• Title/Summary/Keyword: Nitrogen gradient

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How Much Do We Understand the Properties of Supernova Remnants in M81 and M82?

  • Sohn, Jubee;Lee, Myung Gyoon;Lee, Jong Hwan;Lim, Sungsoon;Jang, In Sung;Ko, Youkyung;Koo, Bon-Chul;Hwang, Narae;Kim, Sang Chul;Park, Byeong-Gon
    • The Bulletin of The Korean Astronomical Society
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    • v.40 no.1
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    • pp.47.1-47.1
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    • 2015
  • We present an optical spectroscopic study of 28 supernova remnant (SNR) candidates in M81 and two SNR candidates in M82. The optical spectra of these SNR candidates were obtained using the MMT/Hectospec as a part of the K-GMT Science Program. Based on the [S II]/$H{\alpha}$ ratio and the radial velocity, we find that twenty six out of the M81 candidates are genuine SNRs. Two SNR candidates in M82 are thought to be shocked condensations in the galactic outflow or SNRs. In the spectral line ratio diagrams, M81 SNRs are divided into two groups: an [O III]-strong group and an [O III]-weak group. The [O III]-weak SNRs have larger sizes, and may have faster shock velocity. We estimate the nitrogen and oxygen abundance of the SNRs from the comparison with shock-ionization models. We find a radial gradient in nitrogen abundance, $dLog(N/H)/dlogR=-0.023{\pm}0.009\;dex\;kpc^{-1}$ little evidence for the gradient in oxygen abundance. The nitrogen abundance shows shallower gradient than those of the planetary nebulae and H II regions of M81. We find five X-ray emitting SNRs. Their X-ray hardness colors are consistent with thermal SNRs.

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Analysis of Supercritical Shear Coaxial Jet Using Density Gradient Magnitude (밀도구배강도를 이용한 초임계 전단동축 제트 분석)

  • Lee, Keonwoong;Kim, Dohun;Son, Min;Han, Choyoung;Koo, Jaye
    • Journal of the Korean Society of Propulsion Engineers
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    • v.17 no.6
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    • pp.59-66
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    • 2013
  • Spray characteristics of single round jet with liquid nitrogen and coaxial spray with liquid nitrogen and gaseous argon were observed. Shadowgraph method was used for spray visualization, and density gradient magnitude image was used to analyse the result. In subcritical condition, irregularity of the jet surface was harder in the coaxial spray. In supercritical condition, diffusion of nitrogen injected from shear coaxial injector was faster than single jet. Jet diameter was induced by averaging images, in supercritical condition, difference of diameter of coaxial jet was rapidly decreased than that of single jet.

Two-Step Fed-Batch Culture of Recombinant Escherichia coli for Production of Bacillus licheniformis Maltogenic Amylase

  • Kim, Myoung-Dong;Lee, Woo-Jong;Park, Kwan-Hwa;Rhee, Ki-Hyeong;Seo, Jin-Ho
    • Journal of Microbiology and Biotechnology
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    • v.12 no.2
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    • pp.273-278
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    • 2002
  • Two-step fed-batch fermentations were carried out to overproduce Bacillus licheniformis maltogenic amylase (BLMA) in recombinant Escherichia coli. The first step was to increase the cell mass by controlling the feeding of a glucose solution, while the second step was designed to improve the amylase expression efficiency by supplementing organic nitrogen sources. The linear gradient feeding method was successfully adopted to maintain the glucose concentration below 0.2 g/l during the fed-batch mode, as effectively minimizing acetic acid formation. When the dissolved oxygen (DO) level became limiting, an accumulation of acetic acid and drastic decrease in specific BLMA productivity were observed. Glucose and organic nitrogen sources consisting of yeast extract and casein hydrolysate were simultaneously supplied in the pH-stat mode to further increase the specific BLMA expression efficiency. An organic nitrogen source consisting of 200 g/1 yeast extract and 100 g/1 casein hydrolysate was found to be the best among the various combinations tested. The feeding of an organic nitrogen source in the second-step fed-batch period was highly beneficial in enhancing the BLMA production. The optimized two-step fed-batch culture resulted in 78 g/l maximum dry cell mass and 443 U/ml maximum BLMA activity, corresponding to 1.5-fold increase in the dry cell mass and 3.7-fold enhancement in BLMA production, compared with the simple fed-batch fermentation.

CHEMICAL EVOLUTION OF THE GALAXY: RADIAL PROPERTIES

  • PARK BYEONG-GON;KANG YONG HEE;LEE SEE-WOO
    • Journal of The Korean Astronomical Society
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    • v.29 no.1
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    • pp.63-73
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    • 1996
  • The previous study of chemical evolution of the Galaxy is extended to the radial properties of the Galactic disk. The present model includes radial dependency of the time-dependent bimodal IMF, radial flow of material in the disk, and the change of type I supernova explosion rate with radial distance from the disk center as model parameters and observed gas and stellar density distributions and metallicity abundance gradient as observational constraints. The results of two models in this study explain the observed gas and stellar density distributions well, with the slope of the gas density gradient in the region of 4.5 kpc$Y_1$ and -0.123dex/kpc in model $Y_2$, respectively, which fit well the observed gradient of -0.l1dex/kpc. The abundance gradient reproduced in model $Y_1$ is getting flatter with decreasing radius, while that in model $Y_2$ is getting steeper, which fits better the observed abundance gradient. This result shows the necessity of exponentially increasing type I supernova explosion rate with decreasing radius in order to explain the observed abundance gradient in the disk. The fitness of observed density distribution and star formation rate distribution justifies the reliability of time-dependent bimodal IMF as a compound quantitative chemical evolution model of the Galaxy. The temporal variations of metallicity gradients for carbon, nitrogen and oxygen are also shown.

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Longitudinal and Vertical Variations of Long-term Water Quality along with Annual Patterns in Daecheong Reservoir

  • Lee, Sang-Jae;Shin, Jae-Ki;An, Kwang-Guk
    • Korean Journal of Ecology and Environment
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    • v.43 no.2
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    • pp.199-211
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    • 2010
  • The objectives for this study were to evaluate spatial and temporal characteristics of water quality, based on long-term water quality monitoring data during 1993~2008. We found that physico-chemical and ecological conditions in the Daecheong Reservoir (DR) were modified by the construction of upper dam (i.e., Yongdam Reservoir). total phosphorus (TP), Secchi depth (SD), and chlorophyll-a (CHL) in the DR showed significant longitudinal decreases along the headwater-to-the downlake, indicating a large spatial variation, and this gradient was more intensified during the high-flow season (monsoon). Nutrient-rich water containing high nitrogen and phosphorus in the monsoon season (July~August) passed through the reservoir as a density current in the metalimnetic depth, and also high suspended solids increased in the metalimnetic depth, especially during the monsoon. According to the deviation analysis of Trophic State Index (TSI), >50% of TSI (CHL)-TSI (SD) and TSI (CHL)-TSI (TP) values were negatives, so that inorganic suspended solids (non-votatile solids) influenced the underwater light regime against phytoplankton growth. Also, ratios of CHL:TP after the dam construction evidently increased, compared to the values before the upper dam constructions, indicating a greater yield of phytoplankton in the unit phosphorus. Overall data showed that ecological and functional changes in Daecheong Reservoir occurred after the construction of upper dam (Yongdam Reservoir).

Dyamics of Plant Communities under Human Impact in the Green-Belt nearby Seoul -Structure of Forest Communities and Secondary Succession- (인간간섭하의 수도권 그린벨트 내 식물군집의 동태 - 삼림군집의 구조와 이차천이 -)

  • Kim, Joon-Ho;Yoonsoon Kang;Lee, Sueng-Woo;Cho, Kang-Hyun;Kim, Yongtaek;Saheon Ha;Min, Byeung-Mee
    • The Korean Journal of Ecology
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    • v.12 no.4
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    • pp.209-218
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    • 1989
  • In order to elucidate the relationship among the several forest types in the green-sbelt nearby Seoul, the vascular plant species data collected preferentially from 52 stands were subjected to DCA (detrended correspondence analysis). Eight types of forests were arranged on the I/II plane fo DCA stand ordination, Quercus mongolica, Alnus hirsuta, Populus alba $\times$ glandulosa, Robinia pseudo-acacia, Pinus densiflora, Pinus koraiensis, Larix leptolepis and pinus rigida forest. Correlation analysis between the stand scores of DCA and environmental factors revealed that the axis I of DCA stand ordination implied the gradient of altitude, organic matter, total nitrogen and depth of A horizon. The axis II implied the gradient of total nitrogen and soluble phosphorus. The results of PCA (principal components analysis) by environmental data were in good agreement with that of DCA by floristic data. The recruitments of Quercus spp. Occurred in all kinds of forest types in the green-belt and their recruitments were closely related with altitutde: Quercus dentata in the foot. Quercus serrata in the midslope and Quercus mongolica in the uperslope of the mountain.

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Ab-inito and NMR Studies on the Rotational Barrier for Thioacetamide and Acetamide

  • 최영기;송근일;최영상;윤창주
    • Bulletin of the Korean Chemical Society
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    • v.18 no.10
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    • pp.1094-1099
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    • 1997
  • The rotational barriers of thioacetamide (TA) and acetamide (AA) were studied using the ab-initio molecular orbital theory and NMR spectroscopy. The calculated rotational barriers using MP2/6-31G**//MP2/6-31G** for TA was 72.26 kJ/mol and 58.19 kJ/mol for AA, respectively. These results are good agreement with the experimental data. The tendency for the change of structural parameters is consistent with the result of formamide. In both amides, the rotational barrier arises from the pyramidalization of nitrogen. The chemical shifts of both amides are shifted upfield when temperature is raised, which confirms pyramidalization of nitrogen. The lineshape of 1H-NMR spectra of TA shows quintet which is contributed from two triplet spectra. This means that the distribution of electrons around the nitrogen is rather symmetric. Ab-initio calculations of electric field gradient for both amides confirm the above results. The above experimental results are well understood by Keith's view on thioamides, which excludes the contribution of resonance structure and considers the origin of rotational barrier to be the same in both thioamides and in corresponding amides.

Nutrient Variations in the Jindong Bay during Summer by Ecosystem Modeling (해양생태계모델에 의한 하계 진동만의 영양염변동)

  • 김동선;홍철훈
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.8 no.2
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    • pp.164-176
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    • 2003
  • During summer, the DIN (dissolved inorganic nitrogen) and DIP (dissolved inorganic phosphate) observed in the Jindong Bay in the southern sea of Korea show much higher values in the inner area of the bay. In general, they have high values in the upper (0-1 m) and lower layers (8 m-bottom), but are relatively lower in the middle layer (1-8 m). These features in their distribution are examined using an ecosystem model with considering the wind, tidal current, horizontal gradient of water density and residual flow. The experiments were focused on how to influence nutrients associated with these conditions. In the experiment with tide-induced residual flow, the values of nutrients appeared lower than the observation, and were well corresponded to it when the effects of wind, tide-induced residual current and horizontal gradient of water density were additionally imposed. A statistical analysis identifies these results. This paper suggests that variation of nutrient in the Jindong Bay during summer should be seriously a(footed wind-driven current by the wind and density-driven current is induced by the horizontal gradient of water density as well as tidal current.

The Electrical Breakdown Characterization of Gas Discharge Tube using Brass Electrode for Surge Protector (과전압 보호용 황동전극 기체방전관의 절연파괴 특성)

  • Kim, Min Il;Jeong, Euigyung;Lee, Sei-Hyun;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.21 no.2
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    • pp.205-210
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    • 2010
  • In this study, a brass electrode gas discharge tube (GDT) was prepared to investigate its discharge characterization, which affects surge protection efficiency and lifetime of GDT. Discharge characterization of GDT using a brass electrode was investigated by changing applied voltage gradient and nitrogen gas pressure inside the GDT. As applied voltage gradient in GDT increased, electrical breakdown voltage and threshold energy largely increased and electrical breakdown time delay decreased. It was found that electrical breakdown voltage, electrical breakdown time delay, and threshold energy were largely decreased with decreasing the nitrogen gas pressure in GDT. As a result, electrical breakdown voltage, electrical breakdown time delay, threshold energy needed to be decreased to increase surge protection efficiency and lifetime. It was also found that the nitrogen gas pressure of GDT influenced strongly the performances as well as life span of it.

Effect of Coflow Air Velocity on Heat-loss-induced Self-excitation in Laminar Lifted Propane Coflow-Jet Flames Diluted with Nitrogen (질소로 희석된 프로판 동축류 층류 제트 부상화염에서 열손실에 의한 자기진동에 대한 동축류 속도 효과)

  • Lee, Won-June;Yoon, Sung-Hwan;Park, Jeong;Kwon, Oh-Boong;Park, Jong-Ho;Kim, Tae-Hyung
    • Journal of the Korean Society of Combustion
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    • v.17 no.1
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    • pp.48-57
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    • 2012
  • Laminar lifted propane coflow-jet flames diluted with nitrogen were experimentally investigated to determine heat-loss-related self-excitation regimes in the flame stability map and elucidate the individual flame characteristics. There exists a critical lift-off height over which flame-stabilizing effect becomes minor, thereby causing a normal heat-loss-induced self-excitation with O(0.01 Hz). Air-coflowing can suppress the normal heat-loss-induced self-excitation through increase of a Peclet number; meanwhile it can enhance the normal heat-lossinduced self-excitation through reducing fuel concentration gradient and thereby decreasing the reaction rate of trailing diffusion flame. Below the critical lift-off height. the effect of flame stabilization is superior, leading to a coflow-modulated heat-loss-induced self-excitation with O(0.001 Hz). Over the critical lift-off height, the effect of reducing fuel concentration gradient is pronounced, so that the normal heat-loss-induced self-excitation is restored. A newly found prompt self-excitation, observed prior to a heat-loss-induced flame blowout, is discussed. Heat-loss-related self-excitations, obtained laminar lifted propane coflow-jet flames diluted with nitrogen, were characterized by the functional dependency of Strouhal number on related parameters. The critical lift-off height was also reasonably characterized by Peclet number and fuel mole fraction.