• 제목/요약/키워드: Negative temperature coefficient

검색결과 245건 처리시간 0.028초

Investigation of Autoignition of Propane and n-Butane Blends Using a Rapid Compression Machine

  • Kim, Hyunguk;Yongseob Lim;Kyoungdoug Min;Lee, Daeyup
    • Journal of Mechanical Science and Technology
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    • 제16권8호
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    • pp.1127-1134
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    • 2002
  • The effects of pressure and temperature on the autoignition of propane and n-butane blends were investigated using a rapid compression machine (RCM) , which is widely used to examine the autoignition characteristics. The RCM was designed to be capable of varying the compression ratio between 5 and 20 and minimize the vortex formation on the cylinder wall using a wedge-shaped crevice. The initial temperature and pressure of the compressed gas were varied in range of 720∼900 K and 1.6∼ 1.8 MPa, respectively, by adjusting the ratio of the specific heat of the mixture by altering the ratio of the non-reactive components (N$_2$, Ar) under a constant effective equivalence ratio (ø$\_$f/= 1.0) The gas temperature after the compression stroke could be obtained from the measured time-pressure record. The results showed a two-stage ignition delay and a Negative Temperature Coefficient (NTC) behavior which were the unique characteristic of the alkane series fuels. As the propane concentration in the blend were increased from 20% and 40% propane, the autoignition delay time increased by approximately 41 % and 55% at 750 K. Numerical reduced kinetic modeling was performed using the Shell model, which introduced some important chemical ideas, represented by the generic species. Several rate coefficients were calibrated based on the experimental results to establish an autoignition model of the propane and n-butane blends. These coefficients can be used to predict the autoignition characteristics in LPG fueled Sl engines.

Polymorphic Phase Transition and Temperature Coefficient of Capacitance of Alkaline Niobate Based Ceramics

  • Bae, Seon-Gi;Shin, Hyea-Gyiung;Sohn, Eun-Young;Im, In-Ho
    • Transactions on Electrical and Electronic Materials
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    • 제14권2호
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    • pp.78-81
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    • 2013
  • $0.95(Na_{0.5}K_{0.5})NbO_3-0.05BaTiO_3+0.2wt%\;Ag_2O$ (hereafter, No excess NKN) ceramics and $0.95(Na_{0.5}K_{0.5})NbO_3-0.05BaTiO_3+0.2wt%\;Ag_2O$ with excess $(Na_{0.5}K_{0.5})NbO_3$ (hereafter, Excess NKN) were fabricated by the conventional solid state sintering method, and their phase transition properties and dielectric properties were investigated. The crystalline structure of No excess NKN ceramics and Excess NKN ceramics were shown characteristics of polymorphic phase transition (hereafter, PPT), especially shift from the orthorhombic to tetragonal phase by increasing sintering temperature range from $1,100^{\circ}C$ to $1,200^{\circ}C$. Also, the temperature coefficient of capacitance (hereafter, TCC) of No excess NKN ceramics and Excess NKN ceramics from $-40^{\circ}C$ to $100^{\circ}C$ was measured to evaluate temperature stability for applications in cold regions. The TCC of No excess NKN and Excess NKN ceramics showed positive TCC characteristics at a temperature range from $-40^{\circ}C$ to $100^{\circ}C$. Especially, Excess NKN showed a smaller TCC gradient than those of Excess NKN ceramics in range from $-40^{\circ}C$ to $100^{\circ}C$. Therefore, NKN piezoelectric ceramics combined with temperature compensated capacitor having negative temperature characteristics is desired for usage in cold regions.

더미스터 온도센서를 이용한 나노유체의 대류열전달계수 측정 장치 (Measuring Apparatus for Convective Heat Transfer Coefficient of Nanofluids Using a Thermistor Temperature Sensor)

  • 이신표
    • 대한기계학회논문집B
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    • 제40권2호
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    • pp.103-110
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    • 2016
  • 나노유체의 대류열전달 성능을 평가하는 센서로서 가는 백금 열선이 많이 사용되었다. 그러나 센서의 강도가 약해서 취급에 주의가 필요하고 측정실험에서 센서에 대한 엄밀한 교정과정을 생략하거나 정밀도 높은 기구들을 사용하지 않으면 비현실적인 대류열전달계수가 얻어졌다. 본 연구에서는 백금 열선 대신 더미스터 센서를 채택한 새로운 나노유체 대류 성능 평가장치를 제안하였고 그 작동 원리를 자세히 설명하였다. 순수 엔진오일에 대한 두 센서의 비교 실험을 통하여 더미스터 센서의 실용적 장점을 확인할 수 있었다. 제안된 장치는 개발된 나노유체의 채택 여부를 판단하는 유용한 도구로 사용될 수 있을 것이다.

반응표면분석법에 의한 적층 칩 바리스터의 전기적 특성 (Electrical Properties of Multilayer Chip Varistors in the Response Surface Analysis)

  • 윤중락;정태석;최근묵;이석원
    • 한국전기전자재료학회논문지
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    • 제20권6호
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    • pp.496-501
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    • 2007
  • In order to enhance sintering characteristics on the $ZnO-Pr_6O_{11}$ based multilayer chip varistors (MLVs), a response surface analysis using central composite design method were carried out. As a result, varistor voltage($V_{1mA}$), nonlinear coefficient ($\alpha$), leakage current ($I_L$) and capacitance (C) were considered to be mainly affected by sintered temperature and holding time. MLVs sintered at $1200^{\circ}C$ and above $1200^{\circ}C$ revealed poor electrical characteristics, possibly due to the reaction between electrode materials(Pd) and $ZnO-Pr_6O_{11}$ based ceramics. On the sintering temperature range $1150{\sim}1175^{\circ}C$, nonlinear coefficient ($\alpha$) and leakage current ($I_L$) were shown to be $60{\sim}69$ and below $0.3{\mu}A$, respectively. In particular, MLVs sintered at $1175^{\circ}C$, 1.5 hr and $2^{\circ}C/hr$ (cooling speed) showed stable ESD(Electrical Static Discharge) characteristics under the condition of 10 times at 8 Kv with deviation varistor voltage, and deviation nonlinear coefficient were 0.3% and 0.33% (at positive), 0.55% (at negative), respectively.

밀폐유도용해로 제조된 2원계 Skutterudite CoSb3의 열전특성 (Thermoelectric Properties of Binary Skutterudite CoSb3 Prepared by Encapsulated Induction Melting)

  • 유신욱;정재용;어순철;김일호
    • 한국재료학회지
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    • 제16권5호
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    • pp.312-317
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    • 2006
  • Binary skutterudite $CoSb_3$ compounds were prepared by the encapsulated induction melting (EIM) process, and their thermoelectric, microstructural and mechanical properties were examined. Single-phase ${\delta}-CoSb_3$ was successfully produced by the EIM and subsequent heat treatment at 773 K-873 K for 24 hours in vacuum. Seebeck coefficient increased with increasing heat treatment temperature up to 673 K, showing the positive signs in the range of measuring temperature. However, the samples heat-treated at 773 K-873 K showed negative Seebeck coefficient from room temperature to 400 K, while it showed positive signs above 400 K. Electrical resistivity decreased with increasing temperature, showing typical semiconducting conductivity. Thermal conductivity decreased drastically with increasing heat-treatment temperature. This is closely related with the phase transition to ${\delta}-CoSb_3$.

다결정 실리콘 카바이드를 이용한 마이크로 유량센서 (Micro flow sensor using polycrystalline silicon carbide)

  • 이지공;;이성필
    • 센서학회지
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    • 제18권2호
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    • pp.147-153
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    • 2009
  • A thermal flow sensor has been fabricated and characterized, consisting of a center resistive heater surrounded by two upstream and one downstream temperature sensing resistors. The heater and temperature sensing resistors are fabricated from nitrogen-doped(n-type) polycrystalline silicon carbide(poly-SiC) deposited by LPCVD(low pressure chemical vapor deposition) on LPCVD silicon nitride films on a Si substrate. Cavities were etched into the Si substrate from the front side to create suspended silicon nitride membranes carrying the poly-SiC elements. One upstream sensor is located $50{\mu}m$ from the heater and has a sensitivity of $0.73{\Omega}$/sccm with ${\sim}15\;ms$ rise time in a dynamic range of 1000 sccm. N-type poly-SiC has a linear negative temperature coefficient and a TCR(temperature coefficient of resistance) of $-1.24{\times}10^{-3}/^{\circ}C$ from room temperature to $100^{\circ}C$.

시가화지역 토지이용 및 녹지구조에 따른 온도변화 연구 (Analysis of Temperature Profiles by Land Use and Green Structure on Built-up Area)

  • 홍석환;이경재;한봉호
    • 한국환경생태학회지
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    • 제19권4호
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    • pp.375-384
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    • 2005
  • 본 연구는 시가화지역 토지이용 및 녹지구조에 따른 온도변화를 파악하고자 강남구 내 시가화지역을 대상으로 44개소 조사지를 블록단위로 선정하여 실시하였다. 온도값은 1999${\~}$2002년까지의 Landsat TM 및 ETM+ 영상 6scene을 적용하였다. 도시온도변화에 대한 영향요인 분석결과 토지 이용유형은 그 자체로 도시온도변화의 중요 인자로 작용하지는 않는 것으로 판단되었으며 토양피복유형은 상관관계 분석결과 상관계수가 건폐율이 0.368(2001년 6월)${\~}$0.709(1999년 5월)로 양(+)의 상관관계에 있었으며 녹지율은 -0.551(2001년 6월)${\~}$-0.860(1999년 6월)으로 음(-)의 상관관계를 보였다. 녹지용적(녹지용적계수${\times}$100), 녹피율과 온도값과의 상관관계 분석 결과 녹피율과의 상관계수는 -0.549(2001년 6월)${\~}$-0.817(1999년 6월)의 범위이었으며 녹지용적은 -0.517(2001년 6월)${\~}$-0.882(1999년 6월)로 녹피율과 녹지용적 모두 각 온도값과 강한 음(-)의 상관관계를 보였다. 도시화지역 온도변화 예측모형 구축을 위한 회귀분석 결과 녹지용적이 설명 변수로 채택되었다.

Electrical properties of (Na0.5Bi0.5)(Zr0.75Ti0.25)O3 ceramic

  • Lily, Lily;Yadav, K.L.;Prasad, K.
    • Advances in materials Research
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    • 제2권1호
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    • pp.1-13
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    • 2013
  • Lead-free compound $(Na_{0.5}Bi_{0.5})(Zr_{0.75}Ti_{0.25})O_3$ was prepared using conventional ceramic technique at $1070^{\circ}C$/4h in air atmosphere. X-ray diffraction analysis showed the formation of single-phase orthorhombic structure. Permittivity data showed low temperature coefficient of capacitance ($T_{CC}{\approx}5%$) up to $100^{\circ}C$. Complex impedance studies indicated the presence of grain boundary effect, non-Debye type dielectric relaxation and evidences of a negative temperature coefficient of resistance. The ac conductivity data were used to evaluate the density of states at Fermi level and apparent activation energy of the compound.

온도 보상기능을 갖는 내장형RC OSCILLATOR 설계 (Design of an Embedded RC Oscillator With the Temperature Compensation Circuit)

  • 김성식;조경록
    • 대한전자공학회논문지SD
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    • 제40권4호
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    • pp.42-50
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    • 2003
  • 본 논문에서는 시스템의 클럭을 안정적으로 공급하는 집적화 한 내장형 RC oscillator의 구현에 관한 논문이다. 기존의 RC oscillator는 온도에 따라 주파수변화가 약 15%정도 변화가 있는데 이는 온도에 따른 저항값의 변화와 schmit trigger의 기준전압이 온도에 따라 변화하기 때문이다. 본 연구에서는 온도에 따른 주파수 변화를 최소화하는 방법으로 CMOS bandgap과 온도에 따른 전류의 변화를 이용하였다. CMOS bandgap으로 기준 전압을 얻고 온도에 따라 증가하는 전류원과 온도에 따라 감소 하는 전류원을 서로 합하면 온도에 따라 일정한 전류를 얻어 주파수의 변화를 약 3%이내로 유지하는 회로를 제안한다.

고온가압소결한 $\alpha-SiC-ZrB_2$ 복합체의 전기전도기구 (Electrical Conductive Mechanism of Hot-pressed $\alpha-SiC-ZrB_2$ Composites)

  • 신용덕;주진영;권주성
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제48권2호
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    • pp.104-108
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    • 1999
  • The electrical conductive mechanism and temperature dependence of electrical resistivity of $\alpha-SiC-ZrB_2$ composites with $ZrB_2$ contents were investigated. The electrical resistivity of hot-pressed composites was measured by the Pauw method form $25^{\circ} to 700^{\circ}C$. The electrical resistivity of the composites follow the electrical conduction model for a homogeneous mixture of two kind of particles with different conductivity. Also, the electrical resistivity versus temperature curves indicate the formation of local chains of $ZrB_2$ particles. In case of $\alpha-SiC-ZrB_2$ composites containing above 39vol.% $ZrB_2$ showed positive temperature coefficient resistance(PTCR), whereas the electrical resistivity of $\alpha-SiC-21vol.% ZrB_2$ showed negative temperature coefficient resistance(NTCR).

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