• Title/Summary/Keyword: Near-infrared Absorption

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Algorithm for Finding the Best Principal Component Regression Models for Quantitative Analysis using NIR Spectra (근적외 스펙트럼을 이용한 정량분석용 최적 주성분회귀모델을 얻기 위한 알고리듬)

  • Cho, Jung-Hwan
    • Journal of Pharmaceutical Investigation
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    • v.37 no.6
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    • pp.377-395
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    • 2007
  • Near infrared(NIR) spectral data have been used for the noninvasive analysis of various biological samples. Nonetheless, absorption bands of NIR region are overlapped extensively. It is very difficult to select the proper wavelengths of spectral data, which give the best PCR(principal component regression) models for the analysis of constituents of biological samples. The NIR data were used after polynomial smoothing and differentiation of 1st order, using Savitzky-Golay filters. To find the best PCR models, all-possible combinations of available principal components from the given NIR spectral data were derived by in-house programs written in MATLAB codes. All of the extensively generated PCR models were compared in terms of SEC(standard error of calibration), $R^2$, SEP(standard error of prediction) and SECP(standard error of calibration and prediction) to find the best combination of principal components of the initial PCR models. The initial PCR models were found by SEC or Malinowski's indicator function and a priori selection of spectral points were examined in terms of correlation coefficients between NIR data at each wavelength and corresponding concentrations. For the test of the developed program, aqueous solutions of BSA(bovine serum albumin) and glucose were prepared and analyzed. As a result, the best PCR models were found using a priori selection of spectral points and the final model selection by SEP or SECP.

A Study on LED with Small Form Factor Suitable for Green A of Night Vision Imaging System (야간 투시 영상시스템의 Green A에 적합한 작은 형태인자를 가진 LED에 관한 연구)

  • Kim, Tae Hoon;Yu, Chang Han;Yoon, Hyeon Ju;Kim, Min Pyung;Yoon, Ho Shin
    • Journal of the Semiconductor & Display Technology
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    • v.20 no.4
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    • pp.62-67
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    • 2021
  • In this study, we have successfully developed an unique NVIS Green A compatible LED by combining two technologies. One is white LED made with a black EMC (epoxy molding compound) lead frame. The other is NVIS Green A filter that shields the near infrared region made in the film method. The form factor of the developed NVIS Green A compatible LED was 2.0 × 2.0 × 0.95 mm. And it is possible to satisfy NVIS radiance and color limit specified in MIL-STD-3009 by controlling the concentration of Green A dye and the thickness of the NVIS filter as well as adjusting of color temperature of the white LED. From these results, we are expected that the developed NVIS Green A suitable LED is a promising solution for the weight reduction and the cost reduction of avionic applications.

Implementation of Multi-channel Concurrent Detection Homodyne Frequency-domain Diffuse Optical Imaging System (다채널 동시측정을 적용한 호모다인 주파수영역 확산 광 이미징 시스템의 구현)

  • Jun, Young Sik;Baek, Woon Sik
    • Korean Journal of Optics and Photonics
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    • v.23 no.1
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    • pp.23-31
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    • 2012
  • In this paper, we developed a frequency-domain diffuse optical imaging (DOI) system for imaging non-invasively using near-infrared (NIR) light sources and detectors. 70-MHz modulation and a homodyne scheme were adopted. By calibration of the coupling coefficients, concurrent detection measurements by 4 detector sets were optimized. We presented experimental reconstruction images of absorption and scattering coefficients in a liquid phantom, located an anomaly in the phantom and determined its optical properties. The images by the multi-channel concurrent detection were improved over the results by single-channel sequential detection. Tomographic slices of absorption and scattering coefficients in the phantom with an anomaly were also presented.

Agricultural Application of Ground Remote Sensing (지상 원격탐사의 농업적 활용)

  • Hong, Soon-Dal;Kim, Jai-Joung
    • Korean Journal of Soil Science and Fertilizer
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    • v.36 no.2
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    • pp.92-103
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    • 2003
  • Research and technological advances in the field of remote sensing have greatly enhanced the ability to detect and quantify physical and biological stresses that affect the productivity of agricultural crops. Reflectance in specific visible and near-infrared regions of the electromagnetic spectrum have proved useful in detection of nutrient deficiencies. Especially crop canopy sensors as a ground remote sensing measure the amount of light reflected from nearby surfaces such as leaf tissue or soil and is in contrast to aircraft or satellite platforms that generate photographs or various types of digital images. Multi-spectral vegetation indices derived from crop canopy reflectance in relatively wide wave band can be used to monitor the growth response of plants in relation to environmental factors. The normalized difference vegetation index (NDVI), where NDVI = (NIR-Red)/(NIR+Red), was originally proposed as a means of estimating green biomass. The basis of this relationship is the strong absorption (low reflectance) of red light by chlorophyll and low absorption (high reflectance and transmittance) in the near infrared (NIR) by green leaves. Thereafter many researchers have proposed the other indices for assessing crop vegetation due to confounding soil background effects in the measurement. The green normalized difference vegetation index (GNDVI), where the green band is substituted for the red band in the NDVI equation, was proved to be more useful for assessing canopy variation in green crop biomass related to nitrogen fertility in soils. Consequently ground remote sensing as a non destructive real-time assessment of nitrogen status in plant was thought to be useful tool for site specific crop nitrogen management providing both spatial and temporal information.

Optical Properties and Structure of Black Cobalt Solar Selective Coatings (흑색 코발트 태양 선택흡수막의 광학적특성과 구조)

  • Lee, Kil-Don
    • Journal of the Korean Solar Energy Society
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    • v.31 no.4
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    • pp.48-56
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    • 2011
  • Black cobalt solar selective coatings were prepared by thermal oxidation of electroplated cobalt metal on copper and nickel substrates. The optical properties and structure of the black cobalt selective coating for solar energy utilizations were characterized by glow discharge spectrometry (GDS), ultraviolet-visible-near infrared (UV-VIS-NIR) spectrometer, atom force microscopy(AFM) and X-ray photoelectron spectroscopy(XPS). The optical properties of optimum black cobalt selective coating prepared on copper substrate were a solar absorptance of 0.82 and a thermal emittance of 0.01. From the GDS depth profile analysis of these coatings, the concentration of cobalt particles near the interface was higher than at the surface, but oxygen concentration at the surface was higher than at the interface. These results suggest that the selective absorption was dominated by this chemical composition variation in the coating. The surface of this film exhibited morphology with root-mean-square(rms) roughness of about 144.3nm. XPS measurements data showed that several phases of Co coexist($Co_3O_4$,CoO) in the film.

The reserch evaluation of shadow influence in NOAA AVHRR data

  • Kim, Dong-Hee;Ryutaro, Tateishi;Choi, Seung-Pil
    • 한국지형공간정보학회:학술대회논문집
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    • 2005.08a
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    • pp.101-106
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    • 2005
  • Vegetation shows unique spectrum characteristics compared with other materials. If such characteristics are used, land change pattern can be determined. Thus, vegetation has an absorption belt and a reflective belt in visible and near infrared, and reflectance is very high. Then, various methods of monitoring vegetation paying attention to the absorption wavelength region and reflective region of vegetation are proposed. However, there are various problems in grasping change of vegetation by NDVI, PVI, etc. It is very difficult especially to remove various noise ingredients in the received satellite data. Until now, it is difficult to compensate for shadow effect when NDVI is used in vegetation analysis. The results is, if the shadow is about 60% the pixel will be wrongly classified as may be vegetation or not.

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Sensitized Near IR Luminescence of Er(Ⅲ) Ion in Lanthanide Complexes Based on Diketone Derivatives: Synthesis and Photophysical Behaviors

  • Baek, Nam-Seob;Kwak, Bong-Kyu;Kim, Yong-Hee;Kim, Hwan-Kyu
    • Bulletin of the Korean Chemical Society
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    • v.28 no.8
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    • pp.1256-1260
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    • 2007
  • Two β-diketone derivatives bearing triphenylene (1-naphthalene-2-yl-3-triphenylen-2-yl-propane-1,3-dione (NTPD)) and naphthalene (1,3-di-naphthalene-2-yl-propane-1,3-dione (DNPD)) and their Ln(III) complexes (Ln = Er or Gd) were synthesized and their photophysical properties were investigated. The sensitized emission of Er3+ ion in Er3+-[NTPD]3(terpy) and Er3+-[DNPD]3(terpy) was observed upon excitation at absorption maximum of ligands. Their photophysical studies indicate the sensitization of Er3+ luminescence by energy transfer through the excited triplet state of β-diketone ligand. The energy transfer rate through the excited triplet state of β-diketone ligand to Er3+ ion occurs faster than that of the oxygen quenching rate.

The Near Infrared Spectroscopic Studies of the Hydrogen Bonding Between Thioacetamide and Azines in Nonaqueous Solutions

  • 이상현;박정희;윤창주;최영상
    • Bulletin of the Korean Chemical Society
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    • v.16 no.9
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    • pp.831-834
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    • 1995
  • The nature of hydrogen bonding between thioacetamide and azines has been thoroughly investigated using near IR absorption spectroscopy. The νN-H + amide II combination band in thioacetamide (TA) has been analyzed to determine the thermodynamic constants for the formation of hydrogen bonded 1:1 TA:azine complexes in CCl4 and CHCl3 solutions. The relative stabilities of TA-azine complexes (pyridine->1,2-diazine->1,3-diazine->1,4-diazine-TA) are in good agreement with the relative proton affinities of azines in the gas phase. The results serve as a basis for analyzing the factors which influence the hydrogen bonding formation of TA in nonaqueous solutions.

AN ANALYSIS OF INFRARED IMAGES OF JUPITER IMPACTED BY P/SHOEMAKER-LEVY 9

  • KIM YONG HA;SUNG KIYUN;KIM SANG JOON;COCHRAN W. D.;LESTER D. F.;TRAFTON L.;CLARK B. E.
    • Journal of The Korean Astronomical Society
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    • v.29 no.2
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    • pp.245-253
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    • 1996
  • We have analyzed infrared (IR) images of Jupiter which was observed at the McDonald Observatory, Texas, U.S.A., during the P/SHoemaker-LEvy 9 (SL9) impact period and about one week after the last impact. The IR images were obtained on the 2.7m telescope using a NICMOS array with filters to isolate the $1.5{\mu}m\;NH_3\; band,\;the\;2.3{\mu}m\;CH_4\;band,\;the\;2.12{\mu}m\;H_2\;S(0)$ pressure-induced absorption, and the continua at $1.58{\mu}m\;and\;2.0{\mu}m$ (short K-band). All images except those with the $1.58{\mu}m$ continuum filter show bright impact sites against the relatively dark Jovian disk near the impact latitude of about $45^{\circ}$ S. This implies that dusts originated from the impacts reflect the solar radiation at high altitudes before absorbed by stratospheric $CH_4,\;NH_3 \;or\;H_2$. The impact sites observed with the $2.3{\mu}m$ filter are conspicuously bright against a very dark background. The morphology of impact sites, G, L, and H at 2.3 and $2.12{\mu}m$ filters shows clearly an asymmetric structure toward the incident direction of the comet fragments, in agreement with the studies of visible impact images obtained with the Hubble Space Telescope. Comparisons of reflectances of G, L, and H sites with simple radiative transfer models suggest that optically thick dust layers were formed at high altitudes at which methane absorption attenuates incoming sunlight only by about $1\%$. The dust layers in these sites seem to form at about the same altitude regardless of the magnitude of the impacts, but they appear to descend gradually after the impacts. The dust layers have optical depths of 2-5, according to the models.

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Near-IR Quantum Cutting Phosphors: A Step Towards Enhancing Solar Cell Efficiency

  • Jadhav, Abhijit P.;Khan, Sovann;Kim, Sun Jin;Cho, So-Hye
    • Applied Science and Convergence Technology
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    • v.23 no.5
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    • pp.221-239
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    • 2014
  • The global demand for energy has been increasing since past decades. Various technologies have been working to find a suitable alternative for the generation of sustainable energy. Photovoltaic technologies for solar energy conversion represent one of the significant routes for the green and renewable energy production. Despite of remarkable improvement in solar cell technologies, the generation of power is still suffering with lower energy conversion efficiency, high production cost, etc. The major problem in improving the PV efficiency is spectral mismatch between the incident solar spectrum and bandgap of a semiconductor material used in solar cell. Luminescent materials such as rare-earth doped phosphor materials having the quantum efficiency higher than unity can be helpful for photovoltaic applications. Quantum cutting phosphors are the most suitable candidates for the generation of two or more low-energy photons for the absorption of every incident high-energy photons. The phosphors which are capable of converting UV photon to visible and near-IR (NIR) photon are studied primarily for photovoltaic applications. In this review, we will survey various near IR quantum cutting phosphors with respective to their synthesis method, energy transfer mechanism, nature of activator, sensitizer and dopant materials incorporation and energy conversion efficiency considering their applications in photovoltaics.