• Bulletin of the Korean Chemical Society
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• 제21권5호
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• pp.483-486
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• 2000

A method is described for the fluorimetric determination of nickel, based on the formation of $Ni(II)-\alpha-(2-Benzimidazolyl)-\alpha'$, $\alpha''$ -(N-5-Nitro-2-Pyridylhydrazone)-toluene complex in the presence of a non-ionic surfactant. The complex has practically no fluorescence in the absence of surfactant, but the addition of Triton X-100 makes possible the fluorimetric determination of low concentrations of Ni(II) as it enhances the fluorescenceintensity of the complex by up to about 5-fold. This method is very sensitive and selectrive for the direct determination of nickel ion. The optimum conditions are a Triton X-100 concentration of 2.0 mL(5.0%, v/v) and pH $9.0\pm0.2(ammonium$ chloride-ammonia buffer). The fluorescence is measured at 337 nm of emission wavelength under 300 nm of excitation wavelength. The fluorescence intensity is a linear function of the concentration of Ni(II) in the range 5-70 ng/mL, and the detection limit is 2.0 nm/mL. The proposed method has been successfully applied to the determination of trace amounts of Ni(II) in food and human hair samples.

• 제어로봇시스템학회논문지
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• 제13권7호
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• pp.637-648
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• 2007

This paper presents a sensor fusion method based on indirect Kalman filter(IKF) for error compensation of low-cost inertial sensors and its application to the determination of attitude and position of small flying robots. First, the analysis of the measurement error characteristics to zero input is performed, focusing on the bias due to the temperature variation, to derive a simple nonlinear bias model of low-cost inertial sensors. Moreover, from the experimental results that the coefficients of this bias model possess non-deterministic (stochastic) uncertainties, the bias of low-cost inertial sensors is characterized as consisting of both deterministic and stochastic bias terms. Then, IKF is derived to improve long term stability dominated by the stochastic bias error, fusing low-cost inertial sensor measurements compensated by the deterministic bias model with non-inertial sensor measurement. In addition, in case of using intermittent non-inertial sensor measurements due to the unreliable data link, the upper and lower bounds of the state estimation error covariance matrix of discrete-time IKF are analyzed by solving stochastic algebraic Riccati equation and it is shown that they are dependant on the throughput of the data link and sampling period. To evaluate the performance of proposed method, experimental results of IKF for the attitude determination of a small flying robot are presented in comparison with that of extended Kaman filter which compensates only deterministic bias error model.

• 대한기계학회논문집A
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• 제22권2호
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• pp.268-277
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• 1998

The numerical procedure for calculating non-uniform residual stress fields by using relieved strain data from incremental hole drilling method is presented. Finite element calculations are described to evaluate the relieved coefficients required for the determination of residual stresses. From the results of simulations it is found that this numerical method is well adopted to measuring non-uniform residual stress in the hole depth range of 0.8 times of the hole diameter from the surface. In order to examine the practicability of this method, the hole drilling procedure for the four point bending test is performed. This method is applied to the measurement of residual stresses in the cold-rolled steel pipe. It is shown that the magnitude of residual stress in the pipe is not negligible when compared with yield stress and the residual stress should be duly considered in designing structures with this pipes.

• 대한산업공학회지
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• 제27권1호
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• pp.69-88
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• 2001

In the zigzag milling operation, an important issue is to design a machining strategy which minimizes the cutting time. An important variable for minimization of cutting time is the tool path length. The tool path is divided into cutting path and non-cutting path. Cutting path can be subdivided into tool path segment and step-over, and non-cutting path can be regarded as the tool retraction. We propose a new method to determine the cutting direction which minimizes the length of tool path in a convex or concave polygonal shape including islands. For the minimization of tool path length, we consider two factors such as step-over and tool retraction. Step-over is defined as the tool path length which is parallel to the boundary edges for machining area and the tool retraction is a non-cutting path for machining any remaining regions. In the determination of cutting direction, we propose a mathematical model and an algorithm which minimizes tool retraction length in complex shapes. With the proposed methods, we can generate a tool path for the minimization of cutting time in a convex or concave polygonal shapes including islands.

• Computers and Concrete
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• 제21권1호
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• pp.11-20
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• 2018

The possibilities of non-linear analysis of reinforced-concrete structures are under development. In particular, current research areas include structural analysis with the application of advanced computational and material models. The submitted article aims to evaluate the possibilities of the determination of material properties, involving the tensile strength of concrete, fracture energy and the modulus of elasticity. To evaluate the recommendations for concrete, volume computational models are employed on a comprehensive series of tests. The article particularly deals with the issue of the specific properties of fracture-plastic material models. This information is often unavailable. The determination of material properties is based on the recommendations of Model Code 1990, Model Code 2010 and specialized literature. For numerical modelling, the experiments with the so called "classic" concrete beams executed by Bresler and Scordelis were selected. It is also based on the series of experiments executed by Vecchio. The experiments involve a large number of reinforcement, cross-section and span variants, which subsequently enabled a wider verification and discussion of the usability of the non-linear analysis and constitutive concrete model selected.

• 한국측량학회지
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• 제6권1호
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• pp.13-24
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• 1988

원형 구조물의 표면에 대한 삼차원 위치 결정은 여러 면에서 그 응용이 기대된다. 구조물의 진단을 고려해 볼때 이것은 광범위한 범주에서 하나의 의미있는 Topic이 될 것이며, 이러한 위치 결정을 함에 있어 수렴사진의 활용은 종내의 측량에 비해 많은 이점을 가지고 있다. 본 논문은 Metric과 Non-metric Camera를 이용하여 원사형의 피사체를 수렴사진으로 촬영하고 Bundle-Adjustment에 의해 그 결과를 고찰한 것이다. Bundle-Adjustment에 의한 오차 해석으로부터 표준 오차를 비교함과 아울러 Metric과 Nonmetric Camera로부터 얻은 피사체의 삼차원 좌표도 비교하였다.

• Food Science and Biotechnology
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• 제18권1호
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• pp.60-65
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• 2009

Near infrared reflectance spectroscopy (NIRS) was used as a rapid and non-destructive method to determine the protein content in intact and ground seeds of pea (Pisum sativum L.) germplasms grown in Korea. A total of 115 samples were scanned in the reflectance mode of a scanning monochromator at intact seed and flour condition, and the reference values for the protein content was measured by auto-Kjeldahl system. In the developed ground and intact NIRS equations for analysis of protein, the most accurate equation were obtained at 2, 8, 6, 1 math treatment conditions with standard normal variate and detrend scatter correction method and entire spectrum (400-2,500 nm) by using modified partial least squares regression (n=78). External validation (n=34) of these NIRS equations showed significant correlation between reference values and NIRS estimated values based on the standard error of prediction (SEP), $R^2$, and the ratio of standard deviation of reference data to SEP. Therefore, these ground and intact NIRS equations can be applicable and reliable for determination of protein content in pea seeds, and non-destructive NIRS method could be used as a mass analysis technique for selection of high protein pea in breeding program and for quality control in food industry.

• 분석과학
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• 제34권2호
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• pp.78-86
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• 2021

The objective of this study was to investigate urinary cut-off concentrations of quetiapine and risperidone for distinction between normal and abnormal/non-takers who were being placed on probation. Liquid chromatography-tandem mass spectrometric (LC-MS/MS) method was employed for determination of antipsychotic drugs in urine from mentally disordered probationers. The optimal cut-off values of antipsychotic drugs were calculated using receiver operating characteristic (ROC) curve analysis. The sensitivity and specificity of the method for the detection of antipsychotic drugs in urine were subsequently evaluated. The area under the ROC curve (AUC) was 0.927 for norquetiapine and 0.791 for 9-hydroxyrisperidone, respectively. These antipsychotic drugs are classified readily in the ROC curve analysis. The cut-off values for distinguishing regular and irregular/non-takers were 39.1 ng/mL for norquetiapine and 67.9 ng/mL for 9-hydroxyrisperidone, respectively. The results of this study suggest the cut-off values of quetiapine and risperidone were highly useful to distinguish regular takers from irregular/non-takers.

• Geomechanics and Engineering
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• 제30권4호
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• pp.393-399
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• 2022

The Segregation Potential (SP) is one of the most widely used predictors of frost heave in cold regions. Laboratory step-freezing tests determining a representative SP at the onset of the formation of the last ice lens (near the thermal steady state condition) can predict susceptibility to frost heave. Previous work has proposed empirical semi-log fitting for determination of the representative SP and applied it to several fine-grained soils, but considering only frost-susceptible soils. The presence of fines in coarse-grained soil affects frost susceptibility. Therefore, it is required to evaluate the applicability of the empirical semi-log fitting for both frost-susceptible and non-frost-susceptible soils with fines content. This paper reports laboratory frost heave tests for fines contents of 5%-70%. The frost susceptibility of soil mixtures composed of sand and silt was classified by the representative SP, and the suitability of the empirical semi-log fitting method was assessed. Combining semi-log fitting with simple laboratory frost heave testing using a temperature-controllable cell is shown to be suitable for both frost-susceptible and non-frost-susceptible soils. In addition, initially non-frost-susceptible soil became frost susceptible at a 10%-20% weight fraction of fines. This threshold fines content matched well with transitions in the engineering characteristics of both the unfrozen and frozen soil mixtures.

• 분석과학
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• 제12권5호
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• pp.375-381
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• 1999

본 연구는 기존에 사용되고 있는 음주측정기의 부정확성과 비위생적인 면을 개선하기 위한 비침습적인 알코올 측정기를 개발하기 위해 근적외선분광분석법을 적용하였다. 먼저 근적외선분광분석법으로 혈중 알코올을 측정하기 위한 전 단계로 순수한 알코올을 0.01~0.1%의 농도로 함유한 검체를 측정하였다. MLR(multiple linear regression)방법을 통한 통계적 처리에서 1360, 2256, 2012, 그리고 1358 nm의 네 파장을 선택했을 때 SEC(standard error of calibration)은 0.0039, multiple R은 0.99를 나타냈다. 혈중 알코올 시료 측정시 MLR을 적용했을 때 2266과 2326 nm 파장을 선택했을 경우 가장 유의성 있는 결과를 나타냈다. 또 다른 통계적 방법인 PLSR(partial least squares regression)의 경우 이차 미분 스펙트럼의 1100~1340, 1500~1796, 그리고 2064~2300 nm의 범위에서 4개의 factor를 사용했을 때 0.030의 SEP값을 나타냈다. 이로서 근적외선분광분석법을 이용하여 혈액 중의 알코올을 신속하게 분석할 수 있는 가능성을 제시하였다.