• Title/Summary/Keyword: Nbr

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Study on the Free Volume in Polymer by Positron Annihilation Lifetime Spectroscopy (PALS) (양전자소멸 수명시간 측정을 통한 폴리머소재의 자유부피에 관한 연구)

  • Kim, Yongmin;Shin, Jungki;Kwon, Junhyun
    • Journal of the Korean Society of Radiology
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    • v.6 no.6
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    • pp.489-493
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    • 2012
  • Positron Annihilation Lifetime Spectroscopy is a non-destructive technique to study voids and defects in solids by the measurement of gammas from electron-positron annihilation. In this study, we measured the lifetime of CR, EPDM, NBR, all of which are widely used polymer in various fields. A conventional fast-fast coincidence system in KAERI(Korea Atomic Energy Research Institute) has been used to measure the lifetime spectra, Three lifetime components were analyzed from each lifetime spectra. According to Tao-Eldrup model equation, the size and fraction of free-volume were calculated. Mean radius and free volume fraction of CR, EPDM NBR are $0.1217nm^3$(1.9103%), $0.14780nm^3$(5.3147%), $0.1216nm^3$(2.6381%), respectively. Through these measurements, we identified the feasibility of the PAL system for polymer analysis.

Compounding and Test of Gasket Rubber for Fuel Cell Stack Application (연료전지 스택 가스켓용 고무재료의 제조와 평가)

  • Hur, Byung-Ki;Kang, Dong-Gug;Kim, Hye-Young;Seo, Kwan-Ho;Park, Lee-Soon
    • Elastomers and Composites
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    • v.42 no.4
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    • pp.232-237
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    • 2007
  • We examined the properties of compound and made compound of the optimum state using the properties of each material to evaluate suitability of FKM, VMQ, EPDM, NBR with gasket for fuel cell which is in general use with the material of gasket. It could be found from the compound made with setting the optimum state that NBR is worse than FKM in the chemical property of matter for a long term, and VMQ is worse than FKM in the elution of a metal ion, and EPDM is worse than FKM in the permeability of gas. As a result of leak evaluation of gasket for fuel cell with using FKM, it appeared leak in short time when contracting pressure is getting lower and sealing pressure is getting higher. And as a result of the life prediction with using Arrhenius model, we could predict that it is possible to continuously drive for 60,000 hours.

Filler-Elastomer Interactions. 10. Ozone Treatment on Interfacial Adhesion of Carbon Blacks/NBR Compounds (충전재-탄성체 상호작용. 10. 카본블랙/NBR 복합재료의 계면 접착에 미치는 오존처리의 영향)

  • Cho, Ki-Sook;Zaborski, M.;Slusarski, L.;Park, Soo-Jin
    • Elastomers and Composites
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    • v.38 no.2
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    • pp.139-146
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    • 2003
  • In this work, the influence of ozone treatment on surface properties of carbon black is investigated in terms of X-ray photoelectron spectroscopy (XPS) and contact angles. And their mechanical interfacial properties of the carbon black/acrylonitrile butadiene rubber (NBR) compounds are studied by the crosslink density and composite tearing energy ($G_{IIIC}$). As a result, it is found that the increasing of the ozone concentration leads to an increase of the introduction rate of oxygen-containing functional groups onto carbon black surfaces and to an increase of the surface free energy, resulting in improving both crosslink density and tearing energy ($G_{IIIC}$) of the compounds. The results can be explained by the fact that the oxygen-containing functional groups of carbon black surfaces make an increase of the degree of adhesion at interfaces between carbon blacks and rubber matrix.

Adhesive Bonding Properties between NBR and Polyamide Woven Fabric with Atmospheric Pressure Plasma Treatment (대기압 플라즈마 처리한 폴리아미드 직물과 NBR의 접착특성)

  • Ryu, Sang-Ryeoul;Lee, Dong-Joo
    • Composites Research
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    • v.23 no.6
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    • pp.32-38
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    • 2010
  • The effect of the atmospheric pressure plasma(APP) treatments is experimentally investigated to ascertain the optimum condition to yield the best adhesive properties between a polyamide woven fabric and acrylonitrile butadiene rubber(NBR). For the atmospheric pressure flame plasma(APFP) treatment, the optimum number of treatment at given conditions is 2 times. The thermal deformation of the fabric is more serious with increasing the number of APFP treatment. The adhesive strength of the case with APFP treated fabric is increased about 35% when compare to the case with non-APFP treated one for the interface(bonding agent one or two coatings). When the surface is coated twice with the bonding agent, the adhesive energy with APFP treated fabric is increased about 4 times. It was found that the surface modification of polyamide woven fabric by APFP treatment is a fast, economic and applicable method to improve the adhesive properties between woven fabric and rubber when compared to other APP treatments.

The remote-sensing based estimation of the evapotranspiration change due to the 2019 April Gangwon-do wildfire (2019년 강원도 산불로 인한 증발산 변화 원격탐사기반 추산)

  • Kim, JiHyun;Sohn, Soyoung;Kim, Yeonjoo
    • Journal of Korea Water Resources Association
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    • v.52 no.11
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    • pp.941-946
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    • 2019
  • A wildfire could significantly alter the local hydrological regime, depending on the area and severity, and thus it is critical to understand its effect and feedback using data and simulation. For the wildfire in Gangwon-do on April 4-5, 2019, South Korea, we retrieved the Normalized-Burned Ratio (NBR) index using remote-sensing data (500-m 8-day MODIS surface reflectance data), and detect the damaged-area based on the difference in the NBR (dNBR) before and after the fire. The damaged area was $29.50km^2$ in total, taking up 1.00-6.19% of five catchments. We then used remote-sensing data (500-m 8-day MODIS evapotranspiration data) and estimated that annual evapotranspiration (AET) would decrease as 0.05-1.56% over the five catchments, as compared to the pre-fire AET (2004-2018). This study highlights the importance of improving our understanding about the impact of wildfire on the local hydrological cycle.

Effect of Zinc Dimethacrylate on Mechanical Properties of Dynamically Vulcanized Polypropylene(PP) and Nitrile rubber(NBR) Blends (메타크릴산 아연염의 첨가가 폴리프로필렌-니트릴고무 블렌드의 동적가교 및 기계적물성에 미치는 영향)

  • Lee, Jung-Won;Joo, Hyun-Seok;Kong, Shin-Choon;Chong, Young-Wook
    • Elastomers and Composites
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    • v.41 no.4
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    • pp.245-251
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    • 2006
  • Thermoplastic elastomer was prepared from dynamical vulcanization of isotactic polypropylene(iPP)/nitrile rubber blend (NBR/iPP=70/30 wt/wt) in an internal mixer using dicumyl peroxide (DCP) as a curing agent and zinc dimethacrylate (ZDMA) as a coagent. There was a great improvement in tensile and tear strength, elongation-at-break and lower tension set when ZDMA was incorporated into the blend, which is supposed to be due to the increase in crosslink density or the rubber phase and the reduction in size of the rubber particles. It was revealed that the dynamically vulcanized blend exhibited good reprocessibility, indicating its thermoplastic nature.

Gas Permeation Study of Fuel Hose Composed as Inner Material of FKM Rubber (FKM 고무를 내층재료로 한 연료호스의 가스 투과성 연구)

  • Kim, Do-Hyun;Doh, Kyung-Hwan;Park, Hyun-Ho;Lee, Chang-Seop
    • Elastomers and Composites
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    • v.40 no.2
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    • pp.83-92
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    • 2005
  • To develop an automotive fuel hose suitable to the international environmental regulation, FKM rubber materials as an inner material of fuel hole were prepared with different chemical compositions. Measurement of the properties of thermal resistance, oil resistance, fuel resistance, gas permeability including fundamental properties were performed to investigate compatibility for a fuel hose material. Fundamental properties, thermal resistance, oil resistance, fuel resistance and permeability of FKM rubber materials were improved with fluorine content. When the carbon content was 20 phr, FKM compounds with fluorine contents of 66%, 09% and 71% were shown to satisfy the specification oi fuel hose. The gas permeability of NBR and FKM compounds was measured on the mixed fuel oils prepared with isooctane-toluene and gasoline-methanol. FKM rubber materials showed a small difference in penetrated amount of fuel and showed a permeability superior to NBR material. he permeability of FKM rubber materials was not influenced by the contents of fuel oil. Thermal properties of 69% FKM rubber experienced by permeability testing were not variated.

An Quantitative Analysis of Severity Classification and Burn Severity for the Large Forest Fire Areas using Normalized Burn Ratio of Landsat Imagery (Landsat 영상으로부터 정규탄화지수 추출과 산불피해지역 및 피해강도의 정량적 분석)

  • Won, Myoung-Soo;Koo, Kyo-Sang;Lee, Myung-Bo
    • Journal of the Korean Association of Geographic Information Studies
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    • v.10 no.3
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    • pp.80-92
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    • 2007
  • Forest fire is the dominant large-scale disturbance mechanism in the Korean temperate forest, and it strongly influences forest structure and function. Moreover burn severity incorporates both short- and long-term post-fire effects on the local and regional environment. Burn severity is defined by the degree to which an ecosystem has changed owing to the fire. Vegetation rehabilitation may specifically vary according to burn severity after fire. To understand burn severity and process of vegetation rehabilitation at the damaged area after large-fire is required a lot of man powers and budgets. However the analysis of burn severity in the forest area using satellite imagery can acquire rapidly information and more objective results remotely in the large-fire area. Space and airbone sensors have been used to map area burned, assess characteristics of active fires, and characterize post-fire ecological effects. For classifying fire damaged area and analyzing burn severity of Samcheok fire area occurred in 2000, Cheongyang fire in 2002, and Yangyang fire in 2005 we utilized Normalized Burn Ratio(NBR) technique. The NBR is temporally differenced between pre- and post-fire datasets to determine the extent and degree of change detected from burning. In this paper we use pre- and post-fire imagery from the Landsat TM and ETM+ imagery to compute the NBR and evaluate large-scale patterns of burn severity at 30m spatial resolution. 65% in the Samcheok fire area, 91% in the Cheongyang fire area and 65% in the Yangyang fire area were corresponded to burn severity class above 'High'. Therefore the use of a remotely sensed Differenced Normalized Burn Ratio(${\Delta}NBR$) by RS and GIS allows for the burn severity to be quantified spatially by mapping damaged domain and burn severity across large-fire area.

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Case Study on Determination of the Level of New RoHS II Substances in Domestic Electronic and Electrical Equipments (국내 전기전자 제품에 함유된 신규 RoHS II 물질 검출 사례 연구)

  • Song, Moon-Hwan;Son, Seung-Hwan;Cho, Young-Dal;Choe, Eun-Kyung
    • Clean Technology
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    • v.17 no.2
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    • pp.124-133
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    • 2011
  • In addition to six substances regulated in EU RoHS including lead, mercury, cadmium, hexavalent chromium, polybrominated biphenyls (PBB) and polybrominated diphenyl ethers (PBDE), priority substances are identified in new RoHS II as hexabromocyclododecane (HBCDD), dibutyl phthalate (DBP), butyl benzyl phthalate (BBP) and diethylhexyl phthalate (DEHP). In this study, 20 plastic samples were collected from 12 domestic electrotechnical companies and levels of four restricted substances were determined by gas chromatography-mass spectrometry, Among 20 parts that compose washer, refrigerator or microwave oven, HBCDD was detected in three samples of NBR material with the amount of 42~381 mg/kg while DBP and BBP was not detected in any samples collected respectively, implying that these substance may not be used widely in plastic materials for EEE. However, DEHP was detected in all samples of NBR, PP, PBT, EPDM and PVC materials with the amount of 42 up to 59,400 mg/kg that exceeds the limit value of 0.1 wt% (1,000 mg/kg). Presence of a restricted substance in polymer material makes a great negative influence on a number of final product. To cope with coming RoHS II as well as REACH, action not to use DEHP in plastic material or the relevant notification in case of REACH seems to be needed. Screening test of Arsenic compounds such as diarsenic pentaoxide, diarsenic trioxide, lead hydrogen arsenate, triethyl arsenate that are included in REACH SVHC was done by ICP measurement Arsenium was detected in four samples made of NBR and PBT materials in the level of 15~700 mg/kg. By considering the screening method used in this study, the amount of arsenium compounds in the thermistor made of PBT material has a high chance of exceeding the regulated limit value.

An Quantitative Analysis of Severity Classification and Burn Severity At the targe-fire Areas Using NBR Index of Landsat Imagery (Landsat NBR지수를 이용한 대형산불 피해지 구분 및 피해강도의 정량적 분석)

  • Won, Myoung-Soo;Koo, Kyo-Sang;Lee, Myung-Bo
    • 한국방재학회:학술대회논문집
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    • 2007.02a
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    • pp.231-237
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    • 2007
  • To monitor process of vegetation rehabilitation at the damaged area after large-fire is required a lot of manpowers and budgets. However the analysis of vegetation recovery using satellite imagery can be obtaining rapid and objective result remotely in the large damaged area. Space and airbone sensors have been used to map area burned, assess characteristics of active fires, and characterize post-fire ecological effects. Burn severity incorporates both short- and long-term post-fire effects on the local and regional environment. Burn severity is defined by the degree to which an ecosystem has changed owing to the fire. To classify fire damaged area and analyze burn severity of Samcheok fire area occurred in 2000, Cheongyang fire 2002, and Yangyang fire 2005 was utilized Landsat TM and ETM+ imagery. Therefore the objective of the present paper is to quantitatively classify fire damaged area and analyze burn severity using normalized burn index(NBR) of pre- and post-fire's Landsat satellite imagery.

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