• Title/Summary/Keyword: NiFe alloy

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Effect of Cobalt Contents on the Biocompatibility and Corrosion Properties of Fe-31Cr-27Ni-1.6Mo-1.5W-0.26N Alloy (Fe-31Cr-27Ni-1.6Mo-1.5W-0.26N계 초내식성 스테인리스강의 생체적합성 및 부식특성에 미치는 Co함량의 영향)

  • Jang, Soon Geun;Yoo, Young Ran;Nam, Hee Soo;Shim, Gyu Tae;Kim, Jung Gu;Kim, Young Sik
    • Korean Journal of Metals and Materials
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    • v.46 no.4
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    • pp.209-216
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    • 2008
  • Super austenitic stainless steels shows the high PRE (Pitting Resistance Equivalent) number and the good corrosion resistance. This work controlled the Co contents in Fe-31Cr-1.7Mo-27Ni-0.25N alloys to elucidate the effect of cobalt contents on the biocompatibility and corrosion resistance. Increasing Co contents, the hardness of the annealed alloys tends to be reduced. In aged alloys, cobalt decreased the increments of hardness by aging treatment. Cobalt decreased the critical pitting temperature (CPT) in 6% $FeCl_3$ + 1% HCl solution, but improved the anodic polarization behavior in Hanks' balanced salt solution and artificial saliva solution. Repassivation rate in artificial body solutions was improved by increasing cobalt contents, but didn't show the linear relationship to PRE number of the alloys. The experimental alloys showed the non-cytotoxicity because of its high corrosion resistance.

Ferromagnetism of thin films deposited from paramagnetic stainless steel targets by Facing Targets Sputtering

  • Matsushita, N.;Ono, N.;Naoe, M.
    • Proceedings of the Korean Magnestics Society Conference
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    • 1991.05a
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    • pp.73-74
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    • 1991
  • The films with ferromagnetic fine particles dispersed in nonmagnetic matrix, such as $Fe-Al_2O_3$ and Fe-Cu have been studied for use of magnetic recording medium, optically device and sensor. Their magnetic properties depend strongly on structural parameter such as size and volume fraction of ferromagnetic particles. Fe-Cr-Ni alloy sputtered films also have microstructure with ferromagnetic -- b.c.c phase and nonmagnetic f.c.c phase grains. Magnetic properties of these films depend strongly on such a unique structure. These are depend on the ratio in volume of ferromagnetic particles to nonmagnetic ones $V_F/V_N$, the saturation magnetization Ms increased with increase of $V_F/V_N$. The coercivity Hc of the as-deposited films took maximum value of about 200 Oe at adequate $V_F/V_N$ and then Ms and Squareness S were 500 emu/cc and 0.5, respectively.(omitted)

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Preperation of catalyst having high activity on oxygen reduction (저온형 연료전지용 산소의 고활성 환원 촉매 제조)

  • 김영우;김형진;이주성
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1992.11a
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    • pp.39-40
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    • 1992
  • This paper dealt with the manufacturing of binary alloy catalyst and showed simple electrochemical method for determing catalytic activity of oxygen reduction in acid or alkaline electrolyte. The catalyst was prepared by impregnating transition metal salts on platinum or silver particles adsorbed before on carbon paper substrate. The electrochemical characteristics of the catalysts was investigated with carbon paper electrode or PTFE-boned porous electrode and then cathodic current densities and tafel slopes were compared. As a result, of all binary catalysts utilized in this work, Pt-Fe, Pt-Mo showed better oxygen reduction activity than pure platinum catalyst in acid electrolyte and Ag-Fe, Ag-Pt, and Ag-Ni-Bi-Ti catalyst did than pure silver catalyst in alkaline electrolyte. The current density of Pt-Fe electrode in acid electrolyte was one and half times higher than that of Pt electrode(~500mA/$\textrm{cm}^2$ at 0.7VvsNHE).

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Effects of Hydrogen on the PWSCC Initiation Behaviours of Alloy 182 Weld in PWR Environments

  • Kim, H.-S.;Hong, J.-D.;Lee, J.;Gokul, O.S.;Jang, C.
    • Corrosion Science and Technology
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    • v.14 no.3
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    • pp.113-119
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    • 2015
  • Alloy 82/182 weld metals had been extensively used in joining the components of the PWR primary system. Unfortunately, there have been a number of incidents of cracking caused by PWSCC in Alloy 82/182 welds during the operation of PWR worldwide. To mitigate PWSCC, optimization of water-chemistry conditions, especially dissolved hydrogen (DH) and Zn contents, is considered as the most promising and effective remedial method. In this study, the PWSCC behaviours of Alloy 182 weld were investigated in simulated PWR environments with various DH content. Both in-situ and ex-situ oxide characterizations as well as PWSCC initiation tests were performed. The results showed that PWSCC crack initiation time was shortest in PWR water (DH: 30cc/kg). Also, high stress reduced crack initiation time. Oxide layer showed multi-layered structures consisted of the outer needle-like Ni-rich oxide layer, Fe-rich crystalline oxide, and inner Cr-rich inner oxide layers, which was not altered by the level of applied stress. To analyse the multi-layer structure of oxides, EIS measurement were fitted into an equivalent circuit model. Further analyses including TEM and EDS are underway to verify appropriateness of the equivalent circuit model.

Effects of Heat Treatment and Ti addition on Microstructures in Modified Invar Alloys (개량형 인바합금의 미세조직에 미치는 열처리 및 Ti 첨가 영향)

  • Huh, Min-Sun;Lee, Jung-Han;Lee, Chan-Gyu;Lee, Jae-Hyun
    • Journal of the Korean Society for Heat Treatment
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    • v.13 no.6
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    • pp.412-419
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    • 2000
  • There has been a considerable attention on Invar alloys due to its low thermal expansion property. A low thermal expansion property of Invar alloys, lower than $10^{-6}$ near the room temperature, is attractive for electric transmission lines and precision machine tools. However, the expansion property of Invar alloys is limited below about 520K, and mechanical properties are relatively low to apply to electric transmission line. In order to improve mechanical properties in this alloy, Ti alloying element was added to the $Ni_{38}-Mo_2-Cr_1-Fe$ invar alloy. The microstructure Ti added alloy showed finer than that of the unalloyed one. It was found that the (Mo, Ti), Mo carbide formed by Ti addition obstacled grain growth by pinning effect and supplyed recrystallization sites during heat-treatment. Optimum heat-treatment conditions with Ti addition were also discussed in the modified Invar alloy.

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Magnetic Shielding Study using 3-D Field Analysis (3차원 자기장해석을 이용한 자기차폐 연구)

  • Kim, Chan-Uk;Lee, Dong-Chang
    • Korean Journal of Materials Research
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    • v.9 no.3
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    • pp.251-256
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    • 1999
  • 대전력을 사용하는 제강공장의 L/F설비에서 발생되는 강자계를 효율적으로 차폐하기 위하여 L/F주위의 자기장 분포를 유한해석법을 이용한 사용해석도구인 ANSYS 5.3 3차원 자기장해석기를 통해 해석하고 그 결과를 평판형태의 차폐체에 적용시키고자 하였다. 분석결과, L1 및 L2가 각각 2.7 및 2.9m 이려 높이가 3.5m인 2중차폐체(1차측 차폐: 1mmt의 전기강판, 2차측차폐: 1mmt의 Fe-Ni alloy sheet)를 설치하는 거싱 최적의 처폐방안으로 도출되었다.

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