• Title/Summary/Keyword: Nitrogen concentration

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Removal of Nitrogen and Phosphorus Using Struvite Crystallization (Struvite 결정화에 의한 질소 및 인의 제거)

  • Weon, Seung-Yeon;Park, Seung-Kook;Lee, Sang-Ill
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.4
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    • pp.599-607
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    • 2000
  • In this research, ${NH_4}^+-N$ and ${PO_4}^{3-}-P$ in wastewater were removed by crystallization. Nitrogen and phosphate have been regarded as key nutrients in the eutrophication of rivers and lakes. Struvite, $MgNH_4PO_4{\cdot}6H_2O$, is insoluble in alkaline solutions. Fertilizer industry wastewater contains organic and nitrogen concentration of 330 mg/L and 550 mg/L, respectively. Nitrogen in this wastewater cannot be treated by conventional biological treatment without physicochemical pretreatment, because nitrogen concentration is relatively high compared to organic concentration. Magnesium ions used in this study were from bittern and commercial magnesium salts of $MgCl_2$ and $Mg(OH)_2$. Bittern obtained as a by-product of seasalt manufacture contains $8,000mg\;Ca^{2+}/L$ and $32,000mg\;Mg^{2+}/L$. Optimum initial pH was 10.5~11.0 and the reaction was complete or done in 2 min. Nitrogen removal efficiency using bittern, $MgCl_2 $ and $Mg(OH)_2$ (as source of $Mg^{2+}$) was 71 %, 81% and 83%. respectively. Phosphate removal efficiency was 99%, 98% and 93%, respectively. Therefore, bittern, $MgCl_2$ and $Mg(OH)_2$ can be efficiently used as $Mg^{2+}$ source for crystallization of nitrogen and phosphate. However, bittern is economically favorable $Mg^{2+}$ source for removing nitrogen and phosphate in wastewater.

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Stoichiometric Study for Nitrogen Removal in Anoxic-oxic Process (무산소-산소 공정에서 양론적 질소제거 연구)

  • Lee, Byung-Dae
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.11
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    • pp.1222-1227
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    • 2005
  • Optimal sludge recycling ratio for maximum total nitrogen(TN) removal efficiency was calculated stoichiometrically using nitrification and denitrification reaction with given influent water qualities in anoxic-oxic process which was one of the popular nitrogen removal system. The water quality items for stoichiometric calculation were ammonia, nitrite, nitrate, alkalinity, COD, and dissolved oxygen which could affect nitrification and denitrification. Optimal sludge recycling ratio for maximum TN removal efficiency was expressed by those five influent water qualities. TN concentration calculated stoichiometrically had kept good relationship with reported TN concentration in each tank and final effluent. In addition, it was possible to expect the TN concentration in final effluent by stoichiometric calculation within ${\pm}5.0\;mg/L$.

Comparative Leaf Characteristics of Quercus Mongolica and Rhododendron Schilippenbachii Plants Inhabiting at South- and North- Facing Slopes around Mountain Ridge

  • Park, Yong Mok
    • Journal of Environmental Science International
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    • v.22 no.10
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    • pp.1345-1351
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    • 2013
  • Leaf characteristics of two representative deciduous-tree species in Korean peninsula were compared to assess directional ridge effect on leaf traits of both species. Leaf mass per unit area (LMA) of Rhododendron schilippenbachii in south-facing ridge slope was significantly higher than that in north-facing ridge slope, while Quercus mongolica did not change LMA. Leaf mass of Q. mongolica was increased depending on leaf size irrespective of slope. However, leaf mass of R. schilippenbachii changed differently in responding to expansion of leaf area between both slopes resulting from retardation of leaf expansion in south-facing slope. R. schilippenbachii showed higher leaf nitrogen concentration per unit area (LNCA) in south-facing slope than that in north-facing slope, while Q. mongolica indicated no difference in LNCA between southand north-facing slopes. However, both species revealed no significant difference in leaf nitrogen concentration per unit mass (LNCM) between south- and north-facing slopes. LNCA of Q. mongolica was about two times higher than that of R. schilippenbachii. These results indicate that there is a difference in leaf characteristics including leaf thickness and nitrogen allocation between Q. mongolica and R. schilippenbachii, suggesting the difference of plasticity.

Simultaneous Nitrification and Dennrincation of Recirculating Aquaculture Water by Biofilter Reactor (생물막 여과 반응기를 이용한 양어장 순환수의 동시 질산화 및 탈질산화 반응)

  • Lee, Min-Gyu;Suh, Kuen-Hack;Oh, Yung-Hee
    • Journal of Environmental Science International
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    • v.6 no.4
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    • pp.409-415
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    • 1997
  • In order to Investigate the possibility as a simple technique of wastewater treatment for recirculating aquaculture system, the experiment by a biofilter unfit was carried out. The high and stable removal efficiency of nitrogen could be obtained by selecting the optimum recycle ratio and DO concentration. It was found that the proper combination of nitrifacation and denitrfication step in the reactor would be required for increasing the removal efficiency. The extent of nitrogen removal gradually decreased UO the rise of re- cycle ratio since the depression of denitrificatlon by the lack of hydrogen donor. The depression of nitrogen removal was overcome by increasing the CIN ratio In the wastewater. The extent of phosphorus removal was increased slightly with the increase of DO concentration and recycle ratio, but high removal efficiency was not observed. However, the extent of COD removal was not affected by recycle ratio and DO concentration and showed the stable removal of above 90%.

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The Methods Calculating the Reduction Efficiency of Nitrogen Oxide for the Facilities Including the Low NOx Burners (저녹스 버너 설치 시설의 질소산화물 저감 효율 산정 방법)

  • Lee, Ki Yong;Talukder, Niladri
    • 한국연소학회:학술대회논문집
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    • 2015.12a
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    • pp.295-296
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    • 2015
  • We presented the methods calculating the reduction efficiency of nitrogen oxide for the low $NO_x$ burner as the pollution prevention facilities. The standard $NO_x$ concentration was used on the emission factor of LNG, $3.7g/m^3$. The $NO_x$ reduction efficiency based on the $NO_x$ concentration was presented and the relationships between the $NO_x$ concentration and the emission factor or the specific heat emission factor were derived. These results could be accurately reflected on calculating the amount of the nitrogen oxide emissions. In addition, according to the arrangement of the low $NO_x$ burners the methods of applying their $NO_x$ reduction efficiency were proposed. The $NO_x$ reduction efficiency for the facilities consisting of the low $NO_x$ burners and the non-low $NO_x$ burners could be estimated with information about the reduction efficiency of each low $NO_x$ burners, the fuel consumption rate, and the heating value of fuel.

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Feasibility Study of Constructed Wetland for the Wastewater Treatment in Rural Area (인공습지의 농촌지역 오수정화시설에 적용가능성 연구)

  • 윤춘경;권순국;권태영
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.40 no.3
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    • pp.83-92
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    • 1998
  • Field experiment was performed from August 1996 to January 1998 to examine the applicability of constructed wetland system for wastewater treatment in rural area. The pilot plant was installed in Kon-Kuk University and the school building septic tank effluent was used as an influent to the treatment basin. Hydraulic loading rate was about 0.1 6$0.16^3/m^2$ day and theoretical detention time in the system was 1.38 days. The treatment basin was composed of sand and reed. The influent DO concentration was low and many cases close to zero, but effluent concentration was higher than the influent which implies that oxygen was supplied naturally. The average concentration of influent BOD was 126mg/L, and with average removal rate of 69 % the average effluent concentration was 4Omg/L which satisfied the effluent water quality standard for the system of interest. The average influent concentration of COD was 2Olmg/L and average effluent concentration was 75mg/L with average removal rate of 60%. The performance of BOD and COD tends to deteriorate in the low temperature, and appropriate action needs to be taken during the cold winter time for stable operation. The average influent concentration of SS was 5Omg/L, and effluent was 1 1mg/L with average removal rate of 76% which satisfied the effluent water quality standard for the system of interest. The results for the regulated components, SOD and SS, from the experiment showed that constructed wetland system can meet the effluent water quality standards. The average influent concentration of total phosphorus was 25.6mg/L and average effluent concentration was 7.8mg/L with average removal rate of 63%. Not like the performance of the above components, average nitrogen removal rate was only 11.2% which is not satisfactory. Although, nitrogen is not regulated at this moment, it can cause many environmental problems including eutrophication. Therefore, nitrogen removal efficiency should be improved for actual application. From the result of the field experiment, constructed wetland system was thought to be an appropriate alternative for wastewater treatment in rural area.

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Studies on Varietal Differences in Growth, Nodulation and Nitrogen Fixation in Soybeans, Glycine max (L.) Merrill. III. Relationships between Nitrogen Fixation Activity and Nitrogen Content of Plant Organs during Grain Filling Period (콩의 생육, 근류형성, 질소고정에 있어서 품종간 차이 III. 등숙기간중 식물체 각 기관 질소함량의 경시적 변동과 질소고정활성과의 관계)

  • Kim, Seok-Dong;Ishizuka, Junji;Park, Rae-Kyeong
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.33 no.2
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    • pp.161-168
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    • 1988
  • Five soybean varieties of two early maturing ; Karikei 73 and ss 79168, and three late maturing ; Tohoku 76, Baegunkong and Jangbaegkong were used and evaluated in the study. Of the varieties examined, Karikei 73 was characterized by the delayed leaf senescence. To investigate the periodical trends of nitrogen in plant organs and their roles to the nitrogen fixing activity of root nodules, the concentrations of nitrogen in plant organs during the grain filling period were measured. High positive correlation was recognized between the amount of nitrogen in plant parts and p-ARA, suggesting the higher the activity of nitrogen fixation the greater the amount of nitrogen in plant. But the relationship between the concentration of nitrogen in plant and s-ARA was positive at R4. but negative at R6. This was inferred that the high concentration of nitrogen at R4 gave accelerating effects on s-ARA by increasing the activity of photosynthesis in leaf-blades, while the reduced activity of photosynthesis in leaf-blades at R6 resulted in continued degradation of nitrogenous compounds in plant, and then high concentration of nitrogen in plants brought reduced supply of sugars to nodules.

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Effects of Seeding Microorganisms, Hydrazine, and Nitrite Concentration on the Anammox Activity (혐기성 암모늄 산화균의 활성에 대한 식종미생물, 히드라진 및 아질산성 질소 농도의 영향)

  • Jung, Jin-Young;Kang, Shin-Hyun;Kim, Young-O;Chung, Yun-Chul
    • Journal of Korean Society on Water Environment
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    • v.21 no.5
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    • pp.477-483
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    • 2005
  • Anammox (Anaerobic Ammonium Oxidation) bacteria is recently discovered microorganism which can oxidize ammonium to nitrogen gas in the presence of nitrite under anaerobic conditions. The anammox process can save an energy for nitrification and need not require a carbon source for denitrification, however, the start-up periods takes a long time more than several months due to the long doubling time (approximately 11 days). In order to find the effects of seeding microorganisms, hydrazine, and nitrite concentration on the enhancement of the anammox activity, five kinds of microorganisms were selected. Among the several kinds of seeding microorganisms, the granule from acclimated microorganisms treating high concentration of ammonia nitrogen (A-1) and sludge from piggery wastewater treatment plant (A-2) were found to have a high anammox activity. In the case of A-1, the maximum nitrogen conversion rate represented 0.4 mg N/L-hr, and the amount of nitrite utilization was high compared to those of other seeding microorganisms. The A-4 represented a higher nitrogen conversion rate to 0.7 mg N/L-hr although the ammonium concentration in the serum bottle was high as 200 mg/L. Meanwhile, the anaerobic granule from UASB reactor treating distillery wastewater showed a low anammox activity due to the denitrification by the remained carbon sources in the granule. Hydrazine, intermediate product in anammox reaction, enhanced the anammox activity by representing 1.4 times of nitrogen gas was produced in the test bottle than that of control, when 0.4 mM of $N_2H_4$ was added to serum bottle which contains 5 mM of nitrite. The high concentration of nitrite (10 mM) resulted in the decrease of the anammox activity by showing lower production of nitrogen gas compared to that of 5 mM addition of nitrite concentration. As a result of FISH (Florescence In-Situ Hybridization) experiment, the Amx820 probe showed a more than 13% of anammox bacteria in a granule (A-1).

Fuzzy Control and Optimization for the Wastewater Treatment Process (퍼지제어기를 이용한 하폐수처리공정의 최적화)

  • 천성표;김봉철;김성신
    • Proceedings of the Korean Institute of Intelligent Systems Conference
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    • 2000.11a
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    • pp.452-455
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    • 2000
  • There are increasingly important financial incentives and environmental consideration to improve the effluent quality of wastewater from domestic and industrial users. The activated sludge process is a widely used biological wastewater treatment process. The activated sludge process is complicated due to the many factors such as the variation of influent flowrate and concentration, the complexity of biological reactions and the various operation conditions. Nowadays, not only suspended solids and residual carbon, but also nitrogen and phosphorous concentration of the effluent water must be taken into account for the design and operation of wastewater treatment plants. Also, the effluent quality to be met are more stringent. Therefore, an intelligent control approach is required in order to successful biological nitrogen removal. In this paper, the strategies for dosage of extra carbon in the anoxic zone and DO concentration in the aerobic zone are presented and evaluated through the simulation using the denitrification layout of the IWA simulation benchmark implemented by Matlab$\^$/5.3/Simulink$\^$/3.0. The control strategy to achieve sufficient denitrification rates in an anoxic zone. Methanol is used as an external extra carbon source. The external extra carbon source is required for the nitrogen removal process because nitrogen and organic concentration are fluctuated in the influent flowrate. The dissolved oxygen is calculated by So concentration in the activated sludge model NO.1. The air flowrate of each aerobic reactor is intelligently controlled to achieve the predefined setpoints. Air flowrate is adjusted by the fuzzy logic controller that includes two inputs and one output. The objective function for the optimization procedure is designed to improve effluent quality and reduce the operating cost.

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Experimental study on the applicability of liquid air as the refrigerant in artificial ground freezing for subsea tunnels (해저터널을 위한 동결공법 냉매로서의 액화공기 적용성에 대한 실험적 연구)

  • Son, Young-Jin;Choi, Hyeungchul;Moon, Hung-Man;Choi, Hangseok;Ko, Tae Young
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.18 no.2
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    • pp.175-181
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    • 2016
  • In this paper, the liquid air was selected as the refrigerant in artificial ground freezing to be used for rapid ground freezing and to reduce the risk of suffocation and the applicability of liquid air was verified. In order to evaluate the stability of the liquid air, the oxygen concentration of mixtures with liquid nitrogen and liquid oxygen was experimentally examined to meet the oxygen concentration criteria in the Occupational Safety and Health Act. In addition, the effects of the mixture ratio of liquid nitrogen and liquid oxygen, pressure and flow rate change in the storage vessel on the oxygen concentration in the liquid air were investigated. As a result, the ratio of liquid nitrogen and liquid oxygen 8: 2 was shown to meet the oxygen concentration standards. Pressure and flow rate change in the storage vessel did not have significant effects on the oxygen concentration in the liquid air.