• Title/Summary/Keyword: Nitrogen Recycling

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A Study on Investigate the Suitability of ${NH_4}^+$ Applications of Food Waste Water Instead of Urea in the Incineration of Municipal Solid Waste (생활폐기물 소각시 요구되는 요소수의 대체물질로 음식물 폐수 속의 암모니아 적용에 관한 연구)

  • Go, Sung Gyoo;Cho, Yong Kun;Lee, Young Shin
    • Journal of the Korea Organic Resources Recycling Association
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    • v.20 no.4
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    • pp.97-105
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    • 2012
  • This study examined for possibility of the food wastewater incineration treatment method as one of overland treatment method by incineration through liquefied spray of food wastewater when incinerating domestic wastes under operation and for the relationship, etc of air discharge material discharged in incineration, and the results of study are as follow: The food wastewater as one of overland treatment method was analysed 94-96% of moisture contents. Temperature of incinerator outduct during mixed incineration of food wastewater with MSW was average $897^{\circ}C$ and incineration of only MSW was $925^{\circ}C$. Temperature of the mixed incineration of food wastewater was dropped about $28^{\circ}C$ by incineration of only MSW. Concentration of nitrogen oxides(NOx) among air discharge gases was studied by 50ppm, 46ppm when inputting $200{\ell}/hr$, $300{\ell}/hr$ into the incinerator as the quantity of food wastewater. In the mixed incineration of food wastewater, generation speed of scales in the inside of a tubular exhaust gas boiler became rapid and the scale generation quantity became large but the exhaust gas boiler normally operated since scales were removed in cleaning of the tube with a compressive air cleaning facility and there was no opening clogging phenomena in a filter cloth of the filtering dust collector. The overland treatment method, not ocean dumping of food wastewater can be proposed as a technology since mixed incineration of food wastewater with MSW in the existing domestic waste incineration plant is possible, and operation costs of the incineration facility were reduced since use of chemicals such as ammonia and urinary hydrogen ion excretion, etc used in incineration facilities for removing nitrogen oxides(NOx).

A Scale-Up Test for Preparation of AlN by Carbon Reduction and Subsequent Nitridation Method (탄소환원질화법에 의한 AlN 제조 규모확대 시험결과)

  • Park, Hyung-Kyu;Kim, Sung-Don;Nam, Chul-Woo;Kim, Dae-Woong;Kang, Moon-Soo;Shin, Gwang-Hee
    • Resources Recycling
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    • v.25 no.5
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    • pp.75-83
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    • 2016
  • AlN powder was prepared by carbon reduction and subsequent nitridation method through the scale-up experiments of 0.7 ~ 1.5 kg per batch. AlN powder was synthesized using the mixture of $Al_2O_3$ powder and carbon black at $1,550{\sim}1,750^{\circ}C$ for 0.5 ~ 4 hours under nitrogen atmosphere (flow rate of nitrogen gas: $10{\sim}40{\ell}/min$) at $2.0{\times}10^{-1}Torr$. Experimental results showed that $1,700{\sim}1,750^{\circ}C$ for the reaction temperature, 3 hr for reaction time, and $40{\ell}/min$ for the flow rate of nitrogen gas were the optimal conditions. Also, in order to remove carbon in the synthesized AlN, the remained carbon was removed at $650{\sim}750^{\circ}C$ for 1 ~ 2 hr using horizontal tube furnace. The results showed that 1 : 3.2 mol ratio of $Al_2O_3$ to carbon black, reaction temperature of $750^{\circ}C$, reaction time of 2 hours, rotating speed of 1.5 rpm under atmosphere condition were the optimal conditions. Under these conditions, high-purity AlN powder over 99% could be prepared: carbon and oxygen contents of the AlN powder were 835 ppm and 0.77%, respectively.

Effect of Organic Materials Use Recommendation System on Soil N Mineralization and Rice Productivity in Organic Paddy (유기자원 사용처방 기준 적용에 따른 토양 질소 무기화 및 유기 벼 생산성)

  • Lee, Cho-Rong;Lee, Sang-min;Hwang, Hyeon-Yeong;Kwon, Hyeok-Gyu;Jung, Jung A;An, Nan-Hee
    • Journal of the Korea Organic Resources Recycling Association
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    • v.29 no.2
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    • pp.15-23
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    • 2021
  • This study was conducted to evaluate the field application of the developed recommendation system in organic rice (Oriza sativa L.) paddy and to investigate the mineral nitrogen content in soil and rice productivity. According to the developed system, hairy vetch (HV), rye+rapeseed oil cake (R+OC), rapeseed oil cake (OC) for only basal fertilization (OC-B), OC for split application (OC-S), pig manure compost (PMC), and chemical fertilizer (CHM) were applied to paddy soil at the rate of 107~133 kg N/ha. Results were followed, unhulled rice yield of OC-S (111%), OC-B (110), R+OC (106), HV (101), and PMC (96) were no significantly different with CHM (100). Also there was positive correlation (R2=0.803*) between unhulled rice yield and cumulative inorganic N in soil. For nitrogen use efficiency of rice, OC-B, OC-S, and R+OC were not significantly different with CHM. In conclusions, the developed organic materials use recommendation system was effective for organic rice productivity. It could be useful for organic farmer to apply the organic materials use recommendation system for rice.

Effect of Ammonia Nitrogen Loading Rate on the Anaerobic Digestion of Slurry-typed Swine Wastewater (슬러리형 돈사폐수의 혐기성 소화시 암모니아 부하의 영향)

  • Won, Chul-Hee;Kwon, Jay-Hyouk;Rim, Jay-Myoung
    • Journal of the Korea Organic Resources Recycling Association
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    • v.17 no.1
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    • pp.49-57
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    • 2009
  • This research examined the effect of ammonia nitrogen loading rate(NVLR) on the anaerobic digestion of slurry-typed swine wastewater. The anaerobic reactor was used an upflow anaerobic sludge blanket (UASB) process. This UASB reactor was operated at a NVLR of $0.02{\sim}0.96kg{NH_4}^+-N/m^3/day$. The methane content showed the range of 73.3~77.9% during the steady state period. Free ammonia(FA) concentration increased over inhibition level as pH increase from 7.3 to 8.2. However, in consideration of methane content, methane producing bacteria (MPB) inhibition by FA and total ammonia(TA) was not observed. A stepwise increase of the NVLR resulted in a deterioration in the COD removal rate in UASB reactor. The COD removal rate were 60% for NVLR up to $0.55kg{NH_4}^+-N/m^3/day$. As the NVLR increased from 0.09 to $0.96kg{NH_4}^+-N/m^3/day$, the biogas production rate varied from 3.71 to 9.14L/d and the methane conversion rate of the COD varied from 0.32 to $0.20m^3CH_4/kg$ COD removed. Consequently, in considerations of FA concentration, COD removal rate, and $CH_4$ production rate, the UASB reactor must be operated to lower than $0.40kg{NH_4}^+-N/m^3/day$ of NVLR.

Feasibility Study on the Development of Environmental Friendly Livestock Complex in the Reclaimed Tideland (간척지 자연순환형 친환경축산단지 도입 타당성 연구)

  • Heo, Nam-Hyo;Lee, Seung-Heon;Kim, Byeong-Ki
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.430-433
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    • 2009
  • The development of large-scale environmental friendly livestock complex in the reclaimed tideland is one of different alternatives to increase the competitiveness of internal livestock industry against an international opening markets as DDA and FTA in agricultural field. Recently, it is possible to introduce an environmental friendly livestock complex in the reclaimed tideland by an amendment of the acts for agricultural land. However more studies that are on the basis of nitrogen and phosphorus mass balance need to preserve the agricultural environments as the quality of agricultural water and soil in rural area. In this study, the reference for feasibility study is Whaong reclaimed tideland which located at Whaseong city, Gyeonggi Province, and a basic concept of environmental friendly livestock complex is the production of forage crops with the supply of liquid fertilizer and the production of bioenergy such as biogas by the recycling of pig slurry as a resource. The mass balance of nitrogen based on between forage crops such as maize, barley and liquid fertilizer supplied at the reclaimed tideland, and also it was estimated an economical efficiency as anaerobic digestion plant for treating pig slurry of $100m^3/day$ introduce in an environmental friendly livestock complex.

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Anaerobic/oxic Treatment of Slurry-type Swine Waste

  • Won, Chul-Hee;Rim, Jay-Myoung
    • Environmental Engineering Research
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    • v.13 no.4
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    • pp.203-209
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    • 2008
  • This paper presents the experimental results in five months operation from a combined anaerobic/oxic system treating swine waste with average concentrations in organic matter and nitrogen of 7,930 mgCOD/L and 671 mgTKN/L, respectively. The system was formed using an upflow anaerobic sludge blanket (UASB) reactor and oxic reactor connected in series with a recycling line of oxic effluents to UASB for its denitrification. The UASB reactor was operated at an organic volumetric loading rate (VLR) of $2.1{\sim}4.5\;kgTCOD/m^3$/day and the removal efficiency of TCOD was $66.3{\sim}85.4%$. The overall removal efficiency of TCOD was more than 99%. The oxic reactor was operated at a nitrogen VLR of $0.10{\sim}0.20\;kgTKN/m^3$/day and the nitrification efficiency was 75%. However, the complete denitrification was observed in the UASB reactor that was due to the optimal temperature and sufficient carbon source. The overall removal rate of TN was about 80%. About 76.2% of the influent COD mass was accountable in a COD mass balance at a level of VLR $3.64\;kgCOD/m^3$/day. The production rate of methane was $0.32\;LCH_4/gCOD_{removed}$ when influent organics, VLR, were recorded by $3.4{\sim}4.5\;kgCOD/m^3$/day.

Effects of Pre-aeration on the Anaerobic Digestion of Sewage Sludge

  • Ahn, Young-Mi;Wi, Jun;Park, Jin-Kyu;Higuchi, Sotaro;Lee, Nam-Hoon
    • Environmental Engineering Research
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    • v.19 no.1
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    • pp.59-66
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    • 2014
  • The aim of this study was to assess the effect of pre-aeration on sludge solubilization and the behaviors of nitrogen, dissolved sulfide, sulfate, and siloxane. The results of this study showed that soluble chemical oxygen demand in sewage sludge could be increased through pre-aeration. The pre-aeration process resulted in a higher methane yield compared to the anaerobic condition (blank). The pre-aeration of sewage sludge, therefore, was shown to be an effective method for enhancing the digestibility of the sewage sludge. In addition, this result confirms that the pre-aeration of sewage sludge prior to its anaerobic digestion accelerates the growth of methanogenic bacteria. Removal rates for $NH_3$-N and T-N increased simultaneously during pre-aeration, indicating simultaneous nitrification and denitrification. The siloxane concentration in sewage sludge decreased by 40% after 96 hr of pre-aeration; in contrast, the sulfide concentration in sewage sludge did not change. Therefore, pre-aeration can be employed as an efficient treatment option to achieve higher methane yield and lower siloxane concentration in sewage sludge. In addition, reduction of nitrogen loading by pre-aeration can reduce operating costs to achieve better effluent water quality in wastewater treatment plant and benefit the anaerobic process by minimizing the toxic effect of ammonia.

Metabolic Flux Analysis of Beijerinckia indica for PS-7 Production

  • Wu Jian-Rong;Son Jeong Hwa;Seo Hyo-Jin;Kim Ki-Hong;Nam Yoon-Kwon;Lee Jin-Woo;Kim Sung-Koo
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.10 no.1
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    • pp.91-98
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    • 2005
  • In order to investigate central metabolic changes in Beijerinckia indica, cells were grown on different carbon sources and intracellular flux distributions were studied under varying concentrations of nitrogen. Metabolic fluxes were estimated by combining material balances with extracellular substrate uptake rate, biomass formation rate, and exopolysaccharide (EPS) accumulation rate. Thirty-one metabolic reactions and 30 intracellular metabolites were considered for the flux analysis. The results revealed that most of the carbon source was directed into the Entner-Doudoroff pathway, followed by the recycling of triose-3-phosphate back to Hexose­6-phosphate. The pentose phosphate pathway was operated at a minimal level to supply the precursors for biomass formation. The different metabolic behaviors under varying nitrogen concentrations were observed with flux analysis.

A Comparison of Nitrogen Cycling among Young Pinus koraiensis Plantations of Different Ages (잣나무 유림의 수령에 따른 질소순환의 비교)

  • Cho, Kang-Hyun;Kim, Joon-Ho
    • The Korean Journal of Ecology
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    • v.12 no.4
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    • pp.245-256
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    • 1989
  • Nitrogen cycling was in vestigated in Piuns koraiensis plantations with different ages, 1, 2, 3, 6, 9 and 11 years, which were reforested after clear-cutting. Annual N input by bulk precipitation was 10kg., and output by runoff decreased as the plantation aged, especially in-N. The standing N content of the whole vegetation increased approximately 5 times through 11 years. Understory surpassed P. koraiensis plants in the distribution of standing N content for the initial 9 years, but reversed thereafter. Annual N uptake of P. koraiensis plants increased greatly through 11 years, but that of understory increased somewhat until 9 years and decreased thereafter. The maximum N uptake of the whole vegetation was made in the 9-yr-old plantation. In the 1-yr-old one, 59% of the maximum was already absorbed by understory which mainly consisted to herbs. The recycling coefficient, ratio of annual return to rptake, of the whole vegetation decreased as the plantation aged and the value of understory was greater than that of P koraiensis plants. On the contrary, the N use efficiency, ratio of the net primary production to N uptake, of the whole vegetation increased as the plantation aged and the value of understory was less than that of P. koraiensis plants. Consequently, it is emphasized that understory played an important role in such plantation reforesred after clear-cutting for the initial 9 years.

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Evaluate of high solid manure characteristics and theoretical methane potential in domestic (국내 고상가축분뇨 특성 및 이론적 메탄 잠재성에 대한 평가)

  • Choi, Yongjun;Lee, Sangrak
    • Journal of Animal Environmental Science
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    • v.22 no.1
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    • pp.35-44
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    • 2016
  • This study was conducted to establish a database of high solid manure(HSM) in domestic. Theoretical methane potential and HSM characteristics was evaluated using breef and dairy manure (n=156). Total solids and Volatile solids of HSM increased depending on time flow, the results showed $20.4{\pm}3.2$ and $17.4{\pm}2.8%$. respectively. C/N ratio of breef HSM was higher than dairy HSM C/N ratio. In theoretical methane potential, the result of breef and dairy HSM was showed $505.2{\pm}25.3$ and $493.5{\pm}20.2$, respectively. Nitrogen content of total HSM increased depending on time flow, the result of breef and dairy nitrogen content was showed $1.9{\pm}0.3$ and $2.8{\pm}0.2$, respectively. Carbon content of total HSM showed approximately 10% reduction. The optimal time of bed replacement was indicated between 29 amd 31 days based on the optimal C/N ratio. Therefore, this study was considered that it has high utilization for livestock manure recycling and basis of relevant research.