• Journal of Applied Biological Chemistry
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• v.56 no.4
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• pp.205-211
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• 2013

Nitrate is a naturally occurring compound in plant and can be converted to nitrite in the nitrogen cycle and vice versa. Therefore, it is easy to find nitrate in plants including vegetables. Especially, it is known that high levels of nitrate found in leafy vegetables. Nitrate itself is relatively non-toxic but its metabolites and reaction products such as nitrite, nitric oxide and N-nitroso compounds, may produce adverse health effects such as methaemoglobinaemia and carcinogenesis. To execute the risk assessment of dietary nitrate and nitrite for the intake of vegetables, it is investigated that the levels of nitrate and nitrite in 23 vegetables (798 samples). The range of concentration were 0-6,719mg/kg for nitrate and 0-1,635mg/kg for nitrite, respectively. The Estimated daily intakes (EDI) were 0.85-1.38 mg/kg body weight/day for nitrate and 0.02-0.03 mg/kg body weight/day for nitrite by ages. We conclude that there are no health concerns for eating various vegetables since the EDI were below the Tolerable Daily Intake (3.7 mg/kg body weight/day for nitrate, 0.06 mg/kg body weight/day for nitrite) level established by WHO.

• Journal of The Korean Society of Agricultural Engineers
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• v.60 no.6
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• pp.83-96
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• 2018

The objective of this study was to estimate the climate change impact on water quantity and quality to Saemanguem watershed using SWAT (Soil and water assessment tool) model. The SWAT model was calibrated and validated using observed data from 2008 to 2017 for the study watershed. The $R^2$ (Determination coefficient), RMSE (Root mean square error), and NSE (Nash-sutcliffe efficiency coefficient) were used to evaluate the model performance. RCP scenario data were produced from 10 GCM (General circulation model) and all relevant grid data including the major observation points (Gusan, Jeonju, Buan, Jeongeup) were extracted. The systematic error evaluation of the GCM model outputs was performed as well. They showed various variations based on analysis of future climate change effects. In future periods, the MIROC5 model showed the maximum values and the CMCC-CM model presented the minimum values in the climate data. Increasing rainfall amount was from 180mm to 250mm and increasing temperature value ranged from 1.7 to $5.9^{\circ}C$, respectively, compared with the baseline (2006~2017) in 10 GCM model outputs. The future 2030s and 2070s runoff showed increasing rate of 16~29% under future climate data. The future rate of change for T-N (Total nitrogen) and T-P (Total phosphorus) loads presented from -26 to +0.13% and from +5 to 47%, respectively. The hydrologic cycle and water quality from the Saemanguem headwater were very sensitive to projected climate change scenarios so that GCM model should be carefully selected for the purpose of use and the tendency analysis of GCM model are needed if necessary.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.11a
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• pp.685-693
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• 2011

In the era of energy climate, IGCC technology is one of the powerful solutions for the demands of new energy with low carbon green growth. The present study is conducted to investigate the combustion characteristics of syngas from the coal gasifier to predict problems when it is fed to the gas turbine. Through high and low combustion tests, we understood that hydrogen is the main reason of NOx emission but easily controled by injecting the dilution of nitrogen. CO emission of syngas was comparable with that of methane and pressure fluctuation of syngas was not significant. The data from this study will be used for the optimization of combustion in the Korea first IGCC plant in 2015.

• Proceedings of KOSOMES biannual meeting
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• 2003.05a
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• pp.191-200
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• 2003

Gunsan coastal area is one of region increasing pollution problems. One of the most important factors that cause eutrophication is nutrient materials containing nitrogen and phosphorus which stem from excreation of terrestial sources. At this study, the three-dimensional numerical hydrodynamic and ecosystem model, which was developed by Institute for Resources and Environment of Japan, were applied to analyze the processes affecting the eutrophication. The residual currents, which were obtained by integrating the simulated tidal currents over 1 tidal cycle, showed the presence of a typical. Density driven currents were generated westward at surface and eastward at the bottom in Geum estuary area where the fresh waters are flowing into. The ecosystem model was calibrated with the data surveyed in the field of the study area in annual average. The simulated results of DIN were fairly good coincided with the observed values within relative error of 32.39%. correlation coefficient(r) of 0.99. In the case of DIP, the simulated results were fairly good coincided with the observed values within relative error of 24.26%, correlation coefficient (r) of 0.82. The simulations of DIN and DIP concentrations were performed using ecosystem model under the conditions of 20 ∼ 80% pollution load reductions from pollution sources. In study area, concentration of DIN and DIP were reduced to 20∼80% and under 10% in case of the 80% reduction of the input loads from fresh water respectively. But pollution loads from sediment had hardly affected DIN and DIP concentration. For the environment management of coastal areas, in case of Kunsan area, the most important pollution sources affecting eutrophication phenomenon were found to be the input loads from fresh water.

• Ocean and Polar Research
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• v.30 no.3
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• pp.225-238
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• 2008

In order to investigate the effects of intertidal sediments on the nutrient cycle in coastal environments, the benthic fluxes of ammonium, nitrate, nitrite, phosphate, and silicate at two stations on the intertidal flat of Keunso Bay were determined during each season. The efflux of ammonium was observed at S1 and resulted from the diffusion of remineralized ammonium and acceleration caused by the bioirrigation of macrofauna. The influx of ammonium at S2 was probably due to nitrification in the water column. The influx of nitrate was observed at both stations during all seasons, indicating that the nitrate in the pore water was removed by denitrification. Vigorous bioirrigation led to the efflux of dissolved inorganic nitrogen (DIN) at S1, whereas the influx of DIN at S2 was predominantly caused by denitrification. Contrary to the diffusive and bio-irrigated release of remineralized phosphate from the sediment at S1, the influx of phosphate was observed at S2, which may be attributable to adsorption onto iron oxides in the aerobic sediment layer. Silicate, which is produced by the dissolution of siliceous material, was mostly released from the sediment by molecular diffusion and bioirrigation. However, the influx of silicate was observed at S2 during spring and winter, which was ascribed to adsorption by particulate matter or assimilation by benthic microphytes. The annual fluxes of DIN were 328 mmol $m^{-2}yr^{-1}$ at S1 and -435 mmol $m^{-2}yr^{-1}$ at S2. The annual fluxes of phosphate were negative at both sites (-2.8 mmol $m^{-2}yr^{-1}$ at S1 and -28.9 mmol $m^{-2}yr^{-1}$ at S2), whereas the annual fluxes of silicate were positive at both sites (843 mmol $m^{-2}yr^{-1}$ at S1 and 243 mmol $m^{-2}yr^{-1}$ at S2).

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2001.06a
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• pp.14-14
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• 2001

Nitride films such as TiN, CrN etc. deposited on glass by PVD processes have been developed for many industrial applications. These nitride films deposited on glass were widely used for not only decorative and optical coatings but also wear and corrosion resistance coatings employed as dies and molds made of glass for the example of lens forming molds. However, the major problem of nitride coatings on glass by PVD process is non-uniform film owing to pin-hole and micro crack. It is estimated that nonuniform coating is influenced by a different surface energy between metal nitrides and glass due to binding states. In this work, therefore, for the evaluation of nucleation and growth mechanism of nitride films on glass TiN and CrN film were synthesized on glass with various nitrogen partial pressure by unbalanced magnetron sputtering. Prior to deposition, for the examination of relationship between surface energy and film microstructure plasma pre-treatment process was carried out with various argon to hydrogen flow rate and substrate bias voltage, duty cycle and frequency by using pulsed DC power supply. Surface energy owing to the different plasma pre-treatment was calculated by the measurement of wetting angle and surface conditions of glass were investigated by X-ray Photoelectron Spectroscopy(XPS) and Atomic Force Microscope(AFM). The microstructure change of nitride films on glass with increase of film thickness were analyzed by X-Ray Diffraction(XRD) and Scanning Electron Microscopy(SEM).

• 한국해양학회지
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• v.28 no.4
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• pp.323-331
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• 1993

The concentration-dependence of and the effect of light on urea decomposition, and the suppression of urea decomposition by ammonium were studied to understand adaptations in phytoplankton to utilization of urea in the estuarine system of the Mankyung and Dongjin rivers and a hypertrophied pond. Results of size-fractionation showed that bacterial fraction played a minor role (14%) in urea decomposition in the estuary. However, the role of bacteria in urea decomposition seemed to increase in a hypertrophic pond. Natural phytoplankton communities exhibited a monophonic or biphasic kinetics of urea decomposition over a wide range of concentration (upto 7.7 mM). the addition of high concentration of ammonium and incubation of the euphotic samples in the dark caused reductions in the urea decomposition rates. It is suggested that understanding of adaptations in phytoplankton to urea decomposition would help to study the temporal and spatial variabilities of urea decomposition rates in the field and the significance of urea in nitrogen cycle.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.4 no.3
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• pp.208-214
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• 1999

In order to determine if there is any physiographic preference for sedimentary organic matter preservation, two gravity cores were collected off Gampo, East Sea: one from continental shelf and the other from continental slope. Concentrations of porewater nutrients and total $CO_2$ were all higher in the continental shelf station, St. A, than the continental slope station, St. B. Meanwhile, concentrations of porewater sulfate decreased more rapidly at St. A than at St. B. Sedimentary organic carbon and nitrogen contents were lower and decreased more rapidly at St. A than at St. B. These data characters of porewater chemistry and sedimentary organic matter suggest that the organic matter is more actively decomposed at St. A than at St. B. At least over the study area, therefore, the sedimentary organic matter in the continental slope appears to be better preserved than that in the continental shelf.

• Journal of Korean Society of Water and Wastewater
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• v.19 no.6
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• pp.791-799
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• 2005

The phased isolation intra-clarifier ditch system used in this study is a simplified novel process enhancing simultaneous removal of biological nitrogen and phosphorus in municipal wastewater in terms of elimination of additional pre-anaerobic reactor, external clarifier, recycle of sludge, and nitrified effluent recirculation by employing intrachannel clarifier. Laboratory-scale phased isolation ditch system was used to assess the treatability on municipal wastewater. When the system was operated at the HRTs of 6~12hours, SRTs of 9~31days, and cycle times of 2~8hours, the system showed removals of BOD, TN, and TP as high as 88~97%, 70~84%, and 65~90%, respectively. The rainfall in Korea is generally concentrated in summer because of site-specific characteristics. Especially, the wet season has set in on June to August. In combined sewers, seasonal variations are primarily a function of the amount of stormwater that enters the system. In order to investigate the effect of hydraulic shock loading on system performance, the laboratory-scale system was operated at an HRT of 6hours (two times of influent flowrate) during two cycles (8hours). The system performance slightly decreased by increasing of influent flowrate and decreasing of system HRT. Nitrification efficiency and TN removal were slightly decreased by increasing of influent flowrate (decreasing of system HRT), whereas, the denitrification was not affected by hydraulic shock loading. However, the higher system performance could be achieved again after four cycles. Thus, the phased isolation technology for enhanced biological nutrient removal in medium- and small-scale wastewater treatment plants suffering fluctuation of influent quality and flowrate.

• Journal of computational fluids engineering
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• v.18 no.3
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• pp.1-7
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• 2013

A pure oxygen combustion technology is crucial in Carbon Capture and Storage (CCS) technology especially in capturing of $CO_2$, where CCS will reduce 9 $GtCO_2$ by 2050, which is 19% of the total $CO_2$ reduction amount. To make pure oxygen combustion feasible, a regenerative system is required to enhance the efficiency of pure oxygen combustion system. However, an existing air combustion technology is not directly applicable due to the absence of nitrogen that occupies the 78% of air. This study, therefore, investigates the heat and fluid flow in a regenerative system for pure oxygen combustion by using commercial CFD software, FLUENT. Our regenerative system is composed of aluminium packed spheres. The effect of the amount of packed spheres in regenerator and the effect of presence or absence of a bypass of exhaust gas are investigated. The more thermal mass in regenerator makes the steady-state time longer and temperature variation between heating and regenerating cycle smaller. In the case of absence of bypass, the regenerator saturates because of enthalpy imbalance between exhaust gas and oxygen. We find that 40% of exhaust gas is to be bypassed to prevent the saturation of regenerator.