• Title/Summary/Keyword: Nitrogen efficiency

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Combustion of Diesel Particulate Matters under Mixed Catalyst System of Fuel-Borne Catalyst and Perovskite: Influence of Composition of Perovskite (La1-x A'xBO3: A' = K, Sr; 0 ≤ x ≤ 1; B = Fe, Cr, Mn) on Combustion Activity (Fuel-Borne Catalyst와 Perovskite로 구성된 복합촉매 시스템에 의한 디젤 탄소입자상 물질의 연소반응: 반응성능과 Perovskite 촉매조성 (La1-x A'xBO3: A' = K, Sr; 0 ≤ x ≤ 1; B = Fe, Cr, Mn)의 상관관계)

  • Lee, Dae-Won;Sung, Ju Young;Lee, Kwan-Young
    • Korean Chemical Engineering Research
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    • v.56 no.2
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    • pp.281-290
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    • 2018
  • As the internal combustion engine vehicles of high fuel efficiency and low emission are demanded, it becomes important to procure technologies for improving low-temperature performance of automotive catalyst systems. In this study, we showed that the combustion rate of diesel particulate matter is greatly enhanced at low temperature by applying fuel-borne catalyst and perovskite catalyst concurrently. It was tried to examine the correlation between elemental composition of perovskite catalyst and combustion activity of mixed catalyst system. To achieve this goal, we applied temperature-programmed oxidation technique in testing the combustion behavior of perovskite-mixed particulate matter bed which contained the element of fuel-borne catalyst or not. We tried to explain the synergetic action of two catalyst components by comparing the trends of concentrations of carbon dioxide and nitrogen oxide in temperature-programmed oxidation results.

Characteristics of Air Stripping for Recycling of Ammonia in Aqueous Solutions (수용액중 암모니아 Recycling을 위한 Air Stripping 특성에 관한 연구)

  • Lee Hwa-Yaung;Oh Jong-Kee;Kim Sung-Gyu
    • Resources Recycling
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    • v.12 no.3
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    • pp.31-37
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    • 2003
  • A study on the characteristics of ammonia desorption from aqueous solutions has been performed by air stripping as the first stage of ammonia recycling for the preparation of ammonium sulfate from it. For air stripping experiments, a stripping column made with acrylic tube of 40 mm diameter was employed and compressed air was injected into solutions through air sparger equipped at the bottom of stripping column. As a result of experiments, the stripping efficiency was increased with the aqueous pH and it was found that the appropriate pH for air stripping of ammonia was between pH 10 and 12. As far as the effect of air flow rate on ammonia stripping was concerned, ammonia stripping was not proportional to the air flow rate although it was affected by the air flow rate to some extent. Moreover, when more than 20 cm of water height was maintained, total ammonia desorbed from solution was not varied with the water height. Stripping temperature was also found to play an important role in ammonia desorption and about 90fo of initial ammonia was desorbed in 14 hours at pH 12.8 and at $60^{\circ}C$ Finally, it was believed that stripping temperature as well as the aqueous pH was one of the most important factors in air stripping of ammonia.

Effect of Scoria, Quartz Porphyry and Oak Charcoal Powder Feeding on the Meat Quantity and Quality of Fattening Cross Bred Hanwoo Bulls (점토광물 급여가 한우교잡우의 산육능력 및 육질에 미치는 영향)

  • 강수원;손용석;박남건;진신흠;고서봉
    • Journal of Animal Environmental Science
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    • v.5 no.3
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    • pp.157-170
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    • 1999
  • This study was conducted to investigate the effects of Scoria, Quartz porphyry and Oak charcoal powder feeding by 1% level of concentrate on the fattening cross bred bulls(5/8 Korean Native Cattle, 2/8 Charolais, 1/8 Brahman germ plasma) Feeding trial was conducted with 4 treatment groups which were T1(Full feeding of concentrate and roughage for 12 months), T2(T1 and Scoria addition), T3(T1 and Quartz porphyry addition) and T4(Oak charcoal addition) for 360 days, consisting of 32 heads whose initially weights were about 299.7kg. The results obtained are summarized as follows; 1. During the over-all period, average daily gains by T3, T4, T2 and T1 were 1.024, 0.987, 0.977kg and 0.964, respectively, without a significant difference by treatments. 2. Concentrate intakes per body weight and TDN intakes required per unit of kilogram gain were lower in addition agent groups than in control, and in all the treatments feed efficiency was higher at early stage for 360 fattening day than at end stage. 3. Carcass weight, dressing percent, back-fat thickness and loin eye muscle area by treatments were 330.9 to 348.4kg(average 340.3kg), 55.2~56.2(average 55.8%), 0.41~0.55(average 0.46cm)and 76.0~80.9$\textrm{cm}^2$(average 77.6$\textrm{cm}^2$), respectively, and were improved in addition agent groups than in control. 4. Meat quality grade is higher in addition agent groups than in control, and heads of 1st grade by treatments was 3, 2, 1 and none in T4, T2, T3 and T1, respectively. 5. Incidence heads of diseases by treatment were not apparently different, but diseases of digestive system was decreased in addition agent groups than in control. 6. The nitrate nitrogen content of fattening bull dung which collected in rectum were 0.082~0.089% (average 0.084%), and the content in addition agent groups was smaller than in controll. 7. Income was higher in order of T4, T3, T2, and T1 and incomes of treatment groups were grater than that of control group by 21.4 to 33.5 percent. According to the above results it may be concluded that fattening bulls may be required to feed no more than 1% of Scoria, Quartz porphyry and Oak charcoal powder based on the concentrate feeding level during the fattening period(12 to 24 month of age) to produce high quality meat and increase income.

경사도별 3요소 시용수준이 겉뿌림 산지초지에 미치는 영향 I. 총건물수량 , 수량구성요소 및 식생구성비율의 변화 ( Effects of Nitrogen , Phosphorus and Potassium Application Rates on Oversown Hilly Pasture under Different Levels of Inclination I. Changes in th

  • 정연규;이종열
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.5 no.3
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    • pp.191-195
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    • 1985
  • This field experiment was undertaken to assess the effects of three levels of inclination ($10^{\circ},\;20^{\circ},\;and\;30^{\circ}$) and four rates of $N-P_2O_2-K_2O$ (O-O-O, 14-10-20, 28-25-25, and 42-40-40kg/10a) on establishment, forage yield and quality and botanical composition of new established mixed grass-clover sward. This first part is concerned with the forage yield, yield component and botanical composition. The results obtained after a two-year experiment are summarized as follows: 1. Dry matter yields of mixed grass-clover sward were greatly decreased by increasing the inclination grade of hilly pasture, whereas it of weeds was not significantly influenced. Comparing with weeds, the establishment of introduced pastures was relatively low with increasing the grade of inclination. 2. By increasing the NPK rate, the yields of grasses and mixed forages and the rate of introduced pastures were greatly increased at all grades of inclination, whereas the change in the weed yield was not significant. 3. There were the differenced in the forage yield and yield component, and efficiency of fertilizers by the grade of inclination, which indicated the necessity of different management on the selection of suitable grass species, seeding rate, amount of fertilizer application, and the methods of grassland establishment, management and utilization.

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Effects of Dietary Mugwort on the Performance and Meat Quality of Hanwoo Steers during Refrigerated Storage (쑥 사료를 급여한 거세 한우의 생산성과 냉장 저장 중 육질에 미치는 영향)

  • Kim, Byung-Ki;Choi, Chang-Bon;Kim, Young-Jik
    • Food Science of Animal Resources
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    • v.29 no.3
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    • pp.340-348
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    • 2009
  • A total of fifty Hanwoo steers raised from 14 to 29 months were used to investigated the effects of dietary mugwort on the performance and meat quality during refrigerated storage. A feeding trial was tested for 14.7 months and experimental diets included 0 and 2% dried wild mugwort. Total weight gain and average daily gain in this study were significantly higher in mugwort treatment than control treatment. Feed efficiency was improved by mugwort treatment compared with control treatment. Any difference in GOT (glutamic oxaloacetic transaminase), GPT (glutamic pyrubic transaminase), and BUN (blood urea nitrogen) was not observed between groups. Carcass weight and longissimus muscle area were higher for mugwort treatment than control. As fattening increased, total cholesterol in blood increased. Total cholesterol in blood tended to be lower in mugwort treatment than control treatment (p<0.05). The heating loss, $L^*$, $a^*$, $b^*$, chroma, and hue unit of all treatments were not affected treatment, but showed a significant decrease in all treatments during refrigerated storage. For fatty acid composition in longissimus muscle, dietary mugwort supplementation increased unsaturated fatty acid than saturated fatty acid (p<0.05). Based on these findings, it is obvious that supplementation of mugwort at 2% level will be useful to decrease cholesterol, increase unsaturated fatty acid, and improve growth performance of Hanwoo steers.

Studies on the Nutritional Quality of Rapeseed Protein Isolates (평지(平地)씨 단백질(蛋白質)의 영양가(營養價)에 관(關)한 연구(硏究))

  • Yang, Chang-Il
    • Korean Journal of Food Science and Technology
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    • v.12 no.2
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    • pp.109-114
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    • 1980
  • Protein efficiency ratio (PER), net protein utilization (NPU), nitrogen digestibility (ND), organ weights, and amino acid composition were investigated for rapeseed protein isolates (RPI) prepared by alkaline countercurrent extraction and isoelectric precipitation of defatted rapeseed meal (DRM). The PER values for 3 kinds of RPI obtained at pI of 6.7, 5.6 and 5.0 were 2.8, 3.1 and 2.9, and for DRM 2.5 while the NPU values for these RPI appeared to be 68, 73 and 71 %, and for DRM 56 %, respectively. Mean ND (85%), food intake (87), and weight gain (37.6) for RPI were significantly different from those of DRM (71 %, 77, and 28, respectively). There was no signicant difference in the PER among three RPI and casein (3.0), nor in the NPU among those proteins and casein (74%). These data attributed to the favorable amino acid patterns of proteins isolated which contained balanced essential amino acids in proportions which meet the requirements of human adult(FAO/WHO, 1973).

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Effects of PCBs (Polychlorinated Biphenyls) on Energy Budget in Mysid, Neomysis awatschensis II. Effects of PCBs on Energy Budget in Mysid, Neomysis awatschensis (곤쟁이, Neomysis awatschensis의 에너지수지에 미치는 PCBs의 영향 II. 에너지수지에 미치는 PCBs의 영향)

  • CHIN Pyung;SHIN Yun-Kyung;JEON Eun-Mi
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.31 no.1
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    • pp.104-108
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    • 1998
  • Analysis of energy budget in Neomysis awatschensis exposed to PCB toxicity was carried out by measurement of bioassay, growth, oxygen consumption, nitrogen excretion at 10 and $20^{\circ}C$. Energy contents of the body, molted exoskeleton and eggs, which measured to understand used energy for growth, molt and oxygen consumption were 5.52cal/mg, 2.17 cal/mg and 6.15 cal/mg, respectively. Feeding energies at $10^{\circ}C$ were 3.755ca1 in control group and 3.420 cal at 2.0 ppb concentration, of them, $70.19\%$ and $67.53\%$ of their energies were assimilated. At $20^{\circ}C$, feeding energies were 5.998 cal in control group and 4.166 cal at 2.0 ppb concentration. The assimilation efficiency of the mysid estimated by ash-ratio method ranged between $11.5\~67.5\%$ and $73.4\~70.5\%$ with PCB toxicity at $10^{\circ}C$ and $20^{\circ}C$ respectively. Energy used by respiration of total assimilated energy was $45.18\%$ in control group and $62.27\%$ in 2.0 pub concentration at $20^{\circ}C$, and energy used by metabolism was high 2.0 ppb concentration than control group.

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A Study of the Removal Characteristics of Heavy Metal(loid)s using by Product from NoMix Toilet and its Characterization (NoMix toilet 에서 발생하는 부산물을 이용한 수용액내 (준)중금속 제거 특성 및 가능성 연구)

  • Shim, Jaehong;Lim, Jeong-Muk;Kim, Jin-Won;Kim, Hae-Won;Oh, Byung-Taek
    • Journal of Soil and Groundwater Environment
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    • v.21 no.1
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    • pp.28-39
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    • 2016
  • Struvite (MgNH4PO4 ⋅ 6H2O) and hydroxyapatite (HAP, Ca10(PO4)6(OH)2) precipitation in urine-separating toilets (NoMix toilets) causes severe maintenance problems and also reduce the phosphate and calcium content. Application of urine separating technique and extraction of by-products from human urine is a cost effective technique in waste water treatment. In this study, we extract urine calcite from human urine by batch scale method, using urease producing microbes to trigger the precipitation and calcite formation process. Extracted urine calcite (calcining at 800℃) is a potential adsorbent for removal of heavy metal(loid)s like (Cd2+, Cu2+, Ni2+, Pb2+, Zn2+ and As3+) along with additional leaching analysis of total nitrogen (T-N), phosphate (T-P) and chemical oxygen demand (COD). The transformations of calcite during synthesis were confirm by characterization using XRD, SEM-EDAX and FT-IR techniques. In additional, the phosphate leaching potential and adsorbate (nitrate) efficiency in aqueous solution was investigated using the calcinedurine calcite. The results indicate that the calcite was effectively remove heavy metal(loid)s lead up to 96.8%. In addition, the adsorption capacity (qe) of calcite was calculated and it was found to be 203.64 Pb, 110.96 Cd, 96.02 Zn, 104.2 As, 149.54 Cu and 162.68 Ni mg/g, respectively. Hence, we suggest that the calcite obtain from the human urine will be a suitable absorbent for heavy metal(loid)s removal from aqueous solution.

A Study on the Treatment of Pickled Radish Wastewater Using Surface-modified Membrane (표면개질 분리막을 이용한 단무지폐수 처리에 관한 연구)

  • Seon, Yong-Ho
    • Journal of the Korea Organic Resources Recycling Association
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    • v.19 no.1
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    • pp.64-78
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    • 2011
  • Surface of hydrophobic polyethylene membrane was modified to become hydrophilic by ion beam irradiation. Submerged membrane filtration reactors contained pristine membrane or surface-modified membrane and the influent to reactors was pickled radish wastewater. The objectives of this study was to investigate the variation of flux and pressure and the characteristics of pollutant removal such as organics, suspended solids and nutrients with time. The result of experiments using intermittent pristine membrane showed the occurrence of severe fouling by increasing permeate pressure rapidly in case of pickled radish wastewater but in synthetic wastewater, this phenomenon was not occurred. In experiments of variation flux after chemical cleaning and water cleaning in pristine membrane, chemical cleaning must be necessary for renewals of pollutant membrane. Performance of intermittent operation is higher than that of continuous operation. Reaching fouling time in the case of surface-modified membrane is 6 times as long as pristine membrane. According this reason, replacement expense of surface-modified membrane could be 1/6 of that of pristine membrane. Effluent from this process was relatively good water quality and performance in the removal efficiency of SS, nitrogen and phosphorus was particularly higher.

The Study of Reaction Characteristics of V/W/TiO2 Catalyst Using Se-TiO2 Support On NH3-SCR Reaction (Se-TiO2 지지체를 이용한 V/W/TiO2 NH3-SCR 촉매의 반응 특성 연구)

  • Lee, Yeon Jin;Won, Jong Min;Ahn, Suk Hyun;Hong, Sung Chang
    • Applied Chemistry for Engineering
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    • v.32 no.6
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    • pp.599-606
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    • 2021
  • In this study, an experiment and a reaction characteristic study were conducted to enhance the reaction activity of V2O5/WO3/TiO2 at 300 ℃ or less by adding selenium to the support, in a selective catalytic reduction method using ammonia as a reducing agent to remove nitrogen oxides. Se-TiO2 and TiO2 were synthesized using the sol-gel method, and used as a support when preparing V2O5/WO3/TiO2 and V2O5/WO3/Se-TiO2 catalysts. The reaction activity of our catalyst was compared with that of a commercial catalyst. The denitration efficiency of the catalyst using TiO2 prepared by the sol-gel method was lower than that of the catalyst prepared using commercial TiO2, but was improved by the addition of selenium. Thus, the effect of selenium addition on the catalyst structure was analyzed using BET, XRD, Raman, H2-TPR, and FT-IR measurements and the effect of the increase in specific surface area by selenium addition and the formation of monomer and complex vanadium species on reaction characteristics were confirmed.