• Title/Summary/Keyword: Non-Newtonian

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Scaleup of Electrolytic Reactors in Pyroprocessing (Pyroprocessing 공정에 사용되는 전해반응장치의 규모 확대)

  • Yoo, Jae-Hyung;Kim, Jeong-Guk;Lee, Han-Soo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.7 no.4
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    • pp.237-242
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    • 2009
  • In the pyroprocessing of spent nuclear fuels, fuel materials are recovered by electrochemical reactions on the surface of electrodes as well as stirring the electrolyte in electrolytic cells such as electrorefiner, electroreducer and electrowinner. The system with this equipment should first be scaled-up in order to commercialize the pyroprocessing. So in this study, the scale-up for those electrolytic cells was studied to design a large-scale system which can be employed in a commercial process in the future. Basically the dimensions of both electrolytic cells and electrodes should be enlarged on the basis of the geometrical similarity. Then the criterion of constant power input per unit volume, characterizing the fluid behavior in the cells, was introduced in this study and a calculation process based on trial-and-error methode was derived, which makes it possible to seek a proper speed of agitation in the electrolytic cells. Consequently examples of scale-up for an arbitrary small scale system were shown when the criterion of constant power input per unit volume and another criterion of constant impeller tip speed were respectively applied.

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Effect of Reaction Time on the Rheological Properties of Dextran Formed Solution Produced by Crude Dextransucrase from Leuconostoc rnesenteroides Sikhae (Leuconostoc mesenteroides Sikhae의 Crude Dextransucrase 반응시간에 따른 Dextran 생성액의 유변성)

  • 박춘상;이철호
    • Microbiology and Biotechnology Letters
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    • v.20 no.3
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    • pp.316-323
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    • 1992
  • Studies on the changes in rheological properties, molecular weight distribution and dextran yield after being reacted in lO%(w/w) sucrose concentration were performed with crude dextransucrase produced from Leuconostoc mesenteroides isolated from Sikhae. The reaction rate of dextran formation was monitored by sugar analysis with HPLC and by the changes in apparent viscosity. According to the periodate oxidation test, the dextran produced in this experiment was estimated to have 89% $\alpha$-(1->6) main linkages and 11% $\alpha$-(1->) side linkages. The rheological properties of the dextran solution formed changed with reaction time, and it was related to the changes in molecular weight distribution of dextran as determined by GPC analysis. As the reaction proceeded, the rheological behavior changed from Newtonian to non-Newtonian, showing Binghampseudoplastic and thixothropic flow behavior. The apparent viscosity of dextran formed solution increased with increasing reaction time, reached a maximum value of 2680 cP ($\gamma$=$33.75s^{-1}$, $25^{\circ}C$) by enzyme reaction for 8 hours, and then decreased. The temperature dependency of dextran formed solutions was well expressed by the Arrhenius equation and the activation energy reached a maximum value of 1.69 kcal/mole by enzyme reaction for 8 hours.

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Dynamic Behavior Modelling of Augmented Objects with Haptic Interaction (햅틱 상호작용에 의한 증강 객체의 동적 움직임 모델링)

  • Lee, Seonho;Chun, Junchul
    • Journal of Internet Computing and Services
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    • v.15 no.1
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    • pp.171-178
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    • 2014
  • This paper presents dynamic modelling of a virtual object in augmented reality environments when external forces are applied to the object in real-time fashion. In order to simulate a natural behavior of the object we employ the theory of Newtonian physics to construct motion equation of the object according to the varying external forces applied to the AR object. In dynamic modelling process, the physical interaction is taken placed between the augmented object and the physical object such as a haptic input device and the external forces are transferred to the object. The intrinsic properties of the augmented object are either rigid or elastically deformable (non-rigid) model. In case of the rigid object, the dynamic motion of the object is simulated when the augmented object is collided with by the haptic stick by considering linear momentum or angular momentum. In the case of the non-rigid object, the physics-based simulation approach is adopted since the elastically deformable models respond in a natural way to the external or internal forces and constraints. Depending on the characteristics of force caused by a user through a haptic interface and model's intrinsic properties, the virtual elastic object in AR is deformed naturally. In the simulation, we exploit standard mass-spring damper differential equation so called Newton's second law of motion to model deformable objects. From the experiments, we can successfully visualize the behavior of a virtual objects in AR based on the theorem of physics when the haptic device interact with the rigid or non-rigid virtual object.

Changes in Rheological Properties of Culture Broth During the Biopolymer Production by Bacillus sp (Bacillus sp.에 의한 생물 고분자의 발효 중 배양액의 유변학적 특성 변화)

  • 이신영;이주하
    • KSBB Journal
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    • v.11 no.3
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    • pp.340-346
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    • 1996
  • Variations of rheological properties of culture broth during the production of biopolymer by an alkali tolerant Bacillus sp. were investigated. Correlations among the rheological characteristics of culture broth, cell growth and biopolymer production were examined. Rheology of the culture broth changed in the course of fermentation. The culture broth showed a non-Newtonian flow behavior, as the viscosity and pseudoplasticsity increased during the cultivation. The rheological parameters such as flow index, consistency index, yield stress and apparent viscosity during the cultivation were not influenced by the cell growth, but significantly related to the biopolymer synthesis. Changes in the rheological parameters of the broth were affected not only by the biopolymer concentration, but also by the progress of fermentation. Some rheological parameters showed maximum values just before the completion of biopolymer production and substrate consumption. Hence, it was shown that the rheological characteristics of the culture broth could be used as a good indicator for the detection of the progress or completion of fermentation.

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Damped Oscill ations of the (Hard)Contact Lenses Posterior to the Blink (순목 후 콘택트(하드)렌즈의 감쇄 진동)

  • Kim, Dae-Soo
    • Journal of Korean Ophthalmic Optics Society
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    • v.10 no.3
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    • pp.173-184
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    • 2005
  • A capillary action-induced tension develops in the tear layer between the contact lens and cornea, which leads to the restoring force due to difference in the layer thickness between either upper and lower or left and right side of the lens when it is displaced off the equilibrium position as a result of blinking. Suppose the lens was displaced a certain distance from the equilibrium position, lens starts to oscillate toward the equilibrium position with the decreasing amplitude due to the restoring force as well as the velocity dependent viscous damping force in the tear layer. A mathematical model which consists of the differential equations and their numerical solution was proposed to analyze the damped oscillations of lenses. The model predicts the time dependence of lenses after the blink varying the various parameters such as Be, diameters, masses and positions displaced from equilibrium. As the Be and mass of lens increases the rate of amplitude reduction decreases, which requires a more time for the lens to return to the equilibrium position. It seems that varying the lens' displacement and diameters affect the lens' motion very little.

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Numerical Analysis of Mold Deformation Including Plastic Melt Flow During Injection Molding (플라스틱 유동을 고려한 사출성형 충전공정 중 금형의 변형 해석)

  • Jung, Joon Tae;Lee, Bong-Kee
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.38 no.7
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    • pp.719-725
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    • 2014
  • In the present study, a numerical analysis of an injection molding process was conducted for predicting the mold deformation considering non-Newtonian flow, heat transfer, and structural behavior. The accurate prediction of mold deformation during the filling stage is important to successfully design and manufacture a precision injection mold. While the local mold deformation can be caused by various factors, a pressure induced by the polymer melt is considered to be one of the most significant ones. In this regard, the numerical simulation considering both the melt filling and the mold deformation was carried out. A mold core for a 2D axisymmetric center-gated disk was used for the demonstration of the present study. The flow behavior inside the mold cavity and temperature distribution were analyzed along with the core displacement. Also, a Taguchi method was employed to investigate the influence of the relevant parameters including flow velocity, mold core temperature, and melt temperature.

Production and Rheological Properties of Bioflocculant Produced by Bacillus sp. DP-152

  • SUH, HYUN-HYO;SEONG-HOON MOON;HEE-SIK KIM;HYOUNG-KAB KIM;GEE-ILL JUN;HYUN-GEOUN PARK;DAE-OOK KANG;HEE-MOCK OH;BYUNG-DAE YOON
    • Journal of Microbiology and Biotechnology
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    • v.8 no.6
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    • pp.618-624
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    • 1998
  • The culture conditions for Bacillus sp. DP-152 in the flask were investigated for the production of polysaccharide locculant, DP-152. The optimum pH and temperature for the locculant production were 8.0 and $30^{\circ}C$, respectively. The avorable substrates for flocculant production were soluble tarch and ammonium nitrate. The medium composition was optimized as follows: 30 g soluble starch, 0.75 g $NH_4NO_3,\; 2.0g\; K_2\;HPO_4,\; 0.1\; g KH_2PO_4,\; 0.2g\; MgSO_4.\; 7H_2O,\; and\; 0.2g\; MnSO_4~5H_2O$ in 11 of distilled water. Under this optimized condition, flocculating activity has been improved 4-fold compared with that of the basal medium. In the culture flask, the highest flocculating activity was obtained after 70 h of cultivation and the amount of bioflocculant DP-152 yielded was 12.4 g/$\ell$. The solution of bioflocculant DP-152 showed non-Newtonian characteristics. Bioflocculant DP-152 exhibited apparently higher viscosity at all concentrations compared to that of zooglan (from Zoogloea ramigera), and it was stable over a wide range of temperatures and pHs.

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Visualization and Image Processing for Measurement of Propagational Velocity of Shear Front (유동장의 이동속도측정을 위한 가시화 및 영상처리 방안)

  • Kim Jae-Won;Han Sang-Hoon;Ahn Eun-Young
    • Journal of Korea Multimedia Society
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    • v.8 no.10
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    • pp.1322-1328
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    • 2005
  • The circulation flows passing through the Ekman boundary layer on the rotating disk and transfer the angular momentum into the interior region of the container. Consequently, the circulation enhances the momentum transfer and the interior fluid is divided by a propagating shear front. This investigation focuses on computer vision and image processing technique for analysis of Non-Newtonian Fluids. To visualize marching velocity shear front for the transient flow, a particular shaped particles and light are used. To validate the proposed method, quantitative image are compared with the optical data acquired by a direct measurement of LDV (Laser Doppler Velocimetry).

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Stabilization of Chlorosulfonated Polyethylene (CSM) Rubber Emulsion with Surfactant Mixture (혼합 계면활성제를 이용한 Chlorosulfonated Polyethylene (CSM) Rubber의 유화안정성 연구)

  • Lee, Eun-Kyoung;Choi, Seo-Young;Park, Soo-Jin
    • Elastomers and Composites
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    • v.36 no.4
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    • pp.246-254
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    • 2001
  • In this work, the stabilization of chlorosulfonated polyethylene (CSM) rubber emulsion with surfactants, i.e., nonionic (Span 60) or anionic (Sodium laurylsulfate, SLS) surfactants, was investigated. The phase inversion emulsification by interfacial chemical characteristics was used to emulsify the CSM rubber. As a result, the emulsion phase separation was observed in the case of any single surfactant. However, there was no phase separation in the mixture of Span 60 and SLS in the context of emulsion droplet size tests and rheological behaviors. The droplet size decreases by increasing the surfactant mixture, resulting in increasing the viscosity. The viscosity and shear stress determined from shear rate show a shear thinning and yield behaviors. It was then found that the emulsion stabilization can be improved using the phase inversion emulsification method and surfactant mixture.

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Spray Characteristics of Water-Gel Propellant by Impinging Injector (Water-Gel 모사 추진제의 충돌 분무 특성 연구)

  • Hwang, Tae-Jin;Lee, In-Chul;Kim, Sang-Sun;Koo, Ja-Ye
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.11a
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    • pp.11-14
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    • 2009
  • The implementation of gelled propellants systems offers high performance, thrust-control, energy management of propulsion, storability, and high density impulse of solid propulsion. Present study focused on the spray behavior of liquid sheets formed by impinging jets of non-Newtonian liquids which are mixed by Carbopol 941 0.5%wt. The results are then compared with experiments conducted on spray images formed by impinging jets concerning with air-blast effect at center orifice. When gel propellants are injected by doublet impinging jets at low pressure, closed rim pattern shape appeared. As increasing air mass flow rate(decreasing GLR), spray breakup and atomization phenomenon better improved and spray structure instabilities for the effect of air-blast are also increased.

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