• Title/Summary/Keyword: New constituents

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Application of Fluorescence Excitation Emission Matrices for Diagnosis and Source Identification of Watershed Pollution : A Review (유기물 형광분석법을 활용한 유역 오염 진단 및 오염원 추적: 문헌 연구)

  • Kandaddara Badalge Nipuni Dineesha;Jin Hur;Byung Joon Lee
    • Journal of Korean Society on Water Environment
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    • v.39 no.1
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    • pp.87-101
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    • 2023
  • The constituents of a watershed control a wide range of ecosystem processes, such as, carbon sequestration, nutrient retention, and biodiversity preservation. Maintenance of a healthy watershed is advantageous to humans in many direct and indirect ways. Dissolved organic matter fluorescence analysis is one of the most commonly utilized parameters for water quality measurement, pollution source tracking, and determination of the ecological state of a watershed. Throughout the recent decades, the advancement in data processing, instrumentation, and methods has resulted in many improvements in the area of watershed study with fluorescence analysis. The current trend of coupling advanced instrumentations and new comparative parameters, such as, microplastics of different types, antibiotics, and specific bacterial contaminants have been reported in watershed studies. However, conventional methodologies for obtaining fluorescence excitation emission matrices and for calculating the fluorescence and spectral indices are preferred to advanced methods, due to their easiness and simple data collection. This review aims to gain a general understanding of the use of dissolved organic matter fluorescence analysis for diagnosis and source identification of watershed pollutions, by focusing on how the studies have utilized fluorescence analysis to improve existing knowledge and techniques in recent years.

Near-infrared polarimetric study of near-Earth object 252P/LINEAR: An implication of scattered light from the evolved dust particles

  • Kwon, Yuna G.;Ishiguro, Masateru;Kwon, Jungmi;Kuroda, Daisuke;Im, Myungshin;Choi, Changsu;Tamura, Motohide;Nagayama, Takahiro;Kawai, Nobuyuki;Watanabe, Jun-Ichi
    • The Bulletin of The Korean Astronomical Society
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    • v.44 no.2
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    • pp.44.2-44.2
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    • 2019
  • Comets, one of the least-altered leftovers from the nascent solar system, have probably preserved the primitive structure inside, whereas their surfaces become modified from the initial states after repetitive orbital revolutions around the Sun. Resurfacing makes the surface drier and more consolidated than the bulk nuclei, creating inert refractory dust layer ("dust mantle"). Near-infrared (NIR; 1.25-2.25 m) polarimetry is theoretically expected to maximize contrast of the porosity between inner fresh and evolved dust particles, by harboring more dust constituents in the single wavelength than the optical; thus, intensifies electromagnetic interaction in dust aggregates. Despite such an advantage, only a few studies have been made in this approach mainly due to the limited accessibility of available facilities. Herein, we present our new multi-band NIR polarimetric study of near-Earth object 252P/LINEAR over 12 days near perihelion, together with the results of optical (0.48-0.80m) imaging observations and backward dynamical simulation of the comet. Based on the results, we will characterize the dust properties of the comet and discuss the possible environmental (temperature and UV radiation) effects that could produce the observed phenomena.

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Islamic Radicalism in Indonesia: Historical Development, Ideology and Praxis (인도네시아의 이슬람 급진주의: 역사적 전개과정과 이념적·실천적 특성)

  • Kim, Hyung-Jun
    • The Southeast Asian review
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    • v.19 no.2
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    • pp.57-91
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    • 2009
  • The purpose of this paper is to examine historical development, ideology and praxis of Islamic radicalism in Indonesia. In the second part of this paper, radical trends under Sukarno and Suharto governments will be dealt with, focusing on three streams of Darul Islam, Dewan Dakwah Islamiyah Indonesia and Islamic secret sects. The third part investigates the surge of radical Islamic movements after the fall of Suharto regime. For this, three organizations are again selected for detailed analysis. This paper argues that, judging from active engagements of radical organizations in national and international affairs and favorable attitude of general Muslims toward them, radicalism has recently established itself as one of the major constituents of Indonesian Islam. To put it differently, the current situation signifies that under the Suharto regime, a diversification of so-called the santri has been underway. Contrary to the traditional santri group which emphasizes the fulfillment of faith in the private sphere, another group has been crystallized, which gives priority to Islamic roles in public sphere and attempts to realize these. It is difficult to pinpoint the reasons why this group has emerged. Its effect, however, can relatively easily be grasped. With the surge of this new radical stream, the rhetoric of an establishment of Islamic state and a realization of Islamic law has no longer been tabooed and has been instated as the key element in public discourse of Islam.

The Unfulfilled Journey of a Flâneur: Reading "The Man of the Crowd" through the Eyes of the City (미완의 만보자 -도시의 시선으로 『군중의 남자』 읽기)

  • Nam, Soo-Young
    • Journal of English Language & Literature
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    • v.56 no.4
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    • pp.617-635
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    • 2010
  • This paper argues that what Edgar Allan Poe pursues in ;The Man of the Crowd" (1840) is not a story that can be told but an active reading that must be mediated. It is not only because the subject of the pursuit, the secret of the flaneur, remains veiled until the end, but also because the story proves itself to be a reading of various kinds of other texts: that is, the contemporary urban texts as well as the city itself. Although the 'man of the crowd' and his double (i.e. the narrator) embrace the figure of a modern flaneur, it is highly questionable whether the image of flaneur in the story fully qualifies itself as that of an ideal stroller, who can represent the free spirit of a detached collector. Rather, the narrator's flaneur reflects a panoptic perspective, systematically hierarchizing the constituents of the city. Still, it should be noted that ;The Man of the Crowd" raises questions about the idea of creation and appropriation, observation and originality, and reading and storytelling by ascertaining the impossibility of reading and through assimilating to the contemporary texts not without subtle acknowledgement. In short, this novella tries a new way of storytelling, of which meaning is not to be found in creation but to be mediated in modern experiences.

Phytochemical Identification of Bioactive Constituents of Dendrobii herba (생약석곡(Dendrobii herba)의 생리활성 성분 규명)

  • Bomi Nam
    • Proceedings of the Plant Resources Society of Korea Conference
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    • 2023.04a
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    • pp.18-18
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    • 2023
  • Two new phenanthrenes, namely, (1R,2R)-1,7-hydroxy-2,8-methoxy-2,3-dihydrophenanthrene-4(1H)-one (1) and 2,7-dihydroxyphenanthrene-1,4-dione (2), were isolated from the ethyl acetate-soluble fraction of Dendrobii Herba, together with the eleven known compounds, densiflorol B (3), 6,7-dimethoxyphenanthrene2,5-diol (4), dehydroorchinol (5), 1,5,7-trimethoxy-2-phenanthrenol (6), denthyrsinin (7), ephemerantol A (8), lusianthridin (9), moscatilin (10), gigantol (11), 3-[(1E)-2-(3-hydroxyphenyl)ethenyl]-5-methoxyphenol (12) and (-)-syringaresinol (13). Structures of 1 and 2 were elucidated by analyzing 1D and 2D NMR as well as HR-ESI-MS data. The absolute configuration of compound 1 was confirmed by ECD spectroscopic method. In cytotoxicity evaluation using FaDu human hypopharyngeal squamous carcinoma cell line, compounds 3-6, 8, 10 and 12 showed activities, with IC50 values ranging from 2.55 to 17.70 μM. Among them, compound 10 exhibited remarkable cytotoxic activity with IC50 value of 2.55 μM. This is the first report on the anticancer mechanistic study of compound 10 in HNSCC including FaDu cells.

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Biosynthesis of rare 20(R)-protopanaxadiol/protopanaxatriol type ginsenosides through Escherichia coli engineered with uridine diphosphate glycosyltransferase genes

  • Yu, Lu;Chen, Yuan;Shi, Jie;Wang, Rufeng;Yang, Yingbo;Yang, Li;Zhao, Shujuan;Wang, Zhengtao
    • Journal of Ginseng Research
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    • v.43 no.1
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    • pp.116-124
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    • 2019
  • Background: Ginsenosides are known as the principal pharmacological active constituents in Panax medicinal plants such as Asian ginseng, American ginseng, and Notoginseng. Some ginsenosides, especially the 20(R) isomers, are found in trace amounts in natural sources and are difficult to chemically synthesize. The present study provides an approach to produce such trace ginsenosides applying biotransformation through Escherichia coli modified with relevant genes. Methods: Seven uridine diphosphate glycosyltransferase (UGT) genes originating from Panax notoginseng, Medicago sativa, and Bacillus subtilis were synthesized or cloned and constructed into pETM6, an ePathBrick vector, which were then introduced into E. coli BL21star (DE3) separately. 20(R)-Protopanaxadiol (PPD), 20(R)-protopanaxatriol (PPT), and 20(R)-type ginsenosides were used as substrates for biotransformation with recombinant E. coli modified with those UGT genes. Results: E. coli engineered with $GT95^{syn}$ selectively transfers a glucose moiety to the C20 hydroxyl of 20(R)-PPD and 20(R)-PPT to produce 20(R)-CK and 20(R)-F1, respectively. GTK1- and GTC1-modified E. coli glycosylated the C3-OH of 20(R)-PPD to form 20(R)-Rh2. Moreover, E. coli containing $p2GT95^{syn}K1$, a recreated two-step glycosylation pathway via the ePathBrich, implemented the successive glycosylation at C20-OH and C3-OH of 20(R)-PPD and yielded 20(R)-F2 in the biotransformation broth. Conclusion: This study demonstrates that rare 20(R)-ginsenosides can be produced through E. coli engineered with UTG genes.

Phytochemical analysis of Panax species: a review

  • Yang, Yuangui;Ju, Zhengcai;Yang, Yingbo;Zhang, Yanhai;Yang, Li;Wang, Zhengtao
    • Journal of Ginseng Research
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    • v.45 no.1
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    • pp.1-21
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    • 2021
  • Panax species have gained numerous attentions because of their various biological effects on cardiovascular, kidney, reproductive diseases known for a long time. Recently, advanced analytical methods including thin layer chromatography, high-performance thin layer chromatography, gas chromatography, high-performance liquid chromatography, ultra-high performance liquid chromatography with tandem ultraviolet, diode array detector, evaporative light scattering detector, and mass detector, two-dimensional high-performance liquid chromatography, high speed counter-current chromatography, high speed centrifugal partition chromatography, micellar electrokinetic chromatography, high-performance anion-exchange chromatography, ambient ionization mass spectrometry, molecularly imprinted polymer, enzyme immunoassay, 1H-NMR, and infrared spectroscopy have been used to identify and evaluate chemical constituents in Panax species. Moreover, Soxhlet extraction, heat reflux extraction, ultrasonic extraction, solid phase extraction, microwave-assisted extraction, pressurized liquid extraction, enzyme-assisted extraction, acceleration solvent extraction, matrix solid phase dispersion extraction, and pulsed electric field are discussed. In this review, a total of 219 articles published from 1980 to 2018 are investigated. Panax species including P. notoginseng, P. quinquefolius, sand P. ginseng in the raw and processed forms from different parts, geographical origins, and growing times are studied. Furthermore, the potential biomarkers are screened through the previous articles. It is expected that the review can provide a fundamental for further studies.

A new innovative 3-unknowns HSDT for buckling and free vibration of exponentially graded sandwich plates resting on elastic foundations under various boundary conditions

  • Rabhi, Mohamed;Benrahou, Kouider Halim;Kaci, Abdelhakim;Houari, Mohammed Sid Ahmed;Bourada, Fouad;Bousahla, Abdelmoumen Anis;Tounsi, Abdeldjebbar;Adda Bedia, E.A.;Mahmoud, S.R.;Tounsi, Abdelouahed
    • Geomechanics and Engineering
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    • v.22 no.2
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    • pp.119-132
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    • 2020
  • In this study a new innovative three unknowns trigonometric shear deformation theory is proposed for the buckling and vibration responses of exponentially graded sandwich plates resting on elastic mediums under various boundary conditions. The key feature of this theoretical formulation is that, in addition to considering shear deformation effect, it has only three unknowns in the displacement field as in the case of the classical plate theory (CPT), contrary to five as in the first shear deformation theory (FSDT) and higher-order shear deformation theory (HSDT). Material characteristics of the sandwich plate faces are considered to vary within the thickness direction via an exponential law distribution as a function of the volume fractions of the constituents. Equations of motion are obtained by employing Hamilton's principle. Numerical results for buckling and free vibration analysis of exponentially graded sandwich plates under various boundary conditions are obtained and discussed. Verification studies confirmed that the present three -unknown shear deformation theory is comparable with higher-order shear deformation theories which contain a greater number of unknowns.

Effects of NOx and SOx on the Medium pH and microalgal growth in photo-culture system (광배양 시스템에서 NOx 및 SOx의 배지 pH와 미세조류 생장에 미치는 영향)

  • Yoon, Se Young;Hong, Min Eui;Sim, Sang Jun
    • Transactions of the Korean hydrogen and new energy society
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    • v.24 no.3
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    • pp.255-263
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    • 2013
  • Carbon dioxide reduction technologies using photosynthetic microorganism were suggested to overcome environmental destruction caused by $CO_2$ in flue gases from power plant and other industries. However, there are many toxic constituents in flue gas including CO, NOx, SOx. Continuous and Excessive supply of these noxious gases to cells will leads to inhibition of microalgal growth along with partial cell death. In this study, we tested the noxious effect of SOx and NOx on the pH and microalgal growth under photoautotrophic culture in three microalgae of Neochloris oleoabundans, Chlorella vulgaris and Haematococcus pluvialis. As a result, SOx concentration more than 50 ppm led to the rapid reduction of pH, thereby inhibiting of the growth in Neochloris oleoabundans and Chlorella vulgaris. NOx concentration more the 100 ppm reduced the exponential growth of N. oleoabundans and C. vulgaris. And H. pluvialis exhibited low sensitivity to SOx and NOx. Consequently, the three microalgae of N. oleabundas, C. vulagaris and H. pluvialis showed the normal vegetative growth in 25 ppm of NOx and SOx. Above all, H. pluvialis was useful for the $CO_2$ sequestration of the flue gas including high concentrations of NOx and SOx.

A Review Study of Researches on Jakyakgamcho-tang (작약감초탕(芍藥甘草湯)의 연구동향(硏究動向) 분석(分析))

  • Shin, Young Sub;Lee, Soong In
    • Herbal Formula Science
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    • v.25 no.2
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    • pp.271-302
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    • 2017
  • Objectives : Jakyakgamcho-tang has been used to treat muscular tension, spasm and pain. On this study, new clinical uses of Jakyakgamcho-tang were confirmed and the other pharmacological results were summarized by analysing trends of modern experimental studies and clinical studies. Methods : Papers related to Jakyakgamcho-tang were searched on PUBMED, RISS, and National Assembly Library, and classified by categories and effects of clinical application and a variety of experiment around abstract. Also, figures were used for sketching out a timeline of expressing when these papers were read and core research content was described as a digest for identifying research trends. Results : Until today, there are 104 researches about the antispasmodic, analgesic, anti-inflammatory effects of Jakyakgamcho-tang. In total, 91 papers were analyzed in this study. In matter of subject, researches on the antispasmodic effects were 17 cases, researches on the analgesic effects were 14 cases, researches on gynecological therapeutics were 14 cases, researches on pharmacokinetics were 12 cases, researches on the constituent identification were 7 cases, studies about constituents efficacy were 6 cases, studies about interactions with drugs were 6 cases. Conclusion : The traditional use of Jakyakgamcho-tang on muscle tension, spasm and pain has proven to have effects through the experimental evidences. Other effects of Jakyakgamcho-tang such as gynecological therapeutics, anti-inflammatory effects, are now emerging as a new area in clinical use. Futhermore as an auxiliary treatment, Jakyakgamcho-tang is a good alternative for muscle cramps during maintenance of hemodialysis, myalgia or arthralgia induced by anticancer drugs, amenorrhea induced by neuroleptics.