• Title/Summary/Keyword: NiB

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Structural Study of Tetragonal-Ni1-xPdxSi/Si (001) Using Density Functional Theory (DFT) (Density Functional Theory (DFT)를 이용한 Tetragonal-Ni1-xPdxSi/Si (001)의 구조 연구)

  • Kim, Dae-Hee;Seo, Hwa-Il;Kim, Yeong-Cheol
    • Korean Journal of Materials Research
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    • v.18 no.9
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    • pp.482-485
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    • 2008
  • Tetragonal-$Ni_{1-x}Pd_x$Si/Si (001) structure was studied by using density functional theory (DFT). An epitaxial interface between $2{\times}2{\times}4$ (001) tetragonal-NiSi supercell and $1{\times}1{\times}2$ (001) Si supercell was first constructed by adjusting the lattice parameters of B2-NiSi structure to match those of the Si structure. We chose Ni atoms as a terminating layer of the B2-NiSi; the equilibrium gap between the tetragonal-NiSi and Si was calculated to be 1.1 ${\AA}$. The Ni atoms in the structure moved away from the original positions along the z-direction in a systematic way during the energy minimization. Two different Ni sites were identified at the interface and the bulk, respectively. The two Ni sites at the interface have 6 and 7 coordination numbers. The Ni sites with coordination number 6 at the interface were located farther away from the interface, and were more favorable for Pd substitution.

Phase Changes and Microstructural Properties of Ti Alloy Powders Produced by using Attrition Milling Method (어트리션 밀링법으로 제조된 티타늄합금의 상변화 및 미세조직특성)

  • Cha, Sung-Soo
    • Journal of Technologic Dentistry
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    • v.23 no.1
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    • pp.9-19
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    • 2001
  • Microstructure and phase transformation of Ti-Ni-Cu alloy powders produced by using attrition milling method were studied. Mixed powders of Ti-(50-X)Ni-XCu ($X=0{\sim}20$ at%) in composition range were mechanically alloyed for maximum 20 hours by using SUS 1/4" ball in argon atmosphere. Ball to powder ratio was 50: 1 and impeller speed was 350rpm. Mechanically alloyed with attrition millimg method. powder was heat treated at the temperature up to $850^{\circ}C$ for 1 hour in the $10^{-6}$ torr vacuum. Ti-Ni-Cu alloy powders have been fabricated by attrition milling method. and then phase transformation behaviours and microstructual properties of the alloy powders were investigated to assist in improving the the high damping capacity of Ti-Ni-Cu shape memory alloy powders. The results obtained are as follows: 1. After heat treating of fully mechanically alloyed powder at $850^{\circ}C$ for 1hour. most of the B2 and B 19' phases was formed and $TiNi_3$ were coexisted. 2. The B 19' martensite were formed in Ti-Ni-Cu alloy powders whose Cu-content is less than 5a/o. where as the B19 martensite in those whose Cu-content is more than 10at%. 3. The powders of as-milled Ti-Ni-Cu alloys whose Cu-contents is less than 5at% are amorphous. whereas those of as-milled Ti-Ni-Cu alloys whose Cu-content is more than 10at% are crystalline. This means that Cu addition tends to suppress amorphization of Ti-Ni alloy powders.

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A First-principles Study on the Electronic Structures and Magnetism of Antiperovskite Ti0.96Co0.02Fe0.02O2 (페로브스카이트 구조를 가지는 Ti0.96Co0.02Fe0.02O2의 전자구조와 자성)

  • Song, Ki-Myung;Bialek, B.;Lee, Jae-Il
    • Journal of the Korean Magnetics Society
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    • v.18 no.3
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    • pp.85-88
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    • 2008
  • We calculated the electronic structures of substituted cobalt nitrides, that is $FeCo_3N$ and $NiCo_3Ni$, by using the all electron fullpotential linearized augmented plane-wave (FLAPW) energy band method, and investigated the influence on the magnetic properties of $Co_4N$ due to the substitution of Co atom located at corner sites by iron and nickel atoms. We found that the magnetic moments of CoII atoms located at the face-center positions in these compounds are almost same to that of $Co_4N$. The magnetic moments of Fe and Ni atoms in $FeCo_3N$ and $NiCo_3Ni$ are 3.086 and $0.795\;{\mu}_B$, and they have the localized nature of magnetism.

Effect of heat treatment and sintered microstructure on electrical properties of Mn-Co-Ni oxide NTC thermistor for fuel level sensor (연료액위센서용 Mn-Co-Ni 산화물계 서미스터의 전기적 특성에 미치는 열처리 및 소결미세구조에 관한 연구)

  • 나은상;백운규;최성철
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.13 no.2
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    • pp.88-92
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    • 2003
  • The correlationship between heat treatment condition and electrical properties of the Mn-Co-Ni oxide NTC thermistor for fuel level sensor was investigated by the X-ray diffractometry, density measurement, and electrical properties measurement such as resistivity, B constant, and thermal dissipation constant. It was shown that the heat treatment of NTC thermistor was responsible for sinterability of Mn-Co-Ni oxide. The highest density of 5.10 g/㎤ was obtained at $1250^{\circ}C$, 2 hours, at which the densification was almost completed. This is also manifested from the microstructural observation. It is found that the electrical resistivity and B constant are increased at the elevated sintering temperatures. The NTC specimens prepared in this study showed the conventional decrease of resistance with the measured temperature and the linear behavior of output voltage with fuel levels. Therefore, the electrical properties of thermistor were closely correlated with sintering condition. and the Mn-Co-Ni oxide thermistor prepared in this study has a great possibility enough to apply for an automobile fuel level sensor.

Superparamagnetic Properties of Nanoparticles Ni0.9Zn0.1Fe2O4 for Biomedical Applications

  • Lee, Seung-Wha;Kim, Chul-Sung
    • Journal of Magnetics
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    • v.10 no.1
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    • pp.5-9
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    • 2005
  • Nanoparticles $Ni_{0.9}Zn_{0.1}Fe_2O_4$ is fabricated by a sol-gel method. The magnetic and structural properties of powders were investigated with XRD, SEM, Mossbauer spectroscopy, and VSM. $Ni_{0.9}Zn_{0.1}Fe_2O_4$ powders annealed at $300{^{\circ}C}$ have a spinel structure and behaved superparamagnetically. The estimated size of $Ni_{0.9}Zn_{0.1}Fe_2O_4$ nanoparticle is about 10 nm. The hyperfine fields at 13 K for the A and B patterns are found to be 533 and 507 kOe, respectively. The ZFC curves are rounded at the blocking temperature ($T_B$)and show a paramagnetic-like behavior above $T_B$. $T_B$ of $Ni_{0.9}Zn_{0.1}Fe_2O_4$ nanoparticle is about 250 K. Nanoparticles $Ni_{0.9}Zn_{0.1}Fe_2O_4$ annealed at 400 and $500{^{\circ}C}$ have a typical spinel structure and is ferrimagnetic in nature. The isomer shifts indicate that the iron ions were ferric at the tetrahedral (A) and the octahedral (B). The saturation magnetization of nanoparticles $Ni_{0.9}Zn_{0.1}Fe_2O_4$ annealed at 400 and $500{^{\circ}C}$ are 40 and 43 emu/g, respectively. The magnetic anisotropy constant of $Ni_{0.9}Zn_{0.1}Fe_2O_4$ annealed at $300{^{\circ}C}$ were calculated to be 1.6 ${\times}$ $10^6$ ergs/$cm^3$.

Comparison of Growth and Physiological Responses in Radish for Assay of Nickel Toxicity -II. Effect of Ni on Physiological Responses in Radish- (무에서 니켈 독성검정을 위한 생육 및 생리반응 비교 -II. 니켈에 의한 무의 생리반응-)

  • Han, Kang-Wan;Cho, Jae-Young
    • Applied Biological Chemistry
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    • v.39 no.4
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    • pp.293-296
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    • 1996
  • The present study was carried out to investigate the effect of Ni on germination, cell elongation, ${\alpha}-amylase$ activity, contents of chlorophyll and protein in radish were determined in the water culture. As the concentration of Ni was increased in the water culture, germination of radish was 55% by Ni 10 mg/kg and 30% by Ni 20 mg/kg. The ratio of cell elongation injury was 50%, by two days after Ni 20 mg/kg treatment. The injury ratio of ${\alpha}-amylase$ activity was 45% in the same condition and as the time goes on, inhibition of ${\alpha}-amylase$ activity were slightly decreased. Contents of chlorophyll a and b were decreased two days after treatment and chlorophyll a was more inhibited than chlorophyll b. Also changes of the protein contents was slightly decreased. Activity of ${\alpha}-amylase$ was decreased at germination stage, contents of chlorophyll a and b were decreased at growing stage.

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Thermal Stability of the R Phase of a Rapidly Solidified Ti-47.3Ni (at%) Alloy

  • Moon, Hyo-Jung;Chun, Su-Jin;Nam, Tae-Hyun;Liu, Yinong;Yang, Hong;Kim, Yeon-Wook
    • Transactions on Electrical and Electronic Materials
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    • v.13 no.1
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    • pp.19-22
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    • 2012
  • Transformation behavior of rapidly solidified Ti-47.3Ni (at%) alloy ribbons and thermal stability of the R phase in the ribbons were investigated by means of differential scanning calorimetry (DSC), X-ray diffraction, and transmission electron microscopy. Rapidly solidified Ti-47.3Ni alloy ribbons showed the two-stage B2-R-B19' martensitic transformation behavior. The B2-R transformation in the ribbons was observed even after annealing at 1,223 K, which was attributed to the fact that a specific orientation relationship between $Ti_2Ni$ and matrix in the ribbons is maintained after annealing at 1,223 K. The DSC peak temperature of the B2-R transformation ($T_R^*$) decreased with raising annealing temperature, which was attributed to the increased volume fraction of $Ti_2Ni$, thus causing an increased Ni content in the matrix.