• Title/Summary/Keyword: Neutralization characteristics

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Seasonal Composition Characteristics of TSP and PM2.5 Aerosols at Gosan Site of Jeju Island, Korea during 2008-2011

  • Kim, Won-Hyung;Hwang, Eun-Yeong;Ko, Hee-Jung;Kang, Chang-Hee
    • Asian Journal of Atmospheric Environment
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    • v.7 no.4
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    • pp.217-226
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    • 2013
  • The collection of TSP and $PM_{2.5}$ aerosols has been made at the Gosan Site of Jeju Island during 2008-2011, and their ionic and elemental species were analyzed, in order to examine the seasonal variation and characteristics of aerosol compositions. The anthropogenic components ($NH_4{^+}$, $nss-SO_4{^{2-}}$, $NO_3{^-}$, S, Zn, Pb) and the soil components ($nss-Ca^{2+}$, Al, Fe, Ca) showed high concentrations in spring as the prevailing westerly wind, but the concentrations of the sea-salt components ($Na^+$, $Cl^-$) were high in winter. In TSP, the neutralization by $NH_3$ increased in summer, but the neutralization by $CaCO_3$ increased in spring and fall seasons. The organic acids ($HCOO^-$, $CH_3COO^-$) contributed to the acidification of the aerosols by only 5.0%, so the acidification could be mostly contributed by the inorganic acids ($SO_4{^{2-}}$, $NO_3{^-}$). From the examination of the source origins by factor analysis, the compositions of TSP were influenced by the order of soil > anthropogenic > marine, on the other hand, those of $PM_{2.5}$ were by the order of anthropogenic > marine > soil. The backward trajectory analyses showed that the concentrations of $NH_4{^+}$, $nss-SO_4{^{2-}}$, $NO_3{^-}$ and $nss-Ca^{2+}$ increased highly when the air masses had moved from China continent into Gosan area of Jeju Island.

Comparison of Flocculation Characteristics of Humic Acid by Inorganic and Organic Coagulants: Effects of pH and Ionic Strength

  • Xu Mei-Lan;Lee Min-Gyu;Kam Sang-Kyu
    • Journal of Environmental Science International
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    • v.14 no.8
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    • pp.723-737
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    • 2005
  • The effects of pH (5, 7 and 9) and ionic strength of different salts on the flocculation characteristics of humic acid by inorganic (alum, polyaluminum chloride (PAC) with degree of neutralization, r=(OH/Al) of 1.7) and organic (cationic polyelectrolyte) coagulants, have been examined using a simple continuous optical technique, coupled with measurements of zeta potential. The results are compared mainly by the mechanisms of its destabilization and subsequent removal. The destabilization and subsequent removal of humic acid by PAC and cationic polyelectrolyte occur by a simple charge neutralization, regardless of pH of the solution. However, the mechanism of those by alum is greatly dependent on pH and coagulant dosage, i.e., both mechanisms of charge neutralization at lower dosages and sweep flocculation at higher dosages at pH 5, by sweep flocculation mechanism at pH 7, and little flocculation because of electrostatic repulsion between negatively charged humic acid and aluminum species at pH 9. The ionic strength also affects those greatly, mainly based on the charge of salts, and so is more evident for the salts of highly charged cationic species, such as $CaCl_2$ and $MgCI_2.$ However, it is found that the salts have no effect on those at the optimum dosage for alum acting by the mechanism of sweep flocculation at pH 7, regardless of their charge.

Comparison of Titration Curve Estimation Methods for pH Neutralization Processes

  • Park, Ho-Cheol;Lee, Jie-Tae
    • 제어로봇시스템학회:학술대회논문집
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    • 2001.10a
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    • pp.124.1-124
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    • 2001
  • Control of pH neutralization process plays a very important role in some chemical process. Because of their high nonlinearity, frequent disturbance, and time-varying characteristics, it is difficult to control and estimate pH processes. For the adaptive control of pH processes, a lot of researchers have made an efforts in the modeling and control of pH processes. It is very difficult to obtain information of influent stream such as concentrations and dissociation constants and the titration curve equation is very complex. Therefore, several simple models, which hate small number of unknown parameters and estimate the titration curve, have been available, These models were considered here and were transformed into forms that can applied the linear least square method.

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Chemical Resistance Characteristics of Concrete Surface Coating Agent with Flexibility (유연성을 갖는 콘크리트 표면보호재의 내화학적 특성)

  • Han, Sang-Hoon;Yoon, Ju-Yong;Lee, Byung-Ro;Hong, Ki-Nam
    • Journal of the Korean Society of Safety
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    • v.27 no.3
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    • pp.96-103
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    • 2012
  • The purpose of this study is evaluate the ability of coating materials developed in order to prevent the durability deterioration of the concrete structure. Neutralization test, freezing and thawing test, and sulfate resistance test were performed in this study. Test results show that the developed coating material is effective against durability deterioration.

Neutralization and Ionization of movable ion at insulator-metal interface (절연체-금속계면에서 가동이온의 중성화와 이온화)

  • 이성길;국상훈
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1988.10a
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    • pp.33-35
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    • 1988
  • From the study of mechanism of electrical conduction of film which is made from Polyethylene Terephthalate at very high temperature which is larger than low electric field and glass transition point, we find that there is a extraordinary non ohmic region (I∝V$^n$, 0

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A Study of De-electrification Characteristics of Charged Body By Soft X-Ray Ionizer (연X선 Ionizer에 의한 대전물체의 제전특성에 관한 연구)

  • 이동훈
    • Journal of the Korean Society of Safety
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    • v.13 no.3
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    • pp.67-73
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    • 1998
  • The technology for neutralizing static electricity by soft X-ray radiation has been newly developed. This technology involves ionization of gas molecules in the vicinity of a charged substrate to generate ions and electrons to reduce electrostatic potential. The ULSI device substrate and liquid crystal display substrate tend to get charged instantly to a high potential level when they are handled in the manufacturing process. Soft X-ray radiation is adequate in air or $O_2$ gas at atmospheric pressure. This newly developed neutralization method is effective to be superior to the conventional technique, i.e., an ionizer by using corona discharge ,in every aspect. The new method features excellent neutralization capability and is able to completely reduce electrostatic potential to 0 V within a short time. Moreover, this is a very clean antistatic technology free from particle generation ,ozone generation, and electromagnetic noise, which are problems in using the corona discharge ionizer.

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Properties of Cement Paste by the Addition of Liquefied Red Mud (중화 액상화 레드머드의 첨가량에 따른 시멘트 페이스트의 특성)

  • Lee, Hee-Ra;Kang, Hye-Ju;Lee, Yeong-Hun;Kang, Suk-Pyo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.11a
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    • pp.23-24
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    • 2019
  • In this paper, the compressive strength characteristics of cement paste were compared with the addition of liquefied red mud with the addition of nitric acid in order to improve the strength of the deteriorated cement. The results showed that the compressive strength with between 7 days and 28 days was greater than that of liquefied red mud. The ratio of daily compressive strength of the liquefied red mud is higher than that of the Plain with a 1 percent addition rate, and the ratio of compressive strength is lower than that of the Plain on the 28 days. Therefore, the compressive strength of neutralization liquefied red mud compared to liquidated red mud was relatively high, and the compressive strength of the red mud was shown to be improved to a level almost similar to that of Plain.

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Hydration Characteristics of Cement Paste Added Liquid and Neutralized Red Mud (액상 및 중화 레드머드를 첨가한 시멘트 페이스트의 수화특성)

  • Kang, Hye Ju;Kang, Suk Pyo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.11a
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    • pp.104-105
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    • 2020
  • Red mud is a highly alkaline waste by-product of the aluminum industry. Although recycling of red mud is being actively researched, a feasible technological solution has not been found yet. In this study, we propose that neutralization of red mud alkalinity could assist in its use as a construction material. Neutralized red mud ( pH 6-8) was prepared by adding sulfuric acid to liquefied red mud (pH 10-12). After adding liquid and neutralized red mud to the cement paste, the heat of hydration was measured. As a result of the experiment, the calorific value of the cement paste with liquid red mud was lowered and delayed compared to the cement paste with neutralized red mud.

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Initial Strength Characteristics of Cement Paste Added with Nitric Acid Neutralized Red Mud (질산 중화 레드머드를 첨가한 시멘트 페이스트의 초기강도 특성)

  • Kang, Hye Ju;Kang, Suk Pyo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.05a
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    • pp.70-71
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    • 2021
  • An increasing amount of red mud (RM) is being generated globally with the growth in alumi-num production. To avoid the RM becoming a pollutant, methods for effectively recycling RM at a low cost are being investigated. This study proposes a method for recycling RM as a construc-tion material. The cement paste with neutralized liquefied red mud had higher compressive strength than that of plain cement paste and cement paste with liquefied red mud without neutralization at 1 d of aging; this indicates that nitric acid neu-tralization increases the early-age strength.

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Vegetation and Water Purification Characteristics of Lapilli-Bio Block (화산력-바이오 블록의 식생 및 수질정화 특성)

  • Park, Sungyong;Nam, Boohyun;Kim, Jungmeyon;Choi, KiBong;Yeon, Kyuseok;Kim, Yongseong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.58 no.6
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    • pp.47-54
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    • 2016
  • This study is a basic research on the functional performance review for the use of environmentally friendly construction materials as lapilli-bio block. The neutralization processed Mt. Backdusan and Mt. Hallasan lapilli-bio block were identified vegetation characteristics and water purification properties. As a result, the adsorption of root was more favorable, depending on the material properties of many voids Lapilli. And if the neutralization processed lapilli-bio blocks maintain a long-term immersion conditions in contaminated water was found to be expected from the improvement effect of SS, T-N and T-P. However, field trials and continuous studies are expected to be identified by the use of lapilli-bio block.