• Title/Summary/Keyword: Ni accumulation

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Heavy Metal Accumulation in Oxyloma hirasei from the Upo Wetland

  • Kim, Heung-Tae;Kim, Jae-Geun
    • Journal of Ecology and Environment
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    • v.30 no.1
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    • pp.81-86
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    • 2007
  • Human activities have enhanced the influx of heavy metals to aquatic ecosystem and hanged the abiotic environment such as the sediments supporting benthic organisms. The levels of heavy metals (Cd, Cr, Cu, Ni, Pb and Zn) in the benthic gastropod Oxyloma hirasei and the sediments around their habitat were investigated to examine heavy metal levels and the potential of the gastropod as a bioindicator. We detected different levels of heavy metals in the sediments of two wetland areas, Upo and Mokpo, in the relatively well-conserved Upo wetland, Ramsar Convention Area. Oxyloma hirasei had higher concentrations of heavy metals except Cr and Ni in their soft tissues than in their shells (Cd: $2.10{\sim}3.16$, Cu: $19.73{\sim}28.66$, Pb: $0.67{\sim}1.17$, Zn: $216.1{\sim}285.7\;{\mu}g/g$ dry weight in the soft tissues; Cr: $1.19{\sim}2.58$, Ni: $0.47{\sim}1.16\;{\mu}g/g$ dry weight in the shells). Differences in the Cd, Cu, Ni and Pb concentrations in O. hirasei soft tissues reflected differences in heavy metal concentrations in the sediments at the sampling sites. The coefficients of variation for Cd, Cu and Pb were lower than those for other metals in the soft tissues. Levels of Cd in the tissues of O. hirasei were the highest among the metals examined in this study. Therefore, the soft tissue of O. hirasei appears to be a promising bioindicator particularly for Cd.

Mitigation of Carbon Dioxide and Heavy Metals by Urban Greenspace (도시녹지의 이산화탄소 및 중금속 저감)

  • Park, Joo-Young;Ju, Jin-Hee;Yoon, Yong-Han
    • Journal of Environmental Policy
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    • v.9 no.1
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    • pp.137-154
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    • 2010
  • These objectives of this study were to compute heavy metal and accumulation carbon dioxide fixing quantity from urban green space(street trees and urban parks) in Cheong-ju city and Chungju-city and thus to estimate the effect of urban green space for improving the urban environment. The results are summarized below. 1. Results of the total accumulation of the carbon dioxide fixing quantity of street trees, Cheong-ju city and Chungju-city street tree was 1, 230,000kg-C, 1,270,000 kg-C, respectively. Total accumulation carbon dioxide fixing quantity of Balssan urban park had a 25,000kg-C in Cheong-ju city, Degami sports park had a 6,400kg-C in Chungju-city. 2. Results of heavy metal for street trees, fell in the order Zn > Cu > Cr > Ni >, the highest accumulated heavy metal was Zn, and the lowest was Ni. Total heavy metal concentration according to land-use area, was observed in order, for residental areas(157.26 mg/kg) > industrial areas(141.71 mg/kg) > commercial areas(118.55 mg/kg) > and greenspace areas(61.95 mg/kg) in Cheong-ju city. 3. Total heavy metal concentration for street trees fell in the order of commercial areas(84.48 mg/kg) > residental areas(83.70 mg/kg) > and greenspace(48.23 mg/kg) according to land-use area in Chungju-city. Comparatively, Cheong-ju city had more total heavy metal concentration than Chungju-city. 4. Heavy metal for soil that planted street trees was observed in order of Zn > Cu > Pb( > Ni > Cr > As > Cd), and Zn was highest, and Cd was lowest. Total heavy metal concentration for soil fell in the order commercial area(91.82mg/kg) > industrial area(85.96mg/kg) > residental area(67.55mg/kg) > greenspace(43.13mg/kg) according to land-use area in Cheong-ju city. 5. Heavy metal for soil that planted street trees was observed in order of Zn > Pb > Cu( > Ni > Cr > As > Cd, and Zn was highest. Total heavy metal concentration for soil fell in the order commercial area(87.66mg/kg) > greenspace(72.73mg/kg) $${\geq_-}$$ residental area(70.10mg/kg) in Chungju-city.

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Fabrication of Porous Ni by Freeze Drying and Hydrogen Reduction of NiO/Camphene Slurry (NiO/camphene 슬러리의 동결건조 및 수소환원 공정에 의한 Ni 다공체 제조)

  • Jeong, Jae-Hun;Oh, Sung-Tag;Hyun, Chang-Yong
    • Journal of Powder Materials
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    • v.26 no.1
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    • pp.6-10
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    • 2019
  • In this study, freeze drying of a porous Ni with unidirectionally aligned pore channels is accomplished by using a NiO powder and camphene. Camphene slurries with NiO content of 5 and 10 vol% are prepared by mixing them with a small amount of dispersant at $50^{\circ}C$. Freezing of a slurry is performed at $-25^{\circ}C$ while the growth direction of the camphene is unidirectionally controlled. Pores are generated subsequently by sublimation of the camphene during drying in air for 48 h. The green bodies are hydrogen-reduced at $400^{\circ}C$ and then sintered at $800^{\circ}C$ and $900^{\circ}C$ for 1 h. X-ray diffraction analysis reveals that the NiO powder is completely converted to the Ni phase without any reaction phases. The sintered samples show large pores that align parallel pores in the camphene growth direction as well as small pores in the internal walls of large pores. The size of large and small pores decreases with increasing powder content from 5 to 10 vol%. The influence of powder content on the pore structure is explained by the degree of powder rearrangement in slurry and the accumulation behavior of powders in the interdendritic spaces of solidified camphene.

Impact of anthropogenic activities on the accumulation of heavy metals in water, sediments and some commercially important fish of the Padma River, Bangladesh

  • M Golam Mortuza
    • Fisheries and Aquatic Sciences
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    • v.27 no.2
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    • pp.66-75
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    • 2024
  • Heavy metals are naturally found in the ecosystem, and their presence in the freshwater river is increasing through anthropogenic activities which pose a threat to living beings. In this study, heavy metal concentrations (Zn, Mn, Cu, Cd, Cu, Cr, Pb, and Ni) in different organs (muscle, skin, and gill) of fish from the Padma River were evaluated to quantify, and compare the contamination levels and related human health risks. The results revealed that the heavy metal concentrations in the water, surface sediments, and fish taken from the Padma River were far below the WHO/USEPA's permitted limits. The estimated daily intake (EDI) value in muscle was less than the tolerable daily intake (TDI). The target hazard quotient (THQ) and hazard indexes (HI) were less than 1, showing that consumers face no non-carcinogenic risk (CR). CR values of Cu, Cd, Cr, Pb, and Ni ranged from 4.00 × 10-8 to 6.35 × 10-6, less than 10-4, and total carcinogenic risk (CRt) values ranged from 9.85 × 10-6 to 1.10 × 10-5, indicating some pose a CR from consumption of those fish from the Padma River. To establish a more accurate risk assessment, numerous exposure routes, including inhalation and cutaneous exposure, should be explored.

Alteration of macronutrients, metal translocation and bioaccumulation as potential indicators of nickel tolerance in three Vigna species

  • Ishtiaq, Shabnam;Mahmood, Seema;Athar, Mohammad
    • Advances in environmental research
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    • v.3 no.1
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    • pp.71-86
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    • 2014
  • Macronutrients ($Na^+$, $K^+$, $Ca^{2+}$, $Mg^{2+}$), yield and yield components, bioaccumulation and translocation of metal in plant parts of three Vigna species (V. cylindrica, V. mungo, V. radiata) were evaluated at 0, 50, 100 and $150mgkg^{-1}$ soil of Nickel (Ni). A marked inhibition (p < 0.001) in the distribution of various macronutrients was noticed in these Vigna species except for $Mg^{2+}$ content of the shoot and leaves. Similarly, all species retained more $Ca^{2+}$ in their roots (p < 0.05) as compared to the aerial tissues. Ni induced a drastic decline (p < 0.001) for various yield and yield attributes except for 100 seed weight. Toxicity and accumulation of Ni in plant tissues considerably increased in a concentration dependent manner. Vigna species signify an exclusion approach for Ni tolerance as both bioaccumulation factor (BF) and translocation factor (TF) were less than 1.0. The Ni content of plants being root > shoot > leaves > seeds. Scoring for percentage stimulation and inhibition (respective to control) at varying levels of Ni revealed tolerance of the species in an order of V. radiata > V. cylindrica > V. mungo. The acquisition of Ni tolerance in V. radiata seems to occur through an integrated mechanism of metal tolerance that includes sustainable macronutrients uptake, stronger roots due to greater deposition of $Ca^{2+}$in the roots, restricted transfer of Ni to above ground tissues and seeds as well as exclusion capacity of the roots to bind appreciable amount of metal to them. Thus, metal tolerant potential of V. radiata could be of great significance to remediate metal contaminated soil owing lesser impact of Ni on macro-nutrients, hence the yield.

The impact of municipal waste disposal of heavy metals on environmental pollution: A case study for Tonekabon, Iran

  • Azizpour, Aziz;Azarafza, Mohammad;Akgun, Haluk
    • Advances in environmental research
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    • v.9 no.3
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    • pp.175-189
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    • 2020
  • Municipal solid waste disposal is considered as one of the most important risks for environmental contamination which necessitates the development of strategies to reduce destructive consequences on the ecosystem as related especially to heavy metal accumulation. This study investigates heavy metal (i.e., As, Cd, Co, Cr, Cu, Mn, Ni, Pb, Zn) accumulation in the Tonekabon region, NW of Iran that is related to city waste disposal and evaluates the environmental impact in the Caspian Sea coastal region. For this purpose, after performing field studies and collecting 50 soil specimens from 5 sites of the study area, geochemical tests (i.e., inductively coupled plasma mass spectrometry, atomic absorption spectroscopy and x-ray fluorescence) were conducted on the soil specimens collected from the 5 sites (named as Sites A1, A2, A3, A4 and A5) and the results were used to estimate the pollution indices (i.e., geo-accumulation index, normalized enrichment factor, contamination factor, and pollution load index). The obtained indices were utilized to assess the eco-toxicological risk level in the landfill site which indicated that the city has been severely contaminated by Cu, Mn, Ni, Pb and Zn. These levels have been developed along the stream towards the nearshore areas indicating uptake of soil degradation. The heavy metal contamination was classified to range from unpolluted to highly polluted, which indicated serious heavy metal pollution in the study area as related to municipal solid waste disposal in Tonekabon.

울산 달천광산 인근의 식물체 중금속 축적에 관한 연구

  • Kim Cheol;Cheon Mi-Hui
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2006.04a
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    • pp.131-137
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    • 2006
  • This study was investigated the contents of heavy metals in plants at Dalcheun mine area, in order to offer basic data for phytoremedation on soil contamination by heavy metals. As the results of this study, the contents of Ni, As, Cd in plants were the highest at the west area of Dalcheun mine area. But the content of Zn was similar in all of Dalcheun mine area. For the herbaceous plants, the contents of heavy metals were higher in plants which were included in Gramineae and Compositae than any other families. And then the contents of Ni, Zn, Cd in root were higher $1.4{\sim}1.8$ times than stem, especially the content of As was higher 4 times. For the trees, the contents of heavy metals were usually high in Zanthoxylum piperitum, Pine tree, Chestnut tree, Quercus acutissima and Lindera obtusiloba. The contents of heavy metals with parts of tree were almost same range. All experimental result, we paid attention on two conclusions. First, the contents of heavy metals in herbs was higher than in trees. And second, if there were some spices that the content of heavy metal in leave were higher than in root, they could accumulate that kind of heavy metal. Therefore, It is above 2 times which the content of heavy metal in the leave is higher than in the root about herbs, that kind of plants was regarded as a accumulation species. According as the heavy metals, accumulation species were selected. We think that the accumulation species are able to absorb the heavy metals from the soil, they will make use of phytoremedation on contaminated soil by heavy metals.

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Biophysical Effects Simulated by an Ocean General Circulation Model Coupled with a Biogeochemical Model in the Tropical Pacific

  • Park, Hyo-Jin;Moon, Byung-Kwon;Wie, Jieun;Kim, Ki-Young;Lee, Johan;Byun, Young-Hwa
    • Journal of the Korean earth science society
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    • v.38 no.7
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    • pp.469-480
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    • 2017
  • Controversy has surrounded the potential impacts of phytoplankton on the tropical climate, since climate models produce diverse behaviors in terms of the equatorial mean state and El $Ni{\tilde{n}}o$-Southern Oscillation (ENSO) amplitude. We explored biophysical impacts on the tropical ocean temperature using an ocean general circulation model coupled to a biogeochemistry model in which chlorophyll can modify solar attenuation and in turn feed back to ocean physics. Compared with a control model run excluding biophysical processes, our model with biogeochemistry showed that subsurface chlorophyll concentrations led to an increase in sea surface temperature (particularly in the western Pacific) via horizontal accumulation of heat contents. In the central Pacific, however, a mild cold anomaly appeared, accompanying the strengthened westward currents. The magnitude and skewness of ENSO were also modulated by biophysical feedbacks resulting from the chlorophyll affecting El $Ni{\tilde{n}}o$ and La $Ni{\tilde{n}}a$ in an asymmetric way. That is, El $Ni{\tilde{n}}o$ conditions were intensified by the higher contribution of the second baroclinic mode to sea surface temperature anomalies, whereas La $Ni{\tilde{n}}a$ conditions were slightly weakened by the absorption of shortwave radiation by phytoplankton. In our model experiments, the intensification of El $Ni{\tilde{n}}o$ was more dominant than the dampening of La $Ni{\tilde{n}}a$, resulting in the amplification of ENSO and higher skewness.

Characteristics and Assessment of Metal Pollution and their Potential Source in Stormwater Runoff from Shihwa Industrial Complex, Korea (시화산업단지 강우유출수 내 중금속 오염도 평가 및 오염원 추적 연구)

  • Lee, Jihyun;Jeong, Hyeryeong;Choi, Jin-Young;Ra, Kongtae
    • Korean Journal of Ecology and Environment
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    • v.53 no.1
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    • pp.91-101
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    • 2020
  • Stormwater runoff is known as a major non-point water pollution source that transports heavy metals, which have accumulated in road surface, to stream and coastal area. Dissolved and particulate metals in stormwater runoffs have been investigated to understand the outflow characteristics of heavy metals during rainfall events and to identify their pollution sources. The concentration of dissolved Co and Ni decreased after the outflow with high concentrations at the beginning of the rainfall, and other metals showed different characteristics depending on the rainfall and rate of discharge. Particulate metals showed a similar trend with the temporal variation of suspended solids concentration in stormwater runoffs. The results of geo-accumulation index (Igeo) indicated that the stormwater runoffs from industrial region were very highly polluted with Cu, Zn and Cd. As a result of comparing the metal concentrations of <125 ㎛ for road dust near the study area, Cu, Zn and Cd were originated from inside of metal manufacturing facilities rather than traffic activities at road surface and these metals accumulated on the surface area of facilities were transported to the water environments during stormwater event. The average discharged amounts of heavy metals for one rainfall event were Cr 128 g, Co 12.35 g, Ni 98.5 g, Cu 607.5 g, Zn 8,429.5 g, As 6.95 g, Cd 3.7 g, Pb 251.75 g, indicating that metal runoff loads in the stormwater runoffs are closely related to surrounding industry types.

Evaluation of Heavy Metal Sources and Its Transfer and Accumulation to Crop in Agricultural Soils (농경지 토양의 중금속 오염원 및 농작물로의 중금속 전이·축적 평가)

  • Lim, Ga-Hee;Jo, Hun-Je;Park, Gyoung-Hun;Yun, Sung-Mi;Kim, Ji-In;Noh, Hoe-Jung;Kim, Hyun-Koo;Yoon, Jeong-Ki
    • Journal of Soil and Groundwater Environment
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    • v.23 no.3
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    • pp.27-42
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    • 2018
  • It is important to identify the contaminant sources and to evaluate the fate and transport of heavy metals to crops in agricultural lands. This study was conducted to evaluate metal sources and its transfer and accumulation to crop in agricultural soils. Pollution indices were calculated and multivariate analysis was performed to identify metal sources. To evaluate transfer and accumulation of metals to crops, the contents of phytoavailable metals were evaluated by using single extraction method and the correlation between metal content and soil properties was analyzed. Also the BCF was quantitatively evaluated for investigating the metal transition to each crop grown in the research area. As a result, Cr, Ni, and Co were expected to be mainly derived from geologic factors due to weathering of certain parent rocks. The content of nickel in soils of the research area was slightly higher than that of the concern level criteria based on total concentration, but the amount transferred and accumulated in the crops was actually low. Understanding the contamination characteristics by investigating the pollution sources of heavy metals and its transfer and accumulation to crops through various evaluation techniques could provide important information for proper management of the agricultural land.