• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 1999년도 춘계학술대회 논문집
• /
• pp.80-83
• /
• 1999

We have studied properties(crystal structure, density, absorption, contraction, initial permeability, and permeability) of Ni$_{0.175-x}$Cu$_{x}$Zn$_{0.33}$Fe$_{0.495}$ (x=0~0.175) ferrites with various NiO and CuO, because of development of materials for high frequency inductor. The XRD peaks of all of samples were observed only spine이 phase. As a results of the density, absorption rate, and shrinkage rate, the grain growth progressed rapidly in x=0.1 at 95$0^{\circ}C$, x=0.075 at 105$0^{\circ}C$, and x=0.025 at 115$0^{\circ}C$ for 3 hours. Initial permeability increased with increasing CuO concentration until x=0.1, and then decreased. The complex permeability as a function frequency were high values at sintered 105$0^{\circ}C$ fotr3 hours in x=0.075, 0.1., 0.1.1.

• 한국세라믹학회지
• /
• 제30권10호
• /
• pp.823-828
• /
• 1993

The performance of ferrite composite microwave absorber has been evaluated as the matching frequency, the matching thickness and the band width. Especially, matching frequency is very important in application of microwave absorber because it determines operating frequency range. In this study, the ferrite composite microwave absorbers consisted Ni-Zn ferrite and Zn2Y ferroxplana were prepared in order to control matching frequency. Then, the variation of the material constants and microwave absorbing characteristics were investigated with various ferrite mixing ratio. The material constants of ferrite composite microwave absorber could be controlled by variation ferrite mixing ratio. Therefore, it was confirm that matching frequency of microwave absorber could be shifted by control of material constants.

• 한국자기학회지
• /
• 제13권3호
• /
• pp.109-114
• /
• 2003

NiCuZn 페라이트에 $V_2O_{5}$를 0~0.5 wt% 첨가하여 페라이트 페이스트를 준비한 후,스크린 인쇄법으로 내부전극이 4.5회 회전된 임의의 크기(7.7$\times$4.5$\times$l.4 mm)의 칩인덕터를 제조하여, $V_2O_{5}$ 첨가량에 따른 미세구조 및 자기적 특성 변화를 분석하였다. $V_2O_{5}$첨가량이 증가할수록 액상소결이 발달하여 페라이트 입계에 내부전극 Ag의 확산과 Cu 석출 현상이 촉진되고, 이로 인하여 과대입자성장이 발달되었다. 이러한 현상은 칩인덕터의 자기적 특성에 큰 영향을 미쳐,900 $^{\circ}C$에서 소결된 $V_2O_{5}$ wt% 첨가시편의 주파수 10 MHz에서의 인덕턴스 값이 3.7$\mu$H로 0.3 wt% 첨가 시편의 4.2 $\mu$H보다 작게 나타났는데, 이는 Ag와 Cu의 석출량이 많아짐에 따라 잔류응력 발생이 심화되기 때문으로 생각된다 또한 $V_2O_{5}$ 0.5 wt% 첨가한 시편의 경우 소결온도가 증가함에 따라 품질계수 값이 감소하였는데, 이 결과도 페라이트 입계에서의 Ag나 Cu의 금속성분의 석출량 증가 및 과대입자성장에 의한 입자크기 증대로 인하여 전체 전기비저항이 감소되기 때문인 것으로 생각된다. 결론적으로 자기적 특성을 고려할 때 0.3 wt%가 적정 첨가량으로 나타났다.

• 한국세라믹학회지
• /
• 제16권1호
• /
• pp.3-12
• /
• 1979

The effects of sintering temperature and sintering atmosphere on magnetic properties and microstructuresof Mn-Zn ferrites have been studied. Mixture of 52.8mole% $Fe_2O_3$, 26.4mole% MnO, 15.1mole0% ZnO and 5.7mole% NiO was prepared, and 0.1mole% CaO, 0.02mole% $SiO_2$ were added as minor additives. After calcining and ball milling the powder was granulated for compacting. The specimens were sintered at $1, 250^{\circ}$, $1, 300^{\circ}$and 1, 35$0^{\circ}C$ in the various atmosphere of $N_2$, $N^_2\DIV0.6% O_2$, $N_2＋2.7% O_2$, $N_2＋4.1% O_2$, $N^2＋8.2% O_2$ and air for 3 hours and cooled in $N_2$ atmosphere. The grian growth rate and densities increase as sintering temperature and oxygen content of atmosphere increase. At the sintering temperature of $1, 250^{\circ}C$ the initial permeabilities increase as oxygen content of atmosphere increase. At the sintering temperature of$ 1, 300^{\circ}$and $1, 350^{\circ}$ the initial permeabilities show maximum values at $N_2＋4.1% O_2$ atmosphere. The secondary peaks of initial permeabilities are observed between 100$^{\circ}$and 20$0^{\circ}C$, and the positions of secondary peaks move to higher temperature as oxygen content of atmosphere increases. Q-factors decrease as sintering temperature increases and oxygen content of atmosphere decreases.