• Title/Summary/Keyword: Nitrogen Generator

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NOx Reduction Characteristics of Ship Power Generator Engine SCR Catalysts according to Cell Density Difference (선박 발전기관용 SCR 촉매의 셀 밀도차에 따른 NOx 저감 특성)

  • Kyung-Sun Lim;Myeong-Hwan Im
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.28 no.7
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    • pp.1209-1215
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    • 2022
  • The selective catalytic reduction (SCR) is known as a very efficient method to reduce nitrogen oxides (NOx) and the catalyst performs reduction from nitrogen oxides (NOx) to nitrogen (N2) and water vapor (H2O). The catalyst, which is one of the factors determining the performance of the nitrogen oxide (NOx) ruduction method, is known to increase catalyst efficiency as cell density increases. In this study, the reduction characteristics of nitrogen oxides (NOx) under various engine loads investigated. A 100CPSI(60Cell) catalysts was studied through a laboratory-sized simulating device that can simulate the exhaust gas conditions from the power generation engine installed in the training ship SEGERO. The effect of 100CPSI(60Cell) cell density was compared with that of 25.8CPSI(30Cell) cell density that already had NOx reduction data from the SCR manufacturing. The experimental catalysts were honeycomb type and its compositions and materials of V2O5-WO3-TiO2 were retained, with only change on cell density. As a result, the NOx concentration reduction rate from 100CPSI(60Cell) catalyst was 88.5%, and IMO specific NOx emission was 0.99g/kwh satisfying the IMO Tier III NOx emission requirement. The NOx concentration reduction rate from 25.8CPSI(30Cell) was 78%, and IMO specific NOx emission was 2.00g/kwh. Comparing the NOx concentration reduction rate and emission of 100CPSI(60Cell) and 25.8CPSI(30Cell) catalysts, notably, the NOx concentration reduction rate of 100CPSI(60Cell) catalyst was 10.5% higher and its IMO specific NOx emission was about twice less than that of the 25.8CPSI(30Cell) catalysts. Therefore, an efficient NOx reduction effect can be expected by increasing the cell density of catalysts. In other words, effects to production cost reduction, efficient arrangement of engine room and cargo space can be estimated from the reduced catalyst volume.

A Study on Capacity of Electric Propulsion System by Load Analysis of 6,800TEU Container Ship (6,800TEU 컨테이너선의 부하분석을 통한 전기추진시스템 용량 연구)

  • Jang, Jae-Hee;Son, Na-Young;Oh, Jin-Seok
    • Journal of Navigation and Port Research
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    • v.42 no.6
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    • pp.437-445
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    • 2018
  • IMO (International Maritime Organization) has been strengthening the regulations of ship emission gas such as sulfur oxides (SOX), nitrogen oxides (NOX) and carbon dioxides (CO2) to protect the marine environment. Especially, ECA (Emission Control Area) has been set and operated in the USA and US. As a countermeasure against these environmental regulations, the demand for environmentally, friendly and highly efficient vessels has led to a growing interest in technology related research with respect to electric propulsion systems capable of reducing exhaust gas. Container ships were excluded from the application coverage of the electric propulsion systems for reasons of operation at economical speed. However, in the future, the need for electric propulsion system is expected to rise, because it is easy to monitor and control so that it can be an applicate to smart ship which are represented by fourth industrial revolution technology. In this study, research was carried out to design a generator and battery capacity through the load analysis of the 6,800TEU container ship to apply the electric propulsion system of the container ship. A capacity design based on the load analysis has an advantage that the generator can be operated in a high efficiency section through the load distribution control using the battery.

Simultaneous Removal of $SO_2$ and NOx Using Ozone Generator and Absorption- Reduction Technique (오존발생장치와 흡수환원법을 이용한 배기가스 동시 탈황 탈질 공정)

  • Mok, Young-Sun;Lee, Joo-Hyuck;Shin, Dong-Nam;Koh, Dong-Jun;Kim, Kyong-Tae
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.2
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    • pp.191-196
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    • 2006
  • The injection of ozone, produced by dielectric barrier discharge, into the exhaust gas gives rise to a rapid oxidation of NO that is the main component of nitrogen oxides($NO_x$) in most practical exhaust gases. Once NO is converted into $NO_2$, it on readily be reduced to $N_2$ in the next step by a reducing agent such as sodium sulfide and sodium sulfite. The reducing agents used ca also remove $SO_2$ effectively, which makes it possible to treat $NO_x\;and\;SO_2$ simultaneously. The present two-step process made up of an ozonizing chamber and an absorber containing a reducing agent solution was able to remove about 95% of the $NO_x$ and 100% of the $SO_2$, initially contained in the simulated exhaust gas. The formation of $H_2S$ from sodium sulfide was prevented by using a strong basic reagent(NaOH) together with the reducing agent. The removal of $NO_x$\;and\;SO_2$ was more effective for $Na_2S$ than $Na_2SO_3$.

High Concentration Ozone Generation Characteristics by Variation of Additional Gases and Flow Rates of Inlet Gas (입력가스의 유량변화와 첨가가스에 따른 고농도 오존발생특성)

  • 박승록;이대희
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.16 no.6
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    • pp.95-101
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    • 2002
  • There are many effective parameters to high concentration ozone generation. These parameters became very important elements should be considered before designing ozone generator. After designing, there are many peripheral parameters to greatly affect to high concentration ozone generation also. In this study, of many effective peripheral parameters on high concentration ozone generation, the effects of flow rate of inlet oxygen gas and some kinds of additional gases on ozone concentration were investigated As a result, when inlet oxygen gas was introduced at the range of 0.75[LPM]~2.00[LPM] the highest ozone concentration of 71145[ppm] was obtained at 1.25[LPM]. When the additional nitrogen gas was mixed to oxygen gas at the range of 0.0[vol%]~6.4[vol%] the highest ozone concentration of 73135[ppm] was obtained at 0.8[vol%] of nitrogen gas. This showed 3[%] increasing compared to the case of pure oxygen gas inlet. When the additional argon gas was mixed to oxygen gas at the range of 0.0[vol%]~6.4[vol%] the highest concentration of 67288[ppm]was obtained at 0.8[vol%]of argon gas. This is decreased value compared to that of introducing the pure oxygen.

Heat Exchanger Design Analysis for Propellant Pressurizing System of Satellite Launch Vehicles (소형위성 발사체용 추진제 가압 열교환기 설계 해석)

  • Lee H. J.;Han S. Y.;Chung Y. G.;Cho N. K.;Kil G. S.;Kim Y. K.
    • Journal of computational fluids engineering
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    • v.9 no.3
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    • pp.49-56
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    • 2004
  • A heated and expanded helium is used to pressurize liquid propellants in propellant tanks of propulsion system of liquid propellant launch vehicles. To produce a heated and expanded helium, an hot-gas heat exchanger is used by utilizing heat source from an exhausted gas, which was generated in a gas generator to operate turbine of turbo-pump and dumped out through an exhaust duct of engine. Both experimental and numerical approaches of hot-gas heat exchanger design were conducted in the present study. Experimentally, siliconites - electrical resistance types - were used to simulate the full heat condition instead of an exhausted gas. Cryogenic heat exchangers, which were immersed in a liquid nitrogen pool, were used to feed cryogenic gaseous helium in a hot-gas heat exchanger. Numerical simulation was made using commercially utilized solver - Fluent V.6.0 - to validate experimental results. Helically coiled stainless steel pipe and stainless steel exhausted duct were consisted of tetrahedron unstructured mesh. Helium was a working fluid Inside helical heat coil and regarded as an ideal gas. Realizable k-』 turbulent modeling was adopted to take turbulent mixing effects in consideration. Comparisons between experimental results and numerical solutions are Presented. It is observed that a resulted hot-gas heat exchanger design is reliable based on the comparison of both results.

Environmental Change and Its Enhancement of a Bay Sediment by Using Useful Microbial and Chemical Treatments (연안저질 환경 개선을 위한 유용 미생물제제 및 산화제의 사용에 따른 환경변화 및 효율성 관찰)

  • Cho, Dae-Chul;Bae, Hwan-Jin;Lee, Jung-Yeol;Kwon, Sung-Hyun
    • Journal of Environmental Science International
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    • v.19 no.11
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    • pp.1355-1362
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    • 2010
  • This study was carried out in order to observe how the bay sediment would be changed with microbial treatments and a chemical oxidant like $CaO_2$. The sediment during the treatments was analyzed in terms of pH, ORP, volatile organics content, COD, AVS, T-N, and T-P. With $CaO_2$ treatment, pH was kept over 9.66 and ORP ranged from +4.70~+46.0, which meant an aerobic state meanwhile with the microbial treatment those were worse. In addition the chemical treatment showed better environmental index values than the microbial one: volatile organics content and COD values in the former were 12.9% and 37.9% while those in the latter were 4.5% and 18.7%, respectively. AVS and T-P were 71.1% and 100% versus 56.5% and 85.8%, respectively. However, the microbial treatment was better for T-N(66% higher). On the other hand, both treatment at a time enhanced all the environmental indices but COD meantime pH and ORP values were lower than with the chemical treatment only. Thus additional input of an oxygen generator like $CaO_2$ could improve the environmental state of a bay sediment where the biological treatment is going on.

EXPERIMENTS ON THE PERFORMANCE SENSITIVITY OF THE PASSIVE RESIDUAL HEAT REMOVAL SYSTEM OF AN ADVANCED INTEGRAL TYPE REACTOR

  • Park, Hyun-Sik;Choi, Ki-Yong;Choi, Seok;Yi, Sung-Jae;Park, Choon-Kyung;Chung, Moon-Ki
    • Nuclear Engineering and Technology
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    • v.41 no.1
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    • pp.53-62
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    • 2009
  • A set of experiments has been conducted on the performance sensitivity of the passive residual heat removal system (PRHRS) for an advanced integral type reactor, SMART, by using a high temperature and high pressure thermal-hydraulic test facility, the VISTA facility. In this paper the effects of the opening delay of the PRHRS bypass valves and the closing delay of the secondary system isolation valves, and the initial water level and the initial pressure of the compensating tank (CT) are investigated. During the reference test a stable flow occurs in a natural circulation loop that is composed of a steam generator secondary side, a secondary system, and a PRHRS; this is ascertained by a repetition test. When the PRHRS bypass valves are operated 10 seconds later than the secondary system isolation valves, the primary system is not properly cooled. When the secondary system isolation valves are operated 10 or 30 seconds later than the PRHRS bypass valves, the primary system is effectively cooled but the inventory of the PRHRS CT is drained earlier. As the initial water level of the CT is lowered to 16% of the full water level, the water is quickly drained and then nitrogen gas is introduced into the PRHRS, resulting in the deterioration of the PRHRS performance. When the initial pressure of the PRHRS is at 0.1MPa, the natural circulation is not performed properly. When the initial pressures of the PRHRS are 2.5 or 3.5 MPa, they show better performance than did the reference test.

Effect of Ultrasound on the Decomposition of Sodium Dodecylbenzene Sulfonate in Aqueous Solution (Sodium Dodecylbenzene Sulfonate 수용액의 분해반응에서 초음파 효과)

  • Yim, Bong-Been
    • Journal of the Korean Chemical Society
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    • v.48 no.6
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    • pp.561-567
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    • 2004
  • The influence of ultrasound frequency, dissolved gases, and initial concentration on the decomposition of sodium dodecylbenzene sulfonate(DBS) aqueous solution was investigated using ultrasound generator with 200 W ultrasound power. The decomposition rates at three frequencies(50, 200, and 600 kHz) examined under argon atmosphere were highest at 200 kHz. The highest observed decomposition rate at 200 kHz occurred in the presence of oxygen followed by air and argon, helium, and nitrogen. The effect of initial concentration of DBS on the ultrasonic decomposition was decreased with increasing initial concentration and would depend upon the formation of micelle in aqueous solution. It appears that the ultrasound frequency, dissolved gases, and initial concentration play an important role on the sonolysis of DBS. Sonolysis of DBS mainly take place at the interfacial region of cavitation bubbles by both OH radical attack and pyrolysis to alkyl chain, aromatic ring, and headgroup.

Vibration characteristics of an ultrasonic waveguide for cooling (냉각용 초음파 웨이브가이드의 진동 특성)

  • Kim, Hyunse;Lim, Euisu
    • The Journal of the Acoustical Society of Korea
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    • v.39 no.6
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    • pp.568-575
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    • 2020
  • Ultrasound has been widely used in various industrial fields. One of challenging application areas is cooling microelectronics. Ultrasonic cooling systems can work with air, argon (Ar) and nitrogen (N2) instead of conventional refrigerant such as freon gas, which can cause global warming. Furthermore, ultrasonic systems do not have moving parts, thus high durability can be obtained. So it is necessary to develop ultrasonic cooling systems due to environmental issues and durability points. In this paper, the design and fabrication processes are explained. When designing the system, a feasibility test was performed with a prototype cooler. Based on the result, finite element analysis with ANSYS software was performed. The predicted anti-resonance frequency for a piezoelectric actuator was 34.8 kHz, which was in good agreement with the experimental result of 34.6 kHz with 0.6% error. In addition, the predicted anti-resonance frequency for the ultrasonic waveguide was 39.4 kHz, which also agreed well with the experimental value of 39.8 kHz with 1.0% error. Based on these results, the developed ultrasonic waveguide might be applicable in microchip cooling.

Pre-treatment Characteristics of Night Soil by Microbubble (마이크로버블을 이용한 분뇨의 전처리 특성)

  • Lim, Ji-young;Kim, Hyun-sik;Park, Soo-young;Kim, Jin-Han
    • Journal of the Korea Organic Resources Recycling Association
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    • v.24 no.4
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    • pp.31-37
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    • 2016
  • This study was conducted to investigate the effect of OH radicals on organic matter oxidation and suspended solids removal using microbubble as a pre-treatment technique to reduce the organic load of night soil in connection with sewage. The experiment was conducted for three months at HRT 4 hours using pressurized type microbubble generator. The mean SS removal efficiency was achieved 71%. The average removal efficiency of $TCOD_{Cr}$, TBOD, TN and TP were achieved for 51.5%, 47.9%, and 14.7% respectively, as scum and SS were removed by flotation separation. The removal efficiency of soluble organic matters were 25.0%, 17.1% for $SCOD_{Cr}$, SBOD by air microbubble supply. Soluble nitrogen and phosphorus were removed average of 11.9% and 7.4%, respectively. As s result, it was confirmed that soluble organic matters were removed by air microbubble supplied. Generated OH radicals when the microbubble was collapsed, can decompose the soluble organic matters. Therefore, The microbubble flotation process was installed at the front of night soil treatment process, it will contribute to the stable operation of the subsequent biological treatment facility by oxidation of the dissolved organic matters as well as removal of SS by flotation separation.