• 구강회복응용과학지
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• 제37권4호
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• pp.199-208
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• 2021

목적: 이 연구의 목적은 고투명도 3종류의 지르코니아의 두께 및 하부 배경에 따른 색조 차단 효과를 비교, 평가하는 것이다. 연구 재료 및 방법: 3 종류의 고투명도 지르코니아(Ceramill zolid fx white, Ceramill zolid ht+ white, Ceramill zolid ht+ preshade A2)를 각각 CAD/CAM 방식으로 직경 10 mm의 원판 형태의 4가지 두께(0.6 mm, 1.0 mm, 1.5 mm, 2.0 mm)로 10개씩 시편을 제작하였다. 하부 배경은 직경 10 mm, 두께 10 mm로 A1, A2, A3 레진 하부 배경, 청색의 코어 레진 하부 배경, Ni-Cr 합금 하부 배경을 제작하였으며, 추가로 분광 광도계 제조사에서 제공하는 검정색 및 흰색 하부 배경을 사용하였다. 지르코니아 시편과 기준 배경을 접착제없이 겹쳐 분광 광도계로 L, a^*, b^* 값을 측정하고 다른 하부 배경과의 ΔE 값을 계산하였다. 계산된 평균 ΔE 값을 인지 한계 1.0과 허용 한계 3.7 값을 기준으로 색조 차단 효과를 비교하였다. 통계적 유의성 검증을 위해 비모수 검정인 Kruskal-Wallis 검정을 시행하였다(α = 0.05). 결과: 지르코니아 종류, 하부 배경 및 두께 변화에 따른 평균 ΔE 값의 유의한 차이를 보였다(P = 0.000). 결론: 본 연구 결과에 의하면, 색조를 가지는 고투명도 지르코니아는 청색 레진 코어를 제외한 치아, 복합레진 및 지대주상에 수복될 때 원하는 지르코니아 색조를 얻을 수 있다.

• 한국염색가공학회지
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• 제8권6호
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• pp.40-46
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• 1996

In order to investigate a practical application of fibrous absorbents to transition metals such as copper, nickel, cobalt, chrome, and iron, amidoximated fiber as a particular class of solid chelate agents were prepared from acrylic fibers treatment with hydroxylamine. The adsorption mechanisms of metal ions onto amidoximated acrylic fibers and their complexes were studied. Amidoximation of acrylic fiber with hydroxylamine is found to be first-order reaction, followed by the disappearance of infrared adsorption peaks due to nitrile groups of acrylic fibers. The uptake of metal ions onto amidoximated acrylic fiber is increased with temperature raising and the adsorption is also depended on pH of the soiutions. About 70% of metal ions can be recovered from aqueous solutions of Ni(II), Co(II), Cr(III), and Fe(II) on the concentration below 5x 10$^$^{-4}$ in the range of pH 2.1~10.0. Transition metals are adsorbed to form complex with amidoxime group by the ligand sites such as C=N, NH, NO, NHOH.OH.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제55권11호
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• pp.544-547
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• 2006

In this paper, we present a temperature-controlled system for MEMS electrical resistance heaters without a temperature sensor. To rapidly control the heater temperature, the microheater system developed consists of a power supply, power amplifier, digital ${\underline{P}}roportional-{\underline{I}}ntegral-{\underline{D}}ifferential$ (PID) controller, and a quarter bridge circuit with the microheater and three resistors are nominally balanced. The microheaters are calibrated inside a convection oven to obtain the temperature coefficient with a linear or quadratic fit. A voltage amplifier applies the supply voltage proportional to the control signal from the PID controller. Small changes in heater resistance generate a finite voltage across the quarter bridge circuit, which is fed back to the PID controller to compare with the set-point and to generate the control signal. Two MEMS microheaters are used for evaluating the developed control system - a NiCr serpentine microheater for a preconcentrator and a Nickel microheater for ${\underline{P}}olymerase\;{\underline{C}}hain\;{\underline{R}}eaction$ (PCR) chip.

• 한국전기전자재료학회논문지
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• 제16권2호
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• pp.120-124
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• 2003

This paper describes a MEMS-based micro-fluxgate magnetic sensing element using Ni$\_$0.8/Fe$\_$0.2/ film formed by electroplating. The micro-fluxgate magnetic sensor composed of a thin film magnetic core and micro-structure solenoids for the pick-up and the excitation coils, is developed by using MEMS technologies in order to take advantage of low-cost, small size and lower power consumption in the fabrication. A copper with 20${\mu}$m width and 3${\mu}$m thickness is electroplated on Cr (300${\AA}$) / Au (1500${\AA}$) films for the pick-up (42turn) and the excitation (24turn) coils. In order to improve the sensitivity of the sensing element, we designed the magnetic core into a rectangular-ring shape to reduce the magnetic flux leakage. An electroplated permalloy film with the thickness of 3${\mu}$m is obtained under 2000 gauss to induce magnetic anisotropy. The magnetic core has the high DC effective permeability of ~1,100 and coercive field of ~0.1 Oe. The fabricated sensing element using rectangular-ring shaped magnetic film has the sensitivity of about 150 V/T at the excitation frequency of 2 MHz and the excitation voltage of 4.4 V$\_$p p/. The power consumption is estimated to be 50mW.

• 대한치과보철학회지
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• 제43권2호
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• pp.264-279
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• 2005

Statement of problem. Intraoral corrosion not only affects the esthetic and function of metallic dental restoration, but also has biologic consequences as well. Therefore, corrosion is considered a primary factor when choosing the dental alloy and laboratory technique. Purpose. The objective of this study was to compare the effects of solder and laser weld on corrosion Material and methods. Test specimens were made of 2 types of gold alloys, Co-Cr and Ni-Cr alloy and fabricated 3 methods, respectively: as cast, solder, and laser weld. For the analysis of corroding properties, potentiodynamic polarization test and immersion test conducted. The potentiodynamic polarization scan curve were recorded in 0.9% NaCl solution(pH 7) using Potentiostat/Galyanostat Model 273A. All specimens were exposed to 0.9% NaCl solution(pH 2.3) during 14 days. Elemental release into corrosive solution was measured by atomic emission spectrometry Differences in corrosion potential and mass release were determined using ANOVA. Results and conclusion. Through analyses of the data, following results were obtained. 1. In Pontor MPF and Wiron 99, corrosion potential of the solder group was statistically lower than as cast and laser weld group (p<0.05) , but there was no difference between corrosion potential of solder group and laser weld group in Pontor MPF and no differences between as cast and laser weld group (p>0.05). In Jel-Bios 10 and Wirobond, there was no difference of corrosion potential according to joining methods(p>0.05). 2. In all tested alloys, the amount of released metallic ion was greatest in the solder group(p<0.05). There was no difference between as cast group and laser weld group in Jel-Bios 10 and Wirobond(p>0.05). 3. In scanning electron microscopic examination. except soldered Wiron 99 specimens, it is impossible to discriminate the corrosive property of solder and laser weld. 4. Under the this experimental circumstances, laser weld appears superior to the solder when corrosion is considered.

• 한국농공학회논문집
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• 제59권3호
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• pp.1-10
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• 2017

The aim of this study is to investigate the chemical properties and heavy metal concentration of soils in conventional and organic paddy. We sampled and analyzed topsoil (0~15 cm) and subsoil (15~30 cm) of conventional and organic paddy fields in Yongin and Anseong, South Korea. The statistical significance between groups was determined by Duncan's multiple range test and correlation between soil properties was also analyzed. The results show that organic matter (OM) and T-N of conventional paddy soil were higher than those of organic paddy soil. However, higher T-P concentration was observed in organic paddy soil than conventional paddy soil. As, Pb, and Zn concentration in organic paddy soil were statistically lower than those in conventional paddy soil. The couple of water content (WC) & As, OM & T-N, T-P & $P_2O_5$, T-P & Zn, $P_2O_5$ & Zn, and Cr & Ni had a good positive correlation but the couple of WC & T-P, WC & Zn, T-P & As, and As & Zn had a strong negative correlation. It can be concluded that organic farming is beneficial to soil environment by reducing the amounts of organic matter, T-N, As, Pb, and Zn concentration in paddy soil when compared to conventional farming.

• 대한치과보철학회지
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• 제33권1호
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• pp.1-12
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• 1995

For the purpose of this study, the silicoating on Ni-Cr-Be alloy surface was carried out by using the Silicoater MD. The effect of time delay after silicoating on the bond strength between the metal and resin cement was examined. The groups were divided into 4 : group 1 : Sandblasted with $250{\mu}m$ aluminium oxide, immediatly cemented group 2 : Sandblasted with $250{\mu}m$ aluminium oxide, silicoated and immediatly cemented group 3 : Sandblasted with $250{\mu}m$ aluminium oxide, silicoated and cemented after 7 days group 4 : Sandblasted with $250{\mu}m$ aluminium oxide, silicoated and coated with unfilled resin and cemented after 7 days Specimens were luted with Comspan, Superbond C&B or Panavia EX. The tensile bond strength between the metal and resin cement was measured by using the universal testing machine. The results were as follows : 1. The bond strength in groups 2, 3 and 4 was higher than that of group 1 (p<0.05). There was no statistically significant difference among the bond strength in groups 2, 3 and 4 (p>0.05). 2. In Comspan-cemented groups, there was no significant difference among the bond strength in groups 2, 3 and 4 (p<0.05). 3. In Panavia EX-cemented groups, the bond strength of group 3 was higher than that of group 2 (p<0.05) and there was no significant difference between groups 3 and 4. 4. In Superbond C&B-cemented groups, there was significant difference between groups 2 and 3 (p<0.05) and the bond strength of group 4 was higher than that of group 3 (p<0.05). 5. The highest tensile bond strength was obtained by using the Superbond C&B and no difference in the Panavia EX and Comspan. 6. The modes of bond failure were mainly cohesive failure. The method of storage and transport indicated in this study seems recommendable for laboratory and clinical use at least up to 7 days.

• 한국환경보건학회지
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• 제38권6호
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• pp.493-502
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• 2012

Objectives: The purpose of this study is to investigate the mass concentration of nanoparticles and understand the characteristics of elements of heavy metal concentrations within nanoparticles in the air using Micro-Orifice Uniform Deposit Impactor Model-110 (MOUDI-110), based on indoor and outdoor air. Methods: This Study sampled nanoparticles using MOUDI-110 indoors (office) and outdoors at S University in Asan, Korea in order to reveal the concentration of nanoparticles in the air. Sampling continued for nine months (10 times indoors and 14 times outdoors) from March to November 2010. Mass concentrations of nanoparticle and concentrations of heavy metals (Al, Mn, Zn, Ni, Cu, Cr, Pb) were analyzed. Results: Indoors, geometric mean concentration of nanoparticles ranged in size from 0.056 ${\mu}m$ to 0.10 ${\mu}m$ and those of 0.056 ${\mu}m$ or less recorded 0.929 ${\mu}g/m^3$ and 1.002 ${\mu}g/m^3$, respectively. On the other hand, the levels were lower outdoors with 0.819 ${\mu}g/m^3$ and 0.597 ${\mu}g/m^3$. Mann-Whitney U tests showed that the difference between the indoors and the outdoors was statistically meaningful in terms of particles of 0.056 ${\mu}m$ or less (p<0.05) in size. These results are possibly influenced by the use of printers and duplicators as the factor that increased the concentration of nanoparticles. In seasonal concentration distribution, the level was higher during the summer compared to in the autumn. Those of 0.056 ${\mu}m$ or less in size presented a statistically meaningful difference during the summer (p<0.05). These results may be influenced by photochemical event as the factor that makes the levels high. Regarding zinc, among the other heavy metals, the fine particles ranged in size from 0.056 ${\mu}m$ to 0.10 ${\mu}m$ and those of 0.056 ${\mu}m$ or less recorded 1.699 $ng/m^3$ and 1.189 $ng/m^3$ in the outdoors. In the indoors, the levels were lower, with 0.745 $ng/m^3$ and 0.617 $ng/m^3$. Cr and Ni at the size of 0.056 ${\mu}m$ or less, both of which have been known to pose severe health effects, recorded higher concentrations indoors with 0.736 $ng/m^3$ and 0.177 $ng/m^3$, compared to 0.444 $ng/m^3$ and 0.091 $ng/m^3$ outdoors. By season, Zn, Ni, Cu and Pb posted a high level of indoor concentration during the fall. As for Cr, the level of concentration indoors was higher than outdoors both during the summer and the autumn. Conclusion: This study indicates the result of an examination of nano-sized particles and heavy metal concentrations. It will provide useful data for the determination of basic nanoparticle standards in the future.

• 한국환경과학회지
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• 제29권11호
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• pp.1055-1064
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• 2020

In this research, heavy metals and T-P removal characteristics of plated wastewater are derived using BPC(Break Point Chlorination) process. AA sedimentation pond outflow(Influence) was evaluated for the removal efficiency of heavy metal(Ni) and T-P at a reaction time of 25 minutes by NaOCl input volume(9, 11, 13 and 15 mL). In the case, the higher the NaOCl input volumes, the higher the ORP values were maintained and the higher the removal efficiency tended to be. On the other hand, T-P was judged to have a low relationship between the ORP value and the removal efficiency. In addition, the efficiency of removal heavy metals and T-P in the plated wastewater by injecting 10 mL, 15 mL, 20 mL and 25 mL NaOCl, increased as the amount of NaOCl injected increased, the amount of NaOH input for pH increased. It was found that suspended solid in effluence also increased. It was also observed that the color of the plating wastewater changed from yellowish green to green to charcoal gray to black as the amount of NaOCl injected increased. Treatment characteristics of the reaction time, the longer the reaction time with the substance to be treated after the input of NaOCl, the more the heavy metal removal efficiency tended to increase. Through XRF analysis of the sludge, the constituents in the sludge such as NaCNO, CNCl, Na₃PO₄, CrO₄, 2Na₂CrO₄ and 2NaNO₃ will be analyzed in detail, and the mechanisms of the reaction between the plated wastewater and the complex compound will be elucidated.

• 한국토양비료학회지
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• 제45권4호
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• pp.565-571
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• 2012

This study was conducted to investigate the tolerance of some resistant fungal strains from soils contaminated with heavy metals. Various fungal strains were isolated from soil samples collected from studied sites which heavy metals and other pollutants have been emitted in effluents for several years. Fungi isolated belong to different genera; however, Penicillium spp. showed the most frequent species. The microbial number was remarkably higher in the control soil than contaminated soil samples collected from mining areas. $Pb^{2+}$ and $Zn^{2+}$ had the highest concentration in the polluted soils ranging from 89 - 3,521 ppm and 98 - 4,383 ppm, respectively. The minimum inhibition concentrations (MICs) of $Pb^{+2}$ and $Zn^{+2}$ showed the highest values against the fungal strains. $Ni^{+2}$ and $Co^{+2}$ were the lowest contaminants in the polluted soils with the concentration of 5 to 12.1 ppm and 1.8 to 4.8 ppm, respectively. The tested resistant strains showed the strongest inhibition for $Ni^{+2}$ and $Co^{+2}$ up to 200-400 ppm. Cadmium was the most highly toxic heavy metal for most of strains, however, 1 mM of $Cr^{3+}$, $Cu^{2+}$ and $Pb^{2+}$ accelerated the growth of Penicillium verrucosum KNU3. $Cu^{+2}$ and $Zn^{+2}$ at concentration of 1 mM did not affect the growth rate P. funiculosum KNU4. Tolerance of fungal species to heavy metals appears to be strain and origin dependent.