• Title/Summary/Keyword: Nitrogen Oxide

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미끄럼운동 시 TiN코팅에 형성되는 산화막이 마찰 및 마멸 특성에 미치는 영향

  • Jo, Jeong-U;Im, Jeong-Sun;U, Sang-Gyu;Lee, Yeong-Je
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.05a
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    • pp.310-316
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    • 2002
  • In this study, the effects of oxide layer formed on the wear tracks of TiN coated silicon wafer on friction and wear characteristics were investigated. Silicon wafer was used for the substrate of coated disk specimens, which were prepared by depositing TiN coating with $1{\mu}m$ in coating thickness. AISI 52100 steel ball was used for the counterpart. The tests were performed both in air for forming oxide layer on the wear track and in nitrogen to avoid oxidation. This paper reports characterization of the oxide layer effects on friction and wear characteristics using X-ray diffraction (XRD). Auger electron spectroscopy (AES), scanning electron microscopy (SEM) and sliding tests.

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Temperature Dependance of Propagation Velocity in a Silver Sheathed Bi-family Superconducting Oxid Tape (Bi계 은시스산화물초전도테프의 쿠엔치전파특성의 온도의존성)

  • Kim, Seok-Beom;Aoki, Keisuke;Ishiyama, Atsushi
    • Proceedings of the KIEE Conference
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    • 1994.07a
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    • pp.76-78
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    • 1994
  • Owing to the discover of oxide superconducting over critical temperature100K, it is being made experimentally somewhere under the possibility that there is superconducting magnet by cooling liquid nitrogen. The issues of thermal stability and quench process of Low-Tc superconductor has been studied and used application of oxide superconducting magnets. However the quench propagation property of oxide superconductor, especially experimental data about thermal behavior has not been reported yet. Therefore we measured the effect of temperature dependance of quench propagation velocity, Vq, by using the short samples made up of silver sheathed Bismuth-family (2223phase) superconducting oxide tape.

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Streptococcus mutans Strains Isolated in Korea Can Hardly Metabolize Exogenous Nitric Oxide

  • Lee, Hwa Jeong;Bang, Iel Soo
    • International Journal of Oral Biology
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    • v.40 no.4
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    • pp.217-221
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    • 2015
  • Cariogenic Streptococcus mutans encounters a variety of host defense factors produced in oral cavity. Nitric oxide (NO) and NO-mediated reactive nitrogen species are potential antimicrobials of innate immunity that can threaten the fitness of S. mutans in their ecological niches. Streptococcal strategies to detoxify cytotoxic NO, which allow S. mutans to persist in caries or other environments of the oral cavity, remain unknown. In this study, we directly measured NO consumption rates of S. mutans isolated in Korea. Surprisingly, all S. mutans strains were unable to consume exogenous NO efficiently, while an intracellular parasite Salmonella enterica serovar Typhimurium expressing the NO-metabolizing enzyme flavohemoglobin consumed most of the NO. This result suggested that S. mutans has alternative detoxification systems for tolerating NO-induced nitrosative stresses.

Synthesis of Titanium Diboride and Composites by Carbothermic Reduction of Titanium Oxide and Boric Oxide

  • Yoon, Su-Jong;Jha, Animesh
    • The Korean Journal of Ceramics
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    • v.4 no.4
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    • pp.387-393
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    • 1998
  • The formation of titanium diboride ($TiB_2$ ) via the reduction of $TiO_2$ with boric oxide and carbon was studied in a partially reducing atmosphere of argon mixed with 4 vol.%H2. The effect of reaction time, temperature, partial pressure of nitrogen and $TiO_2/B_2_O3$ stoichiometric ratio on the reducibility of oxides has been studied. The phases formed were analysed by using X-ray rowder diffraction and scanning sosctron microscopic techniques. In this paper, we also investigated the presence of $CaC_2$ as a reducing agent on the reducibility of oxide mixtures and on the Ti-B-C-Ca-O phase equilibria. The morphology of $TiB_2$ formed in the presence of $CaC_2$ is compared with the microstructure of $TiB_2$ formed as a consequence of carbothermic reduction. The observed variation in $TiB_2$ crystals formed is also explained.

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미끄럼시험시 TiN 코팅볼과 스틸디스크에 형성되는 산화막의 특성과 마찰특성에 미치는 영향

  • 조정우;박동신;임정순;이영제
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2001.06a
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    • pp.401-405
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    • 2001
  • The effects of oxide layer formed on TiN coated ball and counter-body have been investigated from the frictional point of view during sliding tests. AISI52100 steel ball was used for the substrate of coated specimens. Two types of coated specimens were prepared by depositing TiN coating with 1 and 4$\mu\textrm{m}$ in coating thickness. AISI1045 steel was used for the disk type counter-body. To investigate the effect of oxide layer on the contact parts of two materials, the tests were performed both in ambient for forming oxide layer on the contact parts and in nitrogen environment to avoid oxidation.

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A Study on the Prediction of Nitrogen Oxide Emissions in Rotary Kiln Process using Machine Learning (머신러닝 기법을 이용한 로터리 킬른 공정의 질소산화물 배출예측에 관한 연구)

  • Je-Hyeung Yoo;Cheong-Yeul Park;Jae Kwon Bae
    • Journal of Industrial Convergence
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    • v.21 no.7
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    • pp.19-27
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    • 2023
  • As the secondary battery market expands, the process of producing laterite ore using the rotary kiln and electric furnace method is expanding worldwide. As ESG management expands, the management of air pollutants such as nitrogen oxides in exhaust gases is strengthened. The rotary kiln, one of the main facilities of the pyrometallurgy process, is a facility for drying and preliminary reduction of ore, and it generate nitrogen oxides, thus prediction of nitrogen oxide is important. In this study, LSTM for regression prediction and LightGBM for classification prediction were used to predict and then model optimization was performed using AutoML. When applying LSTM, the predicted value after 5 minutes was 0.86, MAE 5.13ppm, and after 40 minutes, the predicted value was 0.38 and MAE 10.84ppm. As a result of applying LightGBM for classification prediction, the test accuracy rose from 0.75 after 5 minutes to 0.61 after 40 minutes, to a level that can be used for actual operation, and as a result of model optimization through AutoML, the accuracy of the prediction after 5 minutes improved from 0.75 to 0.80 and from 0.61 to 0.70. Through this study, nitrogen oxide prediction values can be applied to actual operations to contribute to compliance with air pollutant emission regulations and ESG management.

Enhancing Electrical Properties of Sol-Gel Processed IGZO Thin-Film Transistors through Nitrogen Atmosphere Electron Beam Irradiation (질소분위기 전자빔 조사에 의한 졸-겔 IGZO 박막 트랜지스터의 전기적 특성 향상)

  • Jeeho Park;Young-Seok Song;Sukang Bae;Tae-Wook Kim
    • Journal of the Microelectronics and Packaging Society
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    • v.30 no.3
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    • pp.56-63
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    • 2023
  • In this paper, we studied the effect of electron beam irradiation on sol-gel indium-gallium-zinc oxide (IGZO) thin films under air and nitrogen atmosphere and carried out the electrical characterization of the s ol-gel IGZO thin film transistors (TFTs). To investigate the optical properties, crystalline structure and chemical state of the sol-gel IGZO thin films after electron beam irradiation, UV-Visible spectroscopy, X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS) were carried out. The sol-gel IGZO thin films exhibited over 80% transmittance in the visible range. The XRD analysis confirmed the amorphous nature of the sol-gel IGZO films regardless of electron beam irradiation. When electron beam irradiation was conducted in a nitrogen (N2) atmosphere, we observed an increased proportion of peaks related to M-O bonding contributed to the improved quality of the thin films. Sol-gel IGZO TFTs subjected to electron beam exposure in a nitrogen atmosphere exhibited enhanced electrical characteristics in terms of on/off ratio and electron mobility. In addition, the electrical parameters of the transistor (on/off ratio, threshold voltage, electron mobility, subthreshold swing) remained relatively stable over time, indicating that the electron beam exposure process in a nitrogen atmosphere could enhance the reliability of IGZO-based thin-film transistors in the fabrication of sol-gel processed TFTs.

Studies on the Denitrification in the Submerged Paddy Soil -II. The Denitrification Rates Upon Kinds of Applied Organic Matter and Levels of Nitrogen Fertilizer (논토양(土壤)의 탈질작용(脫窒作用)에 관(關)한 연구(硏究) -제(第)II보(報). 유기물(有機物)의 종류(種類) 및 질소시비량차이(窒素施肥量差異)가 탈질(脫窒)에 미치는 영향(影響))

  • Lee, Sang-Kyu;Kim, Seung-Hwan;Park, Jun-Kyu;An, Sang-Bae
    • Korean Journal of Soil Science and Fertilizer
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    • v.19 no.1
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    • pp.76-82
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    • 1986
  • A laboratory experiment was conducted to find out the denitrification rate upon the levels of nitrogen and source of organic matter in submerged sandy and sandy loam soil. The results obtained were sumarized as follows; 1. Evolution of nitrous oxide was increased at 1st and 10 days after incubation. And dinitrogen was increased at 1st and 30 days after incubation. Applications of green manure was enhanced the evolution of nitrous oxide ($N_2O$) and dinitrogen ($N_2$). 2. The cumulative denitrification rates at 50 days was high in Gyuam sandy loam soil (O-M: 1.52%) than that of Hamchang sandy soil (O-M: 3.81%). On the other hand, the cumulative emission of dinitrogen was high in Gyuam sandy loam soil while nitrous oxide was high in Hamchang sandy soil. The total mount of denitrification rate was high in order of green manure > rice straw > compost > control soil. 3. Increases of fertilizer nitrogen was enhanced the rate of emission of dinitrogen and nitrous oxide during the incubation time. 4. According to Michaelis-Menten kinetic equation, denitrification rates and reaction efficiency were remarkably increased by application of readily decomposable organic matter with in higher organic matter content of soil. 5. The negative relationship was observed between the evolution of dinitrogen and carbon ($CO_2+CH_4$) while the nitrous oxide with carbon was positive. 6. Under the this experiment conditions 1 mg of carbon was required for production of 4 mg N as $N_2O$ and 3 mg of N as $N_2$, respectively.

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Evaluation of Oxidation Inhibition and Nitrogen Oxide Scavenging Activity from Curcuma longa L. Extracts (울금(Curcuma longa L.) 추출물의 산화억제 및 질소산화물 소거활성)

  • Oh, Da-Young;Kim, Han-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.1
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    • pp.13-22
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    • 2019
  • The aim of the present investigation was to assess the oxidation inhibition by nitrogen oxide scavenging activity and physiological activities. Bioactive compound of proanthocyanidin $69.000{\pm}2.737mg$ catechin equivalents (CE)/g dry weight. Antioxidant effects (nitric oxide radical scavenging activity, nitrite scavenging activity, ${\beta}$-carotene bleaching assay and lipid peroxidation inhibition activity) of distilled water (DW), 70% ethanol and n-butanol extract of turmeric (Curcuma longa L.). Turmeric extracts yield were DW 17.11%, 70% ethanol 15.26% and n-butanol 4.12%, respectively. Oxidation inhibition activity of the samples exhibited a dose-dependent increase. However, in the current study, none of the samples evaluated showed activity as strong as the BHA and trolox. Total flavonoid content was the highest in the n-butanol extract, followed by 70% ethanol and DW extract. Further, nitrite scavenging activity was the highest for the n-butanol extract. As a result of this experiment, the turmeric can be utilized as a valuable and potential natural oxidation inhibition for the functional food industry.

Enhancement of Nitric Oxide with nonthermal plasma jet and its effect on Escherichia coli inactivation and various type of cancer cell

  • Shaw, Priyanka;Kumar, Naresh;Attri, Pankaj;Choi, Eun Ha
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.230.2-230.2
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    • 2016
  • A new approach for antimicrobial is based on the overproduction of reactive nitrogen species (RNS), especially; nitric oxide (NO) and peroxinitrite ($ONOO^-$-) are important factors to deactivate the bacteria. Recently, non-thermal atmospheric pressure plasma jet (APPJ) has been frequently used in the field of microbial sterilization through the generation of different kinds of RNS/ROS species. However, in previous study we showed APPJ has combine effects ROS/RNS on bacterial sterilization. It is not still clear whether this bacterial killing effect has been done through ROS or RNS. We need to further investigate separate effect of ROS and RNS on bacterial sterilization. Hence, in this work, we have enhanced NO production, especially; by applying a 1% of HNO3 vapour to the N2 based APPJ. In comparison with nitrogen plasma with inclusion of water vapour plasma, it has been shown that nitrogen plasma with inclusion of 1% of HNO3 vapour has higher efficiency in killing the E. coli and different type of cancer cell through the high production of NO. We also investigate the enhancement of NO species both in atmosphere by emission spectrum and inside the solution by ultraviolet absorption spectroscopy. Moreover, qPCR analysis of oxidative stress mRNA shows higher gene expression. It is noted that 1% of HNO3 vapour plasma generates high amount of NO for killing bacteria and cancer cell killing.

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