• Transactions on Electrical and Electronic Materials
• /
• 제2권3호
• /
• pp.1-6
• /
• 2001

A simulation method is proposed to study the amorphous structure of carbon nitride. The material properties of a non-uniform nitrogen distribution in an amorphous CN matrix can be studied. The cohesive energy of a group of randomly generated atoms can be minimized to find the relative positions of atoms. From the calculated configuration of atoms, many properties of amorphous carbon nitride can be calculated such as bulk modulus, P-V curve, sp$^3$/sp$^2$ ratio of carbon, and vibrational spectra. The calculation shows that the cohesive energy of non-uniform nitrogen distribution is lower than that of a uniform distribution. This may suggest that the regular structure of carbon nitride can at most be metastable. It is not easy to incorporate nitrogen atoms into a carbon matrix.

• 한국소성가공학회:학술대회논문집
• /
• 한국소성가공학회 2003년도 춘계학술대회논문집
• /
• pp.49-52
• /
• 2003

The effects of nitrogen on the deformation behavior of duplex stainless steel have been studied The variation of strength was correlated with the characteristic microstructures. Analysis based on Hall-Petch relation confirmed that nitrogen enhances phase-boundary strengthening effect. The evolution of dislocation structure, slip traces, and misorientation distribution during deformation were also characterized to elucidate the effect of nitrogen on inelastic deformation mechanism.

• 소성∙가공
• /
• 제12권4호
• /
• pp.284-289
• /
• 2003

The effects of nitrogen on the deformation behavior of duplex stainless steel have been studied. The variation of strength was correlated with the characteristic microstructures pertaining to nitrogen. Analysis based on Hall-fetch relation confirmed that nitrogen enhances phase-boundary strengthening effect. The evolution of dislocation structure, slip traces and misorientation distribution during deformation were also characterized to elucidate the effect of nitrogen on inelastic deformation mechanism. It has been verified in this study that the higher nitrogen content provides a dual-phase microstructure with smaller strength difference between austenite and ferrite resulting into the earlier transfer of inelastic deformation from austenite to ferrite.

• 한국정밀공학회지
• /
• 제25권7호
• /
• pp.124-130
• /
• 2008

The effect of nitrogen gas pressure in arc ion plating on surface properties of the TiN-coated high speed steel(SKH51) is presented in this paper. The surface roughness, micro-particle, micro-hardness, coated thickness, atomic distribution of TiN, and adhesion strength are measured fur various nitrogen gas pressures. It has been shown that the nitrogen gas pressure has a considerable effect on the surface roughness, adhesion strength, atomic distribution of TiN, and surface deposition of TiN of the high speed steels but that it has little influence on the micro-hardness and coated thickness.

• 한국환경과학회지
• /
• 제11권12호
• /
• pp.1243-1252
• /
• 2002

This paper aims to find the characteristics of concentration distribution of coastal urban air pollutants. For this purpose, It was used the daily meteorological data and the hourly concentration data for $O_3$and NO$_2$ in Busan metropolitan city from 1994 to 1996. It was investigated the annual and monthly distribution of ozone and nitrogen dioxide concentration at each site in Busan, and also investigated the characteristics of concentration change of air pollutants with time under the sea breeze. As a results, the concentration of nitrogen dioxide and ozone tend to be increased every year and nitrogen dioxide concentration is higher than ozone concentration at all sites in Busan. The concentration of ozone is high in summer season and low in winter season, but the concentration of nitrogen dioxide have a reversed trend. The monthly peak concentration of ozone occurred in April and September, while the monthly minimum concentration of nitrogen dioxide occurred in August. Their trend were identified by sites near the coastline than sites stands apart from the coastline. The sea breeze occurred annual mean 81 day in Busan from 1994 to 1996. The main wind direction of sea breeze was classified into southwesterly and southeasterly. In case of southwesterly, It was pronounced the south wind and southwest wind. In case of southeasterly, the occurrence frequency of east wind was high. Especially, the concentrations of urban air pollutants, such as ozone and nitrogen dioxide, were high on time which the sea breeze flow, and the areas that ozone concentration was high moved from outside part to central part of city with time. In costal urban such as Busan, the wind direction of sea breeze is influenced the change of ozone and nitrogen dioxide concentration on time which the sea breeze flow at each site and also influenced the change of air pollutants concentration of sites on the pathway of sea breeze.

• 한국대기환경학회지
• /
• 제2권1호
• /
• pp.33-39
• /
• 1986

Particulate matter was collected by Andersen Air Sampler in the Seoul area during February-October, 1985, in order to investigate size distribution of sulfate and nitrate in aerosol, and conversion of sulfur dioxide to sulfate and that of nitrogen dioxide to nitrate. The size distribution of sulfate and nitrate had fine mode. The ratio of fine sulfate to total sulfate in aerosol and that of fine nitrate to total nitrate showed between 54.6% and 86%, and 55.7% and 95%, respectively, which presumably originated from gaseous reaction of sulfur dioxide and nitrogen dioxide in the atmosphere.

• Journal of Plant Biology
• /
• 제18권3호
• /
• pp.101-108
• /
• 1975

The nitrogen economy and primary production of a Helianthus annuus "Manchurian" population were studied with special reference to the pattern of seasonal changes of vertical distributions of dry matter and nitrogen quantities, and its quantitative significance was discussed in relation to the pattern of the plant population growth, distribution ratios among organs, and turnover rates of dry matter and nitrogen. The population was established in plant density of 11.1plant/$m^2$ at the experimdntal field of Kyungpook National University, Daegu. During the period of population developemnt (April-September, 1973), the annual inflow rates and outflow rates of dry matter and nitrogen were 5560 gDM/$m^2$/year and 89 gN/$m^2$/year, respectively. The distribution ratios of dry matter and nitrogen to leaves were 28% and 45%, to stems 48% and 18%, to roots 13% and 5%, and to flowers and seeds 11% and 32%, respectively. The maximum turnover rates of inflow of dry matter and nitrogen were attained in May-June, and were 216%/month and 210%/month, respectively. The amount of nitrogen demand was 52gN/$m^2$/year (58%) for the foliage growth, 13 gN/$m^2$/year(15%) for the stem growth, 20 gN/$m^2$/year(23%) for the reproductive organs, and 4 gN/$m^2$/year(4%) for the growth of the underground parts. The amount of nitrogen supply by the nitrogen withdrawn from senescing leaves and stems was 25gN/$m^2$/year(28%) and the amount of nitrogen absorption by the root from the environmental soil was 64 gN/$m^2$/year(72%). The ratiio of the a mount of produced dry matter to that of assimilated nitrogen during a year was calculated for this annual plant population as 60, which can be used as the nitrogen utility index.ity index.

• 한국초지조사료학회지
• /
• 제10권3호
• /
• pp.158-163
• /
• 1990

This experiment was to study the effect of pure mineral nitrogen fertilizing on seasonal distribution of dry matter yield and the advisable mineral nitrogen amounts on grassland. The results were as follows: 1. With longer regrowth periods the absolute dry matter yields and the nitrogen-efficiences due to nitrogen fertilizing increased substantially, whereas the quality declined at the relatively lesser cutting frequencies. 2. The first cut at 3-cut regimes, the first and fourth cut at 4-cut regimes, and the second and last cut at 5-and 6-cut regimes showed the highest nitrogen-efficiency, respectively. 3. By the sigmaformed process of production curve the most efficient mineral N-dressing rate per ha and cut was calculated: 42-56kg N on the 3-cut areas, 39-55kg N on the 4-cut areas, 38-47kg N on the 5-cut areas and 35-48kg N/ha/cut on the &cut areas. 4. In dependence on site and kind of calculation the economical borders were reached with the following dressings of mineral N/ha/cut: 90-100kg on the 3-cut areas, 70-100kg on the 4-cut areas and 50- 90kg on the 5-and 6-cut areas.

• 한국해양환경ㆍ에너지학회지
• /
• 제17권2호
• /
• pp.90-103
• /
• 2014

2011년 9월에 동해의 수괴 분포와 용존 무기 및 유기 영양염의 분포 특성을 파악하였다. 수온, 염분, 용존산소의 분포를 통하여 연구해역의 수괴 기원은 WM(water mass)-I, WM-II, WM-III, WM-IV 등 4개의 대표적인 수괴로 구분되었으며, 그 성격은 각각 대마난류표층수, 대마난류중층수, 북한한류수, 동해고유수와 유사하였다. 용존 영양염의 경우, 용존 무기 질소(DIN; dissolved inorganic nitrogen)와 용존 무기 인(DIP; dissolved inorganic phosphorus)은 WM-IV에서 가장 높았으며, WM-III, WM-II, WM-I 순으로 나타났다. 반면에 용존 유기 질소(DON; dissolved organic nitrogen)와 용존 유기 인(DOP; dissolved organic phosphorus)은 무기 영양염과 상반되는 분포를 보였다. 연구해역에서 수괴 전체에 대한 DIN : DIP 비는 약 15.8로 Redfield ratio(16)에 근접한 수치를 보이고 있으나, 혼합층의 경우 5.3으로 무기질소가 식물플랑크톤 성장의 제한 요인으로 작용할 수 있는 것으로 보였다. 하지만 무기 질소가 제한된 혼합층에서 DON은 용존 총 질소(DTN; dissolved total nitrogen) 중 약 70%를 구성하였다. 따라서 풍부한 DON은 동해에서 식물플랑크톤의 성장을 위한 중요한 영양염 공급원으로 판단된다.

• Computers and Concrete
• /
• 제11권4호
• /
• pp.317-336
• /
• 2013

In this study, the pore structure of Portland cement paste is experimentally characterized by MIP (mercury intrusion porosimetry) and nitrogen adsorption, and simulated by a newly developed status-oriented computer model. Cement pastes with w/c=0.3, 0.4 and 0.5 at ages from 1 day to 120 days are comprehensively investigated. It is found that MIP cannot generate valid pore size distribution curves for cement paste. Nevertheless, nitrogen adsorption can give much more realistic pore size distribution curves of small capillary pores, and these curves follow the same distribution mode. While, large capillary pores can be effectively characterized by the newly developed computer model, and the validity of this model has been proved by BSE imaging plus image analysis. Based on the experimental findings and numerical simulation, a hypothesis is proposed to explain the formation mechanism of the capillary pore system, and the realistic representation of the pore structure of hydrated cement paste is established.