• 소성∙가공
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• 제24권1호
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• pp.44-51
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• 2015

The current study seeks to examine the effects of V and C additions on the mechanical and low thermal expansion properties of a high strength invar base alloy. The base alloy (Fe-36%Ni-0.9%Co-2.75%Mo-0.7Cr-0.23Mn-0.17Si-0.3%C, wt.%) contains $Mo_2C$ carbides, which form as the main precipitate. In contrast, alloys with additions of 0.4%V+0.3%C (alloy A) or 0.4%V+0.45%C (alloy B) contain $Mo_2C$+[V, Mo]C carbides. The average thermal expansion coefficients of these high strength invar based alloys were measured in the range of $5.16{\sim}5.43{\mu}m/m{\cdot}^{\circ}C$ for temperatures of $15{\sim}230^{\circ}C$. Moreover, alloy B showed lower thermal expansion coefficient than the other alloys in this temperature range. For the mechanical properties, the [V, Mo]C improved hardness and strengths(Y.S. and T.S.) of the high strength invar base alloy. T.S.(tensile strength) and Y.S.(yield strength) of hot forged alloy B specimen were measured at 844.6MPa and 518.0MPa, respectively. The tensile fractography of alloy B exhibited a ductile transgranular fracture mode and voids were initiated between the [V, Mo]C particles and the matrix. Superior properties of high strength and low thermal expansion coefficient can be obtained by [V, Mo]C precipitation in alloy B with the addition of 0.4%V and 0.45%C.

• 대한치과교정학회지
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• 제25권2호
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• pp.187-200
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• 1995

국산 Ni-Ti합금 교정용 선재(ORTHOLLOY)의 특성을 평가하기 위하여 성분, 인장특성, 굽힘특성, 열처리성, 내식성, 이온용출 등에 대해 조사하고 외국산 Ni-Ti합금 선재(SENTALLOY)의 특성과 비교 분석한 결과는 다음과 같았다. ORTHOLLOY는 초탄성 효과를 나타내는 범위내에서의 Ni과Ti 함량을 포함하고 있었다. 인장실험에서 ORTHOLLOY는 연신율 $2\%$에서 $8\%$정도 범위내에서 하중의 변화가 거의 없는 초탄성 효과를 나타내었다. 3점 굴곡실험에서 ORTHOLLOY는 SENTALLOY 보다 같은 변위량에서 높은 하중값을 나타내었고, 초탄성을 나타내는 변위영역에서의 하중 범위는 ORTHOLLOY의 경우 0.014" 에서 80-100g, 0.016"에서 140-180g, 0.018" 에서 150-200g의 값을 나타내었다. $400^{\circ}C,\;500^{\circ}C$의 열처리에 의해 초탄성을 나타내는 하중범 위가 낮아졌고, 각 열처리 온도에서는 시간이 증가함에 따라 초탄성을 나타내는 하중값의 범위가 낮아졌으며 $600^{\circ}C$에서는 10분간의 열처리로 초탄성 효과가 소실되었다. 용출되어 나온 Ni 이온의 양은 SENTALLOY의 0.01ppm미만의 극소량에 비해 ORTHOLLOY에서는 0.3ppm 전후로 높게 나타났다. 침적 실험후 주사전자현미경 관찰을 통한 표면조직 소견은 SENTALLOY에서는 침적 전후 및 침적 시간의 경과에 관계없이 전체적으로 비교적 균일한 양상을 보였으나 ORTHOLLOY에서는 pitting corrosion양상을 보였다.

• 동력기계공학회지
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• 제17권4호
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• pp.79-85
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• 2013

This study aims at investigating the effect of a fusing treatments on anti-corrosion characteristics of Ni-based self-flux alloy coating. Ni-based coatings were fabricated by flame spray process on steel substrates, and fusing treatments were performed using a vacuum furnace at $800^{\circ}C$ $900^{\circ}C$, $1000^{\circ}C$ and $1100^{\circ}C$. After fusing treatments, corrosion tests were carried out using potentiostat/galvanostat at solution with pH 2 and pH 6. Corrosion potential(Ecorr) and corrosion current density(Icorr) could be analyzed from polarization curve. Fusing-treated coating at $1100^{\circ}C$ showed more favorable anti-corrosion characteristics than as-sprayed coating. Anticorrosive effect of fusing-treated coating at solution with pH 2 was relatively greater than at solution with pH 6. Fusing-treated coating at $1100^{\circ}C$ showed the most excellent anti-corrosion characteristics.

• 멤브레인
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• 제22권1호
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• pp.1-7
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• 2012

니오븀 금속을 기반으로 하는 $Nb_{56}Ti_{23}Ni_{21}$ 합금 분리막의 수소 투과 특성 및 화학적 안정성에 관한 연구를 수행하였다. 이를 위하여 직경 10 mm, 두께 0.5 mm의 $Nb_{56}Ti_{23}Ni_{21}$ 합금 분리막을 제작하였으며, 2가지 조성($H_2$ 100%, $H_2$ 60% + $CO_2$ 40%)의 공급가스를 $450^{\circ}C$의 온도에서 투과시킬 때 압력에 따른 수소 투과 특성에 관한 실험을 진행하였다. 본 실험에서의 최대 수소 투과량은 순수한 수소를 투과시킬 경우 절대압력 3 bar에서 $5.58mL/min/cm^2$로 나타났다. 또한 공급가스 조성에 따른 각각의 경우 모두 Sievert's law에 잘 부합하였으며, 이산화탄소와의 혼합가스 사용시, 투과량은 수소 분압 감소에 비례하여 감소하였다. 투과 실험 후 XRD 분석을 통하여 $Nb_{56}Ti_{23}Ni_{21}$ 합금 분리막의 이산화탄소에 대한 화학적 안정성에 대한 실험을 수행하였다.

• International Journal of Precision Engineering and Manufacturing
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• 제5권1호
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• pp.19-26
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• 2004

The growth of solid particles in TiC-XC-2vo1.% and TiC-XC-30vo1.% Ni alloys, (where X=Zr, W or Mo) was fitted to the equation of the form $d^3$-${do}^3$=Kt during the liquid phase sintering at 1,673K. Also, the grain growth behavior decreased markedly with the addition of ${MO}_2$C or WC and increased with the addition of zrC. The contiguity was greater in the alloys with a smaller growth rate constant and especially, decreased by increasing the Ni content in the TiC-${MO}_2$C-Ni alloy. In addition, the effect of the addition of carbide on the grain growth of 2 vo1.% Ni alloys was found to be similar to that of 30vo1.% Ni alloys. Consequently, the grain growth mechanism cannot be explained by the usual solution / reprecipitation process, but can be explained in terms of a new growth velocity equation, which includes the effects of contiguous carbide grain boundaries in restricting the overall grain growth, as well as the area of the solid / liquid interface in the alloy.

• 한국표면공학회지
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• 제32권2호
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• pp.100-108
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• 1999

The microstructure and corrosion properties of Al-Si diffusion coated PWA1426 alloy have been investigated. Experimental variables are included temperatures of heat-treatment and coating thickness. The microstructure of coated layer and corrosion properties were analysed by SEM, EDS and hot corrosion test. Two major processes have been found to contribute to microstructural changes in the coating. These are, firstly, the transformation of the NiAl to other $Ni_2Al_3$-based phase and secondly, the precipitation of Cr containing phases. Specimens heat treated at $1080^{\circ}C$ showed superior corrosion resistance to heat treated at $880^{\circ}C$. These increase in life was attributed to the transformation of NiAl and increased coating thickness of PWA1426 alloy.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.531-532
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• 2006

The effects of compaction pressure and sintering temperature on the densification of Fe-40wt%Ni alloy nanoparticles were analyzed. The Fe-Ni nanoparticles were fabricated by an arc-discharge method and then, compacted at three different pressures and sintered at 550 to $900\;^{\circ}C$. Densification was completed at temperature as low as $600\;^{\circ}C$ and high-pressure compaction was found to enhance densification. Densification behaviors and microstructure developments have been investigated through density measurements, electron microscopies, and hardness measurements.

• Journal of Advanced Marine Engineering and Technology
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• 제7권1호
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• pp.79-90
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• 1983

The examination for the changes of structures and mechanical properties in directionally solidified Al-Fe-Ni alloys containing the small amount of Fe and Ni was carried out by the varying the composition and solidification rate R of alloy, provided that the temperature gradient was 80 .deg.C/cm. The result were obtained as follows. A) In proportion to the increase of the solidification rate (R), the crystallized phase of this alloy was changed from the Ribbon-type structure to the Rod-type structure. B) The strength was rapidly increased in the changing process of composite shape from the Ribbon-type to the Rod-type with the solidification rate (R) increasing. C) The fiber stress (${\sigma}^f$) and Young's modulus ($E_f$) calculated for the Rod-type structure were 220 kg/$mm^2$ and 11, 800 kg/$mm^2$ respectively, which were in good accord with the rule of Mixtures.

• 한국수소및신에너지학회논문집
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• 제13권2호
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• pp.151-158
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• 2002

The hydorgen storage alloys were produced by melting in arc melting furnace and then solution heat treated at $1,100^{\circ}C$ followed by pulverization. The chemical analysis on the samples showed that the major elements of misch metal(Mm) were La, Ce, Pr and Nd with impurity less than 1wt.%. X-ray diffraction indicated that the structure for these samples were a single phase of hexagonal with $CaCu_5$ type. Compared to the initial particle size $100{\sim}110{\mu}m$, the many fine cracks were found and particle size decreased to $14{\mu}m$ for $MmNi_{4.5}Mn_{0.5}$ after hydriding/dehydring test run. To activate the sample the vessel filled with hydrogen storage alloys was first evacuated for for at $70^{\circ}C$ and then treated for 10.5hr under hydrogen pressure of 20atm for $MmNi_{4.5}Mn_{0.5}$ alloy. The experimental data showed that the hydrogen storage alloy of $MmNi_{4.5}Mn_{0.5}$ had superior adsorption and description properties within a temperature rang of $40^{\circ}C{\sim}80^{\circ}C$ and also they had a good P-C-T curve.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2001년도 추계학술대회 논문집
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• pp.272-276
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• 2001

Multicomponent $Zr_{41.2}Ti_{13.8}Cu_{12.5}Ni_{10}Be_{22.5}$ bulk matallic glass alloy shows good bulk glass forming ability due to its high resistance to crystallization in the undercooled liquid state.1) In this study, DSC and X-ray diffractometry have been performed to confirm the amorphous structure of the master $Zr_{41.2}Ti_{13.8}Cu_{12.5}Ni_{10}Be_{22.5}$ alloy. To investigate the mechanical properties and deformation behaviors of the bulk metallic $Zr_{41.2}Ti_{13.8}Cu_{12.5}Ni_{10}Be_{22.5}$ alloy, a series of compression tests has been carried out at the temperatures ranging from $351^{\circ}C$ to $461^{\circ}C$ and at the various initial strain rates from $2{\times}10^{-4}s^{-1}\;to\;2{\times}10^{-2}s^{-1}$. There are two types of nominal stress-strain curves. The one shows linear stress-strain relationship meaning fracture at maximum stress, the other shows plastic deformation including steady-state flow. Also DSC analysis for the compressed specimens has been performed to investigate the change of thermal stability and crystallization behavior for the various test conditions.