• Journal of Korean Society on Water Environment
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• v.24 no.1
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• pp.30-35
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• 2008

In this study, we investigated the nitrification/denitrification rate and classification of output nitrogen of a sequencing batch reactor (SBR) system with the variation of COD loads ; COD loads of 0.3, 0.4, 0.6, 0.7, 0.8, 1.0 and $1.2kgCOD/m^3{\cdot}d$ were tested to determine the optimum conditions for the operation of the SBR and increase its nitrogen removal efficiency. As the COD loads increased, the nitrification rate at aerobic(I) period and the denitrification rate at anoxic(I) period were decreased. With the variation of COD loads, the amounts of nitrogen removed in the clarified water effluent were 63.9, 54.2, 34.7, 22.5, 13.7, 12.5 and 26.5 mg/cycle, respectively. The amounts of nitrogen removed during the sludge waste process were 19.5, 26.6, 41.0, 47.3, 58.1, 72.4 and 88.1 mg/cycle, respectively. The amounts of nitrogen removed by denitrification were 66.8, 69.3, 68.9, 56.5, 39.5, 7.3 and 0.0 mg/cycle, respectively, indicating that COD load more than $0.7kgCOD/m^3{\cdot}d$ decreases the amounts of denitrified nitrogen. The nitrogen mass balances were calculated as the percentages of nitrogen removed in the clarified water effluent or by denitrification and sludge waste processing in each cycle of SBR operation and were 99.0, 98.5, 95.4, 82.1, 73.0, 60.5 and 74.8% for COD loads of 0.3, 0.4, 0.6, 0.7, 0.8, 1.0 and $1.2kgCOD/m^3{\cdot}d$, respectively.

• Journal of Korean Society on Water Environment
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• v.26 no.1
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• pp.71-80
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• 2010

We studied the nitrogen behavior and budget of Lake Paldang from March to December 2008. The particulate nitrogen (PN) concentrations ranged from 7 to 13% of the total nitrogen concentration (TN) in the stream inflows, the downstream outflow, and the lake water. The nitrate nitrogen ($NO_3-N$) concentration ranged from 67 to 78% of the TN. In the three rivers of Lake Paldang, Gyeongan River (In3 site) had the highest average of the TN, 5.037 mgN/L, but North Han River (In2 site) had the lowest average TN, 1.683 mgN/L. South Han River (In1 site) had the average TN of 2.399 mgN/L. In the dam discharge, TN showed the average 2.063 mgN/L. In the lake water, L4 site (Gyeongan River area) had the highest average TN, 3.781 mgN/L, but L3 site (North Han River) had the lowest average TN, 1.587 mgN/L. Total input of nitrogen loads to Lake Paldang was about 30,875 ton/year in 2008. Inflow rivers contributed 30,643 ton/year (South Han River: 18,111 ton/year (59%), North Han River: 11,333 ton/year (37%), and Gyeongan River: 1,199 ton/year (4%)). The atmospheric deposition had 135 ton/year, the nitrogen release from the bottom sediments had 88 ton/year, and macrophytes had 9 ton/year. Total output of nitrogen loads from Lake Paldang was about 31,256 ton/year. The downstream from dam contributed 29,877 ton/year, and the sediment deposition was 1,379 ton/year.

• Journal of Korean Society on Water Environment
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• v.31 no.1
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• pp.55-66
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• 2015

It has been well known that it is not easy to quantify pollutant loads driven by non-point source pollution due to various factors affecting generation and transport mechanism of it. Especially pollutant loads through baseflow have been investigated by limited number of researchers. Thus in this study, the Web-based WAPLE (WHAT-Pollutant Load Estimation) system was developed and applied at study watersheds to quantify baseflow contribution of pollutant. In YbB watershed, baseflow contribution with WWTP discharge is responsible for 49.5% of total pollutant loads at the watershed. Among these, pollutant loads through baseflow (excluding any WWTP discharge) is responsible for 61.7% of it. In GbA watershed, it was found that 58.4% is contributed by baseflow with WWTP discharge 2.9% and 97.1% is by baseflow. For NbB watershed (without WWTP discharge), 52.3% of pollutant load is transported through baseflow. As shown in this study, it was found that over 50.0% of TN (Total Nitrogen) pollutant loads are contributed by non-direct runoff. Thus pollutant loads contributed by baseflow and WWTP discharge as well as direct runoff contribution should be quantified to develop and implement watershed-specific Best Management Practices during dry period.

• Journal of Applied Biological Chemistry
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• v.43 no.4
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• pp.254-257
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• 2000

Water quality monitoring network was established at the agricultural watershed located at the Namdae-chon watershed of Seolchon-myon, Muju-gun, Chollabuk-do, Korea which is 22,560 ha in size. Based on total amount of stream flow loads of nitrogen and phosphorus from the agricultural watershed were estimated. About 4.48 (1,011 ha), 7.02 (1,585 ha), and 86.82% (19,609 ha) of the site were used for paddy fields, upland fields, and forests, respectively. During the period of 6 months from May 1 to October 31, 1999, the total amounts of precipitation and stream flow were 993.2 mm and $148,533,000m^3$ respectively. The loads of agricultural non-point sources accrued by land use were 83,526 kg, 24,508 kg, 49,705 kg, and 215 kg for total-N, ammonia-N, nitrate-N, and total-P, respectively. Results showed that 23.4 and 0.1 % of the applied nitrogen and phosphorus fertilizers, respectively, were estimated to load into the streams as agricultural non-point sources.

• Journal of The Korean Society of Agricultural Engineers
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• v.59 no.4
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• pp.1-15
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• 2017

Eutrophication of surface waters is of concern worldwide, because it can result in many undesirable water-quality and ecological problems, such as hypoxic 'dead' zones and harmful algal blooms, both associated with considerable economic costs. In this study, we used LSM (Land Surface Model) to simulate nitrogen in five major rivers in the Southern Korean Peninsula. The main objective of this research was to enhance nitrogen data for input of LM3V model in South Korea. Input data for nitrogen fluxes were categorized into three sections including agriculture fertilizer, livestock manure, atmosphere deposition, biological fixation, and sewage pollutants were used as the nitrogen input. For using LM3V model, the nitrogen input data were regenerated by considering states of agriculture and industry in South Korea at a $1/8^{\circ}$ resolution. Then, we simulated stream/river flows and N loads throughout the entire drainage networks in South Korea at a $1/8^{\circ}$ resolution. By using the same parameters for the entire country ($100,210km^2$), composed of 5 river basins with varying climate and land use, the model simulates spatial (11 sites) and temporal (1999~2010) patterns of flows and nitrate-N loads are resonable by comparing observed flow and nitrate-N loads. The r (Pearson's linear correlation) for water temperature, flow and nitrate-N at river were 080~0.93, 0.62~0.92 and 0.5~0.9 respectively. Based on enhanced N input data and model results, we find that LM3V model as land surface model can be applied in South Korea with interaction of atmosphere and land conditions.

• Water Engineering Research
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• v.4 no.3
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• pp.141-154
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• 2003

Nonpoint source pollutants from agriculture are identified as one of the main causes of water quality degradation in the United States. The Hydrological Simulation Program-Fortran (HSPF) was used to simulate runoff, nitrogen, and sediment loads from an urbanizing watershed; the Polecat Creek watershed located in Virginia. Model parameters related to hydrology and water quality were calibrated and validated using observed hydrologic and water quality data collected at the watershed outlet and at several sub-watershed outlets. A comparison of measured and simulated monthly runoff at the outlet of the watershed resulted in a correlation coefficient of 0.94 for the calibration period and 0.74 for the validation period. The annual observed and simulated sediment loads for the calibration period were 220.9 kg/ha and 201.5 kg/ha, respectively. The differences for annual nitrate nitrogen ($NO_3$) loads between the observed and simulated values at the outlet of the watershed were 5.1% and 42.1% for the calibration and validation periods, respectively. The corresponding values for total Kjeldahl nitrogen (TKN) were 60.9% and 40.7%, respectively. Based on the simulation results, the calibrated HSPF input parameters were considered to adequately represent the Polecat Creek watershed.

• Proceedings of the Korea Water Resources Association Conference
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• 2018.05a
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• pp.448-448
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• 2018

In this study, the regression models (Load ESTimator and eight-parameter model) were evaluated to estimate instantaneous pollutant loads under various criteria and optimization methods. As shown in the results, LOADEST commonly used in interpolating pollutant loads could not necessarily provide the best results with the automatic selected regression model. It is inferred that the various regression models in LOADEST need to be considered to find the best solution based on the characteristics of watersheds applied. The recently developed eight-parameter model integrated with Genetic Algorithm (GA) and Gradient Descent Method (GDM) were also compared with LOADEST indicating that the eight-parameter model performed better than LOADEST, but it showed different behaviors in calibration and validation. The eight-parameter model with GDM could reproduce the nitrogen loads properly outside of calibration period (validation). Furthermore, the accuracy and precision of model estimations were evaluated using various criteria (e.g., $R^2$ and gradient and constant of linear regression line). The results showed higher precisions with the $R^2$ values closed to 1.0 in LOADEST and better accuracy with the constants (in linear regression line) closed to 0.0 in the eight-parameter model with GDM. In hence, based on these finding we recommend that users need to evaluate the regression models under various criteria and calibration methods to provide the more accurate and precise results for pollutant load estimations.

• Journal of Korean Society on Water Environment
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• v.26 no.2
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• pp.311-316
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• 2010

We estimated the nitrogen and phosphorus loads of wintering waterfowl feces in Lake Paldang. The average number of individual birds that belonged to Anatidae species was 2,852.5 from 2005 to 2008 in Lake Paldang. The number of Anatidae reached 97.4% of the total number of individual birds. For evaluating the loading amounts of N and P by waterfowl to Lake Paldang, the feces dry weight (g/day) of each Anatidae species was estimated by multiplying the body weight of the each bird by 2.25% and assumed that N and P in feces contain 1.46% and 0.33%, respectively. We assigned probability 1/3 to the nutrient decomposition of the bird feces in water. The nitrogen loading by wintering waterfowl feces was 0.06 ton/year and the phosphorus loading was 0.001 ton/year. These amounts were 0.0002% of all N loadings and 0.0001% of all P loadings. Therefore the wintering waterfowl might have little impact on the water quality in terms of eutrophication in Lake Paldang.

• Journal of The Korean Society of Agricultural Engineers
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• v.46 no.2
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• pp.107-114
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• 2004

NPS pollutant loads from sandy clayey and clayey loam runoff plots were measured. Runoff plots were 2$\times$10 m in size and 8~10% in slope and paddy area was 4,620 $m^2$. Soybean, corn, tobacco and control (natural weed) were cultured. Precipitation during the growing season of June to October, 2002 was 869.5 mm. Runoff and water quality were measured more than 10 times during the measurements depending on the growing stage. Pollutants loads were estimated by using respective concentration and runoff volume. Runoff occurred when daily rainfall exceeded about 30 mm. The largest runoff was observed from the paddy but pollutant loads were larger from upland crops than those from paddy. SS loads from paddy and upland were 1.4 ton/ha/yr and 3.1~4.3 ton/ha/yr, respectively. COD loads 30 kg/ha/yr and 66~90 kg/ha/yr, T-N loads 13 kg/ha/yr and 14~23 kg/ha/yr, T-P loads 1 kg/ha/yr와 4 kg/ha/yr, nitrate nitrogen loads 1 kg/ha/yr and 4~8 kg/ha/yr, and phosphate phosphorus loads 0 kg/ha/yr and 4~6 kg/ha/yr, respectively. It was concluded that NPS pollutant loads from upland crop culture have greater impact on the quality of the receiving water body than those from paddy culture.

• Journal of Korean Society on Water Environment
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• v.24 no.4
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• pp.465-472
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• 2008

Soil and Water Assessment Tool (SWAT) model was selected as a tool for assessing the effect of pollutant sources on the total loads from the Chungju Dam upstream watershed. The model was constructed through calibration of parameters related to nitrogen (N) and phosphorus (P), which was based on the runoff and sediment modeling performed in the previous research. Using this, the spatial and temporal pollutant loadings by source type were investigated. Results of this study indicated that in most forested upstream sub-watersheds, pollutant loadings from point sources were very low, and total loadings by point and non-point sources were also insignificant. On the other hand, in #14 sub-watershed including Jecheon city, the loadings by point source were relatively considerable. For the whole watershed, non-point sources accounted for 99% of sediment, 97% of N, and 93% of P loads. And monthly non-point source loadings were concentrated on rainy summer season, while point source loadings of N and P kept nearly constant throughout the year and were high on dry winter season relative to non-point source.