• Title/Summary/Keyword: Non-crosslinked polyethylene

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A Study on Electric Properties and Accelerated Water Tree Degradation of Environmental-friendly Non-crosslinked Polyethylene (친환경 비가교 폴리에틸렌의 전기적 특성과 워터트리 가속열화에 관한 연구)

  • Lee, June-Ho;Kong, Tae-Sik;Kim, Seong-Jung;Kwon, Ki-Hyung;Lee, Jae-Soon;Gu, Gwang-Hoe;Cho, Kyu-Cheol
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.61 no.6
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    • pp.827-832
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    • 2012
  • The crosslinked polyethylene (XLPE) is the most widely used insulating material for power cable. Due to its thermosetting characteristics, the XLPE can not be recycled, while the needs for the environmental friendly and recyclable insulator is rapidly increasing. In this paper, some important and basic electrical properties of non-crosslinked polyethylene such as conduction current characteristics, water the tree characteristics, AC breakdown test were experimentally investigated. It was shown that some of the tested samples had better performances from the application point of view for replacing current XLPE.

Carboxymethyl cellulose/polyethylene glycol superabsorbent hydrogel cross-linked with citric acid

  • Lee, Deuk Yong;Chun, Cheolbyong;Son, Siwon;Kim, Yena
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.32 no.3
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    • pp.107-114
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    • 2022
  • Carboxymethyl cellulose/poly(ethylene glycol) (CMC/PEG) hydrogels crosslinked with citric acid (CA) are synthesized to evaluate the effect of CMC molecular weight (Mw), PEG and CA concentration on the optical property, swelling rate (SR), degradation rate (DR), and cytotoxicity and cell proliferation of hydrogels. For crosslinked CMC/PEG hydrogels, the FT-IR peak intensity associated with hydroxyl groups decreases due to PEG intercalation (esterification crosslinking) between CMC chains in a similar manner as the concentration of CA crosslinker increases. Crosslinked CMC (Mw = 90,000)/PEG hydrogels with 10 % CA dissolve regardless of PEG content. However, the SR of the CMC (Mw = 250,000)/PEG hydrogels decrease from 4923 % to 168 % with increasing PEG and CA concentrations from 0 to 20 % and from 0 to 25 %, respectively. As the Mw of CMC increases, the DR of the hydrogel is greatly improved. CMC (Mw = 250,000)/PEG10 hydrogels with 10 % CA exhibit the optimum properties of high absorbing capacity (3,200 %) with moderate DR (54 %), stiffness (1.39 ± 0.19 GPa), and cell viability (94.8 ± 1.3 %). CA-crosslinked CMC/PEG hydrogels are highly suitable for wound dressing or personal care applications due to their non-toxicity, good cell proliferation, SR, and mechanical properties.

Ion Permeation in Polyethylene and Ethylene-based Copolymers (폴리에틸렌과 에틸렌계 공중합체에서의 이온투과 현상)

  • 한재홍;박성국;이미경;서광석
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.05a
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    • pp.96-99
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    • 1995
  • Ion permeation in polyethylene and ethyene-based copolymers has been investigat-ed Ions permeate faster through non-crosslink-ed films than through crosslinked films. which can be attributed to the decreased chain flexibility and free volume by crosslinking reaction, In EVA/EAA and EVA/ionomer blends, diffusion coefficients of ion decrease with the increase of EAA and ionomer content This was attributed to the increas of acid group acting as ion trapping site in the blends

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A Study on AC Breakdown and Conduction Characteristics of Environmental-friendly Non-crosslinked Polyethylene (친환경 비가교 폴리에틸렌의 절연파괴와 전도특성에 관한 연구)

  • Kong, Tae-Sik;Kwon, Ki-Hyung;Kim, Seong-Jung;Cho, Kyu-Cheol;Lee, Jae-Soon;Ku, Kwang-Hoi;Lee, June-Ho
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.1426-1427
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    • 2011
  • 전기적, 기계적으로 우수한 성능을 지닌 절연재료인 폴리에틸렌은 장기간 운전 중 열화에 의해 절연성능이 저하되고 시간이 지나면서 케이블의 사고 원인을 제공하게 된다. 본 논문에서 전력용 케이블의 절연체로 널리 사용되고 있는 가교폴리에틸렌(XLPE)를 대신하여 최근 주목을 받고있는 친환경 특성을 부여하기 위한 비가교 폴리에틸렌 재료에 대한 기초적 물성(워터트리성장특성, AC 절연파괴특성, 전도전류 특성)을 실험적으로 비교분석하였다.

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