• Title/Summary/Keyword: Nbr

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Phase Equilibria of the mixed $H_2+CO_2$ Hydrates Including Thermodynamic Promoters (열역학적 촉진제가 포함된 $H_2+CO_2$ 혼합 하이드레이트의 상평형)

  • Park, Sungmin;Lee, Seungmin;Lee, Youngjun;Heo, Jae Hyeok;Seo, Yongwon
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.216.2-216.2
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    • 2010
  • 본 연구에서는 $H_2+CO_2$(40%) 혼합기체로부터 이산화탄소를 효과적으로 분리/회수 하기 위하여 가스 하이드레이트 형성법을 제안하였다. 하이드레이트의 형성 조건을 보다 완화시켜 주기 위하여 열역학적 촉진제로서 TBAB (Tetra-n-butyl Ammonium Bromide, $(C_4H_9)_4NBr$))와 THF(Tetrahydrofuran)를 각각 첨가하여 열역학적 촉진 현상을 살펴보았다. 다양한 농도의 TBAB(10, 40, 60 wt%)와 THF(1, 5.56, 10 mol%)에 대하여 3상(H - Lw - V) 평형을 측정하였다. 그 결과 40 wt%의 TBAB와 5.56 mol%의 THF의 농도에서 가장 큰 촉진효과를 보였으며 그 이상의 농도에서는 오히려 촉진효과가 줄어드는 것을 확인할 수 있었다. 이러한 결과는 혼합가스 하이드레이트 형성시 양론비 이상의 TBAB와 THF가 첨가될 경우 반응에 참여하지 못한 TBAB와 THF가 가스 하이드레이트 형성을 방해하기 때문이다. 열역학적 촉진제로서 실제공정에 적용할 경우 40 wt%의 TBAB와 5.56 mol%의 THF를 사용하는 것이 가장 효과적일 것으로 사료된다. 본 실험에서 얻어진 결과는 가스 하이드레이트 형성법을 이용한 합성가스 분리 공정 개발에 중요한 기초 자료가 될 것이다.

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Optimum design of reinforced concrete columns subjected to uniaxial flexural compression

  • Bordignon, R.;Kripka, M.
    • Computers and Concrete
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    • v.9 no.5
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    • pp.327-340
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    • 2012
  • The search for a design that meets both performance and safety, with minimal cost and lesser environmental impact was always the goal of structural engineers. In general, the design of conventional reinforced concrete structures is an iterative process based on rules of thumb established from the personal experience and intuition of the designer. However, such procedure makes the design process exhaustive and only occasionally leads to the best solution. In such context, this work presents the development and implementation of a mathematical formulation for obtaining optimal sections of reinforced concrete columns subjected to uniaxial flexural compression, based on the verification of strength proposed by the Brazilian standard NBR 6118 (ABNT 2007). To minimize the cost of the reinforced concrete columns, the Simulated Annealing optimization method was used, in which the amount and diameters of the reinforcement bars and the dimensions of the columns cross sections were considered as discrete variables. The results obtained were compared to those obtained from the conventional design procedure and other optimization methods, in an attempt to verify the influence of resistance class, variations in the magnitudes of bending moment and axial force, and material costs on the optimal design of reinforced concrete columns subjected to uniaxial flexural compression.

Study of the Scorch/Cure time Relationships (스코치/가황시간의 상관관계에 관한 연구)

  • Ryou, Jin-Ho;Kim, Chang-Hee;Oh, Taeg-Su
    • Elastomers and Composites
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    • v.31 no.1
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    • pp.33-42
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    • 1996
  • NR, NBR, and CR rubber were prepared by mixing filler in various ratios. Their vulcanization characteristics and thermal properties were studied. Vulcanization characteristics were investigated using cure curve that had been obtained from oscillating disk rheometer study. The Arrhenius law is known to describe the relationship between cure time and temperature of most elastomers. Curing could be done by the addition of sulfur, peroxides, and proper acceleratores. The optimum cure time that affects desirable values of modulus and tensile strength of the vulcanizate is taken as t90 as measured by a rheometer. Rubbers were cured in the rheometer at temperatures ranging from $130^{\circ}C\;to\;180^{\circ}C$ in order to check the validity of the curing system used. A linear relationship between ln(ts2) and ln(t90) was found for all elastomers. The term sensitivity has been used to describe the relationship between a change of ts2 to the corresponding change of t90 due to an increment of temperature. This is related to the formula of the compound.

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A Study on the Development of ac Powder Electroluminescent Lamp (AC 구동 분산형 전장발광램프 개발에 관한 연구)

  • Kim, H.S.;Kim, E.D.;Kang, D.P.;Park, J.M.;Moon, S.I.;Kang, U.;Chun, B.D.
    • Proceedings of the KIEE Conference
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    • 1989.07a
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    • pp.306-309
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    • 1989
  • This paper describes the Manufacturing process and electrical properties of ac thick film electroluminescent lamps which made of the mixture of ZnS:Cu,Cl phosphor powder and polymer binding materials. The phosphor layer is sandwiched between two electrodes, one of which is transparent, and is supported by a substrate. The substrate may be glass or flexible plastic or it may be metallic. In this study we manufactured suspend layer which consists of ZnS:Cu,Cl powder suspended in a NBR. As yet our results are behind other commercial product in electrical properties and brightness. However they can be improved by selection of appropriate polymer binding materials, development of blending technology.

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Determination of Shock Absorption Performance and Shear Modulus of Rubbers by Drop Impact Test (낙하충격실험을 통한 고무의 충격흡수성능과 전단계수 평가)

  • Kang, Dong-Hwan;Seo, Mu-Yeol;Gimm, Hak-In;Kim, Tae-Won
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.33 no.4
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    • pp.321-328
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    • 2009
  • Shock absorption performances of various rubbers were investigated by using drop impact test. Several types of rubber such as NR, NBR, EPDM, SR and PUR with three respective levels of shore hardness were used for the test. As in the cases, the absorbed impact energies in rubbers were measured under seven different loads against impact energy between 5-80J. The impact absorption efficiencies of the rubbers then were evaluated by means of both single impact energy condition and summation of all impact energy applied condition. As shown in the results, PUR and EPDM have better shock absorption performances than other rubbers. Further analysis was extended to determine a shear modulus of SR through the finite element implementation with Blatz-Ko model. As can be seen, relatively higher level of absorption energy results in a decreasing shear modulus.

A Study on the Physical and Chemical Properties of Teat Cup Liners (유두컵 라이너의 물리화학적 특성 조사)

  • Lee Jeong-chi;Park Hyoung-ryun;Kim Myeong-seon;Lee Chung-gil;Lee Chai-yong
    • Journal of Veterinary Clinics
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    • v.22 no.2
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    • pp.100-107
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    • 2005
  • This study was carried out to investigate the physical and chemical properties of teat cup liners. The hardness of the liners was $50\~67$, and their fatigue to failure 38-1,185 cycles. The elongation and tensile strength of these liners were about $134 kgf/cm^2\;and\;473\%$, respectively. The infrared spectrum and the gas chromatogram revealed that the liner A was consisted of NR, SBR, and BR, with a composition ratio of 60:20:20 (part per hundred rubber). The raw rubber materials used for liners B to G, on the other hand, were NBR only. However, the liner H was made of silicon rubber. The thermogravimetric analysis showed that the liners tested in this study contained raw rubber material, carbon black, organic compounds and metallic compounds.

A Study on the Lifetime Prediction of Rubber Mount for Refrigerator Component (냉장고 압축기용 고무마운트 수명예측에 관한 연구)

  • Woo Chang-Su;Park Hyun-Sung
    • Journal of Applied Reliability
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    • v.6 no.2
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    • pp.135-150
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    • 2006
  • Rubber material properties and lifetime evaluation are very important in design procedure to assure the safety and reliability of the rubber components. This paper discusses the failure mechanism and material tests were carried out to predict the useful lifetime of NBR and EPDM for compression motor, which is used in refrigerator component. The heat-aging process leads not only to mechanical properties change but also to chemical structure change so called degradation. In order to investigate the aging effects on the material properties, the accelerated test were carried out. The stress-strain curves were plotted from the results of the tensile test for virgin and heat-aged rubber specimens. The rubber specimens were heat-aged in an oven at the temperature ranging from $70^{\circ}C\;to\;100^{\circ}C$ for a period ranging from 1 to 180 days. Compression set results changes as the threshold are used for assessment of the useful life and time to threshold value were plotted against reciprocal of absolute temperature to give the Arrhenius plot. By using the compression set test, several useful lifetime prediction equations for rubber material were proposed.

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Study on Properties and Accelerated Life-time Test of Rubber O-ring by Temperature Stress

  • Shin, Young-Ju;Kang, Bong-Sung;Chung, Yu-Kyung;Choi, Kil-Yeong;Shin, Sei-Moon
    • Proceedings of the Korean Reliability Society Conference
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    • 2006.05a
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    • pp.48-54
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    • 2006
  • In this thesis, accelerated life test (ALT) method and procedure for rubber O-ring are applied to assure specified reliability of the products at guaranteeing the life of the products. Rubber O-ring is parts that keep intensity or make machine operation smoothly on attrition portion of machine and is used to prevent that oil is leaked. Usually. Rubber O-ring used NBR that is copolymer of acrylonitrile and butadiene. this are superior oil resistance, heat resistance, durability of abrasion, cold resistance, chemical resistance etc. The accelerated life test model for rubber O-ring are developed using the relationship between stresses and life characteristics of products. Using the accelerated life test method and the acceleration life test equipment which is developed, we performed life test, collected life data and analyzed the results of tests. The proposed accelerated life test method and procedure may be extended and applied to testing similar kinds of products to reduce test times and costs of the tests remarkably.

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Anisotropic Conductive Film (ACF) Prepared from Epoxy/Rubber Resins and Its Fabrication and Reliability for LCD

  • Kim, Jin-Yeol;Kim, Eung-Ryul;Ihm, Dae-Woo
    • Journal of Information Display
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    • v.4 no.1
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    • pp.17-23
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    • 2003
  • A thermoset type anisotropic conductive adhesive film (ACAF) comprising epoxy resin and natural butyl rubber (NBR) as the binder, micro-encapsulated imidazole as the curing agent, and Ni/Au coated polymer bead as a conductive particle has been studied. These films have been prepared to respond to requirements such as improved contact resistance, current status less of than 60 ${\mu}m$ and reliability. These films can also be used for connection between the ITO glass for LCD panel and the flexible circuit board. The curing conditions for the connection were 40, 20 and 15 seconds at 150, 170 and 190 $^{\circ}C$, respectively. The initial contact resistance and adhesion strength were 0.5 ${\Omega}/square$ and 0.4 kg/cm under the condition of 30 kgf/$^{cm}^2}$, respectively. After completing one thousand thermal shock cycling tests between -15 $^{\circ}C$ and 100 $^{\circ}C$, the contact resistance was maintained below 0.7 ${\Omega}/square$. Durability against high temperature (80$^{\circ}C$) and high humidity (85 % RH) was also tested to confirm long-term stability (1000 hrs) of the conduction.

Development of Polymer Slip Tactile Sensor Using Relative Displacement of Separation Layer (분리층의 상대 변위를 이용한 고분자 미끄럼 촉각 센서 개발)

  • Kim, Sung-Joon;Choi, Jae-Young;Moon, Hyung-Pil;Choi, Hyouk-Ryeol;Koo, Ja-Choon
    • The Journal of Korea Robotics Society
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    • v.11 no.2
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    • pp.100-107
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    • 2016
  • To realize a robot hand interacting like a human hand, there are many tactile sensors sensing normal force, shear force, torque, shape, roughness and temperature. This sensing signal is essential to manipulate object accurately with robot hand. In particular, slip sensors make manipulation more accurate and breakless to object. Up to now several slip sensors were developed and applied to robot hand. Many of them used complicate algorithm and signal processing with vibration data. In this paper, we developed novel principle slip sensor using separation layer. These two layers are moved from each other when slip occur. Developed sensor can sense slip signal by measuring this relative displacement between two layers. Also our principle makes slip signal decoupled from normal force and shear force without other sensors. The sensor was fabricated using the NBR(acrylo-nitrile butadiene rubber) and the Ecoflex as substrate and a paper as dielectric. To verify our sensor, slip experiment and normal force decoupling test were conducted.