• 대한기계학회논문집
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• 제17권9호
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• pp.2131-2137
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• 1993

This study, examines the performance and the heat pump cycle systematizing characteristics for non-azeotropic refrigerant systems. In order to conduct such an examination, the cycle characteristics of heat pumps for pure R-22, R-114, and their mixtures were experimentally investigated. The results show that cooling/heating capacities for the mixtures was more suited at the evaporating temperature of $5^{\circ}C$ than that of $0^{\circ}C$, $-5^{\circ}C$, and $-10^{\circ}C$. The C.O.P of the 50 wt% mixtures was considerably higher than for pure R-22, and the compression power of the 25 wt% was as much as 60% lower than that of pure R-22. Even small fractional mixture variations can lead to significant changes in the characteristics of the heat pump cycle. This experiment verified the importance of accurate weight fractions of refrigerant mixtures.

• 설비공학논문집
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• 제7권2호
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• pp.225-233
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• 1995

Experiments were performed to investigate the heat transfer characteristics of nonazeotropic mixture R-22+R-114 in a heat pump system. The ranges of parameter, such as heat flux, mass flow rate, and quality were $8,141{\sim}32,564W/m^2$, 24~58kg/h, and 0~1, respectively. The overall compositions of the mixtures were 50 and 100 per-cent of R-22 by weight for R-22+R-114 mixture. The results indicated that there were distinct different heat transfer phenomena between the pure substance and the mixture. In case of pure refrigerant the heat transfer rates for cooling were strongly dependent upon quality of the refrigerant. Overall evaporating heat transfer coefficients for the mixture were somewhat lower than pure R-22 values in the forced convective boiling region. For a given flow rate, the heat transfer coefficient at the circumferential tube wall(top, side, and bottom of the test tube) for R-22/R-114(50/50wt%)mixture, however, was higher than for pure R-22 at side and bottom of the tube. Furthermore, a prediction for the evaporating heat transfer coefficient of the mixtures was developed based on the method of Yoshida et.al.'s. The resulting correlation yielded a good agreement with the data for the refrigerant mixtures.

• 대한기계학회논문집
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• 제19권4호
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• pp.1125-1133
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• 1995

Experiments were performed to investigate the condensing heat transfer characteristics of non-azeotropic mixtures of R-22 and R-114 in a heat pump system with a horizontal smooth tube as a condenser. The ranges of parameters, such as heating capacity, mass flow rate of refrigerant and quality were 780-3,480W, 24-71kg/h, and 0-1, respectively. The overall compositions of R-22 in a R-22/114 mixture were 25, 50, 75 and 100 per cent by wight. The results show that the overall condensing heat transfer coefficients for the mixtures were lower than the pure R-22 values. Local heat transfer coefficient of the pure R-22 was hghest at the top of the test tube. The local heat transfer coefficient of R-22/114 (50/50 wt%) at side and bottom of the test tube was higher than that at the top. From the obtained data, a prediction for the condensing heat transfer coefficients of the mixture was done based on the method of Fujii.

• Journal of Advanced Marine Engineering and Technology
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• 제18권4호
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• pp.53-61
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• 1994

An experimental study on heat pump cycle systematizing characteristics for non-azeotropic refrigerant mixtures of R-22+R-114 was reported. Data were obtained under steady state condition at the ranges of parameters, 550- 2, 170kcal/h, 670-2, 990kcal/h, 24-71kg/h, and 0-1, for as cooling capacity, heating capacity, mass 25, 50, 75, and 100 per cent of R-22 by weight fraction for R-22+R-114 mixtures. The results shown that the C.O.P of the 50wt% of R-22 mixture was considerably larger than for pure R-22 and other weight fraction of R-22 mixtures, but the compression power of the 25wt% of R-22 was lower than that of the pure R-22 and the other weight fraction of R-22 mixtures. The hightest value of cooling capacity was obtained at the conditions of evaporating temperature 5.deg.C and R-22 50wt% mixture. In general, with an increase in the R-22 weight fraction for fixed values of the other parameter, the cooling capacity increased at first, obtained a maximum, and then decreasd. This verified the importance of accurate weight fractions od refrigerant mixtures in the heat pump cycle.

• 연구논문집
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• 통권25호
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• pp.77-90
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• 1995

For improving performance of heat pump system, researcher has adapted 2-stage economizer cycle and developed a high-efficiency screw compressor, new working medium(non-azeotropic mixed refrigerant) and counterflow heat exchangers operating with a small temperature difference. Target of this study is development of high performance heat pump system with the 2-stage economizer system using the non-azeotropic mixed refrigerant. For the purpose of excuting target, we constucted computer simulation programs, compared and examed various types of cycle and non-azeotropic mixture. Based on the results from computer simulation we selected optimum mixtures and reflected design and production process of performance test equipment with the 1-stage econmizer system. In order to accomplish the final target, design and production of the 2-stage economizer system, we performed pilot test using the 1-stage economizer performance test system and finally design and production of the 2-stage economizer system.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2005년도 창립60주년 기념 추계 학술대회
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• pp.105.2-105.2
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• 2005

• 설비공학논문집
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• 제2권3호
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• pp.218-225
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• 1990

Studies on the performance of a heat pump using non-azeotropic refrigerant mixtures are done. In order to estimate the thermodynamic properties for the selected non-azeotropic refrigerant mixtures including R22/R152a, R22/R142b, R22/R114 and R13B1/R152a, Peng-Robinson equation of state is adopted. The pressure-enthalpy diagram and the temperature-entropy diagram are plotted for each refrigerant mixture. Considerations on the capacity modulation for the heat pump system using refrigerant mixtures are taken into. Results show that when the heating load varies, the possibility for the capacity modulation is found in the heat pump system using a compressor with constant volume flow rate. Under a constant heating capacity condition in the heat pump system, the coefficient of performance increases when the refrigerant mixtures are used. The volume flow rate decreases as the mass fraction of lower boiler increases in this case.

• 대한기계학회논문집
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• 제14권5호
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• pp.1337-1348
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• 1990

본 연구에서는 Peng-Robinson 상태 방정식을 기본으로 하여 먼저 단일 성분의 냉매에 대한 열역학적 물성치를 구한 뒤 그 정확도를 검증하고, 동일한 형태의 상태식 과 적절한 혼합 법칙을 통해 혼합냉매의 기액 평형 상태와 냉동 및 열펌프 사이클 해 석에 필요한 엔탈피와 엔트로피 등의 열역학적 물성치를 추산하고자 한다.단일 성 분의 냉매로서는 R13B1, R22, R12, R152a, R114를 택하였고, 혼합냉매로서는 앞의 단 일성분 냉매를 혼합한 것 중에서 그 기초적인 실험 자료가 아미 알려진 R13B1/R114, R22/R114, R12/R114 R152a/R114, R13B1/R152a 및 R13B1/R12를 택하였다. 이는 추후 상이한 냉매를 단일식으로 나타낼 수 있는 대응상태의 원리를 사용한 열물성 계산의 기반이 될 수 있을 것이다.

• 설비공학논문집
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• 제12권5호
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• pp.502-510
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• 2000

Evaporation heat transfer characteristics were studied in a horizontal tube using R22/R114 non-azotropic refrigerant mixture. the heat transfer coefficient was high in the upper part for pure refrigerants, and heat transfer coefficient was low in the lower part for refrigerant mixtures. In the low quality region where nucleate boiling was dominant, the average heat transfer coefficient was low. In the region where forced convection was dominant, heat transfer coefficient was high. Results show that the heat transfer coefficient for pure refrigerants obtained by experiments were lower than those of Yoshida et al. but agreed well with Jung et al., and Chen et al. data. But the heat transfer coefficients for refrigerant mixtures were lower about 20% than those predicted by the equation for pure refrigerant.

• 기술사
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• 제34권2호
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• pp.23-27
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• 2001

Until 1996, CFC refrigerants haven't been used because it destroyed ozone that affecting In ecosystem. And HCFC will prohibit until 2020. In Europe, they attempt to move up its fulfillment. Until now the change have completed CFC into HFC134a and is considerated HCFC into HFC410A and HFC407C. But HFC41 OA has high condenser temperature and HFC407C is non-azeotropic refrigerant mixture and gliding temperature phenomenon. New refrigerant ell POE, PVE, PAG was also developed.