• 대한화학회지
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• 제48권2호
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• pp.215-219
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• 2004

• Korean Chemical Engineering Research
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• 제55권1호
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• pp.19-26
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• 2017

Increasing global energy demand has resulted in an energy crisis. The dye sensitizer solar cell (DSSC) is an alternative source because of its ability to convert the sun's energy into electrical energy. Our aim was to determine the effect of synthesized Ni(II)-Chlorophyll for enhancing the efficiency of solar cells based DSSC. Complex compound Ni(II)-Chlorophyll was successfully synthesized as a dye sensitizer of $Ni(NO_3)_2.6H_2O$ and chlorophyll ligand with saponification method. Characterization results with spectrophotometer UV-Vis showed that the complex compounds of Ni(II)-Chlorophyll have a maximum wavelength of 295.00 nm, 451.00 and 665.00 nm. The bond between the ligand and metal appears in the vibration Ni-O at wave number $455.2cm^{-1}$. Complex compoun Ni(II)-Chlorophyll has a magnetic moment 7.10 Bohr Magneton (BM). The performance of complex compound Ni(II)-Chlorophyll as a dye sensitizer shows the value of short-circuit current (Jsc) at $3.00mA/cm^2$, open circuit voltage (Voc) at 0.15 V and the efficiency (${\eta}$) 0.20%.

• 한국산학기술학회논문지
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• 제11권12호
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• pp.5221-5231
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• 2010

Ni(II)이온과 2-(2-Hydroxyethylamino)-2-(hydroxymethyl)-1,3-propanediol(Monotris)과의 착물형성을 $25^{\circ}C$ 이온강도 0.10M 에서 전위차법으로 연구하였다. $NiL^{2+}$ 착물은 히드록실기의 산소 원자 뿐만아니라 아민의 질소기도 금속에 배위하였다. pH가 증가하면서 $NiL^{2=}$는 3개의 수소이온이 해리된 $Ni_2L_2H_{-3}^+$의 이핵착물이 형성되었다.

• 한국자기공명학회논문지
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• 제18권2호
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• pp.74-81
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• 2014

The $N_2O_2$ tetradentate Schiff base ligand, N,N'-bis(salicylidene)pentane-1,3-diamine (Salpn), coupled with 1:2 concentration ratio of 1,3-diaminopentane and salicylaldehyde was used to produce a series of macrocyclic Nikel(II) complexes. In the metal complexation, it was observed that Salpn macrocyclic ligand can adopt more than a metal ion giving an unique multinuclear metal complexes including Ni(II)Salpn and $Ni(II)_3(Salpn)_2$. Characteristic IR ${\upsilon}(M-O)$ peaks for Ni(II)Salpn and $Ni(II)_3(Salpn)_2$ were observed to be $1028cm^{-1}$ and $1024cm^{-1}$, respectively. Characteristic UV-Vis absorption ${\lambda}_{max}$ peaks for $Ni(II)_3(Salpn)_2$ were observed to be 241nm and 401 nm. Structural characterization of $Ni(II)_3(Salpn)_2$ by NMR exhibits that the salicylidene ring moiety has two different resonance signals originated from the magnetically asymmetric diligand and trinuclear bis complex. Complete NMR signal assignments and characterizations elucidating structural features of $Ni(II)_3(Salpn)_2$ were described in detail.

• 대한화학회지
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• 제44권3호
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• pp.207-211
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• 2000

Tween80 미셀용액에서 착화제로서 APDC틀 이용하여 Ni(II)를 정량하는 방법에 대해 연구하였다. Ni(PDC)$_2$ 착물의 홉수 스펙트럼 chloroform에서 보다는 Tween80에서 더 좋은 모양과 더 좋은 감도를 보여 주었다. Ni(PDC)$_2$ 착물은 pH 7.0에서 그리고 100분 정도까지 매우 안정하였으며, APDC를 Ni(II)의 몰수의 10배 이상 넣어 주면 정량적으로 착물이 형성되었다. Tween80의 농도는 0,1%가 적절하였고,0.1% Tween80 용액에서 Ni(PDC)$_2$ 착물의 검정곡선은 좋은 직선성(R2=0.9955)을 보여주었다. 이 분석법의 검출한계와 정량한계는 각각 0.09 ${\mu}g$/mL와 0.28${\mu}g$/mL이었으며, 강물시료에 적용한 회수율은 100% 보다 조금 크게 나타났다. 비록 여러 금속이온들이 방해를 하지만, 실제시료에 들어있는 Ni(II)을 정량하는데 이용할 수 있을 것이다.

• Bulletin of the Korean Chemical Society
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• 제27권11호
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• pp.1747-1751
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• 2006

The dinuclear tetraazadiphenol macrocyclic nickel(II) complexes [$Ni_2$([20]-DCHDC)]$Cl_2$ (I), [$Ni_2$([20]-DCHDC)]$(ClO_4)_2{\cdot}2CH_3CN $ (II(b)) and [$Ni_2$([20]-DCHDC)$(NCS)_2$] (III) {$H_2$[20]-DCHDC = 14,29-dimethyl-3,10,18,25-tetraazapentacyclo-[25,3,1,$0^{4,9}$,$1^{12,16}$,$0^{19,24}$]ditriacontane-2,10,12,14,16(32),17,27(31), 28,30-decane-31,32-diol} have been synthesized by self-assembly and characterized by elemental analyses, conductances, FT-IR and FAB-MS spectra, and single crystal X-ray diffraction. The crystal structure of II(b) is determined. It crystallizes in the monoclinic space group P2(1)/c. The coordination geometries around Ni(II) ions in I and II(b) are identical and square planes. In complex III each Ni(II) ion is coordinated to $N_2O_2$ plane from the macrocycle and N atoms of NCS- ions occupying the axial positions, forming a square pyramidal geometry. The nonbonded Ni…Ni intermetallic separation in the complex II(b) is 2.8078(10) $\AA$. The FAB mass spectra of I, II and III display major fragments at m/z 635.1, 699.4 and 662.4 corresponding to [$Ni_2$([20]-DCHDC)(Cl + 2H)]$^+$, [$Ni_2$([20]-DCHDC)$(ClO_4\;+\;2H)]^+$ and [$Ni_2$([20]-DCHDC)(NCS) + 6H]$^+$, respectively.

• Bulletin of the Korean Chemical Society
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• 제34권7호
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• pp.2125-2130
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• 2013

A new nickel(II) complex $[NiL^1]^{2+}$ ($L^1$ = 1-(2-aminoethyl)-3-(N-{2-aminoethyl}aminomethyl-1,3-diazacyclohexane) containing one 1,3-diazacyclohexane ring has been prepared selectively by the metal-template condensation of formaldehyde with N-(2-aminoethyl)-1,3-propanediamine and ethylenediamine at room temperature. The complex reacts with nitroethane and formaldehyde to yield the pentaaza macrocyclic complex $[NiL^2]^{2+}$ ($L^2$ = 8-methyl-8-nitro-1,3,6,10,13-pentaazabicyclo[13.3.1]heptadecane) bearing one C-$NO_2$ pendant arm. The reduction of $[NiL^2]^{2+}$ by using Zn/HCl produces $[NiL^3(H_2O)]^{2+}$ ($L^3$ = 8-amino-8-methyl-1,3,6,10,13-pentaazabicyclo[13.3.1]heptadecane) bearing one coordinated C-$NH_2$ pendant arm that is readily protonated in acid solutions. The hexaaza macrocyclic complex $[NiL^4]^{2+}$ ($L^4$ = 8-phenylmethyl-8-nitro-1,3,6,8,10,13-hexaazabicyclo[13.3.1]heptadecane) bearing one N-$CH_2C_6H_5$ pendant arm has also been prepared by the reaction of $[NiL^1]^{2+}$ with benzylamine and formaldehyde. The nickel(II) complexes of $L^1$, $L^2$, and $L^4$ have square-planar coordination geometry in the solid states and in nitromethane. However, they exist as equilibrium mixtures of the square-planar $[NiL]^{2+}$ (L = $L^1$, $L^2$, or $L^4$) and octahedral $[NiL(S)_2]^{2+}$ species in various coordinating solvents (S); the proportion of the octahedral species $[NiL(S)_2]^{2+}$ is strongly influenced by the ligand structure and the nature of the solvent. Synthesis, spectra, and chemical properties of the nickel(II) complexes of $L^1-L^4$ are described.

• 대한화학회지
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• 제30권5호
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• pp.456-464
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• 1986

branched poly(ethylene imine) (BPEI)와 2가 전이금속인 Fe(II), Co(II), Ni(II) 및 Cu(II)간의 착물생성을 가시선 흡수 및 30${\circ}$, 0.1M KCl수용액 중에서 pH적정법으로 연구하였다. M(II)-BPEI착물의 안정도 상수는 M(II)-BPEI착물의 안정도 상수는 Gergor등에 의해 수정된 Bjerrum법으로 계산하였다. M(II)-BPEI착물의 생성 곡선으로 부터 ethylene imine group이 Fe(II)이온에 네자리, Co(II), Ni(II) 및 Cu(II) 이온에 각각 두 자리 배위된 착물이 생성됨을 알 수 있었다. Cu(II)-BPEI착물의 경우 pH 3.4~3.8을 기준으로 산성도가 감소 또는 증가함에 따라 최대 흡광도(${\lambda}_{max}$)는 장파장 쪽으로 이동하고, 흡광도는 pH증가에 따라 감소하였다. 총괄 안정도 상수(log $K_2$)는 Co(II) < Cu(II) < Ni(II) < Fe(II)순으로 증가하였다.

• Bulletin of the Korean Chemical Society
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• 제23권1호
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• pp.81-85
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• 2002

A new di-N-cyanoethylated 14-membered tetraaza macrocycle 1,8-bis(2-cyanoethyl)-3,5,7,7,10,12,14,14-octamethyl-1,4,8,11-tetraazacyclotetradecane $(L^2)$ and its nickel(II) complex $[NiL^2(OAc)]^+$ have been prepared. The square-planar complex $[NiL^2](C IO_4)_2$ can be prepared by addition of $HClO_4$ to a hot aqueous solution of $[NiL^2(OAc)]^+$ The Ni-N (tertiary amino group) bond distances $(2.008{\AA})$ of $[NiL^2](C IO_4)_2$ are relatively long, and the complex exhibits a d-d transition band at unusually long wavelength (ca. 515 nm). The complex $[NiL^2](C IO_4)_2$ rapidly reacts with acetate ion or ethylenediamine (en) to produce $[NiL^2(OAc)]^+$ or [Ni(en)_3]^{2+}$, respectively, and is readily decomposed in NaOH (0.01 M) solution. The chemical properties of $[NiL^2]^{2+}$ as well as its synthetic procedure are quite different from those for other related 14-membered tetraaza macrocyclic complexes. Effects of the N-cyanoethyl and C-methyl groups on the properties of $L^2$.

• 분석과학
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• 제11권5호
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• pp.332-340
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• 1998

Salicylaldehyde와 2-hydroxy-1-naphthaldehyde를 2-aminophenol과 2-amino-p-cresol에 반응시켜 세자리 Schiff base 리간드($SIPH_2$, $SIPCH_2$, $HNIPH_2$, $HNIPCH_2$)들을 합성하였다. 이들 리간드를 Ni(II) 이온과 반응시켜 세자리 Schiff base Ni(II) 착물들을 합성 하였다. 이들 리간드와 그 착물들의 가상적인 구조와 특성을 원소분석, $^1H$-NMR, IR, UV-vis 분광법과 열 무게 분석법으로 알아보았다. Schiff base 리간드와 Ni(II) 착물의 몰비는 1:1로 결합하며, Ni(II)착물들은 3분자의 수화물이 배위된 6배위의 8면체 구조임을 알았다. 지지 전해질로서 0.1 M TBAP를 포함한 DMSO 용액에서 순환 전압전류법과 미분 펄스 전압전류법으로 세자리 Schiff base 리간드와 이들의 Ni(II) 착물들의 전기 화학적인 산화 환원 과정을 알아보았다. 세자리 Schiff base 리간드들의 전기 화학적 환원은 확산 지배적이고 비가역적으로 진행되었다. Ni(II) 착물의 전기화학적 환원과정은 1단계 1전자 반응으로 확산 지배적이고 준가역적으로 진행되었다. Ni(II) 착물들의 환원전위는 [$Ni(II)(HNIP)(H_2O)_3$]>[$Ni(II)(SIP)(H_2O)_3$]>[$Ni(II)(SIPC)(H_2O)_3$]>[$Ni(II)(HNIPC)(H_2O)_3$]순으로 양전위 방향으로 이동하였으며, 리간드의 영향은 크게 받지 않았다. 이들 결과로 부터 본 연구에서 합성한 Ni(II)착물은 [$Ni(II)(HNIPC)(H_2O)_3$] 착물이 DMSO용매에서 가장 안정함을 알 수 있다.