• Title/Summary/Keyword: Non-Newtonian

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Dynamic Characteristic of Magnetic Fluids in a Circular Pipe (원관내 자성유체의 동적특성)

  • 유신오;박정우;최병호;서이수
    • Journal of the Korean Magnetics Society
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    • v.10 no.1
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    • pp.42-47
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    • 2000
  • In the present work, we analyze theoretically the flow of magnetic fluids in a circular pipe with longitudinal magnetic field. We used governing equations induced Shliomis and Polar theory of Eringen. Using theoretical equations and distributions for the velocity, vorticity and angular velocity as the magnetic response, it is shown that magnetic fluid flow is non-Newtonian fluid. We investigate dynamic characteristic of magnetic fluid by comparing longitudinal magnetic field with transverse magnetic field. And, the limits, influence magnetic fluid, of the intensity of the magnetic field with polar, size and magnetic effect parameters are shown.

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Functional and Rheological Properties of ${\gamma}$-Polyglutamic Acid Produced by Alkalophilic Alcaligenes sp. (호 알카리성 Alcaligenes sp.가 생산하는 ${\gamma}$-Polyglutamic Acid의 기능성 및 리올로지 특성)

  • 이신영;강태수
    • KSBB Journal
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    • v.10 no.5
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    • pp.547-552
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    • 1995
  • Some functional and rheological properties of the ${\gamma}$-polyglutamic acid(${\gamma}$-PGA) produced from alkalophilic Alcaligenes sp. were investigated. Viscosity synergism with thickening agents, capacities for gelling, entrapig of heavy metals, and flocculability of ${\gamma}$-PGA were not observed, but the relatively good compatability with various polyvalent metallic ins, excellent absorption ability and spinability were observed. The ${\gamma}$-PGA solution showed non-Newtonian flow behavior and exhibited pseudoplastic property with a yield stress at above 1% concentration. The values of flow index for 1% solution were in the range of 0.41∼0.75 showing shear rate dependency and the value of yield stress was 2.28 Pa. The value of consistency index was 0.868 Pa$.$Sn and was exponentially dependent on concentration.

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CAE Analysis of Powder Injection Molding Process for Dental Scaler Mold (치과용 스케일러 금형의 분말사출성형 CAE 해석설계)

  • Ko Y. B.;Park H. P.;Chung S. T.;Rhee B. O.;Hwang C. J.
    • Transactions of Materials Processing
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    • v.14 no.6 s.78
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    • pp.570-576
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    • 2005
  • Powder Injection Molding(PIM) has recently been recognized as an advanced manufacturing technology for low-cost mass production of metal or ceramic parts of complicated geometry With this regards, design technology of dental scaler tip PIM mold, which has complex shape and small core pin (diameter=0.6mm), with the help of computer-aided analysis of powder injection molding process was developed. Computer-aided analysis for dental scaler tip mold was implemented by finite element method with non-Newtonian fluid, modified Cross model viscosity, PvT data of powder/binder mixture. Compter-aided analysis results, such as filling pattern, weldline formation, air vent position prediction were compared with experimental result, and eventually have been shown good agreement. The core pin (diameter=0.6mm) deflection analysis of dental scaler tip PIM mold during PIM filling process was also investigated before mold fabrication.

The Rheological and Mechanical Model for Relaxation Spectra of Polydisperse Polymers

  • Kim, Nam Jeong;Kim, Eung Ryul;Hahn Sang Joon
    • Bulletin of the Korean Chemical Society
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    • v.13 no.4
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    • pp.413-419
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    • 1992
  • The theoretical equation for the relaxation spectrum of nonlinear viscoelastic polymeric material was derived from the Ree-Eyring and Maxwell non-Newtonian model. This model consists of infinite number of hyperbolic sine law Maxwell elements coupled in parallel plus a spring without a dashpot. Infinite number of nonlinear viscoelastic Maxwell elements can be used by specifying distribution of relaxation times, hole volumes, molecular weights, crystallite size and conformational size, etc. The experimentals of stress relaxation were carried out using the tensile tester with the solvent chamber. The relaxation spectra of nylon 6 filament fibers in various electrolytic solutions were obtained by applying the experimental stress relaxation curves to the theoretical equation of relaxation spectrum. The determination of relaxation spectra was performed from computer calculation.

Solvent Effect on Stress Relaxation of PET Filament Fibers and Self Diffusion of Crystallites

  • Nam Jeong Kim;Eung Ryul Kim;Sang Joon Hahn
    • Bulletin of the Korean Chemical Society
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    • v.12 no.5
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    • pp.468-473
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    • 1991
  • Viscoelastic properties of PET filament fibers on stress relaxation were investigated in the solvents of $H_2$O, 0.05% NaOH and 50% DMF using an Instron (UTM4-100 Tensilon) with solvent chamber. The theoretical stress relaxation equation derived by applying the Ree-Eyring's hyperbolic sine law to dashpot of three element non-Newtonian model was applied to the experimental stress relaxation curves, and the model parameters $G_1,G_2$, ${\alpha}$ and ${\beta}$ were obtained. By analyzing temperature dependency of the relaxation time, the values of activation entropy, activation enthalpy and activation free energy for flow in PET filament fiber were evaluated, the activation free energy being about 25.7 kcal/mol. The self diffusion coefficient and hole distance were obtained from parameters ${\alpha}$, ${\beta}$ and crystallite size in order to study the self diffusion and the orientation of crystallites in amorphous region and the effect of solvent.

Rheological Modeling of Nanoparticles in a Suspension with Shear Flow (전단 흐름을 갖는 서스펜션 내부 나노 입자의 유변학적 특성 연구)

  • Kim, Gu;Fukai, Jun;Hironaka, Shuji
    • Applied Chemistry for Engineering
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    • v.30 no.4
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    • pp.445-452
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    • 2019
  • Shear thickening is an intriguing phenomenon in the fields of chemical engineering and rheology because it originates from complex situations with experimental and numerical measurements. This paper presents results from the numerical modeling of the particle-fluid dynamics of a two-dimensional mixture of colloidal particles immersed in a fluid. Our results reveal the characteristic particle behavior with an application of a shear force to the upper part of the fluid domain. By combining the lattice Boltzmann and discrete element methods with the calculation of the lubrication forces when particles approach or recede from each other, this study aims to reveal the behavior of the suspension, specifically shear thickening. The results show that the calculated suspension viscosity is in good agreement with the experimental results. Results describing the particle deviation, diffusivity, concentration, and contact numbers are also demonstrated.

The Effects of Packing and Cooling Stages on the Molded Parts in Injection Molding Process (사출 성형시 보압 및 냉각 과정이 성형품에 미치는 영향)

  • 구본흥;신효철;이호상
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.17 no.5
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    • pp.1150-1160
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    • 1993
  • The behavior of polystyrene in the strip cavity during the packing and cooling stages for an injection molding process is examined numerically. The mathematical model is based on the unified post-filling model and finite element/finite difference methods are used to solve simultaneously the continuity, momentum and energy equations coupled to an equation of state. Simulated results show that the density of the molded parts is lower in the core than at the skin, and that the hotter the melt or the higher the packing pressure, the higher the density in the core. The density variation during the packing stage comes up to 50% compared with the total density variation. Also, the density variation after gate sealing and the effect of cooling rate on the equation of state are negligible.

Numerical Study of Internal Flow in Twin Screw Extruder and Its Mixing Performance Analysis (이축 스크루 압출기내 유동의 수치 해석과 혼합 성능 분석)

  • Kim, Nak-Soo;Kim, Hong-Bum;Lee, Jae-Wook
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.30 no.1 s.244
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    • pp.32-41
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    • 2006
  • We analyzed the non-Newtonian and non-isothermal flow in the melt conveying zone in co-rotating and counter-rotating screw extruder system with the commercial code, STAR-CD, and compared the mixing performance with respect to screw speed and rotating direction. The viscosity of fluid was described by power-law model. The dynamics of mixing was studied numerically by tracking the motion of particles in a twin screw extruder system. The extent of mixing was characterized in terms of the residence time distribution and average strain. The results showed that high screw speed decreases the residence time but increases the shear rate. Therefore higher screw speed increases the strain and has better mixing performance. Counter-rotating screw extruder system and co-rotating screw extruder has the similar shear rate with the same screw speed in spite of different rotating direction. However, the counter-rotating screw has good mixing performance, which is resulted from longer residence time than that of co-rotating screw extruder.

Physico-Chemical and Rheological Properties of a Bioflocculant BF-56 from Bacillus sp. A56

  • Suh, Hyun-Hyo;Moon, Seong-Hoon;Seo, Weon-Taek;Kim, Kyung-Kab;Jeon, Gee-Ill;Park, Hyun-Geoun;Park, Yong-Il
    • Journal of Microbiology and Biotechnology
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    • v.12 no.2
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    • pp.209-216
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    • 2002
  • Bacillus sp. A56 was studied, because of its high flocculating activity. The flocculating substance produced by this strain was purified by ethanol precipitation, cetylpyridinium chloride (CPC) precipitation, and gel permeation chromatography (GPC). The FT-IR spectrum of the purified bioflocculant, designated as BF-56, showed typical characteristics of polysaccharides. The non-sugar substituents, and sugar components of BF-56 containing glucose, fucose, glucuronic acid, and galactose in an approximate molar ratio of 2.76:1.10:1:0.12, suggested that it was a novel bioflocculant with an estimated molecular mass of over $7{\times}10^3$ kDa. Rheological analysis of BF-56 revealed that it was a pseudoplastic that had higher apparent viscosity rate at dilute concentrations than those of zooglan. The solution of bioflocculant BF-56 exhibited non-Newtonian characteristics and it was compatible to high concentrations of salts such as KCl, NaCl, $CaCl_2,\;or\;FeCl_3.$ The present results suggested strong possibility of bioflocculant BF-56 to be fully applicable to industries such as wastewater treatment.

Numerical analysis of internal flow and mixing performance in polymer extruder II: twin screw element

  • Kim, Nak-Soo;Kim, Hong-Bum;Lee, Jae-Wook
    • Korea-Australia Rheology Journal
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    • v.18 no.3
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    • pp.153-160
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    • 2006
  • We analyzed the non-Newtonian and non-isothermal flow with Carreau-Yasuda viscosity model in co-rotating and counter-rotating twin screw extruder systems. The mixing performances with respect to the screw speed, the screw pitch, and the rotating direction have been investigated. The dynamics of mixing was studied numerically by tracking the motions of particles. The extent of mixing was characterized in terms of the deformation rate, the residence time distribution, and the average strain. The results showed that the high screw speed decreases the residence time but increases the deformation rate. Small screw pitch increases the residence time. It is concluded that the high screw speed increases the dispersive mixing performance, while the small screw pitch increases the distributive mixing performance. Co-rotating screw extruder has the better conveying performance and the distributive mixing performance than counter-rotating screw extruder with the same screw speed and pitch. Co-rotating screw extruder developed faster transport velocity and it is advantageous the flow characteristics to the mixing that transfers polymer melt from one barrel to the other barrel.