• Nuclear Engineering and Technology
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• v.55 no.7
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• pp.2697-2711
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• 2023

In this study, the validity of reducing the number of gas turbine stages designed for a nitrogen Brayton cycle coupled to a sodium-cooled fast reactor was assessed. The turbine performance was evaluated through computational fluid dynamics (CFD) simulations under different off-design conditions controlled by a reduced flow rate and reduced rotational speed. Two different multistage gas turbines designed to extract almost the same specific work were selected: two- and three-stage turbines (mid-span stage loading coefficient: 1.23 and 1.0, respectively). Real gas properties were considered in the CFD simulation in accordance with the Peng-Robinson's equation of state. According to the CFD results, the off-design performance of the two-stage turbine is comparable to that of the three-stage turbine. Moreover, compared to the three-stage turbine, the two-stage turbine generates less entropy across the shock wave. The results indicate that under both design and off-design conditions, increasing the stage loading coefficient for a fewer number of turbine stages is effective in terms of performance and size. Furthermore, the Ellipse law can be used to assess off-design performance and increasing exponent of the expansion ratio term better predicts the off-design performance with a few stages (two or three).

• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.10
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• pp.317-324
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• 2020

Combined cycle power plants (CCPP) that use natural gas as fuel are easier to start and stop, and have lower pollutant emissions, so their share of domestic power generation facilities is steadily increasing. However, CCPP have a high concentration of nitrogen dioxide (NO2) emission in the initial start-up and low-load operation region, which causes yellow plume and civil complaints. As a control technology, the yellow plume reduction system was developed and operated from the mid-2000s. However, this technology was unable to control the phenomenon due to insufficient preheating of the vaporization system for 10 to 20 minutes of the initial start-up. In this study, CFD analysis and demonstration tests were performed to derive a control technology by injecting a reducing agent directly into the gas turbine exhaust duct. CFD analysis was performed by classifying into 5 cases according to the exhaust gas condition. The RMS values of all cases were less than 15%, showing a good mixing. Based on this, the installation and testing of the demonstration facilities facilitated complete control of the yellow plume phenomenon in the initial start-up.

• Journal of Energy Engineering
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• v.10 no.4
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• pp.363-369
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• 2001

Process design and performance evaluation were made for medium-size gasification combined/cogeneration plant. Based on the designed plant process configuration, the effects of $NO_x$ reduction techniques on the $NO_x$ emission, the power output, the efficiency and the stability of plant are investigated by applying various $NO_x$ reduction methods such as unsaturated/saturated nitrogen injection and fuel saturation of gas turbine combustor. The $NO_x$ reduction by nitrogen injection is more remarkable than that by fuel saturation, and its effect can be more enhanced by using saturated nitrogen. In addition, the applications of $NO_x$ reduction techniques accompany the improvement of plant power output and efficiency with the decrease of $NO_x$ emission, while it can cause unstable gas turbine operation.

• Environmental Engineering Research
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• v.21 no.3
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• pp.311-317
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• 2016

A new type of biofilter packed with composite carriers was designed for tertiary denitrification of the secondary effluent with removal of both oxidized nitrogen and suspended solids (SS). At the empty bed residence time of 15 min and organic carbon to nitrate nitrogen ($C/NO_3-N$) ratios of 2, 1.5 and 1 g/g, the removal percentage of $NO_3-N$ was 67%, 58% and 36% in the ethanol biofilter, and was 61%, 43% and 26% in the acetate biofilter, respectively. The biofilters packed with composite carriers removed SS effectively, with the effluent turbidity in both biofilters of less than 3 NTU. During the operating cycle between the biofilter backwashings, the $NO_3-N$ removal percentage decreased initially after backwashing, and then gradually increased. Under $C/NO_3-N$ ratios of 2, 1.5 and 1 g/g, the $NO_3-N$ reduction rate was 1.75, 1.04 and $0.68g/m^2/d$ in the ethanol biofilter, and was 1.56, 1.07 and $0.76g/m^2/d$ in the acetate biofilter, respectively. In addition, during denitrification, the ratio of the consumed chemical oxygen demand to the removed $NO_3-N$ was 5.06-8.23 g/g in the ethanol biofilter, and was 4.26-8.6 g/g in the acetate biofilter.

• Journal of Advanced Marine Engineering and Technology
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• v.36 no.4
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• pp.484-489
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• 2012

The objective of this work presented here was focused on analysis of particulate matter and nitrogen oxide characteristics in ESC test mode from heavy-duty diesel engine installed on-road vehicles applicable to prime propulsion engine for marine vessels. The authors confirmed that a large quantity particulate matter were emitted in high power density condition, nitrogen oxide characteristics were dependent on exhaust gas temperature. Particulate matters were reduced by 1/100~1/1,000 times in post DPF with test modes but filtration efficiency was decreased in the engine power fluctuation. In the case of the high speed and power condition, the exhaust level of particulate matters was increased according to increment of temperature of gas flowing into DPF. The orders of magnitude for particle concentration levels from the analysis of size distribution of particulate matters of test engine was different. Both emitting nano-sized particles below 100nm regardless of DPF and non-DPF.

• 한국해양학회지
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• v.5 no.1
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• pp.14-29
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• 1970

Tidal variations of various chemical constituents in the laver bed sea waters in Wan Do Gun were determined over one spring tidal cycle from Oct. 1968 to Feb. 1969. Total ranges and means of the contents at Pyung-il Do and Wan Do are as follows. Although the average monthly variations of each content at Pyung-il Do were similar to those at Wan Do, most of the contents at Pyung-il Do were at a slightly higher level than at Wan Do. The values of silicate-silicon, phosphate- phosphorus and soluble iron, however, showed high levels at Wan Do. Chlorinity, magnesium, calcium, dissolved oxygen, silicate-silicon and phosphate-phosphorus contents increased from Oct. 1968 to Feb. 1969, though the content of soluble iron decreased before December and slightly increased in January and February. The average monthly variations of ammonia-nitrogen and nitrate-nitrogen contents were irregular. The nitrite-nitrogen content appeared in trace amounts in the months with a comparatively high water temperature, i.e., October and November, but in midwinter it was undetected. The ranges of the tidal variations of the contents of each chemical constituent were not significantly wide, though the contents varied excessively by the hour, and this may show the irregularity of the water quality in Wan Do Gun coastal area. As a rule, no regular tidal variation of the chlorinity was observed except slightly decreased value at ebb tide at Wan Do. In general, although the pattern of the variations of calcium and magnesium contents were similar to that of the chlorinity, no definite relationships between these constituents and chlorinity were observed. Tidal variations of the dissolved oxygen content, nutrient salts and soluble iron were irregular.

• Biomedical Science Letters
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• v.9 no.1
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• pp.29-36
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• 2003

Progesterone levels in the blood plasma or skim milk of cows are considered to be very useful indicator fur the detection of estrus cycle and early pregnancy diagnosis. During 13 to 14 days after estrus the level of progesterone in plasma or skim milk were not different between the inseminated arid non-inseminated cows. In the pregnant cows the peak level of progesterone reached on 14th day after artificial insemination (AI), but in the absence of conceptus the level declines after the 14th day slowly, and then very rapidly towards the basal level after the 17th day. This low level persists about 4 days, including those of estrus and ovulation a highly characteristic pattern which differs so markedly from that in the pregnant cows. Progesterone levels in blood plasma or skim milk can provided a reliable diagnosis of early pregnancy and monitoring ovarian activity in cows. The mean $\pm$ standard deviation of milk urea nitrogen(MUN) and protein concentration in the cows at 9 herds were 17.7$\pm$2.35 mg/dL and 3.2$\pm$0.17%, respectively. The days of nonpregnant after parturition was shorter in the cows in which the lower level of MUN than higher level of MUN concentration.

• Journal of Korean Society for Atmospheric Environment
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• v.33 no.1
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• pp.54-63
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• 2017

Atmospheric nitrogen containing organic compounds(e.g. amino acids) has attracted considerable attention from the viewpoint of the oceanic biogeochemical cycle of nitrogen as well as the long range transfer. However, only a few measurements of organic nitrogen compounds have been conducted due to analytical difficulties. In this study, total of nine amino acids such as Glutamic acid, Histidine, Arginine, Tyrosine, Cystine, Valine, Methionine, Phenylalanine, Lysine have been analytically determined by Liquid Chromatography - Mass Spectrometry Mass Spectrometry (LC-MSMS). As results, Fragmentor Voltage (FV), Precursor Ion, Collision Energy, Product Ion related to individual amino acid compounds are shown. Based on the operational conditions, Lysine, Glutamine Acid, Tyrosine were analyzed during the China Oriented Smog Period. High concentrations of Lysine, Glutamine Acid, and Tyrosine are discussed with organic carbon (OC), elemental carbon (EC), and water soluble ions. The results can provide to understand the sources with aging process related to amino acids influenced by the long-range transport from the Yellow Sea area.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.538-539
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• 2013

여러 장점으로 인해 OLED는 디스플레이 및 조명 등 적용분야가 넓어지고 있지만, 수분 및 산소에 취약하여 그 수명이 제한되는 단점이 있다. 이를 해결하고자 현재까지는 glass cap을 이용한 encapsulation 기술이 적용되고 있지만, flexible 기판에 적용하지 못하는 문제가 있다. 이러한 문제를 해결하고자 여러 가지 thin film encapsulation 기술이 적용되고 있으나 보다 신뢰성이 높은 기술의 개발이 절실한 때이다. Encapsulation 무기 박막 물질로서 $Si_3N_4$ 박막은 PE-CVD (Plasma Enhanced Chemical Vapor Deposition) 등의 박막 증착법을 사용한 많은 연구가 진행되어, 저온에서의 좋은 품질의 박막 증착이 가능하지만, 100도 이하의 thermal budget을 갖는 OLED Encapsulation에 사용하기에는 충분하지 않았다. CVD 박막의 특성을 더욱 개선하기 위해 최근 ALD (Atomic Layer Deposition) 방법을 통한 $Al_2O_3$ film 증착 방법이 연구되고 있지만, 낮은 증착 속도로 인해 양산에 걸림돌이 되고 있다. 본 연구에서는 또 다른 해결책으로서 Digital CVD 방법을 이용한 양질의 $Si_3N_4$ 박막의 증착을 연구하였다. 이것은 ALD 증착법과 유사하며, 1st step에서 PECVD 방법으로 4~5 ${\AA}$의 얇은 silicon 박막을 증착하고, 2nd step에서 nitrogen plasma를 이용하여 질화 반응을 진행하고, 이러한 cycle을 원하는 두께가 될 때까지 반복적으로 진행된다. 이 때 1 cycle 당 증착속도는 7 ${\AA}$/cycle 정도였다. 최적의 증착 방법과 조건으로 기존의 CVD $Si_3N_4$ 박막 대비 1/5 이하로 pinhole을 최소화 할 수는 있지만 완벽하게 제거하기는 힘든 문제가 있고, 이를 해결하기 위한 개선을 위한 접근 방법이 필요하다고 판단하였다. 본 연구에서는 무기물 박막인 carbon nitride를 이용한 SiN/C:N multilayer 증착 연구를 진행하였다. Fig. 1은 CVD 조건으로 증착된 두께 750 nm SiN film에서 여러 층의 C:N film layer를 삽입했을 때, 38 시간의 85%/$85^{\circ}C$ 가속실험에 따라 OLED의 발광 사진이다. 그림에서 볼 수 있듯이 C:N 층을 삽입하고 또한 그 박막의 수가 증가함에 따라서 OLED에 대한 encapsulation 특성이 크게 개선됨을 확인할 수 있다.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.41 no.8
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• pp.639-648
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• 2013

This paper describes on the NOx/CO emission characteristics, temperature characteristics and flame structures when firing coal derived synthetic gas especially for gases of Buggenum and Taean IGCC. These combustion characteristics were observed by conducting ambient-pressure elevated-temperature combustion tests in GE7EA model combustor when varying heat input and nitrogen dilution ratio. Nitrogen addition caused decrement in adiabatic flame temperature, thus resulting in the NOx reduction. At low heat input condition, nitrogen dilution raised the CO emission dramatically due to incomplete combustion. These NOx reduction and CO arising phenomena were observed at certain flame temperature of $1500^{\circ}C$ and $1250^{\circ}C$, respectively. As increasing nitrogen dilution, adiabatic flame temperature and combustor liner temperature were decreased and singular points were detected due to change in flame structure such as flame lifting. From the results, the effect of nitrogen dilution on the NOx/CO and flame structure was examined, and the test data will be utilized as a reference to achieve optimal operating condition of the Taean IGCC demonstration plant.