• Title/Summary/Keyword: Nitrogen cycle

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Macroscopic Characteristics of Evaporating Dimethyl Ether(DME) Spray (Dimethyl Ether(DME)의 증발과 거시적 분무 특성)

  • Yu, Jun;Lee, Ju-Kwang;Bae, Choong-Sik
    • Transactions of the Korean Society of Automotive Engineers
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    • v.11 no.3
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    • pp.58-64
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    • 2003
  • Dimethyl Ether(DME) has been considered as one of the most attractive alternative fuels for compression ignition engine. Its main advantage in diesel engine application is high efficiency of diesel cycle with soot free combustion though conventional fuel injection system has to be modified due to the physical properties of DME. Experimental study of DME and conventional diesel spray employing a common-rail type fuel injection system with a 5-hole sac type injector was performed in a constant volume vessel pressurized by nitrogen gas. Spray cone angles and penetrations of the DME spray were characterized and compared with those of diesel. For evaluation of the evaporating characteristics of the DME, shadowgraphy technique employing an Ar-ion laser and an ICCD camera was adopted. Tip of the DME spray was formed in mushroom-like shape at atmospheric chamber pressure, which disappeared in higher chamber pressure. Spray tip penetration and spray cone angle of the DME became similar to those of diesel under 3MPa of chamber pressure. Higher injection pressure provided wider vapor phase area while it decreased with higher chamber pressure condition.

Environmental analysis of present and future fuels in 2D simple model marine gas tubines

  • El Gohary, M. Morsy
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.5 no.4
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    • pp.559-568
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    • 2013
  • Increased worldwide concerns about fossil fuel costs and effects on the environment lead many governments and scientific societies to consider the hydrogen as the fuel of the future. Many researches have been made to assess the suitability of using the hydrogen gas as fuel for internal combustion engines and gas turbines; this suitability was assessed from several viewpoints including the combustion characteristics, the fuel production and storage and also the thermodynamic cycle changes with the application of hydrogen instead of ordinary fossil fuels. This paper introduces the basic environmental differences happening when changing the fuel of a marine gas turbine from marine diesel fuel to gaseous hydrogen for the same power output. Environmentally, the hydrogen is the best when the $CO_2$ emissions are considered, zero carbon dioxide emissions can be theoretically attained. But when the $NO_x$ emissions are considered, the hydrogen is not the best based on the unit heat input. The hydrogen produces 270% more $NO_x$ than the diesel case without any control measures. This is primarily due to the increased air flow rate bringing more nitrogen into the combustion chamber and the increased combustion temperature (10% more than the diesel case). Efficient and of course expensive $NO_x$ control measures are a must to control these emissions levels.

Internal modifications to reduce pollutant emissions from marine engines. A numerical approach

  • Lamas, M.I.;Rodriguez, C.G.;Rodriguez, J.D.;Telmo, J.
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.5 no.4
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    • pp.493-501
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    • 2013
  • Taking into account the increasingly stringent legislation on emissions from marine engines, this work aims to analyze several internal engine modifications to reduce $NO_x$ (nitrogen oxides) and other pollutants. To this end, a numerical model was employed to simulate the operation cycle and characterize the exhaust gas composition. After a preliminary validation process was carried out using experimental data from a four-stroke, medium-speed marine engine, the numerical model was employed to study the influence of several internal modifications, such as water addition from 0 to 100% water to fuel ratios, exhaust gas recirculation from 0 to 100% EGR rates, modification of the overlap timing from 60 to $120^{\circ}$, modification of the intake valve closing from 510 to $570^{\circ}$, and modification of the cooling water temperature from 70 to $90^{\circ}C$. $NO_x$ was reduced by nearly 100%. As expected, it was found that, by lowering the combustion temperature, there is a notable reduction in $NO_x$, but an increase in CO (carbon monoxide), HC (hydrocarbons) and consumption.

Nitrification and Denitrification by Using a Sequencing Batch Reactor System (Sequencing Batch Reactor (SBR)를 이용한 질산화와 탈질산화)

  • PARK Jong-Ho;LEE Won-Ho;CHO Kyu-Seok;HWANG Gyu-Deok
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.36 no.3
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    • pp.247-253
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    • 2003
  • Sequencing Batch Reactor (SBR) was operated under various experimental conditions to improve the efficiency of biological filters used for the treatment of recycled wastewater from aquaculture. This SBR system was operated for removing COD, ammonia and suspended solid that were the major pollutants in aquaculture wastewater. Aerobic and anoxic conditions after FILL mode were applied intermittently for effective removal of nitrogen. SETTLE and DRAW modes were followed by the complete aerobic and anoxic REACT mode. The total volume of the SBR was 75 liter, while the working volume in a cycle was 35 liters. When the final operating strategy of the SBR was FILL/REACT/SETTLE/DRAW of 0.5/10/1/0.5 hr. the removal efficiencies of TCODcr, $NH_{4}^{+}-N,$ and T-N were 94, 98, and $89\%,$ respectively.

Distribution of Canavanine and Free Amino Acids in Legumes, Robinia pseudo-acacia, Wistaria floribunda, and Canavalia lineata (콩과식물인 아까시나무(Robinia pseudo-acacia), 등나무(Wistaria floribunda) 및 해녀콩(Canavalia lineata)에서 canavanine과 유리아미노산의 분포)

  • Yu, Gyung-Hee;Young Myung Kwon
    • The Korean Journal of Ecology
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    • v.18 no.4
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    • pp.433-440
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    • 1995
  • The constituents and proportions of non-protein free amino acids including canavanine were measured in roots and leaves of legumes, Robinia pseudo-acacia L., Wistaria floribunda L., and Canavalia lineata L. by using high performance liquid chromatography during dormant and fertilizing seasons. in all the three plant species, asparagine was the most abundant amino acid occurring 30% of total free amino acids, and canavanine was the second most abundant amino acid contributing 10% of total free amino acids throughout dormant and fertilizing seasons. In dormant season, roots contained 2 to 3 folds of free amino acids including canavanine and asparagine compared to those in fertilizing season. When proportions of asparagine and canavanine to total gree amino acids in various parts of C. lineata were examined in fertilizinng season, the level of asparagine was the highest in roots while that of canavanine was in seeds. On the basis of these results, it is assumed that canavanine appears and functions as a nitrogen-storing compound in roots and leaves throughout the whole life cycle of the investigated plants.

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Characteristic Evaluation Based on the Heat Treatment Conditions of Super Duplex Stainless Steel with 0.2% N as an Additive - Part 1: Mechanical Properties and Microstructure (0.2% N을 첨가한 수퍼 2상 스테인리스강의 열처리 조건에 따른 특성 평가 - 제1보: 기계적 특성 및 미세조직)

  • Ahn, Seok-Hwan;Kang, Heung-Joo;Nam, Ki-Woo
    • Journal of Ocean Engineering and Technology
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    • v.22 no.4
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    • pp.46-50
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    • 2008
  • Super duplex stainless steel has along life in severe environments because of its strength and corrosion resistance. If 0.2$\sim$0.3% Nitrogen in aninterstitial solid solution is added, the austenite structure is reinforced. This improves the solid solution hardening and the anticorrosionability. In this study, the mechanical properties and structures of the super duplex stainless steel with the 0.2% N additive were investigated to determine the effect of various volume fractions on the austenite phase. The various volume fractions and distributions of the austenite structure in the applied test specimens were obtained by changing the heat treatment temperature and cycle. The characteristics by amounts of the $\sigma$ phase obtained from the precipitation heat treatment were alsoinvestigated. From the results, when the austenite volume fraction increases, the tensile strength decreases and elongation increases. And the $\sigma$ phase was rapidly increased by increasing the heat treatment time. When the volume fraction of the $\sigma$ phase increased, tensile strength increased.

Study the Properties of Silicon Nitride Films prepared by High Density Plasma Chemical Vapor Deposition

  • Gangopadhyay, Utpal;Kim, Do-Young;Parm, Igor Oskarovich.;Chakrabarty, Kaustuv;Kim, Chi-Hyung;Shim, Myung-Suk;Yi, Jun-Sin
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.1127-1130
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    • 2003
  • The characteristics of silicon nitride films deposited in a planar coil reactor using a simple high-density inductively coupled plasma chemical vapor deposition technique have been investigated. The process gases used during silicon nitride deposition cycle were pure nitrogen and a mixture of silane and helium. It has been pointed out that the strong H-atom released from the growing SiN film and Si-N bond healing are responsible for the improved electrical and passivation properties of SiN.

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Characteristic Evaluation according to Heat Treatment Conditions of Super Duplex Stainless Steel with Additive 0.2% N - Part 2: Fatigue Crack Propagation Behavior (0.2% N을 첨가한 수퍼 2상 스테인리스강의 열처리 조건에 따른 특성 평가 - 제2보: 피로균열진전 거동)

  • Ahn, Seok-Hwan;Kang, Heung-Joo;Seo, Hyun-Soo;Nam, Ki-Woo;Lee, Kun-Chan
    • Journal of Ocean Engineering and Technology
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    • v.23 no.5
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    • pp.79-84
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    • 2009
  • Super duplex stainless steel has long life in severe environments by showing the enough strength and corrosion resistance. Therefore, the fracture mechanics approach needs to support the structural strength integrity for the used material. In this study, fatigue crack propagation behavior was investigated to super duplex stainless steel with 0.2% nitrogen. The various volume fraction and distribution of austenite structure for applied specimen in test were obtained by changing the heat treatment temperature and cycle. From test results, fatigue crack propagation rate showed two kinds of tendency between da/dN and ${\Delta}K$ according to distribution of austenite structure and structure anisotropy.

Recent Trends of Using Alternative Nutrient Sources for Microalgae Cultivation as a Feedstock of Biodiesel Production (바이오디젤 생산원료로써 미세조류의 배양을 위한 대체 영양원 사용 기술)

  • Dang, Nhat Minh;Lee, Kisay
    • Applied Chemistry for Engineering
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    • v.29 no.1
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    • pp.1-9
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    • 2018
  • Microalgae is considered as one of environmentally sustainable and potential feedstocks to produce biodiesels. However, recent studies on life cycle assessments (LCA) of microalgal buidiesels have shown that energy requirement is not small to produce biodiesel from microalgae, especially during cultivation stage. The costs for carbon sources, nutrients like nitrogen or phosphorous, and water for cultivation can contribute up to 80% of the total medium costs. In the present article, recent trends on the utilization of several promising nutrient sources such as municipal wastewaters, organic fertilizers, combustion exhaust emissions and organic solid wastes were reviewed, and the potential strategies to be used as substitutes of artificial culture media, especially for the biodiesel production, were discussed.

A Study of the Matter Production and Decomposition of Quercus serrata and Carpinus Iaxiflora Forests at Piagol in Mt. Juri (지이산 피아골의 졸참나무와 서나무 군락의 물질생산과 분해에 관한 연구)

  • Chang, Nam-Kee;In-Ja Kim
    • The Korean Journal of Ecology
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    • v.6 no.3
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    • pp.198-207
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    • 1983
  • The dry-matter production, the litter decomposition and the nutrient cycle were studied on Quercus serrata and Carpinus laxiflora forests at Piagol in Mt. Jiri. With the growth curves of the annual ring, the time schedules for the maximum productivities and maximum yields were measured. In Q.serrata forest, the maximum productivity was 11.36 tons $ha^-1 yr^-1$ at the 49th year and the maximum yield was 115.78 tons $ ha^-1$ at the 73th year, and in C. laxiflora 7.24 tons $ha^-1 yr^-1$at the 35th year and 82.5 tons $$ha^-1 $$at the 53th year, respectively. The maximum productivities and the maximum yields of the leaves, stems and roots of the trees were calculated. The contents of nitrogen, phosphorus, potassium and organic carbon were measured.. While inorganic materials were the most abundant in the leaves, organic materials in stems. The maximumproductivities and the maximum yields of the constituents of the trees were calculated, assuming that the constituents of the trees increase allometrically. The decomposition rates were as follows: k = 0.301 for Q.serrata forest, and k = 0.364 for C. laxiflora forest. The litter of the former was decayed more slowly than that of the latter. The halftimes for decomposition were 3.2 and 1.9 years, respectively.

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