• Title/Summary/Keyword: Near-infrared Absorption

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The Near-Infrared Imaging Spectroscopy to Visualize the Distribution of Sugar Content in the Flesh of a Melon

  • Tsuta, Mizuki;Sugiyama, Junichi;Sagara, Yasuyuki
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1526-1526
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    • 2001
  • To improve the accuracy of sweetness sensor in automated sorting operations, it is necessary to clarify unevenness of the sugar content distribution within fruits. And it is expected that the technique to evaluate the content distribution in fruits contribute to the development of the near-infrared (NIR) imaging spectroscopy. Sugiyama (1999) had succeeded to visualize the distribution of the sugar content on the surface of a half-cut green fresh melon. However, this method cannot be applied to red flesh melons because it depends on information of the absorption band of chlorophyll (676 nm), which is affected by the color of the fresh. The objective of this study was to develop the universal visualization method depends on the absorption band of sugar, which can be applied to various kinds of melons and other fruits. The relationship between the sugar contents and absorption spectra of both green and red fresh melons were investigated by using a NIR spectrometer to determine the absorption band of sugar. The combination of 2$\^$nd/ derivative absorbances at 902 nm and 874 nm was highly correlated with the sugar contents. The wavelength of 902 nm is attributed to the absorption band of sugar. A cooled charge-coupled device (CCD) imaging camera which has 16 bit (65536 steps) A/D resolution was equipped with rotating band-pass filter wheel and used to capture the spectral absorption images of the flesh of a vertically half-cut red fresh melon. The advantage of the high A/D resolution in this research is that each pixel of the CCD is expected to function as a detector of the NIR spectrometer for quantitative analysis. Images at 846 nm, 874 nm, 902 nm and 930 nm were acquired using this CCD camera. Then the 2$\^$nd/ derivative absorbances at 902 nm and 874 nm at each pixel were calculated using these four images. On the other hand, parts of the same melon were extracted for capturing the images and squeezed for the measurement of sugar content. Then the calibration curve between the combination of 2$\^$nd/ derivative absorbances at 902 nm and 874 nm and sugar content was developed. The calibration method based on NIR spectroscopy techniques was applied to each pixel of the images to convert the 2$\^$nd/ derivative absorbances into the Brix sugar content. Mapping the sugar content value of each pixel with linear color scale, the distribution of the sugar content was visualized. As a result of the visualization, it was quantitatively confirmed that the Brix sugar contents are low at the near of the skin and become higher towards the seeds. This result suggests that the visualization technique by the NIR imaging spectroscopy could become a new useful method fer quality evaluation of melons.

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Heat-ray Shielding Property of Nanocomposites of Poly(acrylic acid) Doped with Copper Sulfide

  • Gotoh, Yasuo;Shibata, Kazuaki;Fujimori, Yoshie;Ohkoshi, Yutaka;Nagura, Masanobu
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.71-72
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    • 2003
  • The aim of our study is to prepare nanocomposites consisting polymer/inorganic nanoparticles and investigate their physical properties as a functional material. In this study, a nanocomposite of copper sulfide (CuS) nanoparticles introduced into a poly(acrylic acid) matrix was prepared and the optical absorption property was measured. The composite exhibited strong absorption of both ultraviolet and near-infrared rays, indicating that the composite is applicable to a solar radiation shielding filter. The wavelength of the near infrared absorption was controlled from ca.1000 nm to 1700 nm by heat and acidic solution treatments.

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Near Infrared Spectroscopy for Measuring Soil Properties

  • Ryu, Kwan-Shig;Kim, Bok-Jin;Park, Woo-Churl;Cho, Rae-Kwang
    • Near Infrared Analysis
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    • v.1 no.1
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    • pp.37-41
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    • 2000
  • The purpose of this research was to develop a the reflection technique with near infrared (NIR) radiation for estimating soil components. NIR reflectance was scanned at 2nm intervals from 1100 to 2500nm with an InfraAlyzer 500 (Bran & Luebbe Co.). Over 400 soil sample from fields of different crops and land-use over Youngnam and Honam regions were used to obtain mean diffuse reflection of the soil for the calibration and validation of the calibration set in estimating moisture, organic matter (OM) and total nitrogen (T-N) of the soils. Multiple linear regression (MLR) was used to evaluate the correlation of NIR spectroscopy method. Reflection pattern of NIR spectra for finely sized sample (<0.5mm) and coarsely sized soil(<2mm) did not show much difference. The results showed that NIR spectroscopy and coarsely sized soil (<2mm) did not show much difference. The results showed that NIR spectroscopy could be used as a routine soil testing method in estimating OM, moisture, T-N in soil samples simultaneously.

SYSTEMATIC STUDY OF INTERSTELLAR ICES IN NEARBY GALAXIES

  • Yamagishi, M.;Kaneda, H.;Oyabu, S.;Ishihara, D.;Onaka, T.;Shimonishi, T.;Suzuki, T.
    • Publications of The Korean Astronomical Society
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    • v.27 no.4
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    • pp.249-252
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    • 2012
  • The absorption features due to interstellar ices, especially $H_2O$ and $CO_2$ ices, provide us with crucial information on present and past interstellar environments, and thus the evolutionary histories of galaxies. Before AKARI, however, few detections of ices were reported for nearby galaxies. The AKARI's unique capability of near-infrared spectroscopy with high sensitivity enables us to systematically study ices in nearby galaxies. Thus we have explored many near-infrared spectra ($2.5-5{\mu}m$) of the 211 pointed observations, searching for the absorption features of ices. As a result, out of 122 nearby galaxies, we have significantly detected $H_2O$ ice from 36 galaxies and $CO_2$ ice from 9 galaxies. It is notable that the ices are detected not only in late-type galaxies but also in early-type galaxies. We find that $CO_2$ ice is more compactly distributed near the galactic center than $H_2O$ ice. Finally, we suggest that the gas density of a molecular cloud and UV radiation may be important factors to determine the abundance of ices.

PRELIMINARY STUDY ON NIR SPECTRA OF RETROGRADED STARCH

  • Terazawa, Yoko;Maekawa, Takaaki;Kawano, Sumio
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1515-1515
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    • 2001
  • Retrogradation of starch is one of important quality indexes for food based on starch such as rice. Therefore, in this research, possibility of near infrared spectroscopy to determine the degree of the retrogradation was examined. The degree of the retrogradation was indicated as the degree of geratinization analyzed by BAP(-amylase-pullulanase) method. 20 samples which have a wide range of the degree of the retrogradation were prepared and the NIR spectra of the samples were measured in reflectance mode with the NIR Systems 6500. In the correlation plots calculated from the 2nd derivative values of the MSC treated spectra and the degree of the geratinization, the major negative peaks of 1544 nm and 2258 nm, and the major positive peaks of 1460 nm, 1602 nm, 1766 nm and 2136 nm could be observed, indicating that NIR absorption at the positive peak wavelengths became strong while the absorption at the negative peak wavelengths became weak as the degree of the retrogradation increased. Because there is negative correlation between the degree of the retrogradation and the degree of the geratinization. As a result of MLR using the 2nd derivative values of the MSC treated spectra and the degree of the geratinization, good calibration equation which include 2258 nm as the first wavelength and 1764 nm as the second one could be obtained, indicating that NIR spectroscopy has a possibility to detect the retrogradation of starch. In order to find the assignment of the bands observed in the correlation plots, further study may be needed.

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Skin depth profiling by using fiber optic probes in the near infrared

  • Woo, Young-Ah;jung, Suh-Eun;Kim, Hyo-Jin
    • Proceedings of the SCSK Conference
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    • 2003.09b
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    • pp.218-218
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    • 2003
  • Recently we showed the prototype portable device for the determination of human skin moisture by using near infrared spectroscopy. In order to optimize the acquiring condition of NIR spectrum of skin and control the target information of water depending the site such as epidermis and dermis, skin depth profiling was investigated changing the distance between illuminations and receiving of radiation in the terminal of fiber probe. The colleted light information could be controlled by changing the distance of the fiber optic probes. It was confirmed that the longer distance we used, the deeper site from the skin surface we could get information from in this study. Four kinds of probes with distances such as 0.03 mm, 0.1 mm, 0.5 mm, and 1.0 mm were used. In addition, the gap size from 0.3 mm to 3.0 mm was studied to control the intensity of water absorbance effectively and to avoid saturation of water absorption. We also investigated the reference materials depending the reflectance ratio for water absorption not to be saturated because of the strong absorptivity of water. Furthermore, spectroscopic information regarding free water and bound water around 1850 nm was investigated by using the different distance of fiber optic probes. This study would be great help to control the spectroscopic information of water to be measured depending the site where water exists.

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The Syntheses and Application of NIR Dyes Based On Light Absorbing Properties

  • Park, Soo-Youl;Shin, Seung-Rim;Shin, Joung-Il;An, Kyoung-Lyong;Lee, Sang-Oh;Jun, Kun
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2010.03a
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    • pp.49-50
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    • 2010
  • The near-infrared absorbing donor-acceptor chromophores have been investigated by varying the electron donating and accepting molecular moiety. A series of near-infrared absorbing chromophores were offered narrow and intense absorption band in a various organic solvents. The dyes synthesised were, however, strongly bathochromic shift which extended well into the near-infrared region. The functional uses of dyes are vast in number, and it is convenient to classify them in some way. In all cases, it is the $\Pi$-chromophore that plays a major role in the functional application. "Light absorption" is of course the most commonly used property of a dye chromophore, and it can be employed directly, e.g. in light filters and optical data recording, or it can be used to drive further functional processes, e.g. fluorescence, photochromism, photosensitization.

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PROPERTIES OF DUST IN EARLY-TYPE GALAXIES BASED ON THE ALL-SKY-SURVEY DATA AND NEAR-INFRARED SPECTRA

  • Mori, T.;Oyabu, S.;Kaneda, H.;Ishihara, D.;Yamagishi, M.
    • Publications of The Korean Astronomical Society
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    • v.27 no.4
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    • pp.263-264
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    • 2012
  • We present the properties of dust and the near-infrared spectral features in nearby early-type galaxies. The properties of dust are obtained from the AKARI far-infrared all-sky survey diffuse map. The AKARI/IRC is used for the near-infrared spectra. We improve spectral data with the new dark subtraction method on the basis of the knowledge acquired in our laboratory experiments of the engineering-model detector for the IRC. We have succeeded in fitting the continuum by a power-law function and detecting CO and SiO absorption features in early-type galaxy spectra. Comparing the properties of dust and near-infrared spectral features, we find that the power-law slope depends on dust temperature, but not on the dust mass, which suggests that low-luminosity AGNs may contribute to the changes in the power-law slope and dust temperature.

Growth and Variance of Properties Er2O3 Doped Near Stoichiometric LiNbO3Single Crystals by the Czochralski Method (Czochralski법으로 Er2O3이 첨가된 Near Stoichiometric 조성 LiNbO3 단결정의 성장 및 특성변화)

  • ;;;Masayuki Habu;Takeshi Ito;Masakimi Natori
    • Journal of the Korean Ceramic Society
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    • v.40 no.8
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    • pp.746-750
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    • 2003
  • Using the Czochralski method, Er$_2$O$_3$ doped near stoichiometric LiNbO$_3$ single crystals were grown 15~20 mm in diameter and 30-35 mm in length for Z-axis. Lattice constants were inspected by the X-Ray Diffractometer (XRD) and through Fourier Transform-Infrared Spectrophotometer (FT-IR), it observed absorption band. Also, the distributions of Er concentration were confirmed by the Electron Probe Micro Analysis (EPMA).

Outburst signatures of Class I source, IRAS 16316-1540

  • Yoon, Sung-Yong;Lee, Jeong-Eun;Lee, Seokho;Park, Sunkyung
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.2
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    • pp.55.4-55.4
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    • 2016
  • We observed 10 Class I sources as part of the IGRINS (Immersion GRating INfrared Spectroscoph) Legacy Program, "IGRINS Survey of Protoplanetary Disks (PI: Jeong-Eun Lee)". Unlike other Class I sources, IRAS 16316-1540 shows broad absorption features in the near-infrared spectra (H and K bands). The broadened absorption features have been detected toward FU Orionis-type objects. Boxy or double-peaked absorption profiles can be produced by a Keplerian disk that has the hot mid-plane heated by a burst mass accretion. We could fit the broad absorption features of IRAS 16316-1540 with a K5 V template stellar spectrum convolved with a disk rotation profile of 45 km s-1. Therefore, rotationally broadened absorption features detected in this Class I source suggest that the episodic accretion process occurs from the early stage of star formation.

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