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Study on Atmospheric Corrosion for Two Different Marine Environments in India

  • Saha, Jayanta Kumar
    • Corrosion Science and Technology
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    • v.6 no.3
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    • pp.120-127
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    • 2007
  • In any developing nation major investment goes for infrastructure and it is not exception in India. Good numbers of buildings, bridges, shopping malls, car parks etc. are coming up with steel for sustainable development. Thus protecting the structures from corrosion are the challenges faced by professionals for all types of steel structures. About 3% of GDP is accounted for loss due to corrosion. To combat this up to date corrosion map is called for as the country has wide variation of climatic zones with vastcoastline. Logically organic paint system can be prescribed based on the corrosion rate on bare steel with respect to environment. Present paper will emphasis on the study conducted on two types of structural steel coated with organic paint located in twomarine environment having been exposed for three years, Test coupons made from steels both bare and coated are deployed at two field stations having marine (Digha) and industrial marine (Channai) environments. Various tests like AC impedance DC corrosion, polarisation, salt spray test, $SO_2$ chamber and Raman spectroscopy were carried out both in laboratory on fresh as well as coupons collected from exposure sites. Rust formed on the bare and scribed coated coupons are investigated. It is found that normal marine environment at Digha exhibits higher corrosion rate than polluted marine environment in Channai. Rust analysis indicates formation of ${\propto}$-FeoOH protects or reduces corrosion rate at Channai and formation of non-protective ${\gamma}$-FeoOH increases corrosion rate at Digha. The slower corrosion rate in Channai than at Digha is attributed due to availability of $SO_2$, in the environment, which converts non‐protective rust ${\gamma}$-FeoOH to protective rust ${\propto}$-FeoOH. While comparing the damage on the coated panels it is found that low alloy structural steel provides less damage than plain carbon steel. From the experimentations a suitable paint system specification is drawn for identical environments for low medium and high durability.

A Kinetic Study for Exopolysaccharide Production in Submerged Mycelial Culture of an Entomopathogenic Fungus Paecilomyces tenuipes C240 (동충하초 Paecilomyces tenuipes C240의 균사체 배양에 의한 세포외 다당체 생산의 동력학적 연구)

  • Xu Chung Ping;Yun Jong Won
    • Journal of Life Science
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    • v.15 no.1 s.68
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    • pp.15-20
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    • 2005
  • The unstructured model was tested to describe mycelial growth, exopolysaccharide formation, and substrate consumption in submerged mycelial culture of Paeeiliomyees tenuipes C240. The Logistic equation for mycelial growth, the Luedeking-Piret equation for exopolysaccharide formation, and Luedeking­Piret-like equations for glucose consumptions were successfully incorporated into the model. The value of the key kinetic constants were: maximum specific growth rate ${\mu}m,\;0.7281\;h^{-1};$ growth­associated constant for exopolysaccharide production $(\alpha),\;0.1743g(g\;cells)^{-1}$; non-growth associated constant for exopolysaccharide production $(\beta),\;0.0019g(g\;cells)^{-1}\;;$ maintenance coefficient $(m_s),\;0.0572g\;(g\;cells)^{-1}$. When compared with batch experimental data, the model successfully provided a reasonable description for each parameter during the entire growth phase. The model showed that the production of exopolysaccharide in P. tenuipes C240 was growth-associated. The model tested in the present study can be applied to the design, scale-up, and control of fermentation process for other kinds of basidiomycetes or ascomycetes.

Preparation of Non-flammable Wiper Paper by Simple H3PO3 Treatment (아인산 처리에 의한 불연성 와이퍼 용지의 제조)

  • Lee, Hong Chan;Lee, Shichoon
    • Journal of Convergence for Information Technology
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    • v.10 no.6
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    • pp.77-86
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    • 2020
  • A thin and porous non-flammable wiper was prepared by phosphorus acid solution treatment and subsequent oven annealing. The H3PO3 treatment improved flame retardancy of wiper paper to nonflammable level. Thermogravimetric analyses showed that residues increased to 50% at 700℃, which means this treatment helps dehydration of the cellulose chain and promotes the formation of char-like structures during the burning. FT-IR and X-ray photoelectron spectroscopy showed that some of the added H3PO3 could react with the functional groups of the cellulose chain. The reacted H3PO3 components promote dehydration of the cellulose components and the formation of a char-like structure and improve the flame retardancy of the wiper paper.

W Chemical Mechanical Polishing (CMP) Characteristics by oxidizer addition (산화제 첨가에 따른 W-CMP 특성)

  • Park, Chang-Jun;Seo, Yong-Jin;Lee, Kyoung-Jin;Jeong, So-Young;Kim, Chul-Bok;Kim, Sang-Yong;Lee, Woo-Sun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07a
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    • pp.46-49
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    • 2003
  • Chemical mechanical polishing (CMP) is an essential dielectric planarization in multilayer microelectronic device fabrication. In the CMP process it is necessary to minimize the extent of surface defect formation while maintaining good planarity and optimal material removal rates. The polishing mechanism of W-CMP process has been reported as the repeated process of passive layer formation by oxidizer and abrasion action by slurry abrasives. Thus, it is important to understand the effect of oxidizer on W passivation layer, in order to obtain higher removal rate (RR) and very low non-uniformity (NU%) during W-CMP process. In this paper, we compared the effects of oxidizer or W-CMP process with three different kind of oxidizers with 5% hydrogen peroxide such as $Fe(NO_3)_3$, $H_2O_2$, and $KIO_3$. The difference in removal rate and roughness of W in stable and unstable slurries are believed to caused by modification in the mechanical behavior of $Al_3O_3$ particles in presence of surfactant stabilizing the slurry.

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Effect of Filter Aid Treatment on the Quality Characteristics of Salt-Fermented Anchovy Sauce (멸치액젓의 품질특성에 미치는 여과조제 처리의 효과)

  • JO Jin-Ho;DO Jeong-Ryong
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.32 no.6
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    • pp.770-773
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    • 1999
  • To obtain the basic data for the improvement of flayer and color in salt-fermented anchovy (Engraulis japonicus) sauce and for the inhibition of non-soluble precipitates formation during storage, experiments were carried out on the changes of chemical properties by treatment with 1, 3, 5 and $7\%$ (w/v) of active carbon and filter aids such as active clay, $Al_2O_3$ diatomaceous earth, and celite. Deceleration rate were $32\~33\%$ in case of $5\%$ (w/v) active carbon or $5\%$ (w/v) active clay treatments, but deodoration effect was not expected in all treatments. The inhibition rate of non-soluble precipitates formation in me of $5\%$ (w/v) active clay, diatomaceous earth and $Al_2O_3$ treatments. was shown as $82\%,\;73\%$, and $70\%$, respectively.

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The Development of the Components of the Length Measurement Concept in the Procedure of Measurement Using a Ruler

  • Antic, Milica D.;Dokic, Olivera J.
    • Research in Mathematical Education
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    • v.22 no.4
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    • pp.261-282
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    • 2019
  • The research related to testing pupils' achievement in the field of Measurement and Measure in initial teaching of geometry points to an insufficient adoption of the basic components of the length measurement concept among pupils. In order to discover the cause, we looked at the basic components on which the procedure of measuring length using a ruler is based, highlighted the possibilities of introducing the procedure in measuring length, and determined pupils' achievement during the procedure of measuring length using a ruler. The research sample consisted of 145 pupils, out of which 72 were the 2nd grade pupils and 73 were the 4th grade pupils. A descriptive method was applied in the research. The technique we used was testing, and for the statistical data processing we used a χ2 test. The results of the research show that, when drawing a straight line of a given length using a ruler, there is no statistical difference in achievement between the 2nd and 4th grade pupils, nor in the pupils' knowledge regarding drawing a ruler independently, while drawing a straight line of a given length using a "broken" ruler 4th grade pupils are statistically better. The results of the research indicate that pupils' achievement is better in doing standard tasks than in non-standard ones, given that the latter require conceptual knowledge. The components of the concept of length measurement using ruler have not been sufficiently developed yet, and these include: zero-point, partitioning a measured object in a series of consecutive measurement units and their iteration. We shed more light on the critical stage in the procedure of length measurement - the transition from non-standard to standard units and the formation of the length measurement scale. For further research, we propose to look at the formation of the concept of length measurement using the ruler through all its components and their inclusion in the mathematics curriculum, as well as examining the correlation of pupils' achievement in the procedure of measuring length with their achievement in measuring area (and volume).

Occurrence and Genesis of Zeolites from the Tertiary Volcanic Sediments in the Guryongpo Area, Korea (浦項 九龍浦 지역 第 3 紀 火山堆積岩 中의 沸石鑛物의 産出狀態와 成因)

  • Choi, Yun-Seung;Kim, Soo-Jin
    • Journal of the Mineralogical Society of Korea
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    • v.6 no.1
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    • pp.38-47
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    • 1993
  • Clinoptilolite and mordenite are important constituents of the Nuldaeri Trachytic Tuff and Guryongpo Dacitic Tuff of the Tertiary Janggi Group which were deposited in a lacustrine environment. The diagenetic cystallization sequences of zeolites in different tuffaceous sediments and their chemical behaviors have been studied to know the process of their formation. The paragenetic sequence established from textural observations and chemical data : Ca-smectite ${\leftrightarrow}$(Ca, K)-clinoptilolite${\leftrightarrow}$(K, Na)-mordenite, indicates that the chemical activities of alkalic ions and Si/Al activity ratio in pore fluids changed systematically with diagenetic alteration. The chemical trend of zeolite formation is characterized by decreasing Ca and Mg, non-variable Na and increasing K in the Nuldaeri Trachytic Tuff and by decreasing Ca and Mg, non-variable Na and increasing-decreasing K in the Guryongpo Dacitic Tuff. The paragenesis from glass via smectite to alkali zeolites indicates a sequence of incongruent dissolution reactions and subsequent crystallization. Inhomogeneity in chemical composition of each zeolite may be attributed to such processes.

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Formation of Poly(vinylidene difluoride) Membranes with Various Pore Sizes by a Phase Inversion Process and Membrane Performance of Aqueous and Non-aqueous Solution System (상전환법에 의한 다양한 기공크기를 갖는 폴리비닐리덴플루오라이드 막의 제조와 수계 및 비수계 용액 내에서의 막 성능)

  • Lee Kew-Ho;Kim In-Chul
    • Membrane Journal
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    • v.15 no.1
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    • pp.22-33
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    • 2005
  • Asymmetric PVDF membranes were prepared by the phase inversion from casting solutions containing PVDF, NMP as solvent and 1,4-dioxane, DGDE, acetone, or GBL as additives by immersing them in water. The effects of various additives on the casting solution properties, permeation properties, and membrane structures were investigated. Low miscibility of 1,4-dioxane, DGDE and acetone with the coagulant (water) compared with NMP resulted in reducing the membrane pore size. When DGDE is used as an additive, the pore size was reduced because of its incipient sharp interface formation in the water. GBL increased membrane pore size because of its polarity compared to that of NMP. The PVDF membranes with various pore sizes could be obtained by controlling the amount of additive. The effect of mixed solvent (aqueous and non-aqueous solution) on permeation through membrane was investigated. Not only solution viscosity but surface tension affected solvent permeation.

Luteolin attenuates migration and invasion of lung cancer cells via suppressing focal adhesion kinase and non-receptor tyrosine kinase signaling pathway

  • Masraksa, Wuttipong;Tanasawet, Supita;Hutamekalin, Pilaiwanwadee;Wongtawatchai, Tulaporn;Sukketsiri, Wanida
    • Nutrition Research and Practice
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    • v.14 no.2
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    • pp.127-133
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    • 2020
  • BACKGROUND/OBJECTIVES: Non-small cell lung cancer is mostly recognized among other types of lung cancer with a poor prognosis by cause of chemotherapeutic resistance and increased metastasis. Luteolin has been found to decrease cell metastasis. However, its underlying mechanisms remain unresolved. The objective of this study was to examine the effect (and its mechanism) of luteolin on the migration and invasion of human non-small cell lung cancer A549 cells. MATERIALS/METHODS: Cell viability was investigated by 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide assay. Wound healing and transwell assays were evaluated to assess migration and invasion, respectively. Western blot analysis and immunofluorescence were further performed to investigate the role of luteolin and its mechanisms of action. RESULTS: Administration with up to 40 μM luteolin showed no cytotoxic activity on lung cancer A549 cells or non-cancer MRC-5 cells. Additionally, luteolin at 20-40 μM significantly suppressed A549 cells' migration, invasion, and the formation of filopodia in a concentration-dependent manner at 24 h. This is similar with western blot analysis, which revealed diminished the phosphorylated focal adhesion kinase (pFAK), phosphorylated non-receptor tyrosine kinase (pSrc), Ras-related C3 botulinum toxin substrate 1 (Rac1), cell division control protein 42 (Cdc42), and Ras homolog gene family member A (RhoA) expression levels. CONCLUSIONS: Overall, our data indicate that luteolin plays a role in controlling lung cancer cells' migration and invasion via Src/FAK and its downstream Rac1, Cdc42, and RhoA pathways. Luteolin might be considered a promising candidate for suppressing invasion and metastasis of lung cancer cells.

Non-stoichiometric AlOx Films Prepared by Chemical Vapor Deposition Using Dimethylaluminum Isopropoxide as Single Precursor and Their Non-volatile Memory Characteristics

  • Lee, Sun-Sook;Lee, Eun-Seok;Kim, Seok-Hwan;Lee, Byung-Kook;Jeong, Seok-Jong;Hwang, Jin-Ha;Kim, Chang-Gyoun;Chung, Taek-Mo;An, Ki-Seok
    • Bulletin of the Korean Chemical Society
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    • v.33 no.7
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    • pp.2207-2212
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    • 2012
  • Dimethylaluminum isopropoxide (DMAI, $(CH_3)_2AlO^iPr$) as a single precursor, which contains one aluminum and one oxygen atom, has been adopted to deposit non-stoichiometric aluminum oxide ($AlO_x$) films by low pressure metal organic chemical vapor deposition without an additional oxygen source. The atomic concentration of Al and O in the deposited $AlO_x$ film was measured to be Al:O = ~1:1.1 and any serious interfacial oxide layer between the film and Si substrate was not observed. Gaseous by-products monitored by quadruple mass spectrometry show that ${\beta}$-hydrogen elimination mechanism is mainly contributed to the $AlO_x$ CVD process of DMAI precursor. The current-voltage characteristics of the $AlO_x$ film in Au/$AlO_x$/Ir metalinsulator-metal (MIM) capacitor structure show high ON/OFF ratio larger than ${\sim}10^6$ with SET and RESET voltages of 2.7 and 0.8 V, respectively. Impedance spectra indicate that the switching and memory phenomena are based on the bulk-based origins, presumably the formation and rupture of filaments.