• 소성∙가공
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• 제8권3호
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• pp.247-247
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• 1999

The segregation (distribution) of nickel and the composition of its constituents influence the low thermal expansion characteristics (Invar effect) in Fe-30 wt.% Ni-12.5 wt.% Co-xC Invar alloy. The change of coefficient of the thermal expansion and magnetic properties were studied as an aspect of carbon addition causing the segregation of Ni in primary austenite of as-cast Fe-30 wt.% Ni-12.5 wt.% Co Invar alloy. The coefficient of thermal expansion of Fe-30 wt.% Ni-12.5 wt.% Co-xC Invar alloy showed its lowest value at 0.08 wt.% carbon, increased with increasing carbon content in the range of 0.08-1.0 wt.%C, kept constant at 1.0-2.0 wt.%C and decreased at carbon higher than 2.0 wt.%. The effective distribution of the coefficient of nickel in as-cast Fe-30 wt.% Ni-12.5 wt.% Co-xC Invar alloy increased with increasing carbon content. The volume fraction of they phase of Fe-30 wt.% Ni-12.5 wt.% Co-xC alloy increased with increasing carbon content. The microstructure of Fe-30 wt.% Ni-12.5 wt.% Co-xC alloy changed with the carbon content was independent of the coefficient of thermal expansion. The Curie temperature changed linearly with the carbon content and was similar to the change of the coefficient of thermal expansion. Moreover, the coefficient of thermal expansion decreased when the ratio of saturation magnetization to Curie temperature ($\sigma_s/T_c$) increased, decreasing the Curie temperature and showed a specific relationship with the magnetic properties of the Fe-30 wt.% Ni-12.5 wt.% Co-xCInvar alloy.

• 한국표면공학회지
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• 제36권6호
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• pp.455-460
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• 2003

Microstructural and magnetic properties of nanocrystalline Fe-46 wt%Ni and Fe-36 wt%Ni alloys were investigated. Alloys were prepared by the electrodeposition process. The electrolytes were iron sulfate/nickel chloride-based and iron chloride/nickel sulfamate-based solutions. Fe-46 wt%Ni alloy was FCC structure with grain size of 10 nm, but FCC and BCC phases were found in Fe-36 wt%Ni alloy and its grain size was smaller. Effective permeability of Fe-36 wt%Ni alloy was higher than that of Fe-46 wt%Ni alloy in the high frequency range because of large electrical resistivity and small eddy current loss resulted from grain size decrease. Up to $300^{\circ}C$ of annealing temperature, grain growth of Fe-Ni alloys slowly occured. Conversely, annealing above $450^{\circ}C$ led to a drastic grain growth. In that case, effective permeability was decreased at the temperature lower than $300^{\circ}C$ but at $300^{\circ}C$ or higher effective permeability was increased. At the high frequency of 1 MHz, electrodeposited Fe-Ni alloys had higher effective permeability with an decrease in the grain size.

• 한국표면공학회지
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• 제36권6호
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• pp.461-465
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• 2003

The microstructures and magnetic properties of electrodeposited Fe-45 wt%Ni-P alloys have been investigated. The structures of electrodeposited Fe-45 wt%Ni alloy was FCC i.e. ${\gamma}$ phase and the size of crystallite was 10 nm. The structure of electrodeposited Fe-45 wt%Ni-1 wt%P alloy showed ${\gamma}$ phase and 7 nm sized nanocrystalline. The electrodeposited Fe-45 wt%Ni-P alloys containing 2∼3 wt% of P exhibited ${\gamma}$ ＋ $\alpha$ dual phases. The electrodeposited Fe-45 wt%Ni-P alloys above 3.5 wt% showed an amorphous structure. P in the alloys acted grain refining and phase changing element. The resistivity of the electrodeposited alloys increased with P contents. Effective permeability at high frequency (above 1 MHz) increased with P contents up to 2 wt% and this was ascribed to the easier magnetization rotation owing to the reduction of eddy current. Effective permeability decreased with P contents above 3 wt% and this was ascribed to the transformation of the ferromagnetism of Fe-45 wt%Ni alloy gradually into paramagnetism with the introduction of P into the electrodeposited alloy matrix.

• 한국분말재료학회지
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• 제5권1호
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• pp.42-49
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• 1998

A study on the improvement of the impact energy in 93W heavy alloy with a Ni/Fe ratio of 9/1 has been carried out as a function of heat treatment temperature. The obtained results were compared to that of the traditional alloy system in which the Ni/Fe ratio is 7/3 or 8/2. With increasing heat treatment temperature from 1150 to 125$0^{\circ}C$, the impact energy of the alloy with the Ni/Fe ratio of 9/1 is remarkably increased from 42 to 72 J, which is higher than that of traditional alloy, up to 118$0^{\circ}C$ and then saturated. Fracture mode was also changed from brittle W/W boundary failure to W cleavage. The temperature showing the dramatic shrinkage by dilatometric anaysis of the heavy alloy with Ni/Fe ratio of 9/1 was found to be 1483 $^{\circ}C$, which is higher than that (146$0^{\circ}C$) of the heavy alloy with Ni/Fe ratio of 7/3. Auger Electron Spectroscopy showed that the segregation of impurities, such as S, P, and C in W/W grain boundary was considerably decreased with increasing heat treatment temperature from 1150 to l18$0^{\circ}C$. From the above results, it was found that the impurity segregation in W/W grain boundary played an important role on the decrease of impact properties, and the heat treatment temperature should be appropriately chosen, as considering the Ni/Fe ratio of the alloy, in order to get good impact properties.

• 한국진공학회지
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• 제10권2호
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• pp.201-206
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• 2001

본 연구에서는 RF 마그네트론 스퍼터링 방법을 이용하여 저탄소강 기판에 증착시킨 Fe-Ni계 합금 박막의 집합조직 발달을 조사하였다. Fe-Ni 합금 조성은 산업적 응용을 고려하여 인바합금(Invar alloy, Fe-36.5 wt%Ni)과 퍼멀로이(Permalloy, Fe-81 wt%Ni) 두 종류로 선택하였고, 증착시간을 변수로 제작하였다. 이들 합금 박막의 집합조직은 박막에서 전형적으로 나타나는 섬유집합조직(fibre texture)의 형태로 발달하였다. 인바합금 박막에서는 증착 초기에 <110>//ND 섬유집합조직이 발달하지만 증착시간이 증가함에따라 <210>//ND 섬유집합조직으로 변화하였다. 퍼멀로이 박막은 증착초기에 <221>//ND+<311>//ND의 혼합 집합조직을 나타내며 증착시간의 증가와 함께 <210>//ND 섬유집합조직으로 변화하였다. 이러한 집합조직의 변화를 박막의 미세조직의 진화와의 연관성이란 측면에서 고찰하였다.

• Journal of Information Display
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• 제5권4호
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• pp.27-30
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• 2004

This paper investigates the effects of coating such as Invar (Fe-36% Ni), Fe-Ni Alloys and $WO_3$ on the doming property of aluminum killed (AK) shadow masks, which may be used for flat CPTs. Invar and Fe-Ni Alloys are deposited on AK shadow mask in plasma atmosphere and annealed. $WO_3$ is screen-printed on the deposited layer. The coating is observed to cause a decrease in the doming property of the shadow masks due to their lower thermal expansion coefficients and anti-doming properties.

• 한국주조공학회지
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• 제25권2호
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• pp.73-79
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• 2005

Effects of Cr and Ni addition on damping capacity, mechanical property, and corrosion resistance of Fe-17%Mn martensitic alloy have been studied. Martensite start temperature($M_{S}$) of the alloy decreases linearly with increasing Cr and Ni contents up to 15%. The damping capacity decreases gradually from 27 to 22% in specific damping capacity(SDC) with increasing Cr and Ni contents from zero to 10%, and decreases rapidly with further Cr and Ni content in Fe-17%Mn alloy. The tensile strength of the alloy maintains a level of 60 $kgf/mm^{2}$ regardless of Cr content with an elongation of 20 to 25%. But, in case of Fe-17%Mn-x%Ni alloy, the tensile strength decreased rapidly with the Ni content of above 10% because of austenite morphology. Immersion test in 5% NaCl solution leads to the result that the corrosion resistance of the alloy becomes excellent above 10% Cr. From the above results, it is concluded that the optimum Cr content to improve the mechanical property and corrosion resistance of the alloy in 5%NaCl solution with a lesser decrease in damping capacity is about 10%. In the case of 5% $H_{2}SO_{4}$ condition, the Fe-17%Mn-10%Ni is an optimum alloy.

• 한국표면공학회지
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• 제43권2호
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• pp.57-63
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• 2010

In this study, thermal stability of the mechanical properties of Ni-P-B and Ni-P-Fe layers electroplated on Alloy 600 material was evaluated by measuring their microhardness, tensile strength, and elongation after heat treatment at $325^{\circ}C$ and $400^{\circ}C$. According to the results, there was no noticeable change in microhardness of the two electrodeposits before and after heat treatment at the temperatures for 30 days. In the case of a Ni-P-B electrodeposit, ultimate tensile strength (UTS) slightly increases with heat treatment time, while its elongation decreases, showing good thermal stability in the mechanical properties at high temperature. On the other hand, UTS and elongation of Ni-P-Fe decrease with heat treatment time, which is very unusual observation. This result was attributed to the bad microstructure of Ni-P-Fe having many defects in the deposit formed early stage of an electroplating process and their redistribution to link to become large ones during heat treatment.

• 열처리공학회지
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• 제13권2호
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• pp.85-90
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• 2000

The influence of transformation cycles (${\alpha}^{\prime}{\leftrightarrow}{\gamma}^{\prime}$) on the microstructure and mechanical properties of lath and lenticular martensites has been studied in Fe-Ni alloys. The width of lath in Fe-15%Ni alloy decreased with increasing the number of transformation cycles, while no appreciable change in dislocation density inside the lath was observed. In case of Fe-31%Ni alloy, a number of dislocations were additionally introduced into the martensite plate after the transformation cycling. Tensile strength and Vickers hardness of lath martensite decreased with the increase in number of transformation cycles, whereas those of lenticular martensite increased up to 1 cycle and then remained constant. Elongation of two alloys was deteriorated after 1 transformation cycling, corresponding to the tensile strength. But the decrement of elongation in Fe-31%Ni alloy was smaller than that in Fe-15%Ni alloy.

• 소성∙가공
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• 제14권2호
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• pp.121-125
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• 2005

Electroforming is a process that employs technology similar to that used for electroplating but which is used for manufacturing metallic articles, rather than as a means of producing surface coatings. Electroforming provides a cost-effective means of producing alloys and fully dense nanocrystalline metals as foils, sheets and complex shapes. Fe-Ni nanocrystalline alloy foils with composition in the $36\~80wt\%$ Ni range were fabricated by electroforming. The thickness of electroformed foils was in the range of $5\~30{\mu}m$. TEM and XRD analysis was applied for measuring the grain size. Very fine grain size$(\~10nm)$ was obtained in alloy foils. The yield and tensile strength of electroformed Fe-Ni alloy were 2000-2800 MPa and 2500-3300 MPa respectively. The magnetic permeability at high frequency of electroformed Fe-Ni foil was higher than that of thicker foils.