carried out. Through the tests, a relation between water-cement ratio and carbonation depth is derived and also carbonation increase rate is derived in the function of crack width.

• Proceedings of the Korean Society of Veterinary Clinics Conference
• /
• 2006.11a
• /
• pp.114-114
• /
• 2006

• Proceedings of the Korean Society For Composite Materials Conference
• /
• 2001.05a
• /
• pp.23-28
• /
• 2001

Since non-corrosive Fiber Reinforced Polymer(FRP) tendons have been in increasing use for underground and coastal structures constantly contacted with fresh water or sea water because of their superiority to metallic ones in corrosion-resistance, new non-metallic anchoring system for FRP tendons has been developed and investigated to verify the effectiveness of tendon force, which consist of mainly FRP pipes and Highly Expansive Mortar(HEM). The major factors considered in this experiment were expansive pressures of HEM during its hydration, sleeve lengths and types, and anchoring methods of tendon. New anchoring system were investigated from the pull-out tests. The pull-out procedures of the FRP tendons in the various pipe filled with HEM were analyzed and improved ideas were suggested to develop novel non-metallic anchoring system for FRP tendons The pull-out tests for the FRP tendon and new non-metallic anchoring system were conducted. The results show that non-metallic anchoring system for the FRP tendon has been more stablized due to the gradual expansive pressrure of HEM, as tims goes. Since tile lower stiffness of FRP pipes causes the weakness of anchoring force, it requires the increase of stiffness using a carbon fiber or an increased section area.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.9 no.1
• /
• pp.1-12
• /
• 2021

The present study proposes the modified-stoichiometric model for describing hydration of sodium silicate-based alkaliactivated slag(AAS), and compares the results with the thermodynamic modelling-based calculations. The proposed model is based on Chen and Brouwers(2007a) model with updated database as reported in recent studies. In addition, the calculated results for AAS are compared to those for hydrated portland cement. The maximum difference between the proposed model and the thermodynamic calculation for AAS was at most 20%, and the effects of water-to-binder ratio and activator dosages were identically described by both approaches. In particular, the amount of non-evaporable water was within 10% difference, and was in excellent agreement with the experimental results. Nevertheless, notable deviation was observed for the chemical shrinkage, which is largely dependent on the volume of hydrates and pores.

• Advances in concrete construction
• /
• v.9 no.3
• /
• pp.279-287
• /
• 2020

This paper focuses on the engineering properties of Bentonite-Cement-Sodium silicate (BCS) grout, which was prepared by partially replacing the ordinary Portland cement in Cement-Sodium silicate grout with lithium bentonite (Li-bent) and sodium bentonite (Na-bent), respectively. The effect of different Water-to-Solid ratio (W/S) and various replacement percentages of bentonite on the apparent viscosity, bleeding, setting time, and early compressive strength of BCS grout were investigated. The XRD method was used to detect its hydration products. The results showed that both bentonites played a positive role in the stability of BCS grout, increased its apparent viscosity. Na-bent prolonged the setting time of BCS, while 5% of Li-bent shortened the setting time of BCS. The XRD analysis indicated that the hydration products between the mixture containing Na-bent and Li-bent did not differ much. Using bentonite as supplementary cementitious material (SCM) to replace partial cement is a promising way to cut down on carbon dioxide emissions and to produce low-cost, eco-friendly, non-toxic, and water-resistant grout. In addition, Li-bent was superior to Na-bent in improving the strength and the thickening of BCS grouts.