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Effect of Potassium Promoter on the Adsorption of Carbon Monoxide on Silica Supported Ruthenium

  • Lee, Jo-Woong;Chang, Sei-Hun;Pak, Hyung-Suk;Shin, Kook-Joe;Kim, Myung-Kun;Chung, Won-Il
    • Bulletin of the Korean Chemical Society
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    • v.9 no.3
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    • pp.137-143
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    • 1988
  • We have investigated the infrared spectra for carbon monoxide chemisorbed on silica supported ruthenium with and without potassium coating within the frequency range of 1800-2200 $cm^{-1}$ at various ruthenium concentrations and CO pressures. For the system without potassium coating, three bands were observed in the infrared spectra when CO was adsorbed on both the reduced and oxidized form of supported ruthenium. However, the relative intensities of these three bands were found to have no interdependence. Therefore, we have assigned each of these bands as arising from the CO stretching vibration for carbon monoxide molecules adsorbed on the Ru sites of different nature. On coating with potassium, the 2030 $cm^{-1}$ band observed for the system without potassium coating was found to suffer red shift by 10-30 $cm^{-1}$ and we conclude that this bathochromic shift is caused by enhancement in the capability of back donation of electrons from the metal atom to the antibonding ${\pi}{\ast}$ orbitals of CO due to the presence of potassium.

Evaluation of the Effects of Carbon Dioxide on the Production of Engineered Biochar (기능성 바이오차 생산을 위한 이산화탄소의 영향 평가)

  • Lee, Sangyoon;Lee, Taewoo;Kwon, E. Eilhann
    • Journal of Soil and Groundwater Environment
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    • v.27 no.2
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    • pp.41-49
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    • 2022
  • To abate the environmental burdens arising from CO2 emissions, biochar offers a strategic means to sequester carbons due to its recalcitrant nature. Also, biochar has a great potential for the use as carbon-based adsorbent because it is a porous material. As such, developing the surface properties of biochar increases a chance to produce biochar with great adsorption performance. Given that biochar is a byproduct in biomass pyrolysis, characteristics of biochar are contingent on pyrolysis operating parameters. In this respect, this work focused on the investigation of surface properties of biochar by controlling temperature and reaction medium in pyrolysis of pine sawdust as case study. In particular, CO2 was used as reaction medium in pyrolysis process. According to pyrolytic temperature, the surface properties of biochar were indeed developed by CO2. The biochar engineered by CO2 showed the improved capability on CO2 sorption. In addition, CO2 has an effect on energy recovery by enhancing syngas production. Thus, this study offers the functionality of CO2 for converting biomass into engineered biochar as carbon-based adsorbent for CO2 sorption while recovering energy as syngas.

Do Previous Promotion Awards Affect Current Decisions? Investigation of Intertemporal Correlations of Personnel Decisions

  • Kim, Jonghwan
    • Asia-Pacific Journal of Business
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    • v.11 no.4
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    • pp.1-19
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    • 2020
  • Purpose - This study analyzes the intertemporal patterns in personnel decisions made between a supervisor and a subordinate to understand potential supervisor bias in the decisions. A correlation between the current and the most recent personnel decisions made for a subordinate by a current supervisor captures certain relationship-embedded and time-invariant factors in effect. The characteristics speak to the nature of a supervisor bias arising from a relationship, or favoritism. Design/methodology/approach - This study manually collects the executive profile data from annual reports of key Samsung Group affiliates and compile a longitudinal sample of 3,675 executive-years. It mainly explores the logistic regression analysis. Findings - The study finds that a supervisor' previous promotion award to a subordinate does not improve but decreases the likelihood of promotions in ensuing years, suggesting the containment of favoritism; and that the time since the last promotion award to a subordinate by the current supervisor increases the likelihood of both promotions and dismissals of the subordinate. Research implications or Originality - The findings are generally consistent with the theory suggesting that incentive schemes that align interests between an individual and an organization will contain the form of a supervisor bias.

Comprehensive Mutation Analysis of PIK3CA, p14ARF, p16INK4a and p21Waf1/Cip1 Genes is Suggestive of a Non- Neoplastic Nature of Phenytoin Induced Gingival Overgrowth

  • Swamikannu, Bhuminathan;Kumar, Kishore S.;Jayesh, Raghavendra S.;Rajendran, Senthilnathan;Muthupalani, Rajendran Shanmugam;Ramanathan, Arvind
    • Asian Pacific Journal of Cancer Prevention
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    • v.14 no.5
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    • pp.2743-2746
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    • 2013
  • Background: Dilantin sodium (phenytoin) is an antiepileptic drug, which is routinely used to control generalized tonic clonic seizure and partial seizure episodes. A few case reports of oral squamous cell carcinomas arising from regions of phenytoin induced gingival overgrowth (GO), and overexpression of mitogenic factors and p53 have presented this condition as a pathology with potential to transform into malignancy. We recently investigated the genetic status of p53 and H-ras, which are known to be frequently mutated in Indian oral carcinomas in GO tissues and found them to only contain wild type sequences, which suggested a non-neoplastic nature of phenytoin induced GO. However, besides p53 and H-ras, other oncogenes and tumor suppressors such as PIK3CA, p14ARF, p16INK4a and $p21^{Waf1/Cip1}$, are frequently altered in oral squamous cell carcinoma, and hence are required to be analyzed in phenytoin induced GO tissues to be affirmative of its non-neoplastic nature. Methods: 100ng of chromosomal DNA isolated from twenty gingival overgrowth tissues were amplified with primers for exons 9 and 20 of PIK3CA, exons $1{\alpha}$, $1{\beta}$ and 2 of p16INK4a and p14ARF, and exon 2 of $p21^{Waf1/Cip1}$, in independent reactions. PCR amplicons were subsequently gel purified and eluted products were sequenced. Results: Sequencing analysis of the twenty samples of phenytoin induced gingival growth showed no mutations in the analyzed exons of PIK3CA, p14ARF, p16INK4a and $p21^{Waf1/Cip1}$. Conclusion: The present data indicate that the mutational alterations of genes, PIK3CA, p14ARF, p16INK4a and $p21^{Waf1/Cip1}$ that are frequently mutated in oral squamous cell carcinomas are rare in phenytoin induced gingival growth. Thus the findings provide further evidence that phenytoin induced gingival overgrowth as a non-neoplastic lesion, which may be considered as clinically significant given the fact that the epileptic patients are routinely administered with phenytoin for the rest of their lives to control seizure episodes.

Domestic Restrictions on the Opening of Retail Stores

  • Yoon, Myoung-kil;Kim, Yoo-oh;Lee, Min-kweon;Nam, Kung-sok
    • Journal of Distribution Science
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    • v.4 no.1
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    • pp.121-140
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    • 2006
  • This study has explored a number of problems arising from distribution restrictions and the ways to improve efficiency. As matters stand, since the cooperation between larger stores and local retailers is limited due to the nature of the market, the current situations call for bottom up restrictions such as the active promotion of smaller merchants and traditional marketplaces, the enhancement of the competitiveness of smaller merchants and manufacturers through the establishment of a customized consulting support program for individual shops, and the continual support for traditional marketplaces with facilities and management modernization. The government should maintain the optimal balance between the efficiency and effectiveness of the distribution industry through such bottom up restrictions as shown above, rather than the top down restrictions primarily relying on the hurdles to the establishment of stores. The problems raised in this study include: (i) the decline of traditional marketplaces and the alleged over saturation of stores; (ii) the possible abuse of indiscreet restrictive measures; (iii) the harmful effects of the monopoly or oligopoly by larger distributors; and (iv) the lack of systematic programs to promote development. The ways to improve efficiency are: (i) the establishment of the policies to specialize and nurture traditional marketplaces; (ii) the effort to prevent the injury arising from monopoly; (iii) the two tire strategies for the coexistence of larger and smaller businesses; and (iv) the administration of joint sales promotion and training.

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Seismic assessment of transfer plate high rise buildings

  • Su, R.K.L.;Chandler, A.M.;Li, J.H.;Lam, N.T.K.
    • Structural Engineering and Mechanics
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    • v.14 no.3
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    • pp.287-306
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    • 2002
  • The assessment of structural performance of transfer structures under potential seismic actions is presented. Various seismic assessment methodologies are used, with particular emphasis on the accurate modelling of the higher mode effects and the potential development of a soft storey effect in the mega-columns below the transfer plate (TP) level. Those methods include response spectrum analysis (RSA), manual calculation, pushover analysis (POA) and equivalent static load analysis (ESA). The capabilities and limitations of each method are highlighted. The paper aims, firstly, to determine the appropriate seismic assessment methodology for transfer structures using these different approaches, all of which can be undertaken with the resources generally available in a design office. Secondly, the paper highlights and discusses factors influencing the response behaviour of transfer structures, and finally provides a general indication of their seismic vulnerability. The representative Hong Kong building considered in this paper utilises a structural system with coupled shear walls and moment resisting portal-frames, above and below the TP, respectively. By adopting the wind load profile stipulated in the Code of Practice on Wind Effects: Hong Kong-1983, all the structural members are sized and detailed according to the British Standards BS8110 and the current local practices. The seismic displacement demand for the structure, when built on either rock or deep soil sites, was determined in a companion paper. The lateral load-displacement characteristic of the building, determined herein from manual calculation, has indicated that the poor ductility (brittle nature) of the mega-columns, due mainly to the high level of axial pre-compression as found from the analysis, cannot be effectively alleviated solely by increasing the quantity of confinement stirrups. The interstorey drift demands at lower and upper zones caused by seismic actions are found to be substantially higher than those arising from wind loads. The mega-columns supporting the TP and the coupling beams at higher zones are identified to be the most vulnerable components under seismic actions.

A Study on the Application of UNIDROIT Principles in International Commercial Transaction (국제상거래에서의 UNIDROIT원칙 적용에 관한 연구 - 국제물품매매계약에 관한 유엔협약(CISG)과의 비교를 중심으로 -)

  • Woo, Kwang-Myung
    • International Commerce and Information Review
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    • v.14 no.3
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    • pp.453-479
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    • 2012
  • The increase in international trade is clearly reflected by litigation and arbitration. Despite the importance of international commercial transaction, until very recently little was known about how the law interacts with actual practice. The CISG obviously plays an important role, but we are concerned with using choice of law to resolve issue that the CISG leaves unresolved. The case law UPICC is now accessible by means of UNILEX, the database on international case law that focus on CISG cases. The courts and arbitration tribunals throughout the world are developing a growing body of international case law on issues not resolved by the CISG, though arising from transactions to which the CISG applies. The application of the CISG is obligatory due to its nature as hard law an international convention. However, UPICC are only restatements and more flexibility, comprehensive instrument than CISG. This article offers to promote the UPICC application from their present status as a mere soft law instrument through analysing UNILEX cases.

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Collaborative Governance in Philippine Science and Technology Parks: A closer look at the UP - Ayala Land Technohub

  • Sale, Jonathan P.
    • World Technopolis Review
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    • v.4 no.1
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    • pp.23-32
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    • 2015
  • Public-private partnerships (PPPs) are very popular governance practices, as they enable the private partner to engage in business and have profits while the public partner improves the provision of public services. PPPs are organizational arrangements with a sector-crossing or sector-blurring nature, and are modes of governance - governance by partnerships or collaborative governance (Schuppert 2011). New models and applications of PPPs have been developed over time. Collaborative governance entails information exchange, action or movement harmonization, resource sharing, and capacity enhancement among the partners (Sale 2011; 2012a). As the national university, the University of the Philippines (UP) serves as a research university in various fields of expertise and specialization by conducting basic and applied research and development, and promoting research in various colleges and universities, and contributing to the dissemination and application of knowledge, among other purposes. (Republic Act 9500) It is the site of two (2) science and technology parks (Sale 2012b), one of which is the UP - Ayala Land Technohub. A collaboration between industry and the academe, the Technohub is envisioned as an integrated community of science and technology companies building a dynamic learning and entrepreneurial laboratory (UP-AyalaLand Technohub). This paper takes a closer look at the UP - Ayala Land Technohub as an example of a PPP or collaborative governance in science and technology parks. Have information exchange, action or movement harmonization, resource sharing, and capacity enhancement taken place in the Technohub? What are some significant outcomes of, and issues arising from, the PPP? What assessment indicators may be used? Is a governance instrument needed?

Nursing Considerations on Korean Shamanism (한국적 샤머니즘의 간호학적 고찰)

  • Kim, Ae-Ri
    • The Korean Nurse
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    • v.33 no.4
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    • pp.86-98
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    • 1994
  • We have examined the development and conceptual definition of shamanism and divination through significant characteristics of various illnesses. However, the terrminology has been inconsistent and its real conceptual meaning is not well defined. Divination is a historically dominant religious practice which represents the core of Korean folk culture. Despite prevalent prejudice toward its primitive nature, we cannot deny its profound relationship to our unconscious, especially our reliance on its religious role whenever we face crisis or conflict. It is therefore appropriate to use the term divination in this context. Shamanism originated as humanity's oldest mode of communication with divine - a religion, The shaman is not a sorceress but a priestess, a healer, a spritual guide, a leader, a mystic, traditionally having a different significance from that of the contemporary diviner or "shaman". The traditional concept of illness has been profoundly altered to serve new functions: while the shamanistic view is based upon spiritual abduction, divination on the other hand invokes concepts of spiritual invasion phenomena such as spirit intrusion, taboo violations, soul loss, object instrusion, deviations from the appropriate spiritual path besiegement, and curess or predestination (the idea that the sufferer is born with his fate), We should therefore try to understand divination from a more holistic point of view, rather than attempting to fit it into the standrd medical illness. We must recognize divination as a phenomenon within our culture, since most people have a mixed conception of illness arising from a combination of divinational and modem concepts, Since divination's humanistic approach is ingrained in our people, to irresponsibly ignore the spiritual aspects of treatment would exert a negative influence on our culture, Especially now, while attraction is focused on Korean culture and its influence on every aspect of our livies, it is important for nurses to expand our horizons in order to create a way of nursing more suitable to Korean culture. Increased importance is now being given to the opinions of patients themselves about their own illness and health, so nurses should seek to understand how patients accept their illness and what particular kinds of help they expect to receive. Consequently, an understanding of traditional divinations will enable us to utilize these characteristics on the job in order to enhance nursing care.

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A Study on Latent-gi by Yexiangyan "Wenrejingwei" ("온열경위(溫熱經緯)" 중(中) 섭향암(葉香巖)의 삼시복기외감(三時伏氣外感)에 관한 연구(硏究))

  • Ahn, Joon-Mo;Song, Ji-Chung;Jeong, Hyun-Jong;Keum, Kyung-Soo
    • Journal of the Korean Institute of Oriental Medical Informatics
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    • v.16 no.2
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    • pp.163-187
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    • 2010
  • The concept of latent-gi(伏氣) was first mentioned in Yellow Emperor's Canon of Internal Medicine. For example, Elementary Questions states, "Damage by cold in winter necessarily engenders warm disease in the spring." Zhang Zhong-Jing of Han Dynasty in On Cold Damage and Miscellaneous Diseases mentions warm disease, stating, for example, "Greater yang disease with heat effusion and cough and without aversion to cold is warm disease. If sweating is applied, and there is generalized heat, this is wind warmth." However, the concept of warm disease was not central to his systematic presentation of externally contracted disease which placed the emphasis on wind and cold as the major causes of these diseases. Zhang Zhong-Jing's theories centuries after in the Sung Dynasty were to become the focus of the cold damage school, whereas the concept of warm disease was to become the focus of a rival school, the warm disease school. In the Sui-Tang Period, The Origin and Indications of Disease mentions warm diseases, their causes, patterns, and major principles of treatment. Successive generations of doctors wrote about warm disease, and in the Ming Dynasty writings on the subject become more prolific. This development is attributable on the one hand to the opening up of the south of China where febrile diseases tended to be of a different nature than in the north, and on the other to pestilences arising as a result of wars. In this period, Wu You-Xing in On Warm Epidemics explained in detail the laws governing the origin, development and pattern identification of warm epidemics. Notably, he posed the etiological notion of a contagious perverse gi.

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