• Title/Summary/Keyword: Non-Formation

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Photoluminescence Characteristics of p-Phenylene Vinylene and Its Derivatives in Solution and in Nanoaggregates

  • Eom, Intae;Lim, Seon Jeong;Park, Soo Young;Joo, Taiha
    • Rapid Communication in Photoscience
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    • v.4 no.3
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    • pp.70-72
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    • 2015
  • Oligomers of p-phenylene vinylene and its derivatives have drawn much attention due to their unusual emission characteristics of showing increased emission when they form into nanoparticles. We have investigated the optical properties of the oligo-(p-phenylene vinylene) and its cyano-substituted derivatives in solution and in nanoaggregate media by femtosecond and picosecond time resolved fluorescence as well as stationary spectroscopies. All the spectroscopic data are consistent with the conclusion that the cyano substitution on the ${\beta}$-position of oligo-(p-phenylene vinylene) leads to breakage of the otherwise planar structure of cyano-unsubstituted molecules, which opens up an extremely efficient, as fast as 100 fs, non-radiative relaxation channel of the excited state. Formation of the nanoaggregates reverts the effect to make the molecules planar and to block the non-radiative relaxation channel. Therefore, concerning the applications in organic electroluminescent devices and organic light emitting diodes, substitution by the cyano group is not advantageous, although such modification should be useful in respect of controlling fluorescence intensity in different media.

Effect of Strarting Structures and Intercritical Annealing on Low Temperatures Mechanical Properties of a HSLA Steel (초기조직 및 이상역열처리가 저합금 고강도강의 저온기계적 성질에 미치는 영향)

  • Cho, H.K.;Park, K.G.;Shin, D.H.;Maeng, S.C.
    • Journal of the Korean Society for Heat Treatment
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    • v.7 no.1
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    • pp.53-60
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    • 1994
  • Austenite formation and Low temperatures mechanical properties of HSLA steel of different starting structures have been studied by intercritical annealing(IA). The different starting structures are: ferrite+pearlite(FP1), martensite(M1), cold worked ferrite+pearlite(FP2) and cold worked martensite(M2). In most cases tensile strength and elongation was increased by decreasing the testing temperatures regardless of the IA time. Tensile strength of the cold worked starting structures was higher than that of the non-cold worked starting structures. However not any noticeable difference in elongation was found between two cases. Low temperatures impact properties were affected by the starting structures. Charpy V-notch impact transition temperatures of the M-starting structures were around $-40^{\circ}C$, and those of the FP starting structures were around $-10^{\circ}C$. Impact energy was lower in the cold worked specimens than in the non-cold worked specimens at the same starting structures. DP structure obtained from the M-starting structure has shown superior low temperatures mechanical properties than the DP structure obtained from the FP-starting structure.

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Role of Symbol and Formation of Intuition by the Mediation of Symbols in Geometric Proof (기하 증명에서 기호의 역할과 기호 중재에 의한 직관의 형성)

  • Kim, Hee;Kim, Sun-Hee
    • Journal of Educational Research in Mathematics
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    • v.20 no.4
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    • pp.511-528
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    • 2010
  • Students' intuition in formal proof should be expressed as symbols according to the deductive process. The symbol will play a role of the mediation between the intuition and the formal proof. This study examined the evolution process of intuition mediated by the symbol in geometry proof. According to the results first, symbol took the great roles when students had the non-formed intuition for the proposition. The signification of symbols could explain even the proof process of the proposition with the non-expectable intuition. And when students proved it by symbols, not by figure nor words, they could evolute the conclusive intuition about the proposition.

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Effects of Placing Micro-Implants of Melatonin in Striatum on Oxidiative Stress and Neuronal Damage Mediated by N-Methyl-D-Aspartate (NMDA) and Non-NMDA Receptors

  • Kim, Hwa-Jung;Kwon, Jin-Suk
    • Archives of Pharmacal Research
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    • v.22 no.1
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    • pp.35-43
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    • 1999
  • Overstimulation of both kainate (KA) and N-methyl-D-aspartate (NMDA) receptors has been reported to induce excitatoxicity which can be characterized by neuronal damage and formation of reactive oxygen free radicals. Neuroprotective effect of melatonin against KA-induced excitotoxicity have been documented in vitro and in vivo. It is, however, not clear whether melationin is also neuroportective against excitotoxicity mediated by NMDA receptors. In the present work, we tested the in vivo protective effects of striatally infused melatonin against the oxidative stress and neuronal damage induced by the injection of KA and NMDA receptors into the rat striatum. Melatonin implants consisting of 22-gauge stainless-steel cannule with melatonin fused inside the tip were placed bilaterally in the rat brain one week prior to intrastriatal injection of glutamate receptor subtype agonists. Melatonin showed protective effects against the elevation of lipid peroxidation induced by either KA or NMDA and recovered Cu, Zn-superoxide dismutase activities reduced by both KA and NMDA into the control level. Melatonin also clearly blocked both KA- and NMDA-receptor mediated neuronal damage assessed by the determination of choline acetyltransferase activity in striatal monogenages and by microscopic observation of rat brain section stained with cresyl violet. The protective effects of melatonin are comparable to those of DNQX and MK801 which are the KA- and NMDA-receptor antagonist, respectively. It is suggested that melatonin could protect against striatal oxidative damages mediated by glutamate receptors, both non-NMDA and NMDA receptors.

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Updates on the Diagnosis of Helicobacter pylori Infection in Children: What Are the Differences between Adults and Children?

  • Yang, Hye Ran
    • Pediatric Gastroenterology, Hepatology & Nutrition
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    • v.19 no.2
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    • pp.96-103
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    • 2016
  • Helicobacter pylori infection is acquired mainly during childhood and causes various diseases such as gastritis, peptic ulcer disease, mucosa-associated lymphoid tissue (MALT) lymphoma, and iron deficiency anemia. Although H. pylori infection in children differs from adults in many ways, this is often overlooked in clinical practice. Unlike adults, nodular gastritis may be a pathognomonic endoscopic finding of childhood H. pylori infection. Histopathological findings of gastric tissues are also different in children due to predominance of lymphocytes and plasma cells and the formation of gastric MALT. Although endoscopy is recommended for the initial diagnosis of H. pylori infection, several non-invasive diagnostic tests such as the urea breath test (UBT) and the H. pylori stool antigen test (HpSA) are available and well validated even in children. According to recent data, both the $^{13}C$-UBT and HpSA using enzyme-linked immunosorbent assay are reliable non-invasive tests to determine H. pylori status after eradication therapy, although children younger than 6 years are known to have high false positives. When invasive or noninvasive tests are applied to children to detect H. pylori infection, it should be noted that there are differences between children and adults in diagnosing H. pylori infection.

An Effects of $CO_2$ Addition on Flame Structure in a Non-premixed Counterflow Flame (비예혼합 대향류 화염에서 $CO_2$ 첨가가 화염 구조에 미치는 영향 연구)

  • Lee, Kee-Man
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.3
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    • pp.166-173
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    • 2007
  • A numerical study was conducted to have the effect of $CO_2$ addition to fuel on the chemical reaction mechanism with the change of the initial concentration of $CO_2$ and the axial velocity gradient. From this study, it was found that there were two serious effects of $CO_2$ addition on a non-premixed flame ; a diluent effect by the reactive species reduction and chemical effect of the breakdown of $CO_2$ by the third-body collision and thermal dissociation. Especially, the chemical effect was serious at the lower velocity gradient of the axial flow. It was certain that the mole fraction profile of $CO_2$ was deflected and CO was increased with the initial concentration of $CO_2$. It was also ascertained that the breakdown of $CO_2$ would cause the increasing of CO mole fraction at the reaction region. It was also found that the addition of $CO_2$ did not alter the basic skeleton of $H_2-O_2$ reaction mechanism, but contributed to the formation and destruction of hydrocarbon products such as HCO. The conversion of CO was also suppressed and $CO_2$ played a role of a dilution in the reaction zone at the higher axial velocity gradient.

The effect of permanent magnet in MAP of magnesium alloy for external case of notebook compute (노트북 케이스용 마그네슘의 자기연마가공에서 영구자석의 효과)

  • Kim, Sang-Oh;Gang, Dea-Min;Kwak, Jae-Seob;Jung, Young-Deug
    • 한국금형공학회:학술대회논문집
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    • 2008.06a
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    • pp.45-50
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    • 2008
  • In previous study, it showed that the MAP was greatly effective polishing process for magnesium plate. But it had lower efficiency than magnetic materials such as SM45C. It was very difficult to cut non-magnetic materials using the MAP process because the process was fundamentally possible by help of a magnetic force. This study aimed to verify analytically formation of the magnetic field in a case of the non-magnetic materials especially focused on magnesium plate. So, In this study, the magnetic density flux was predicted using simulation program. As a result, the magnetic density flux was lower at the center of pole on inductor than outside. It had same result on the experimental verification. And magnetic force was lower according to increase of working gap. So, to improve the magnetic force, permanent magnet was installed under the workpiece. In that case, the magnetic density flux not only at center but also at outside of pole was increased. Therefore, the efficiency of magnetic abrasive polishing was also increased. A design of experimental method was adopted for assessment of parameters' effect on the MAP results of magnesium plate for improving the magnetic force.

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Effect of Aerva lanata against oxalate mediated free radical toxicity in urolithiasis

  • Begum, Vava Mohaideen Hazeena;Mahesh, Ramalingam;Ramesh, Thiyagarajan;Soundararajan, Periasamy
    • Advances in Traditional Medicine
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    • v.8 no.1
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    • pp.59-66
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    • 2008
  • This study was undertaken to evaluate the antioxidant potential of A. lanata on oxalate mediated free radical toxicity in ethylene glycol induced calcium oxalate urolithic rats. Calcium oxalate (CaOX) stone was induced by 0.75% ethylene glycol in drinking water for 28 days. From $29^{th}$ day onwards, the CaOX urolithic rats were treated with A. lanata aqueous suspension (2,000 mg/kg body weight/dose/day) orally for another 28 days. At the end of experimental periods the animals were sacrificed, samples were collected and analyzed the lipid peroxidation product, protein oxidation product, enzymatic and non-enzymatic antioxidants in normal and experimental groups. Lipid peroxidation and protein oxidation products were significantly elevated while enzymatic and non-enzymatic antioxidant levels were significantly decreased in ethylene glycol induced CaOX urolithic rats when compared with control rats. The above alterations were reverted to near control in rats treated with aqueous suspension of A. lanata. This study suggests that A. lanata could prevent the free radical formation from calcium oxalate urolithiasis in rats and protecting the renal cells from oxidative injury.

Study of Soot Formation in Fuel Rich Combustion (농후 연소 추진제의 Soot 생성 특성에 관한 연구)

  • Yu, Jung-Min;Lee, Chang-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2007.04a
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    • pp.143-147
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    • 2007
  • Kerosene and diesel are compounded fuels with various types of hydrocarbon elements and difficult to model the chemical kinetics. This study focuses on the prediction of the non-equilibrium reaction of fuel-rich combustion with detailed kinetics developed by Dagaut using PSR(perfectly stirred reactor) assumption. In Dagaut's surrogate model for kerosene and diesel, chemical kinetics consists of 2352 reaction steps with 298 chemical species. Also, Frenklach's soot model was implemented along with detailed kinetics to calculate the gas properties of fuel rich combustion efflux.

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Development of Basta Resistant Tobacco Using Artificial Phosphinothricin Acetyltransferase Gene (인공합성 Phosphinothricin Acetyltransferase 유전자에 의한 Basta 내성 연초식물체의 개발)

  • 양덕춘
    • Korean Journal of Plant Resources
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    • v.11 no.2
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    • pp.188-194
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    • 1998
  • This experiment was conducted to introduce phosphinothricin acetyl -transferase(PAT) gene, resistant to basta and non-selective herbidide, into tobacco(Nicotiana tabacum cv.BY4). For shoot formation,tobacco leaf disks were placed on the MS medium supplemented with 2.0mg/L BA and 0.1mg/L NAA. In this medium condition, tobacco leaf disces were cocultivated with A. tumefaciens MP90 containing NPT IIand PAT resistant to kanamycin and Basta, respectively. Shoots were obtained in the medium containing antibiotics, and those were transferred to rooting medium supplemented with 0.1mg/L NAA and antibiotics. The plants obtaining roots were transplanted into soil. Phenotype of transgenic tobacco plant was mostly as normal plant. However, about 5% was abnormal plant, which did not set seeds. PCR analysis and southern blot were performed to determine transformation. As the results, it was confirmed that PAT gene was stably integrated into tobacco genome.When herbicide, basta, was sprayed to the plants confirmed by PCR, the transgenic plants showed normal growth, whereas normal plants died. Therefore, the result of this experiment show that tobacco transformation for the resistance to basta, non-selective herbicide, was successful because PAT gene was stably integrated into tobacco.

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