• Title/Summary/Keyword: No 수열

Search Result 116, Processing Time 0.043 seconds

수열합성법으로 성장된 ZnO 박막의 열처리에 따른 특성 변화

  • Kim, Min-Su;Im, Gwang-Guk;Kim, So-ARam;Nam, Gi-Ung;Lee, Jae-Yong;No, Geun-Tae;Lee, Dong-Yul;Kim, Jin-Su;Kim, Jong-Su;Lee, Ju-In;Im, Jae-Yeong
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2011.02a
    • /
    • pp.78-78
    • /
    • 2011
  • 수열합성법을 이용하여 Si(111) 기판에 ZnO 박막을 성장하였다. ZnO 박막의 성장을 위한 씨앗층은 plasma-assisted molecular beam epitaxy (PA-MBE)를 이용하였다. 씨앗층의 표면 거칠기(root-mean-square roughness)는 2.5 nm이고, 씨앗층 위에 성장된 ZnO 박막은 다양한 크기의 입자들로 이루어져 있었으며 두께는 약 $1.8{\mu}m$로 매우 일정하였다. 배향성을 알아보기 위하여 texture coefficient (TC)를 계산해 보았다. TC(100)과 TC(200)은 a-축 배향성을, TC(002)는 c-축 배향성을 나타내는데, c-축으로 더 우세한 배향성(99.5%)을 보였다. TC 비율(TCa-axis/TCc-axis)은 열처리 온도를 $700^{\circ}C$까지 올렸을 때, 점차적으로 증가하였고, 그 이상의 열처리 온도(< $900^{\circ}C$)에서는 급격히 감소하였다. 잔류응력과 Zn와 O의 bond length도 유사한 경향을 보였다. $700^{\circ}C$까지 열처리 온도가 증가함에 따라, 잔류응력은 증가하였고 bond length는 감소하였다. Near-band-edge emission (NBE)의 피크 강도는 열처리 온도가 $700^{\circ}C$까지 증가함에 따라 점차적으로 증가하였다. 열처리 온도가 $800^{\circ}C$ 이상 증가함에 따라 deep-level emission (DLE)가 적색편이(red-shift)하였다. $700^{\circ}C$로 열처리를 한 ZnO 박막이 가장 우세한 (002)방향의 배향성을 보였을 뿐만 아니라 가장 큰 발광효율 증가를 보였다.

  • PDF

Density control of ZnO nanowires using PDOT:PSS (PDOT:PSS를 이용한 ZnO 나노선의 밀도조절)

  • No, I.J.;Shin, P.K.
    • Proceedings of the KIEE Conference
    • /
    • 2011.07a
    • /
    • pp.1451-1452
    • /
    • 2011
  • ZnO 나노선을 수열합성법을 이용하여 합성 하였다. ZnO 나노선을 이용하여 고효울 소자 제작하기 위해 반듯이 필요한 조건인 밀도 조절을 위해 PDOT:PSS를 에어브로쉬를 이용하여 분사하여 Dot의 형태로 열처리 한후 나노선을 합성 하였고 SEM 이미지를 통하여 밀도가 조절된 것을 확인 하였다.

  • PDF

Cross-Correlation Distribution of a p-ary m-Sequence Family Constructed by Decimation (Decimation에 의해 생성된 p-진 m-시퀀스 군의 상호 상관 값의 분포)

  • Seo, Eun-Young;Kim, Young-Sik;No, Jong-Seon;Shin, Dong-Joon
    • The Journal of Korean Institute of Communications and Information Sciences
    • /
    • v.33 no.9C
    • /
    • pp.669-675
    • /
    • 2008
  • For an odd prime p, n=4k and $d=((p^2k+1)/2)^2$, there are $(p^{2k}+1)/2$ distinct decimated sequences, s(dt+1), $0{\leq}l<(p^{2k}+1)/2$, of a p-ary m-sequence, s(t) of period $p^n-1$. In this paper, it is shown that the cross-correlation function between s(t) and s(dt+l) takes the values in $\{-1,-1{\pm}\sqrt{p^n},-1+2\sqrt{p^n}\}$ and their, cross-correlation distribution is also derived.

Hydrothermal carbonization of sewage sludge for solid recovered fuel and energy recovery (수열탄화를 이용한 하수 슬러지의 고형연료화 및 에너지 회수 효율)

  • Kim, Daegi;Lee, Kwanyong;Park, Kiyoung
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.29 no.1
    • /
    • pp.57-63
    • /
    • 2015
  • Recently, Korea's municipal wastewater treatment plants generated amount of wastewater sludge per day. However, ocean dumping of sewage sludge has been prohibited since 2012 by the London dumping convention and protocol and thus removal or treatment of wastewater sludge from field sites is an important issue on the ground site. The hydrothermal carbonization is one of attractive thermo-chemical method to upgrade sewage sludge to produce solid fuel with benefit method from the use of no chemical catalytic. Hydrothermal carbonization improved that the upgrading fuel properties and increased materials and energy recovery, which is conducted at temperatures ranging from 200 to $350^{\circ}C$ with a reaction time of 30 min. Hydrothermal carbonization increased the heating value though the increase of the carbon and fixed carbon content of solid fuel due to dehydration and decarboxylation reaction. Therefore, after the hydrothermal carbonization, the H/C and O/C ratios decreased because of the chemical conversion. Energy retention efficiency suggest that the optimum temperature of hydrothermal carbonization to produce more energy-rich solid fuel is approximately $200^{\circ}C$.

Precision Control of Water Bath Temperature using Air Cooled Variable Refrigerant Flow Chiller (공랭식 변유량 냉매 냉동기를 적용한 수조 온도의 정밀 제어)

  • Jeong, Kwang-Ju;Kim, Young Il
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
    • /
    • v.14 no.4
    • /
    • pp.27-34
    • /
    • 2018
  • This study compared constant water bath performances of conventional water-cooled refrigerator and electric heater with an air-cooled VRF chiller and electric heater equipped with optimal control algorithm. In heating mode, the air cooled VRF chiller and electric heater combination reduced the set temperature arrival time by an average of 42 minutes, and energy was also reduced by 18%. In cooling mode, the two systems took 70 minutes to reach the set temperature and showed no difference. Energy was reduced by 33.5% with the new system. For constant temperature maintaining experiment, after reaching the set temperature of $15^{\circ}C$, $20^{\circ}C$ and $22^{\circ}C$, temperature deviations were all in the range of $-0.2^{\circ}C$ to $+0.1^{\circ}C$. Energy was reduced by an average of 84.9%. Through this study, possibility of precise temperature control by an air cooled VRF chiller system was confirmed.

Cooling Performance Analysis of Ground-Source Heat Pump System with Capacity Control with Outdoor Air Temperature (외기 온도 제어 방식을 적용한 지열 히트펌프 시스템의 냉방 성능 분석)

  • Sohn, Byonghu
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
    • /
    • v.17 no.4
    • /
    • pp.68-78
    • /
    • 2021
  • In order to solve the increasing deterioration of the energy shortage problem, ground-source heat pump (GSHP) systems have been widely installed. The control method is a significant component for maintaining the long-term performance and for reducing operation cost of GSHP systems. This paper presents the measurement and analysis results of the cooling performance of a GSHP system using capacity control with outdoor air temperature. For this, we installed monitoring equipments including sensors for measuring temperature, flow rate and power consumption, and then monitored operation parameters from July 9, 2021 to October 2, 2021. From measurement results, we analyze the effect of capacity control with outdoor air temperature on the cooling performance of the system. The average performace factor (PF) of the heat pump was 6.95, while the whole system was 5.54 over the measurement period. Because there was no performance data of the existing GSHP system, it was not possible to directly compare the existing control method and the outdoor air temperature method. However, it is expected that the performance of the entire system will be improved by adjusting the temperature of cold water produced by the heat pump, that is, the temperature of cold water on the load side according to the outside air temperature.

Hydrothermal Precipitation of PZT Powder (PZT분말의 수열합성에 관한 연구)

  • 이경희;이병하;대문정기;천하희흥지;강원호;박한수
    • Journal of the Korean Ceramic Society
    • /
    • v.24 no.4
    • /
    • pp.397-403
    • /
    • 1987
  • Pb(Zr0.52Ti0.48)O3 powders were prepared by hydrothermal synthesis. Using soluble salts such as Pb(NO3)2, TiCl4 and ZrOCl2$.$8H2O and oxide such as PbO and TiO2 as starting materials, PZT powder was hydrothermally synthesized at the temperature range between 150$^{\circ}C$ and 200$^{\circ}C$. The result showed that reactivity by alkali was decreased in the sequence of Pb(NO3)2, TiCl4, ZrOCl2, PbO, TiO2 and ZrO2. Using the first three soluble salts, PZT powder was synthesiged at 150$^{\circ}C$ for 1hr. In PbO-TiCl4-ZrOCl2 system, PZT powder was synthesized at 150$^{\circ}C$ for 8rs. In Pb(NO3)2-TiO2-ZrOCl2 system, PZT powder was synthesized at 150$^{\circ}C$ for 16hrs, in PbO-TiO2-ZrOCl2 system, the powder was synthesized at 200$^{\circ}C$ for 8hrs.

  • PDF

Microwave Hydrothermal Sythesis of PbTiO$_3$ and PMN Ceramic Powders (마이크로파 수열법에 의한 PbTiO$_3$ PMN 세라믹분말의 합성)

  • Bai, Kang
    • Journal of the Korean Ceramic Society
    • /
    • v.35 no.5
    • /
    • pp.465-471
    • /
    • 1998
  • Lead titanate(PT) and lead magnesium niobate(PMN) ceramic powders were prepared by microwave hy-drothermal method using teflon bomb. Raw materials were Pb(NO3)2 and TiO2 for lead titanate and Pb(NO3)2 Nb2O5 and Mg(NO)3.6H2O for PMN with NaOH as mineralizer in both cases. in lead titanate synthsis rate of microwave hydrothermal method was faster three times than one f conventional hydrothermal methods In lead magnesium niobate synthsis the mixture of perovskite and pyrochlore phases was obtained by single step technique and the PMN was not obtained by double step technique due to low temperature limitation of teflon bomb.

  • PDF

Decomposition Characteristics of 4-Chlorophenol Treated in Fe2O3 Supported γ-Alumina Catalyst and O3 (Fe2O3/γ-Al2O3 세라믹촉매와 오존을 이용한 4-클로로페놀의 분해특성)

  • 박병기;이정민;서동수
    • Journal of the Korean Ceramic Society
    • /
    • v.41 no.6
    • /
    • pp.485-492
    • /
    • 2004
  • We prepared cylindrical y-alumina pellets using amorphous alumina and pore generating agent. The pellets were immersed in an aqueous solution of the mixture of Fe(NO$_3$)$_3$ㆍ9$H_{2}O$ and $CH_3$COOH. They were then hydrothermally treated at 20$0^{\circ}C$ for 3 h in autoclave, dried and calcined. For the application of environmental catalyst for its, we investigated the decomposition characteristics of 4-chlorophenol and the initiation characteristics of OH' conversion action in $O_3$ environment with or without the Fe$_2$O$_3$ supported ${\gamma}$-alumina catalyst and $O_3$ molecule.

Two-Dimensional Lanthanum-BDC Coordination Polymer:Hydrothermal Synthesis and Structure of [La4(BDC)6(H2O)5](H2O)(BDC=benzene-1,3-dicaboxylate) (2차원 La-BDC 배위 고분자: [La4(BDC)6(H2O)5](H2O)의 수열합성 및 구조(BDC=benzene-1,3-dicaboxylate))

  • Kim, Hye Jin;Min, Dong Won;Heo, Hyun Su;Lee, Soon W.
    • Journal of the Korean Chemical Society
    • /
    • v.45 no.6
    • /
    • pp.507-512
    • /
    • 2001
  • The hydrothermal reaction between lanthanum(Ⅲ) nitrate $(La(NO3)3${\cdot}$6H_2O)$ and benzene-1,3-dicarboxylic acid $(H_2BDC)$ in the presence of 1,2-bis(4-pyridyl)ethane gave a 2-D lanthnum-BDC coordination polymer with an empirical formula of $〔La_4$(BDC)_6(H_2O)_5$〕(H_2O)$ (1). X-ray structure analysis of compound 1 revealed that this polymer contains four distinct La metals. The three La metals are 7-coordinate with three different structures: a capped trigonal prism, a capped octahedron, and a pentagonal bipyramid. The remaining La metal has a 8-coordinate, square antiprismatic structure.

  • PDF