• Title/Summary/Keyword: Nitrate loss

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Source Identification of PM2.5 at the Tokchok Island on the Yellow Sea (황해상 덕적도 PM2.5오염원의 확인)

  • 윤용석;배귀남;김동술;황인조;이승복;문길주
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.4
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    • pp.317-325
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    • 2002
  • An air pollution monitoring station has been operated at Tokchok Island since April 1999 to characterize the background atmosphere in the vicinity of the Yellow Sea. In this study, eight chemical species in PM$_{2.5}$ and three gaseous species were analyzed. A total of 53 samples were collected for the analysis of PM$_{2.5}$ and gaseous species from April, 1999 to April, 2001. The overall mean mass concentration of PM$_{2.5}$ was 20.8 $\mu\textrm{g}$/㎥ and the eight soluble ionic species accounted for about 46.8% of PM$_{2.5}$ mass. Approximately 80% of samples appeared to experience the chloride loss effect. Air pollutant sources of PM$_{2.5}$ measured at Tokchok Island were qualitatively identified by the principal component analysis. It was found that five principal components are secondary aerosol, soil, incineration, phase change of nitrate, and ocean.and ocean.

Effect of Calcium Spraying on Storage Quality of Onion(Allium Cepa L) (칼슘살포가 양파의 저장성에 미치는 영향)

  • 김희대;김우일;서전규;최종욱;이문중;김찬용
    • Food Science and Preservation
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    • v.7 no.1
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    • pp.19-22
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    • 2000
  • This study was carried out investigate the storability of onions on calcium spraying, after cutting foliage, 6 different treatemnt , the dilution spraying of calcium nitrate 9 3%, 6%) , calcium carbonate(3%, 6%), dust scattering and the controls were evaluated for rotting, sprouting, healthy bulb and total weight loss ratio during storage. Rotting ratio on the dilution spraying of 6% calcium carbonate was lower than that of the control after 4 months storage by 16.7%. Sprouting and total weight loss were decreased in the dilution spraying of 6% calcium carbonate.

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Effect of Precipitants and Precipitation Conditions on Synthesis of β-Ga2O3 Powder (침전제의 종류 및 침전 공정의 변화가 β-Ga2O3 분말 합성에 미치는 영향)

  • Hwang, Su Hyun;Choi, Young Jong;Ko, Jeong Hyun;Kim, Tae Jin;Jeon, Deok Il;Cho, Woo Suk;Han, Kyu Sung
    • Korean Journal of Materials Research
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    • v.24 no.4
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    • pp.214-220
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    • 2014
  • In this research, a precipitation method was used to synthesize ${\beta}-Ga_2O_3$ powders with various particle morphologies and sizes under varying precipitation conditions, such as gallium nitrate concentration, pH, and aging temperature, using ammonium hydroxide and ammonium carbonate as precipitants. The obtained powders were characterized in detail by XRD, SEM, FT-IR, and TG-DSC. From the TG-DSC result, GaOOH phase was transformed to ${\beta}-Ga_2O_3$ at around $742^{\circ}C$, and weight loss percent was about 14 % when $NH_4OH$ was used as a precipitant. Also, ${\beta}-Ga_2O_3$ formed at $749^{\circ}C$ and weight loss percent was about 15 % when $(NH)_2CO_3$ was used as a precipitant. XRD results showed that the obtained $Ga_2O_3$ had pure monoclinic phase in both cases. When $(NH)_2CO_3$ was used as a precipitant, the particle shape changed and became irregular. The range of particle size was about $500nm-4{\mu}m$ based on various concentrations of gallium nitrate solution with $NH_4OH$. The particle size was increased from $1-2{\mu}m$ to $3-4{\mu}m$ and particle shape was changed from spherical to bar type by increasing aging temperature over $80^{\circ}C$.

EFFECT OF TWO PVY STRAINS ON YIELD AND CHEMICAL CONSTITUENTS OF TOBACCO PLANT (두가지 계통의 PVY가 잎담배 수량 및 내용성분에 미치는 영향)

  • 박은경;김정화;이영근
    • Journal of the Korean Society of Tobacco Science
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    • v.7 no.1
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    • pp.7-13
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    • 1985
  • Effect of the two PVY strains(PVY-VB and PVY-VN) on yield and chemical constituents of tobacco plants was determined in roar. NC2326 and Burley 21. The virus was inoculated 6 and 8 weeks after transplanting, respectively. The strains and time of inoculation were most critical factors for yield reduction. The greatest reduction was caused by the necrotic strain (PVY-VN) inoculated 6 weeks after transplanting, accounting for the loss of 40% in var. NC2326 and of 45% in var.. Burley21. When inoculated 8 weeks after transplanting with the necrotic strain, only 17% reduction was recorded in roar. Burley21, but no reduction occurred in roar. NC2326. Generally less reduction was caused by the PVY-VB strain, ranging 12-16% depending on the time of inoculation and/or variety. Compared to healthy tobacco, PVY infected tobacco contained higher concentrations of total nitrogen, protein nitrogen, nitrate nitrogen, and lower total sugar in cured leaf of roar. NC2326. Total alkaloid, P, Mg, Ca, and K levels were not altered. In var. Burley21, protein nitrogen and nitrate nitrogen increased, but other chemical components were not changed. Necrotic strain-infected tobacco with a severe symptom had higher nitrogen than did mild strain-infected tobacco.

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Solution-Processed Anti Reflective Transparent Conducting Electrode for Cu(In,Ga)Se2 Thin Film Solar Cells (CIGS 박막태양전지를 위한 반사방지특성을 가진 용액공정 투명전극)

  • Park, Sewoong;Park, Taejun;Lee, Sangyeob;Chung, Choong-Heui
    • Korean Journal of Materials Research
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    • v.30 no.3
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    • pp.131-135
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    • 2020
  • Silver nanowire (AgNW) networks have been adopted as a front electrode in Cu(In,Ga)Se2 (CIGS) thin film solar cells due to their low cost and compatibility with the solution process. When an AgNW network is applied to a CIGS thin film solar cell, reflection loss can increase because the CdS layer, with a relatively high refractive index (n ~ 2.5 at 550 nm), is exposed to air. To resolve the issue, we apply solution-processed ZnO nanorods to the AgNW network as an anti-reflective coating. To obtain high performance of the optical and electrical properties of the ZnO nanorod and AgNW network composite, we optimize the process parameters - the spin coating of AgNWs and the concentration of zinc nitrate and hexamethylene tetramine (HMT - to fabricate ZnO nanorods. We verify that 10 mM of zinc nitrate and HMT show the lowest reflectance and 10% cell efficiency increase when applied to CIGS thin film solar cells.

Preparation of Electromagnetic Wave Shielding Fabrics by Electroless Silver Plating using PdCl2 and Dextrose (포도당 환원제와 PdCl2 촉매를 사용한 무전해 은도금 PET 직물의 제조)

  • Kim, Su-Mi;Song, Wha-Soon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.32 no.2
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    • pp.319-327
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    • 2008
  • The purpose of this study is to propose the development of high quality electromagnetic wave shielding fabrics. Silver nitrate is used for polyester fabric as an electromagnetic wave shielding material. The effects of activators and electroless silver plating condition on the evenness and adhesion of silver to fabrics, are observed through the SEM micrographs. Surface morphology and wash-ability are measured using SEM. The results are as follows: The optimum weight loss by alkaline hydrolysis of polyester fabrics is about 20%. The optimum concentration of $SnCl_2$ and $PdCl_2$in catalyst reaction using $PdCl_2$ as an activator is 2.5g/L and 0.5g/L, respectively. The optimum concentration of dextrose to improve adhesion between the silver plating and fabrics is 45g/L. The optimum concentration of silver nitrate in the catalyst reaction, using $PdCl_2$ as an activator is 56g/L, respectively. The optimum plating temperature and time are $15^{\circ}C$ and 30minutes, respectively.

Mobility of Nitrate and Phosphate through Small Lysimeter with Three Physico-chemically Different Soils (소형 라이시메터시험을 통한 토양특성에 따른 질산과 인산의 이동성 비교)

  • Han, Kyung-Hwa;Ro, Hee-Myong;Cho, Hyun-Jun;Kim, Lee-Yul;Hwang, Seon-Woong;Cho, Hee-Rae;Song, Kwan-Cheol
    • Korean Journal of Soil Science and Fertilizer
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    • v.41 no.4
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    • pp.260-266
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    • 2008
  • Small lysimeter experiment under rain shelter plastic film house was conducted to investigate the effect of soil characteristics on the leaching and soil solution concentration of nitrate and phosphate. Three soils were obtained from different agricultural sites of Korea: Soil A (mesic family of Typic Dystrudepts), Soil B (mixed, mesic family of Typic Udifluvents), and Soil C (artificially disturbed soils under greenhouse). Organic-C contents were in the order of Soil C ($32.4g\;kg^{-1}$) > Soil B ($15.0g\;kg^{-1}$) > Soil A ($8.1g\;kg^{-1}$). Inorganic-N concentration also differed significantly among soils, decreasing in the order of Soil B > Soil C > Soil A. Degree of P saturation (DPS) of Soil C was 178%, about three and fifteen times of Soil B (38%) and Soil A (6%). Prior to treatment, soils in lysimeters (dia. 300 mm, soil length 450 mm) were tabilized by repeated drying and wetting procedures for two weeks. After urea at $150kg\;N\;ha^{-1}$ and $KH_2PO_4$ at $100kg\;P_2O_5\;ha^{-1}$ were applied on the surface of each soil, total volume of irrigation was 213 mm at seven occasions for 65 days. At 13, 25, 35, 37, and 65 days after treatment, soil solution was sampled using rhizosampler at 10, 20, and 30 cm depth and leachate was sampled by free drain out of lysimeter. The volume of leachate was the highest in Soil C, and followed by the order of Soils A and B, whereas the amount of leached nitrate had a reverse trend, i.e. Soil B > Soil A > Soil C. Soil A and B had a significant increase of the nitrate concentration of soil solution at depth of 10 cm after urea-N treatment, but Soil C did not. High nitrate mobility of Soil B, compared to other soils, is presumably due to relatively high clay content, which could induce high extraction of nitrate of soil matrix by anion exclusion effect and slow rate of water flow. Contrary to Soil B, high organic matter content of Soil C could be responsible for its low mobility of nitrate, inducing preferential flow by water-repellency and rapid immobilization of nitrate by a microbial community. Leached phosphate was detected in Soil C only, and continuously increased with increasing amount of leachate. The phosphate concentration of soil solution in Soil B was much lower than in Soil C, and Soil A was below detection limit ($0.01mg\;L^{-1}$), overall similar to the order of degree of P saturation of soils. Phosphate mobility, therefore, could be largely influenced by degree of P saturation of soils but connect with apparent leaching loss only more than any threshold of P accumulation.

Effect of 15% Carbamide Peroxide Agents with and without Potassium Nitrate and Fluoride(PF) on the Tooth Color and Surface Microhardness of Human Enamel (15% 치아미백제의 potassium nitrate와 fluoride(PF) 함유 여부에 따른 치아색조와 미세경도 변화)

  • Woo, Hee-Sun;Shim, Youn-Soo
    • The Journal of the Korea Contents Association
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    • v.12 no.1
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    • pp.353-360
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    • 2012
  • The purpose of this study was to evaluate tooth color and microhardness after 15% carbamide peroxide(CP) bleaching treatments with/without potassium nitrate and fluoride(PF), which were used home bleaching. Thirty tooth specimens were obtained from thirty premolar and were randomly divided into three groups: 1, untreated controls(Distilled water): 2, treatment with 15% CP bleaching agent; 3, treatment with 15% CP bleaching agent (contained 3% potassium nitrate and 0.11% fluoride). All groups were treated 6h per day for 14 days then immersed in distilled water. Changes in enamel color were evaluated on Baseline and Day 14. Microhardness were evaluated on Baseline, Days 7 and 14. All the bleached enamel specimens revealed increased whiteness without control group. Groups 2 and 3 showed significantly decreased enamel microhardness compared to control group. On Day 7, Groups 2-3 showed significantly decreased enamel microhardness compared to control group and respective baseline data. The percentage microhardness loss(PML) look at Day 7 and 14 for Group 1, respectively, there was little difference between 1.7 and 0.8. However, Group 2 was 21.9 and 3.5, Group 3 was 16.7 and 1.4 as a baseline and Day 7 were significantly different (p<0.05). The PML of group 2 was significantly highest than that of group 3 on Day 7. As a result, the data indicate that the addition of PF did not influence the whitening efficacy of the bleaching agent negatively. PF-containing bleaching agent reduce the percentage microhardness loss. PF-containing tooth bleaching your teeth with a whitening effect can be reduced by decreasing the hardness of enamel.

Nutrient Losses from a Paddy Field

  • Cho, Jae-Young;Han, Kang-Wan
    • Journal of Applied Biological Chemistry
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    • v.43 no.4
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    • pp.258-263
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    • 2000
  • The study was carried out to investigate the nutrient losses at a paddy field located at the southwest of central Korea from May 1, 1997 to April 30, 1998. The studying area was 10 ha. The amounts of nutrients loaded by runoff water were measured as follows. The total-N was 1,031 and $61kg\;10ha^{-1}$ during the irrigation and non-irrigation periods, respectively. The total amount of N from both periods was $1,092kg\;10ha^{-1}\;yr^{-1}$. The total-P was 23 and $2kg\;10ha^{-1}$ during the irrigation and non-irrigation periods, respectively. The total amount of P from both periods was $25kg\;10ha^{-1}\;yr^{-1}$. For percolationloss, the losses of total-N, ammonia-N, nitrate-N, and total-P were 167,30,122, and $3kg\;10ha^{-1}$, respectively. The respective loss ratios of N and P by runoff water were 55.2 and 11.9%, while the loss ratios of N and P by percolationwere 8.4 and 1.4%.

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Internal Mixing of Pollutants for Submicron Particles Observed during Springtime in Japan

  • Matsumoto, Jun;Narukawa, Masahiro;Takahashi, Kenshi;Matsumi, Yutaka;Yabushita, Akihiro;Shimizu, Atsushi;Matsui, Ichiro;Sugimoto, Nobuo
    • Asian Journal of Atmospheric Environment
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    • v.3 no.1
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    • pp.27-41
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    • 2009
  • Internally mixed states of submicron particles during transport from the Asian continent to the Pacific Ocean were analyzed using a single-particle time-offlight mass spectrometer. The observation was conducted at Tsukuba in Japan in the spring of 2005 in order to investigate springtime transport of particles from the continent. The sum of ion intensities of sulfate (${HSO_4}^-$) detected in particles originating from the continental air masses counted for 75% of that in all particles during the observation. By analyzing correlations among compounds, origins and internally mixed states of compounds were estimated. It was found that nitrate was mixed with sulfate-rich particles as the air mass approached Japan. It was confirmed that Asian mineral dust particles played significant roles for transport of continental sulfate to Japan. As a result of analysis on internal mixing of chlorine and nitrate, it was implied that the chlorine loss in fine sea salt particles had already proceeded at Tsukuba. It was characteristic that fluoride ions were significantly detected, coal combustion in the Asian Continent can be an important source of fluorides detected in Japan through the westward transportation of fine particles including fluorides.