• Journal of Korean Society for Atmospheric Environment
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• v.16 no.3
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• pp.257-264
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• 2000

An aftertreatment device which reduce exhaust gas of natural gas vehicle(NGV), NGV catalyst has important meaning as to reduce the exhaust emission. In this study, the characteristics of NGV catalyst were investigated and the effect parameters of NGV catalyst were analyzed and were predicted by changing the various parameters such as temperature, and gas concentration. The conversion efficiency of NGV catalyst converter was also predicted by Pd-loading, mass flow rate and gas composition.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.22 no.2
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• pp.205-212
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• 1998

Experiments were conducted to investigate the temperature profile and the emissions conversion efficiency of catalytic converters for natural gas vehicles. Two types of the catalyst structure and several transient engine operating conditions were used. The dual-bed catalyst effectively reduced the emissions in a transient period due to the low heat capacity of the front bed. The lanthanoid additives were effective in improving catalyst durability. When the natural gas fueled engine were operated outside of a very narrow window of excess air ratio (from 0.993 to 1.004), the HC and NOx conversion efficiency dropped off. The drop-off were especially fast on the lean side of the window.

• Transactions of the Korean Society of Automotive Engineers
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• v.11 no.2
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• pp.134-139
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• 2003

This study was carried out to investigate the aging and conversion characteristics of oxidation catalysts for a natural gas vehicle with lean-bum system. The conversion of $CH_4$ was observed over the various composition ratio of PMs(Precious metals) and washcoating methods. On the fresh catalysts, Pd affected on the activity of $CH_4$ at low temperature more than other PMs in Pd-only and Rh/Pd/Pt catalysts. The activity at low temperature increased as a mount of Pd increases. On the aged catalysts, the $CH_4$ conversion efficiency of Pd-only catalyst with mono-layer washcoat decreased more than that of the other catalysts of $CH_4$ conversion. It was observed that the thermal durability of Rh/Pd/Pt catalysts with double-layer washcoat was better than the single washcoat catalyst.

• Transactions of the Korean Society of Automotive Engineers
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• v.10 no.3
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• pp.93-100
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• 2002

For natural gas and LPG fuel, measurements on the concentrations of individual exhaust hydrocarbon species have been made as a function of air-fuel ratio in a 2-liter four-cylinder engine using a gas chromatography. NMHC in addition to the species of HC, other emissions such as CO$_2$, CO and NOx were examined for natural gas and LPG at 1800rpm far two compression ratios (8.6 and 10.6). Fuel conversion efficiencies were also investigated together with emissions to study the effect of engine parameters on the combustion performances in gas engines especially under the lean bum conditions. It was found that CO$_2$ emission decreased with smaller C value of fuel, leaner mixture strength and the higher compression ratio. HC emissions from LPG engine consisted primarily of propane (larger 60%), ethylene and propylene, while main emissions from natural gas were mothane (larger than 60%), ethane, ethylene and propane on the average. The natural gas was proved to give the less ozone formation than LPG fuel. This was accomplished by reducing the emissions of propylene, which has relatively high MIR factor, and propane that originally has large portion of LPG. In addition, natural gas shows a benefit in other emissions (i.e. NMHC,NOx, CO$_2$and CO), SR and BSR values except fuel conversion efficiency.

• International Journal of Automotive Technology
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• v.6 no.6
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• pp.591-598
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• 2005

A three-way catalyst system of a natural gas vehicle (NGV) has characteristics of higher fuel consumption and higher thermal load than a lean-bum catalyst system. To meet stringent emission standards in the future, NGV with the lean-bum engine may need a catalyst system to reduce the amounts of HC, CO and NOx emission, although natural gas system has low emission characteristics. We conducted experiments to evaluate the conversion efficiency of the NOx reduction catalyst for the lean-burn natural gas engine. The NOx reduction catalysts were prepared with the ${\gamma}-Al_{2}O_3$ washcoat including Ba based on Pt, Pd and Rh precious metal. In the experiments, effective parameters were space velocity, spike duration of the rich condition, and the temperature of flowing model gas. From the results of the experiments, we found that the temperature for maximum NOx reduction was around $450^{\circ}C$, and the space velocity for optimum NOx reduction was around $30,000\;h^{-1}$ And we developed an evaluation model of the NOx reduction catalyst to evaluate the conversion performance of each other catalysts.

• Transactions of the Korean Society of Automotive Engineers
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• v.8 no.1
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• pp.92-100
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• 2000

The model gas reaction tests were carried out to investigate the purification characteristics of methane on the exclusive catalyst for NGV. The experiment was conducted with the factors which affect the conversion efficiency of methane, such as Redox ratio, coexistence components of CO, MO, $H_2$O, precious metals and additives. The catalyst loaded with larger amount of pd and with additive La showed lower light-off temperature. In the presence of CO and NO, the conversion efficiency of methane was varied according to the kind of additive loaded. The conversion efficiency of methane was dropped for the catalyst loaded with La under lean air-fuel ratio, while it increased for the one loaded with Ti+Zr for the same condition. It was shown that the water vapor inhibited methane from oxidation by its poisoning on the surface of catalyst.

• Transactions of the Korean hydrogen and new energy society
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• v.20 no.2
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• pp.151-160
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• 2009

Natural gas combustion characteristics of mass produced oxygen carrier particles were investigated in a batch type bubbling fluidized bed reactor. Five particles, NiO/bentonite, OCN601-650, OCN702-1100, OCN703-950, OCN703-1100 were used as oxygen carrier particles. Natural gas and air were used as reactants for reduction and oxidation, respectively. During reduction reaction, high fuel conversion and high $CO_2$ selectivity were achieved for most of oxygen carriers. During oxidation, NO emission was very low. These results indicate that inherent $CO_2$ separation and low NOx combustion are feasible for the natural gas fueled chemical-looping combustion system. Among the five oxygen carriers, OCN703-1100 particle was selected as the best candidate for demonstration of long-term operation in large-scale chemical-looping combustor from the viewpoints of fuel conversion, $CO_2$ selectivity, $CH_4$ concentration, and CO concentration.

• Transactions of the Korean Society of Automotive Engineers
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• v.13 no.3
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• pp.123-130
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• 2005

In this study, we evaluated the CH4 and CO conversion efficiencies over the oxidation catalysts for natural gas vehicle with lean-burn system. On the fresh catalyst, the conversion efficiency was increased when the loading of precious metal was increased. On the aged catalyst, the conversion efficiency was decreased as increasing the excess air ratio. We could confirm the measuring conversion efficiency of the unsteady state with the FTIR and that of steady state with the GC The temperature increasing ratio of unsteady state is acceptable from 3$^{\circ}C$/min. to 15$^{\circ}C$/min. for the evaluation of catalyst conversion performance , which has within the 4$\%$ of the difference of conversion efficiency. We observed a physical behavior of the thermal aged catalyst's surface using TEM and BET device. It was found that the precious metal was grown to the micro-scopic size by thermal aging process.

• Transactions of the Korean Society of Automotive Engineers
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• v.14 no.6
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• pp.73-81
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• 2006

A commercial diesel engine was converted into a dedicated natural gas engine to reduce the exhaust emissions in a retrofit of a diesel-fueled vehicle. The cylinder head and piston were remodeled into engine parts suited for a spark ignition engine using natural gas. The remodeling of the combustion chamber changed the compression ratio from 21.5 to 10.5. A multi-point port injection(MPI) system for a dedicated natural gas engine was also adopted to increase the engine power and torque through improved volumetric efficiency, to allow a rapid engine response to changes in throttle position, and to control the precise equivalence ratio during cold-start and engine warm-up. The performance and exhaust emissions of the retrofitted natural gas engine after remodeling a diesel engine are investigated. The emissions of the retrofitted natural gas engine were low enough to satisfy the limits for a transitional low emission vehicle(TLEV) in Korea. We concluded that a diesel engine can be effectively converted into a dedicated natural gas engine without any deterioration in engine performance or exhaust emissions.

• Journal of the Korean Institute of Gas
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• v.20 no.6
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• pp.95-101
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• 2016

For a natural gas steam reforming, comparative studies of the performance in a conventional packed-bed reactor and a membrane reactor, a new conceptual reactor consisting of a reactor with series of hydrogen separation membranes, have been performed. Based on experimental kinetics reported by Xu and Froment, a process simulation model was developed with Aspen $HYSYS^{(R)}$, a commercial process simulator, and effects of various operating conditions like temperature, $H_2$ permeance, and Ar sweep gas flow rate on the performance in a membrane reactor were investigated in terms of reactant conversion and $H_2$ yield enhancement showing improved $H_2$ yield and methane conversion in a membrane reactor. In addition, a preliminary cost estimation focusing on natural gas consumption to supply heat required for the system was carried out and feasibility of possible cost savings in a membrane reactor was assessed with a cost saving of 10.94% in a membrane reactor.