• Title/Summary/Keyword: Nitrogen degradation ratio

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Prediction of Chlorophyll-a Changes due to Weir Constructions in the Nakdong River Using EFDC-WASP Modelling

  • Seo, Dong-Il;Kim, Min-Ae;Ahn, Jong-Ho
    • Environmental Engineering Research
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    • v.17 no.2
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    • pp.95-102
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    • 2012
  • To evaluate the effect of the 4 major rivers restoration project in the Nakdong River to water quality of the river, the Environmental Fluid Dynamics Code (EFDC) and Water Quality Analysis Simulation Program (WASP), are applied in series. Results showed overall decrease in biochemical oxygen demand ($BOD_5$) concentrations and increase in chlorophyll-a concentrations, while total nitrogen and total phosphorous concentrations did not show significant changes, relatively. Decrease in $BOD_5$ concentrations seems to be influenced by an increased hydraulic residence time, which may allow more time for the degradation of organic material. Changes in Chlorophyll-a (Chl-a) concentration, due to the project were more significant for the upper stream areas that show relatively low Chl-a concentration ranges (less than 20 g/L). After the introduction of the Geumho River in the middle part of the Nakdong River, rapid growth of phytoplankton was observed. However, in this middle part of the Nakdong River, the ratio of Chl-a concentration change are less significant, compared to the upper stream areas, due to the project. In the lower stream area, Chl-a concentration decreased after the project. This seems to be resulted from the decreased light availability, due to increased depth, while the nutrient concentrations have been high enough to support phytoplankton growth.

벙커-C유 분해미생물의 선발 및 현장 생리적용성 검정

  • Park, Jin-Hui;Kim, Yeong-Sik;Lee, Tae-Jin
    • 한국생물공학회:학술대회논문집
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    • 2003.04a
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    • pp.600-604
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    • 2003
  • This study pointed at isolation of bunker-C oil degrading bacteria and then estimation of it's degrading capability in environmental conditions. Degradation ratio of the excellent isolate was appeared to 40.5% and 44.7% when the oil was treated to 1% and 5%, respectively. The isolate was identified to Acinetobater calcoaceticus SEBCM. In pH test, high degrading effect was appeared to about 73% at pH 6 and pH 7, and low degrading ratio was 37% at pH 4. Its growth condition at temperature has not large variation in $15^{\circ}C\;{\sim}30^{\circ}C$, Quantity of nitrogen for it's good growth was ranged of $0.5\;g/L{\sim}2\;g/L$. As these results, we realized that this isolate have good activity when treated to $15\;{\sim}30^{\circ}C$ of temperature and $6{\sim}7$ of pH.

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Release of Organic Matter and Behavior of Nitrogen in the Degradation of Sewage Sludge Using Ultrasound (초음파를 이용한 하수 슬러지 분해에서 유기물 방출과 질소 거동)

  • Yoon, Yong-Soo;Kang, Gwang-Nam;Choi, Suk-Soon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.10 no.4
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    • pp.75-80
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    • 2002
  • The sewage sludge with concentrated MLSS, ranging from 5967 to 8400mg/L was degraded by ultrasound. In this study, ultrasound treatment was used to investigate the behavior characterization of SBOD, sludge biodegradation, C/N ratio, TN, turbidity and sludge morphology. From the experimental results of C/N ratio change and TN removal, the optimal irradiation time was found to be 10 minutes. The results showed the relative index of sludge biodegradation(SBOD/TCOD) was enhanced to 0.76 from the initial value of 0.013 at the 5967mg/L MLSS, during the 60minutes treatment. Throughout this research, the results provide useful engineering reference data for reuse of sewage sludge using ultrasound.

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Evaluation of Trophic State of a Small-scale Pond (Wonheung) in Ecological Park (소규모 생태연못(원흥이 방죽)의 부영양화 평가)

  • Lee, Heung Soo;Chung, Se Woong;Choi, Jung Kyu;Shin, Sang Il
    • Journal of Korean Society on Water Environment
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    • v.24 no.6
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    • pp.741-749
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    • 2008
  • Many small-scale ponds that serve as ecological habitat, recreation and irrigation are faced to eutrophication problem, which causes aesthetic nuisance and ultimately loss of their functions. Thus accurate evaluation of the trophic state of these ponds is essential to provide rational information to the stakeholders so that they can develop effective management actions. In this study, the trophic state of a small pond (Wonheung) that experiencing water quality degradation due to vicinity land development was assessed using various Trophic State Indexes (TSIs) and statistical analysis including Principal Components Analysis (PCA) based on the field monitoring data obtained from May to December, 2007. The results showed that the pond is under eutrophic state with average total nitrogen (T-N) and total phosphorus (T-P) concentrations of $708.1{\mu}g/L$ and $59.3{\mu}g/L$, respectively. The factor loading plot obtained from PCA showed distinct two influencing factors, PC 1 and PC 2. PC 1 was grouped by T-P, Chlorophyll a (Chl-a), suspended solids (SS), TN/TP ratio, and transparency that all strongly related to the eutrophication state, while PC 2 by temperature, conductivity, dissolved oxygen (DO) and turbidity that explains the seasonal water quality variations. The limiting factor was identified as light rather than phosphorus by both T-N/T-P ratio and TSI indexes analysis. The results and methodology adopted in this study can be used for water quality assessment for other small ponds and lakes.

Phytohydrography and the Vertical Pattern of Nitracline in the Southern Waters of the Korean East Sea in Early Spring (춘계 한국 동해 남부해역에서의 식물 수문학적 수역과 질산염약층의 수직양상)

  • Shim, Jae Hyung;Yang, Sung Ryull;Lee, Won Ho
    • 한국해양학회지
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    • v.24 no.1
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    • pp.15-28
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    • 1989
  • A study on quantitative phytoplankton samples, hydrographic conditions (temperature, salinity, dissolved oxygen), and nutrients has been performed in the southern waters of the Korean East Sea in early spring. Phytoplankton community showed close correlation with hydrographic conditions. This study area could be divided into three phytohydrographic regions; 1) East Korean Warm Water Region (a branch of Tsushima Current), 2) North Korean Cold Water Region, and 3) offshore water region not affected by other two water regions. Vertical distribution of phytoplankton is dependent upon stability of water column and nutrient concentration. Nutrient concentration shows characteristic distribution according to water masses. N/P ratio of ca. 3 in surface layer indicates that nitrogen is the major limiting nutrient in this area. N/P removal ratio was 12.54 ($r^2$ = 0.96), consistent with the Redified ratio. Primary nitrite maxima at the nitracline depths are thought to be formed by phytoplankton exudation. Secondary nitrite maximum was observed in coastal area with dissolved oxygen content of >5.2 ml/l much higher than <0.25 ml/l in other areas. The mechanism of secondary maximum is different from that of other regions, and whether it may be due to in situ degradation of organic matter by bacterial activity is still open to discuss.

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Degradation Characteristics of Paper Sludge and Changes of Heavy Metals in Soil (토양중 제지슬러지의 분해 특성 및 중금속 변화)

  • Lee, Hong-Jae;Jeong, In-Ho;Cho, Ju-Sik;Heo, Jong-Soo
    • Korean Journal of Environmental Agriculture
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    • v.15 no.3
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    • pp.296-305
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    • 1996
  • Chemical characteristics of paper sludge, degradation of the sludge in soil and $CO_2$ generation, and changes of nitrogen and heavy metals in soil treated with the sludge were investigated. The results obtained was summarized as follows: 1. Degradation rate of paper sludge in soil was 19% at room temperature, and 28% at $incubation(30^{\circ}C)$ temperature after 12-weeks treatment. 2. T-C, T-N and the C/N ratio of the sludge in soil at room temperature were 15.5%, 0.22% and 71 respectively, and 14.5%, 0.24% and 60, respectively, at $incubation(30^{\circ}C)$ temperature after 12-week treatment. 3. $CO_2$ genaration in soil treated with 1%, 3% and 5% of the sludge was 247mg/100g, 334mg/100g and 458mg/100g, respectively, at room temperature, and 385mg/100g, 550mg/100g and 618mg/100g, respectively, at incubation temperature after 12 weeks treatment. 4. Mineralization ratio of organic nitrogen in soil treated with 1%, 3% and 5% of the sludge was 8.7%, 13.4% and 16.2%, respectively, at $incubation(30^{\circ}C)$ temperature after 12-weeks treatment. 5. The amounts of DTPA-extractable Cu, Cd, Zn, Pb, and Cr in Soil treated with paper sludge were $0.7{\sim}2.2$, $0.1{\sim}0.17$, $1.4{\sim}2.8$, $1.4{\sim}2.8$, and $0{\sim}0.7mg/kg$, respectively. Mean while, those of $HNO_3$ extractable Cu, Cd, Zn, Pb, and Cr were $7.9{\sim}10.0$, $0.6{\sim}0.9$, $17.6{\sim}34.4$, $14.7{\sim}18.5$, and $5.8{\sim}9.0mg/kg$, respectively.

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A Study on Degradation of Nitrogen Compounds by Biofilm Reactor Packed with Porous Media (다공성 담체를 이용한 생물막 반응조의 질소화합물 분해에 관한 연구)

  • Cho, Hae-Mi;Kim, So-Yeon;Yoon, Ji-Hyun;Han, Gee-Bong
    • Journal of Korean Society on Water Environment
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    • v.23 no.5
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    • pp.776-780
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    • 2007
  • A biofilm reactor packed with porous media was investigated for nitrogen removal of synthetic wastewater. The effect of different loading rates on the nitrification was sustained to be steady state with stable efficiency of 50~60% in the range of $0.0083{\sim}0.017gNH_4-N/gMLVSS{\cdot}day$ of F/MN ratio and $1{\sim}2kgNH_4-N/m^3{\cdot}day$ of media volumetric loading rate. However, nitrification efficiency was rapidly decreased to 25~30% as F/MN ratio and media volumetric loading rate were increased to the range of $0.025{\sim}0.034gNH_4-N/gMLVSS{\cdot}day$ and $3{\sim}4kgNH_4-N/m^3{\cdot}day$, respectively. Also the consumption rate of alkalinity was higher under 8 hours of HRT than unter 6 hours of HRT. Accordingly the influent loading rate variation by detention time with influent flow influenced more on the nitrification efficiency than the influent loading rate variation by the influent concentration did. The temperature effect on the nitrification showed 25% higher in summer than in winter as the results reported by other researchers who reported that the nitrification efficiency in biofilm showed 20% increase from 55% to 75% when the temperature was raised from $20^{\circ}C$ to $25^{\circ}C$. Denitrification with sulfur-media showed 90% removal efficiency under steady-state with no effect from the increase of influent concentration and empty bed contact time (EBCT) change such as EBCT was decreased from 8.4 hr to 4.3 hr and $NO_3-N$ loading rate was changed within the range of $0.1{\sim}0.4kgNO^3-N/m^3{\cdot}day$. Accordingly Denitrification with sulfur-media is feasible for post denitrification at the concentration less than $80mgNO^3-N/L$.

Characteristics of The Wastewater Treatment Processes for The Removal of Dyes in Aqueous Solution(1) - Chemical Precipitation or Biological Treatment - (수용액 중의 염료 제거를 위한 폐수처리공정의 특성(1) -화학적 응집 및 생물학적 처리-)

  • Han Myung Ho;Huh Man Woo
    • Textile Coloration and Finishing
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    • v.17 no.2 s.81
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    • pp.31-39
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    • 2005
  • This study was conducted to remove the dyes in dye wastewater by the chemical precipitation or biological treatment which are one of the main pollutants in dye wastewater. In order to remove the disperse dyes effectively in aqueous solution by chemical precipitation process, coagulation and flocculation tests were carried out using several coagulants on various reaction conditions. It was found that the Ferrous sulfate was the most effective coagulant for the removal of disperse dye(DB79), and we could get the best result for the removal of disperse dye(DB56) in the aspects of TOC removal efficiency and sludge yield. When the Ferrous sulfate dosage was 800mg/l, the sludge settling velocity was very fast$(SV_{30}=4\%)$, and the color was effectively removed in the disperse dye(DB79) solution. Although the color removal was ineffective when the Alum was used as a coagulant, the sludge yield decreased in comparison with the Ferrous sulfate or the Ferric sulfate being used in the disperse dye(DB56) solution. In order to decolorize disperse dye(DR17) by using biological treatment process, a strain which has potential ability to degrade disperse dyes was isolated from natural system. The optimal culture conditions of temperature and pH were found to be $40^{\circ}C\;and\;8.5\~9$, respectively. When yeast extract was mixed with polypeptone at the mixing ratio of 1:1 as a nitrogen source, decolorization efficiency was highest$(93\%)$ among the nitrogen sources. The strain screened was excellent to adjust to pH, and it seems to have ability to control pH needed to growth. The optimal culture conditions in concentration of $MgSO_{4.}\cdot7H_2O\;and\;KH_2PO_4$ were $0.1\%(w/v)\;and\;0.2\%(w/v)$, respectively. Strains degrading and decolorizing reactive dyes, RB198 and RR141 which were isolated from water system, are named RBK1 and RRK. And the cell growth characteristics of RBK1 and RRK were investigated. The optimal culture conditions of temperature and pH were found to be 30t' and 7.0, respectively. Optimum nitrogen source was peptone, and it was found that decolorization efficiencies by strains RBK1 and RRK, were $85\%\;and\;62\%$, respectively, with introduction of 4,000mg/l of peptone. In the case of RBK1, color removal efficiencies were very high below 400mg/l. Decolorization efficiency was over $90\%$ at 20hours of culture time. The Color degradation ability of RRK was lower than that of RBK1.

Analysis of Non-point Source Pollution using GIS Technique (GIS를 이용한 충주호주변의 비점원 오염 분석 연구)

  • 김윤종;유일현;김원영;류주영;이영훈;민경덕
    • Spatial Information Research
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    • v.3 no.1
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    • pp.1-18
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    • 1995
  • Despite the widespread use of GIS over the past ten years, it has been limited application for regional modeling of pollutant loadings such as sediment, nitrogen, and phosphorus(non-point source pollution), The goals of this study were to: select important processes and parameters of watersheds that contribute to non-point source pollution degradation, develop a ranking model to use the environmental geologic data and verify the model by comparing results with existing water quality data(Chung-ju Lake) for specific watersheds, The GIS database consisted of topography, geology, soils, precipitation, rainfall erosivity, land use, and watershed boundaries. The index(NPSP) for assessing non-point source pollution was comprised in the following three seperate components: soil loss index(SLI) assesses the potential soil erosion and sedim-ent delivery from field to stream; run-off potential ratio(R.P.R) predicts the potential production of surface runoff; chloropgyll-a index ranks the potential manure(animal or human) production within a watershed. The GIS model was a valuable tool to assess the impact of environmental pollation in watersheds.

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Effect of RuO$_2$ Thin Film Microstructure on Characteristics of Thin Film Micro-supercapacitor ($RuO_2$박막의 미세 구조가 박막형 마이크로 슈퍼캐패시터의 특성에 미치는 영향)

  • Kim, Han-Ki;Yoon, Young-Soo;Lim, Jae-Hong;Cho, Won-Il;Seong, Tae-Yeon;Shin, Young-Hwa
    • Korean Journal of Materials Research
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    • v.11 no.8
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    • pp.671-678
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    • 2001
  • All solid-state thin film micro supercapacitor, which consists of $RuO_2$/LiPON/$RuO_2$ multi layer structure, was fabricated on Pt/Ti/Si substrate using a $RuO_2$ electrode. Bottom $RuO_2$ electrode was grown by dc reactive sputtering system with increasing $O_2/[Ar+O_2]$ ratio at room temperature, and a LiPON electrolyte film was subsequently deposited on the bottom $RuO_2$ electrode at pure nitrogen ambient by rf reactive sputtering system. Room temperature charge-discharge measurements based on a symmetric $RuO_2$/LiPON/$RuO_2$ structure clearly demonstrates the cyclibility dependence on the microstructure of the $RuO_2$ electrode. Using both glancing angle x-ray diffraction (GXRD) and transmission electron microscopy (TEM) analysis, it was found that the microstructure of the $RuO_2$ electrode was dependent on the oxygen flow ratio. In addition, x- ray photoelectron spectroscopy(XPS) examination shows that the Ru-O binding energy is affected by increasing oxygen flow ratio. Furthermore, TEM and AES depth profile analysis after cycling demonstrates that the interface layer formed by interfacial reaction between LiPON and $RuO_2$ act as a main factor in the degradation of the cyclibility of the thin film micro-supercapacitor.

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