• Journal of the Korean institute of surface engineering
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• 제36권6호
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• pp.461-465
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• 2003

The microstructures and magnetic properties of electrodeposited Fe-45 wt%Ni-P alloys have been investigated. The structures of electrodeposited Fe-45 wt%Ni alloy was FCC i.e. ${\gamma}$ phase and the size of crystallite was 10 nm. The structure of electrodeposited Fe-45 wt%Ni-1 wt%P alloy showed ${\gamma}$ phase and 7 nm sized nanocrystalline. The electrodeposited Fe-45 wt%Ni-P alloys containing 2∼3 wt% of P exhibited ${\gamma}$ ＋ $\alpha$ dual phases. The electrodeposited Fe-45 wt%Ni-P alloys above 3.5 wt% showed an amorphous structure. P in the alloys acted grain refining and phase changing element. The resistivity of the electrodeposited alloys increased with P contents. Effective permeability at high frequency (above 1 MHz) increased with P contents up to 2 wt% and this was ascribed to the easier magnetization rotation owing to the reduction of eddy current. Effective permeability decreased with P contents above 3 wt% and this was ascribed to the transformation of the ferromagnetism of Fe-45 wt%Ni alloy gradually into paramagnetism with the introduction of P into the electrodeposited alloy matrix.

• Journal of the Korean Magnetics Society
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• 제5권2호
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• pp.134-139
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• 1995

We produced $(Co_{93}Cr_{7})-P-Ni$ thin films for longitudinal magnetic recording media using OC magnetron sputtering system The variation of magnetic properties of $(Co_{93}Cr_{7})-P-Ni$ pseudo-ternary system with the composition was examined. We obtained the coercivity up to 1500 Oe. The coercivity iocrease could be ascribed to in-plane anisotropy enhaocement, grain size decrease, magnetic decoupling between particles. TEM micrographs showed that the grains were well-decoupled by the addition of phosphorous.

• Journal of the Korean institute of surface engineering
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• 제48권3호
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• pp.100-104
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• 2015

The nickel alloys gets a great deal of attention due to their good mechanical, chemical and magnetic properties. Especially Ni-P alloy systems are very attractive due to their good corrosion resistance and the wear resistance in important technological applications. In this study, the effects of phosphorus acid concentration in plating solution on composition of Ni-P alloy coatings were studied. The Ni-P electrodeposits of the various P contents were investigated in order to understand effect of the composition on mechanical properties of Ni-P electrodeposits. The mechanical properties of electrodeposits increased as the P content in electrodeposits increase. The results of mechanical properties were explained by grain size and P solid solution effect. The effects of heat treatment on mechanical properties of Ni-P alloy coatings were also studied.

• Advances in Energy Research
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• 제8권4호
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• pp.223-231
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• 2022

An ex-situ gravitational fixed bed pyrolysis reactor was used over Al₂O₃ supported Ni₂P based catalyst with various Ni/P molar ratios (0.5-2.0) and constant nickel loading of 5.37 mmol/g Al₂O₃ to determine the hydrodeoxygenation of rubberwood sawdust (RWS) at atmospheric pressure. The 3D catalysts formed were characterized structurally as well as acidic properties were determined by hydrogen-temperature programmed reduction (TPR). The Ni₂P phase formed completely on Al₂O₃ for 1.5 Ni/P ratio, although lesser crystallite sizes of Ni₂P were seen at Ni/P ratios less than 1.5. Additionally, it was shown that when nickel loading level increased, acidity increased and specific surface area dropped, probably because nickel phosphate is not easily converted to Ni₂P. When Ni/P ratio was 1.5, Ni₂P phase fully formed on Al₂O₃. The catalytic activity was explained in terms of impacts of reaction temperature and Ni/P molar ratio. At relatively high temperature of 450℃, the high-value deoxygenated produce was predominantly composed of n-alkanes. Based on the findings, it was suggested that hydrogenolysis, hydrodeoxygenation, dehydration, decarbonylation, and hydrogenation are all part of mechanism underlying hydrotreatment of RWS. In conclusion, the synthesized Ni₂P/ Al₂O₃ catalyst was capable of deoxygenating RWS with ease at atmospheric pressure, primarily resulting in long chained (C₉-C₂₄) hydrocarbons and acetic acid.

• Journal of the Korean institute of surface engineering
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• 제51권4호
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• pp.197-201
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• 2018

Dynamic nano-indentation method was applied to characterize thin electroformed Ni-P layers. The Ni-P layers were produced in a sulphamic acid bath at $50^{\circ}C$ in $0.02A/cm^2$ for 10-60 minutes. The chemical analyses by XRD and EDX showed that the Ni-P layers were very fine grains with mainly $Ni_3P$ with Ni. The surface roughness determined by atomic force microscopy increased with thickness, which was relative to the surface morphology. The nano-hardness and the stiffness of the thin Ni-P layers with thickness of 1.9, 6.2 and $7.5{\mu}m$ were 5.52, 6.52 and 6.77 [GPa] and 56.7, 76.2 and 108.0 [${\mu}N/nm$], respectively. The elastic modulus of the Ni-P layer increased with thickness such as 37.29, 54.50 and 78.76 [GPa], respectively. The surface roughness of the electroplated Ni-P layers with diverse thickness was 8.66, 18.56 and 35.22 [nm], respectively. The enhanced nano-mechanical properties were related to mainly residual stress of the Ni-P layers.

• Journal of the Korean institute of surface engineering
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• 제52권4호
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• pp.187-193
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• 2019

Electroless Ni-P coatings are widely used in the chemical, mechanical, and electronic industries because of their excellent wear and abrasion resistance. In this study, the effect of $TiO_2$ particles of composite coating was investigated. To improve the corrosion resistance, electroless $Ni-P-TiO_2$composite coating was studied by varying the $TiO_2$ content. The morphology and phase structure of $Ni-P-TiO_2$ composite coatings were analyzed by scanning electron microscopy(SEM), X-ray diffractometry(XRD) and X-ray photoelectron spectroscopy(XPS). The result showed that $Ni-P-TiO_2$composite coating is composed of Ni, P, Ti and O. It exhibits an amorphous structure, high hardness and good corrosion resistance to the substrate. $Ni-P-TiO_2$ composite coatings have higher open circuit potential than that of the substrate, which obtained at $TiO_2$ content of 5.0 g/L optimal integrated properties.

• Applied Chemistry for Engineering
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• 제24권4호
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• pp.438-442
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• 2013

In the present work, electroless plating was used for coating thin films consisting mainly of Ni and P on carbon fiber. Structural changes appeared upon the post-annealing at various temperatures of the Ni-P film on carbon fiber was studied using various analysis methods. Scanning, a flat surface structure of Ni-P film on carbon fiber was found after electroless plating of Ni-P film on carbon fiber without post-annealing, whereas annealing at $350^{\circ}C$ resulted the formation of porous structures. With increasing the annealing temperature to $650^{\circ}C$ with an interval of $50^{\circ}C$, the pore size increased, but the density decreased. X-ray diffraction (XRD) showed the existence of metallic Ni, and Ni-P compounds before post-annealing, whereas the post-annealing resulted in the appearance of NiO peaks, and the decrease in the intensity of the peak of metallic Ni. Using X-ray photoelectron spectroscopy (XPS), phosphorous oxides were detected on the surface upon annealing at $650^{\circ}C$, and $700^{\circ}C$, which can be attributed to the phosphorous compounds originally existing in the deeper layers of the Ni films, which undergo sublimation and escape from the film upon annealing. Escape of phosphorous species from the bulk of Ni-P film upon annealing could leave a porous structure in the Ni films. Porous materials can be of potential applications in diverse fields due to their interesting physical properties such as high surface area, and methods for fabricating porous Ni films introduced here could be easily applied to a large-scale production, and therefore applicable in diverse fields such as environmental filters.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 한국표면공학회 2013년도 춘계학술대회 논문집
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• pp.59-59
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• 2013

Ni-P 도금 피막층에 W를 함유시켜 고내식성을 목적으로 하는 Ni-W-P 도금에 대하여 연구 하였다. 도금액 조건의 최적화 및 도금온도와 pH 등이 가 피막특성에 미치는 영향을 조사하여 피막 크랙이 발생하지 않고 내식성 및 내마모성이 우수한 무전해 Ni-W-P 도금 공정을 확립하였다.

• Journal of the Korean institute of surface engineering
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• 제56권5호
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• pp.299-308
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• 2023

In this study, phosphorus (P)-doped nickel cobaltite (P-NiCo₂O₄) and nickel-cobalt layered double hydroxide (P-NiCo-LDH) were synthesized on nickel (Ni) foam as a conductive support using hydrothermal synthesis. The thermal properties, crystal structure, microscopic surface morphology, chemical distribution, electronic state of the constituent elements on the sample surface, and electrical properties of the synthesized P-NiCo₂O₄ and P-NiCo-LDH samples were analyzed using thermogravimetric analysis-differential scanning calorimetry (TGA-DSC), X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), cyclic voltammetry (CV), galvanostatic charge-discharge (GCD), and electrochemical impedance spectroscopy (EIS). The P-NiCo₂O₄ electrode exhibited a specific capacitance of 1,129 Fg^-1 at a current density of 1 Ag^-1, while the P-NiCo-LDH electrode displayed a specific capacitance of 1,012 Fg^-1 at a current density of 1 Ag-1. When assessing capacity changes for 3,000 cycles, the P-NiCo₂O₄ electrode exhibited a capacity retention rate of 54%, whereas the P-NiCo-LDH electrode showed a capacity retention rate of 57%.

• Journal of the Microelectronics and Packaging Society
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• 제27권3호
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• pp.29-34
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• 2020

The behavior of brittle fracture of electroless nickel immersion gold (ENIG) /Sn-3.0wt.%Ag-0.5wt.%Cu (SAC305) solder joints was evaluated. The pH of the electroless nickel plating solution for ENIG surface treatment was changed from 4.0 to 5.5. As the pH of the Ni plating solution increased, pin hole in the Ni-P layer increased. The thickness of the interfacial intermetallic compound (IMC) of the solder joint increased with pH of Ni plating solution. The high speed shear strength of the SAC305 solder joint on ENIG surface finish decreased with the pH of the Ni plating solution. In addition, the brittle fracture rate of the solder joint was the highest when the pH of the Ni plating solution was 5.