• Title/Summary/Keyword: Negatively charged

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Electrical and Rheological Properties of Colloidal of Alumina Suspensions

  • Wang, Xu-Hong;Yoshihiro Hirata
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 2000.06a
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    • pp.215-232
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    • 2000
  • The Valence(Z) of positively and negatively charged alumina particles in the dilute suspensions was analyzed with the electrical conductivity of the suspensions. The mobility of negative particles was lower than that of positive particles at a similar Z value because of the stronger effect of chemical bonding over the hydrated particle surfaces. The apparent viscosity of acidic suspensions of 1-40 vol % solid was lower than that of basic suspensions. This result was discussed based on the three important effects of the valence, concentration and nature of hydrated surface of alumina particles. The density of alumina compacts consolidated by filtration through gypsum molds became lower for the basic suspensions than for the acidic suspensions. This result was correlated to the properties of the colloidal alumina suspensions.

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The Charge decay characteristics of Polymer surface by Corona discharge (코로나 하전한 고분자의 표면전하감쇄)

  • Lee, B.S.;Kim, Y.B.;Park, J.K.;Kim, J.S.;Lee, J.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 1995.07c
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    • pp.1156-1158
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    • 1995
  • Charge decay, thermally stimulated current(TSC), charging and discharging currents(I) are measured for negatively corona-charged polymers. In this study, we will make an experiment in charge decay on polymer surface, TSC, polarity effect and the others in order to analysis it's mechanism. Especially polyvinylidene fluoride(PVDF) film is the best functional material which has been so far. Therefore, It's worthy of notice to investigate it's characteristic. And then some other functional polymers will be focused on. An experimental result was missed out for the shortage of setting. So, this thesis will be explained on the theory and direction of reseach hereafter.

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A Thermogravimetric Study of the Non-stoichiometry of Iron-Doped Nicked Oxide$(Ni_{1-x}Fe_x)1-{\delta}$O

  • Krafft, Kunt N.;Martin, Manfred
    • The Korean Journal of Ceramics
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    • v.4 no.2
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    • pp.156-161
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    • 1998
  • We have measured changes of the non-stoichiometry, $\Delta\delta$, in Fe-doped nicked oxide , by thermogravimetry for four iron fractions, x=0.01, 0.031, 0.057 and 0.10, and three temperatures, T=1273, 1373 and 1473 K. The obtained data can be modelled by a defect structure in which substitutional trivalent iron ions, FeNi, are compensated by cation vacancies, $V_{Ni}$", and (4:1)-clusters. These clusters consist of tetravalent interstitial iron, $Fe_i\;^4$

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Neuraminidase Treatment Enhances Allogeneic Stimulation of Unprimed $CD8^+$ T Cells

  • Kim, Kil-Hyoun
    • BMB Reports
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    • v.30 no.6
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    • pp.385-389
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    • 1997
  • Many cell types are known to stimulate $CD8^+$ T cells in allogeneic recognition such as mixed lymphocyte reaction (MLR). Whereas dendritic cells are most potent among them. T cells are usually considered very poor in stimulating $CD8^+$ T cells although there are some tumor cells that are weakly stimulatory. T cells, as a stimulator, cultured in the presence of concanavalin A that were otherwise nonstimulatory to $CD8^+$ T cells appeared to stimulate $CD8^+$ T cells strongly when they were pretreated with neuraminidase. The enhancement of MLR by neuraminidase could be achieved by treating either the stimulators or responders with neuraminidase. Removal of negatively-charged sialic acid moieties from the cell surface, which reduced electrostatic repulsion between responders and stimulators to give better cell-cell contact might be responsible for the enhanced MLR. In addition, neuraminidase treatment also appeared to deliver activation signal to responding T cells since it could activate $CD8^+$ T cells in synergy with phorbol myristate acetate. The maximal responses were observed when both responders and stimulators were treated with neuraminidase.

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Interactions of Lysozyme with Phospholipid Liposmes

  • Jung, Kyoung-Ok;Kim, Mi-Young;Jeong, In-Cheol;Kim, Andre;Kim, Do-Hui;Kang, Shin-Won;Park, Jang-Su
    • Journal of Photoscience
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    • v.7 no.2
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    • pp.63-66
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    • 2000
  • A study of the interaction between lysozyme and phospholipid liposomes is essential for a systematic approach for understanding the action mechanism of lysozyme. So we want to clarify the interactions of lysozyme with phospholipid liposmes. We observed that lysozyme more interacts with negatively charged liposomes than with neutral liposome. More hydroxy groups of the phospholipid was very important on that interactions. We recognized the importance of electrostatic interactions in the process of fusion induced by lysozyme. As indicated by UV/Vis experiments, leakage and fusion are two uncoupled process.

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Development of Polymeric Adsorbents for the Treatment of Colored Waste Waters and Re-use of the Treated Water (II) - Quaternary Aminized Cellulosic Adsorbent - (유색폐수처리를 위한 고분자 흡착제의 개발과 처리수의 사용(II) - 4급 아민화 셀룰로오스 흡착제 -)

  • Soo-Min Park;Woo-Kyung Sung
    • Textile Coloration and Finishing
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    • v.4 no.3
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    • pp.131-135
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    • 1992
  • Quaternary aminized cellulosic adsorbents (C $A_{QA}$ ) which exhibit adsorption capacities for anionic dyestuffs for the treatment of colored waste water and re-use of the treated water were studied. The isotherms and thermodynamic parameters of C.I. Acid Orange 7, solution considered as a model of negatively charged coloring matters for C $A_{QA}$ , were determined. Batch method and flow method were employed to determine decoloring capacity of cellulosic adsorbents for Orange 7. The cellulosic adsorbents exhibited much better adsorption capacity than activated carbon. Furthermore the exhausted cellulosic adsorbents could be readily regenerated by washing with dilute sodium hydroxide.

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Efficiency of methyl-esterified eggshell membrane biomaterials for intensified microalgae harvesting

  • Choi, Hee-Jeong
    • Environmental Engineering Research
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    • v.22 no.4
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    • pp.356-362
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    • 2017
  • This study investigates the use of methyl-esterified eggshell membranes (MESM) for the harvesting of microalgae species under various conditions. Eggshell membranes were esterified with HCl to impact polycationic characteristics. After methyl esterification, the negative surface charge property of eggshell membrane was changed from negative to positive for all pH values to improve microalgae sorption capacity. The harvesting efficiency of microalgae by MESM reached 78-99% for all pH ranges evaluated. In addition, a 150 mesh particle size and $10mg\;L^{-1}$ MESM dose were found to yield up to 98% microalgae harvesting. These results indicate that the high cationic charge of MESM strongly adsorbs the negatively-charged microalgae. MESM is biocompatible and can be applied to the harvest of microalgae.

Thermodynamics of Partitioning of Substance P in Isotropic Acidic Bicelles

  • Baek, Seung Bin;Lee, Hyeong Ju;Lee, Hee Cheon;Kim, Chul
    • Bulletin of the Korean Chemical Society
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    • v.34 no.3
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    • pp.743-748
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    • 2013
  • The temperature dependence of the partition coefficients of a neuropeptide, substance P (SP), in isotropic acidic bicelles was investigated by using a pulsed field gradient nuclear magnetic resonance diffusion technique. The addition of negatively charged dimyristoylphosphatidylserine to the neutral bicelle changed the SP partitioning a little, which implies that the hydrophobic interaction between the hydrophobic residues of SP and the acyl chains of lipid molecules is the major interaction while the electrostatic interaction is minor in SP binding in a lipid membrane. From the temperature dependence of the partition coefficients, thermodynamic functions were calculated. The partitioning of SP into the acidic bicelles is enthalpy-driven, as it is for small unilamellar vesicles and dodecylphosphocholine micelles, while peptide partitioning into a large unilamellar vesicle is entropy-driven. This may mean that the size of lipid membranes is a more important factor for peptide binding than the surface curvature and surface charge density.

Interactions of Phospholipid Liposomes and Bovine Lactoferrin (Phospholipid Liposomes과 Bovine Lactoferrin의 상호작용)

  • Kim, Mi-Young;Kang, Shin-Won;Park, Jang-Su;Nam, Myoung-Soo
    • Korean Journal of Agricultural Science
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    • v.37 no.3
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    • pp.543-545
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    • 2010
  • Apo, holo, native-type of lactoferrin showed a similar pattern of circular dichroism(CD) spectra. Lactoferrin appeared to interact more easily with negatively charged liposome than neutral liposome. Holo-type of lactoferrin showed the highest degree of leakage, whereas apo-type of lactoferrin showed the lowest level of leakage. Holo-type lactoferrin could more easily interact with phospholipid liposomes than apo-type lactoferrin, when used as an artificial membrane.

Electroless Deposition and Surface-Enhanced Raman Scattering Application of Palladium Thin Films on Glass Substrates

  • Shin, Kuan Soo;Cho, Young Kwan;Kim, Kyung Lock;Kim, Kwan
    • Bulletin of the Korean Chemical Society
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    • v.35 no.3
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    • pp.743-748
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    • 2014
  • In this work, we describe a very simple electroless deposition method to prepare moderate-SERS-active nanostructured Pd films deposited on the glass substrates. To the best of our knowledge, this is the first report on the one-pot electroless method to deposit Pd nanostructures on the glass substrates. This method only requires the incubation of negatively charged glass substrates in ethanol-water mixture solutions of $Pd(NO_3)_2$ and butylamine at elevated temperatures. Pd films are then formed exclusively and evenly on glass substrates. Due to the aggregated structures of Pd, the SERS spectra of benzenethiol and organic isonitrile could be clearly identified using the Pd-coated glass as a SERS substrate. This one-step fabrication method of Pd thin film on glass is cost-effective and suitable for the mass production.