• Journal of Hydrogen and New Energy
• /
• v.24 no.1
• /
• pp.1-11
• /
• 2013

Additives such as glycerol, methanol, acetone, and ethanol were used to prevent $NaBO_2$ from precipitation, and their effects on hydrogen generation properties of $NaBH_4$ hydrolysis were investigated. When the concentration of additives was 5 wt%, the additives such as methanol, acetone, and ethanol could not prevent $NaBO_2$ precipitation. Although glycerol prevented $NaBO_2$ precipitation, conversion efficiency decreased to 78.0% due to its viscosity. Based on test results, hydrogen generation tests were also performed at various concentration of glycerol and methanol to investigate the concentration effects on hydrogen generation properties. As the concentration of glycerol increased from 1 wt% to 3 wt%, conversion efficiency increased owing to additive effect. When its concentration increased to 5 wt%, conversion efficiency decreased due to its viscosity. As the concentration of methanol increased from 5 wt% to 10 wt%, conversion efficiency increased owing to additive effect. When its concentration increased to 15 wt%, conversion efficiency decreased due to $NaB(OCH_3)_4$ precipitate. Although conversion efficiency decreased about 1% when 3 wt% glycerol was added, $NaBO_2$ precipitation was prevented. Consequently, addition of 3 wt% glycerol to $NaBH_4$ solution improves stability of hydrogen generation system.

• Journal of the Korean Ceramic Society
• /
• v.45 no.4
• /
• pp.214-219
• /
• 2008

The zirconia ceramics are widely used because of their excellent mechanical properties. Recently, many researches to make a colored zirconia was achieved to satisfy the individual aesthetic requirements. In this study, the synthesis of black-color spinel-based inorganic pigments which are stable above $1400^{\circ}C$ and the fabrication of black-colored zirconia using the synthesized pigments are investigated. Inorganic pigments which have spinel structure and near black color were synthesized by a solid state reaction method using a $Fe_2O_3,\;Cr_2O_3$, CoO and NiO powder as a starting materials at $1600^{\circ}C$. Most of synthesized pigments were black colored spinel phases and single spinel phase was successfully synthesized at the composition range of $Cr_2O_3:25{\sim}35%,\;Fe_2O_3:45{\sim}55%$, CoO:20% and NiO:$6{\sim}10%$. The black-colored zirconia was fabricated at $1410^{\circ}C$ with the 5 wt% synthesized pigments and their properties were evaluated. The results showed that the strength value was more than 848 MPa, absorption rate was 0.1%, the brightness of color was $L^*:40{\sim}42$, the tone of color is $a^*:0.2{\sim}0.8$ and $b^*:-1.1{\sim}2.4$. As a result, the black-colored zirconia was suitable for a artificial jewelry or decoration zirconia goods.

• Korean Journal of Materials Research
• /
• v.16 no.5
• /
• pp.329-335
• /
• 2006

In order to improve thermal efficiency of the fossil fuel power plants, we need to develop advanced materials with superior durability in the ultra-super critical state, which requires surface modifications for superior surface properties. In this study, we coated the Incoloy 901 and 12-17Cr steels for turbine buckets and valves with nitriding, boriding, and $Cr_3C_2-NiCr$ HVOF(high velocity oxygen flow) method. Then the samples were heat treated at $650^{\circ}C$ for 100 hours in vacuum. We analyzed the evolution behaviors of nitrides such as $Fe_3N,\;Fe_4N$, and CrN and borides such as FeB and $Fe_2B$ with XRD and SEM/EDS by comparing hardnesses and compositions of the coated layers before and after the heat treatments.

• The Bulletin of The Korean Astronomical Society
• /
• v.42 no.1
• /
• pp.42.3-42.3
• /
• 2017

We present the analysis of chemical abundances and kinematics for six hypervelocity star (HVS) candidates. These objects are G/K-type low-mass stars in the Galactic disk, while other HVSs previously found are B-type high-mass objects in the Galactic halo. The stellar orbits and kinematics of our HVS candidates suggest that they do not originate in the Galactic center or in an accretion event, indicative of yet-unknown mechanisms that produce kinematically-extreme disk stars. In order to study in detail their origin, we obtained medium-resolution (R~6000) spectra of these stars and derived abundances of several chemical elements (Mg, Ca, Si, Ti, Cr, Fe, and Ni). From the comparison of the chemical abundances with the Galactic stellar components (disk, bulge, halo, and dwarf galaxies) and the kinematic properties of our HVSs, we conclude that two of them are likely ejected from the Galactic disk, one originated from the Galactic center as for the young B-type HVSs, and the other one might be ejected from either the Galactic disk or other regions.

• Journal of the Korean Magnetics Society
• /
• v.10 no.1
• /
• pp.1-6
• /
• 2000

Amorphous Fe$_{79.7}$Si$_{9.3}$B$_{9.7}$Ni$_{1.4}$ ribbon alloys were fabricated by a single roll method. To enhance D. C. bias properties, the magnetic and micro-structural changes have been investigated as the variation of annealing time and condition. The D. C. bias properties were found to be directly related to micro-structural changes. Primary ${\alpha}$-Fe dendrites with 200∼300 nm showed the best D. C. bias properties, which resulted from the magnetic domain wall pinning effect. Due to the differences of cooling rate, the growth shape and distribution of the dendrites is divided into two areas.

• Microbiology and Biotechnology Letters
• /
• v.51 no.1
• /
• pp.26-31
• /
• 2023

A map gene encoding methionyl-specific aminopeptidase (MAP; EC 3.4.11.18) was cloned from Tetragenococcus halophilus CY54. Translated amino acid sequence of CY54 MAP showed high similarities with those from Enterococcus faecalis (83.8%) and Streptococcus salivarius (62.2%) but low similarities with MAPs from Lactobacillus and Lactococcus genera. The map gene was overexpressed in E. coli BL21(DE3) using pET26b(+),pET26b(+), and the recombinant MAP was purified by using an Ni-NTA column. The size of recombinant MAP was 29 kDa as determined by SDS-PAGE. The optimum pH and temperature of CY54 MAP were pH 5.0 and 60℃, respectively. The activity of CY54 MAP was most significantly increased by Co²⁺ ion (159%), and showed the highest activity at 12% NaCl. K_m and V_max were 0.64 ± 0.006 mM and 10.12 ± 0.014 U/mg protein, respectively when met-pNA was used as the substrate. This is the first report on a MAP from Tetragenococcus species.

• Journal of Microbiology
• /
• v.41 no.3
• /
• pp.189-195
• /
• 2003

To enhance the reductive dechlorination of polychlorinated biphenyls (PCBs) under anaerobic conditions, we examined the adjunctive effects of cobalt (Co) and nickel (Ni), which are the central metals of transition-metal cofactors of coenzyme F$\_$430/ and vitamin B$\_$12/, respectively, on the dechlorination of Aroclor 1248. After 32 weeks of incubation, the average numbers of chlorines per biphenyl in culture vials supplemented with 0.2, 0.5, and 1.0 mM of Co reduced from 3.88 to 3.39, 2.92, and 3.28, respectively. However, the numbers of chlorine after supplementing with Ni decreased from 3.88 to 3.43, regardless of the Ni concentrations. The observed congener distribution patterns of all vials with different conditions were similar to the pattern produced by the dechlorination process of H' after 21 weeks of incubation, and these patterns were unchanged up to week 32, except for vials supplemented with 0.5 and 1.0 mM of Co. In vials containing 0.5 mM of Co, meta-rich congeners, such as 25/ 25-,24/25-, and 25/23-chlorobiphenyls (CBPs), which were found as accumulated products of dechlorination in other conditions, were further dechlorinated, and 25/2-, 24/2-, and 2/2-CBPs were concomitantly increased after 32 weeks of incubation. In this case, the congener distribution was similar to the dechlorination pattern of process M. From these results, we suggested that the enrichment of cultures with Co might stimulate the growth of specific populations of meta-dechlorinators, and that populations might promote a change in the dechlorination process from H' to M, which is known to be less effective on the dechlorination of the more highly chlorinated congeners of PCBs.

• Journal of the Microelectronics and Packaging Society
• /
• v.18 no.3
• /
• pp.9-17
• /
• 2011

Nano-composite solders have been studied to improve the properties of Pb-free solder joints. The nanoparticles in the composite solders were carbon nanotubes(CNTs), metals (Ag, Ni, Cr, etc.), ceramics (SiC, $ZrO_2$, $TiB_2$, etc.). To fabricate the nano-composite solders, mechanical mixing methods and in-situ fabrication method has been used for well-dispersed nano phase. The characteristic properties of the nano-composite solders were high creep resistance, low undercooling, low IMC growth rate and fine microstructures. More researches on the nano-composite solders are required to improve the processibility and the reliability of the nano-composite solder joints.

• Journal of Ocean Engineering and Technology
• /
• v.5 no.1
• /
• pp.88-96
• /
• 1991

Fatigue life and retardtion behavior after through-thickness were examined experimentally by using a CT specimen and surface-cracked specimen. The material used was 3% Ni-Cr-Mo steel. The fatigue crack shape before through-thickness is almost semicircular, and the measured aspect ratio is larger than the value obtained by calculation using the K value proposed by Newman-Raju. It is found that the crack growth behavior on the back side after through-ghickness is unique and can be divided into three stages a, b and c. A retardation parameter has been used successfully to predict the growth of cracks in specimen, and in this time, retardation factor is 4.3. By using the crack propagation rule considering on retardation state and the K value proposed by the authors, the remarkable crack growth behavior and the change in crack shape can be evaluated quantitatively.

• Journal of Magnetics
• /
• v.3 no.3
• /
• pp.89-91
• /
• 1998

The magnetisation behaviour of polycrystalline permalloy/copper multilayers with mixed antiferromagnetic/ferromagnetic coupling was investigated as function of temperature. The results are discussed in a framework of a realistic model of anitferromagnetically coupled layers connected by ferromagnetic pinholes. A microstructure of pinholes (their density and dimensions) was varied either by a proper annealing treatment or by choosing samples with various Cu spacer thicknesses. It was demonstrated that the temperature changes of the net magnetic moment measured in a magnetic field smaller than the saturation field was strongly affected by the composition of the pinholes, their density, cross-sectional area and their lengths.