• Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
• /
• 2003.02a
• /
• pp.113-116
• /
• 2003

The growth properties of $Y_2$O$_3$ and CeO$_2$ films for the buffer layers on Ni tapes were studied comparatively. The water vapor larger than 2$\times$10$^{-5}$ Torr and the substrate temperature higher than $700^{\circ}C$ were required for the proper growth of $Y_2$O$_3$ films, while the upper limits of the water vapor and the lower limit of the substrate temperatures for the proper growth of CeO$_2$ were 1$\times$10$^{-5}$ Torr and 50$0^{\circ}C$, respectively. These imply that the windows of the growth conditions of CeO$_2$ are wider than those of $Y_2$O$_3$. However the formation of cracks in CeO$_2$ films were its disadvantage, while $Y_2$O$_3$ showed no cracks. PACS. No 85.25.K, 81.15.A.

• Progress in Superconductivity and Cryogenics
• /
• v.19 no.2
• /
• pp.48-52
• /
• 2017

Discrepancy between a power supply current and an actual "spiral" coil current makes the conventional 4-probe measurement of a critical current ($I_c$) of a no-insulation (NI) high temperature superconductor (HTS) coil inaccurate and time-consuming. This paper presents a fast and accurate approach for $I_c$ measurement of NI HTS coils. With an NI HTS coil energized at a constant ramping rate, a complete analytic expression for the spiral coil current was obtained from a first-order partial differential equation that derived from an equivalent circuit model of the NI coil. From the analytic solution, both spiral coil current and radial leak current can be obtained simultaneously, which enables fast and accurate measurement of the NI coil $I_c$. To verify the proposed approach, an NI double-pancake (DP) coil, wound with GdBCO tapes of $6mm{\times}0.1mm$, was constructed and its $I_c$ was repeatedly measured with various ramping rates in a bath of liquid nitrogen at 77 K. The measured results agreed well with the calculated ones, which validates the proposed approach to measure $I_c$ of an NI HTS coil.

• Journal of the Korean Ceramic Society
• /
• v.43 no.12 s.295
• /
• pp.788-797
• /
• 2006

An anode-supported SOFC single cell having $5{\mu}m$ thin electrolyte was fabricated cost-effectively by tape casting, laminating, and co-filing of anode (NiO-YSZ), cathode (LSM-YSZ), and electrolyte (YSZ) components. The optimal slurry compositions of the green tapes for SOFC components were determined by an analysis of the mean diameter, the slurry viscosity, the tensile strength/strain of the green tapes, and their green microstructures. The single cells with a dense electrolyte and porous electrodes could be co-fired successfully at $1325\sim1350^{\circ}C$ by controlling the contents of pore former and the ratio of coarse YSZ and fine YSZ in the anode and the cathode. The single cell co-fired at $1350^{\circ}C$ showed $100.2mWcm^{-2}$ of maximum power density at $800^{\circ}C$ but it was impossible to apply it to operate at low temperature because of low performance and high ASR, which were attributed to formation of the secondary phases in the cathode and the interface between the electrolyte and the cathode.

• Progress in Superconductivity
• /
• v.7 no.2
• /
• pp.120-129
• /
• 2006

We comparatively studied the epitaxial growth conditions of $CeO_2$ and $Y_2O_3$ thin buffers on textured Ni tapes using rf magnetron sputtering and investigated the feasibility of getting a single mixture layer or sequential layers of $CeO_2$ and $Y_2O_3$ for more simplified buffer architecture. All the buffer layers were first deposited using the reducing gas of $Ar/4%H_2$ and subsequently the reactive gas mixture of Ar and $O_2$, The crystalline quality and biaxial alignment of the films were investigated using X-ray diffraction techniques (${\Theta}-2{\Theta},\;{\phi}\;and\;{\omega}\;scans$, pole figures). The $CeO_2$ single layer exhibited well developed (200) epitaxial growth at the condition of $10%\;O_2$ below an $450^{\circ}C$, but the epitaxial property was decreased with increasing the layer thickness. $Y_2O_3$ seldom showed optimum condition for (400) epitaxial growth. The sequential architecture of $CeO_2/Y_2O_3/CeO_2$ having good epitaxial property was achieved by sputtering at a temperature of $700^{\circ}C$ on the initial $CeO_2$ bottom layer sputtered at $400^{\circ}C$. Cracking of the sputtered buffer layers was seldom observed except the double layer structure of $CeO_2/Y_2O_3$.

• Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
• /
• 2002.02a
• /
• pp.339-339
• /
• 2002

In the RABiTS approach to coated conductor development, successful (both economic and technological) depends on the refinement and optimization of each of three important components: the metal tape substrate, the buffer layer(s), and the HTS layer. Here we will report on the ORNL approach and progress in each of these areas. - Most applications will require metal tapes with low magnetic hysteresis, mechanical strength, and excellent crystalline texture. Some of these requirements are competing. We report on progress in obtaining a good combination of these characteristics on metal alloys of Ni-Cr and Ni-W. - The deposition of appropriate buffer layers is a crucial step. Recently, base research has shown that the presence of a stable sulfur superstructure present on the metal surface is needed for the nucleation and epitaxial growth of vapor-deposited seed buffer layers such as YSZ, CeO$_2$ and SrTiO$_3$. We report on the details and control of this superstructure for nickel tapes, as well as recent results for Cu and Ni-13%Cr. - Processes for deposition of the HTS coating must economically provide large values of the figure-of-merit for conductors, current x length. At ORNL, we have devoted efforts to a precursor/post-annealing approach to YBCO coatings, for which the deposition and reaction steps are separate. We describe motivation for and progress toward developing this approach. - Finally, we address some issues for the implementation of coated conductors in real applications, including the need for texture control and electrical stabilization of the HTS coating.

• Progress in Superconductivity
• /
• v.8 no.1
• /
• pp.27-32
• /
• 2006

[$YBa_2Cu_3O_{7-x}$] thin films were deposited on various buffered-templates by a metal organic chemical vapor deposition(MOCVD). Three different templates of $CeO_2/YSZ/CeO_2/pure-Ni(CYC),\;CeO_2/YSZ/Y_2O_3/Ni-3at.%W(YYC)$ and $CeO_2/IBAD-YSZ$/stainless steel were used. The Ni and Ni-W alloy tapes were biaxially textured by cold rolling and annealing heat treatment. The dense YBCO films were grown on both the IBAD and YYC templates with no microcrack, while the YBCO films on the CYC templates were grown with the formation of microcracks and NiO. The YBCO film on the YYC template showed the higher $I_c$ than that on CYC template. Especially, the IBAD templates with a thin $CeO_2$(type I) and thick $CeO_2$(type II) top layer were used to compare the deposition nature of the YBCO on them. Comparing the current property of the YBCO films on IBAD templates, the YBCO film deposited on thick $CeO_2$ layer was better than the film on thin $CeO_2$ layer.

• Progress in Superconductivity and Cryogenics
• /
• v.25 no.1
• /
• pp.16-20
• /
• 2023

The International Electrotechnical Commission (IEC) 61788-26:2020 provides guidelines for measuring the critical current of Rare-earth barium copper oxide (REBCO) tapes using two methods: linear ramp and step-hold methods. The critical current measurement criterion, 1 or 0.1 μV/cm of electric field from IEC 61788-26 has been normally applied to REBCO coils or magnets. No-insulation (NI) winding technique has many advantages in aspects of electrical and thermal stability and mechanical integrity. However, the leak current from the NI REBCO coil can cause distortion in critical current measurement due to the characteristic resistance which causes the radial current flow paths. In this paper, we simulated the NI REBCO coil by applying both linear ramp and step-hold methods based on a simplified equivalent circuit model. Using the circuit analysis, we analyzed and evaluated both methods. By using the equivalent circuit model, we can evaluate the critical current of the NI REBCO coil, resulting in an estimation error within 0.1%. We also evaluate the accuracy of critical current measurement using both the linear ramp and step-hold methods. The accuracy of the linear ramp method is influenced by the inductive voltage, whereas the accuracy of the step-hold method depends on the duration of the hold-time. An adequate hold time, typically 5 to 10 times the time constant (τ), makes the step-hold method more accurate than the linear ramp method.

• Transactions on Electrical and Electronic Materials
• /
• v.6 no.4
• /
• pp.186-189
• /
• 2005

We have fabricated superconducting HTSC ceramic thick films by chemical process. c-axis oriented HTSC thick films have been attempted bi-axially textured Ni tapes. The x-ray diffraction pattern of the HTSC thick films contained superconducting phase crystal. The critical temperature and critical current density was 110K.

• 한국초전도학회:학술대회논문집
• /
• v.13
• /
• pp.81-81
• /
• 2003

• 한국초전도학회:학술대회논문집
• /
• v.14
• /
• pp.92-92
• /
• 2004