• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.47 no.6
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• pp.139-146
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• 2015

We manufactured natural dyed Korean traditional paper (Hanji) for cultural properties conservation and storage with goldthread (Coptis chinensis) and silver nitrate ($AgNO_3$). Goldthread and silver nitrate are known to be an excellent antimicrobial activity. The effect of content of goldthread and silver nitrate on properties of dyed Hanji was investigated. Color strength of dyed Hanji decreased with increasing content of silver nitrate. After-mordanting with 3% silver nitrate improved lightfastness of dyed Hanji. Tannic acid treatment increased K/S value of dyed Hanji. As the amount of the increase in goldthread content was reduced silver nitrate content. Sim-mordanting method was used for simplifying manufacture process. Silver nitrate sim-mordanting method increased K/S value of goldthread than after-mordanting method.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.47 no.5
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• pp.120-126
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• 2015

In this study, we used various dyes from natural pigments such as tumeric, goldthread, indigo, pagoda tree flower, sappanwood, and safflower to make the Hanji wallpaper with super eight colors of yellow, orange, green, turquoise, violet, red, blue, and magenta. As a result of measuring the lightfastness, magenta dyed with sappanwood showed the worst effect, but blue dyed with only indigo showed the best effect. In terms of the spot test by water, red wallpaper dyed with safflower showed the clear spot, but blue, turquoise, and green dyed with indigo resulted in a little spot. The orange, violet, and magenta dyed with goldthread and sappanwood showed antibacterial activity, and the turquoise, green, and blue also has a little antibacterial activity. However, yellow and red didn't show the some result as expected. In the experiment for efficiency of formaldehyde removal, all Hanji wallpapers dyed with natural pigments showed the significant removal effect of formaldehyde, especially turquoise and red were the highest.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.48 no.3
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• pp.80-90
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• 2016

The purpose of this study was to investigate the functional properties of natural dyed Hanji for cultural properties conservation and storage. To estimate functional properties of Hanji, antimicrobial, insect repellent test, and Oddy test were executed. Hanji dyed with 10% Golden thread (Coptis chinensis), a natural dye and silver nitrate mordanting showed the most excellent antifungal activities against A. niger, P. chrysogenum, and Trichoderma sp. before and after aging. The insects repellent test followed didn't indicate significant effects on treated Hanji against Lasioderma serricorne, Sitophilus zeamais, and Tribolium castaneum. According to Oddy test result, Hanji dyed with Golden thread and silver nitrate caused no significant corrosions on copper, silver, and lead after aging 28 days.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.35 no.1
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• pp.48-53
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• 2003

The objective of this study was to find in what color Korean handmade paper(Hanji) is dyed when it is dyed with a pigment extracted from waste onion peelings using different kinds of mordant, and how the paper is discolored and variety of strength under the condition of accelerated aging test. The results of this experiment are as follows. 1. Korean handmade paper was dyed in different colors according to the kinds of mordant. Mainly it was dyed in orange-brown, and sometimes in gold or khaki. 2. Korean handmade paper dyed was not discolored much, which suggests that the pigment is strong under the condition of aging. 3. As for durability, Korean handmade paper dyed in gold was strongest. Korean handmade paper, to which aluminum sulfate, iron sulfate or sodium dichromate was applied as mordant, had poor durability. Thus, these were not suitable as mordant.

• Journal of Conservation Science
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• v.30 no.2
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• pp.219-234
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• 2014

Fabrics, natural dyed fabrics, papers, natural dyed papers and paints were examined effects of colors and mechanical properties for materials of museum collections under anoxic treatment. Anoxic conditions using nitrogen and argon were oxygen concentration 0.01%, temperature($20^{\circ}C$, $25^{\circ}C$, $30^{\circ}C$), 50% RH and exposure time 30 days. Examined fabrics were raw silk fabric, UV irradiated raw silk fabric, degummed silk fabric, UV irradiated degummed silk fabric, cotton fabric, and UV irradiated cotton fabric. Natural dyed silk and cotton fabrics were dyed with fresh indigo, indigo, safflower, gromwell, madder sappanwood, amur cork tree, turmeric, gardenia, barberry root, pagoda tree flower, cochineal, lac, alnus japonica, gallnut, chestnut shell, and combination(indigo and safflower, indigo and amur cork tree, indigo and pagoda tree flower, indigo and sappanwood). Papers were Korean papers(mulberry paper, mulberry(70%) and rice straw(30%) mixed paper), Japanese paper(gampi paper), cotton paper, refined linen paper, cotton, linen & manila mixed fibre furnish, copy paper, news print, and alum sized mulberry paper. Natural dyed papers were dyed with indigo, sappanwood, madder, safflower, gardenia, amur cork tree, and pagoda tree flower. Paints were painted on alum-sized papers and silk fabrics using glue and pigments(azurite, malachite, cinnabar, vermilion, orpiment, gamboge, red lead, haematite, iron oxide red, indigo(lake), lac, cochineal, safflower, madder root lake, celadonite, smalt, ultramarine blue, lapis lazuli, prussian blue, kaolin, lead white, oyster-shell white, and clam-shell white). The color differences(${\Delta}E^*$) of all examined materials were below 1.5 or lowered than control samples after anoxic treatment. The variations of tenacity of yarns of fabrics and natural dyed fabrics after anoxic treatment were within that of standard silk and cotton fabrics. Gases(nitrogen and argon) and temperatures of anoxic treatment did not also affected color differences and variations of tenacity of materials.

• Journal of the Korean Society of Clothing and Textiles
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• v.24 no.5
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• pp.619-627
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• 2000

Historically, dyed textiles were symbols of status and, because of their expense, reserved only for people of wealth and specalist, Early dye sources probably included plant, animal and mineral extracts. As synthetic dyes have been developed, beginning with synthetic indigo in 1897, reliance on natural dye sources diminished. But renewed interest in natural dyes is fueled by a pro-environment consumer aware of the ecological liabilities of the dye industry. Han Jee was imported from China where it was influenced to period of the three kingdoms(Silla, Baekje, Kokuryo). After that, Han Jee was used for paper in old Korea for long thime before paper was came with civilization. In this paper, dyeing of Han Jee with loess were investigated according to dyeing temperature, dyeing time, loess concentration, and effects of additives. As a reuslts, λmax of Han Jee dyed by loess was 710nm. ΔE values of Han Jee increased by loess concentration, dyeing time, dyeing temperature. Dyeing with additives treatment increased dyeability. Especially, Han Jee treated with aluminium acetate shows the largest dyeability of the Han Jee. The Han Jee dyed loess had very good lightfastness.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.41 no.2
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• pp.40-46
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• 2009

The purpose of this study was to estimate natural dyeing properties of Korean traditional paper (Hanji). We dyed the Korean traditional paper with dyestuff which extracted from wood meal of Cotinus coggygria Scop (smoke tree) using hot-water, ethanol and $K_{2}CO_{3}$ solution. As mordants, 0.5% of $AlK(SO_4)_2$, $FeCl_2$, and $CuCH_3(COO)_2$ solution were used respectively. The color of dyed Hanji mainly depended on not the methods of extraction but the kinds of mordant. The dyed Hanji mordant with $AlK(SO_4)_2$ colored vivid yellow, $FeCl_2$ colored dark olive, and $CuCH_3(COO)_2$ colored brown and/or orange. The dyed Hanji with hot-water extractive had the highest K/S value and ethanol and $K_{2}CO_{3}$ solution extractives were followed. The K/S value of dyed Hanji mordant with $AlK(SO_4)_2$ was higher than that of $FeCl_2$ and $CuCH_3(COO)_2$. The dyeing effectiveness of after-mordanting method was superior to the others but sim-mordanting method was the worst.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.42 no.2
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• pp.82-87
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• 2010

The Hanji dyed with persimmon juice were useful goods in the past, but they are not widely used nowadays despite of their many strong points such as antibacterial and water-resistant properties. The object of this study is to provide useful data for developing new products by using them. We dyed traditional Korean hand-made papers (Hanji) with colorants extracted from fruits of Diospyros kaki and investigated the effect of various dyeing factors (mordant, mordanting method, pH of dyeing solution, light exposure time etc.) on optical and mechanical properties of the dyed Hanji. Changing mordant affected the color of dyed Hanji. The dyed Hanji after-mordanted with Cu mordant had the highest K/S value and showed the deepest yellow and red shade. The best mordanting method was an after-mordanting. The K/S value of dyed Hanji increased with decreasing pH of dyeing solution. The tensile index and size degree values of the Hanji were increased after dyeing.

• Journal of the Korean Society of Costume
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• v.28
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• pp.205-212
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• 1996

This paper is to study the characteristics of fabrics dyed with astringent unripe persimmon juice. The cotton silk rayon and nylon fabrics were dyed with astringet unripe persimmon juice. The structures of natural fabrics dyed fabrics and dyed fabrics followed by washing were examined by scanning electron mi-croscopy. Surface reflexibility of VIS trans-mittance of UV VIS and NIR were analyzed. The study conclues as follows: 1. Colour of cotton fabrics dyed with persim-mon juice became darkended as a function of exposing time to sunlight. That colour was chaged after washing. 2. Blocking effect of ultraciolet light and visible ray was increased in all dyed fabrics. Especially dyed cotton fabric blocked UV light perfectly and the blocking effect was still remained after 9 washings. 3. Persimmon juice dyeing produced coating effect to fabrics besides dyeing effect accord-ing to the scanning electron micrographs. In a word the cotton fabric dyed with per-simmon juice has blocking effect of UV light stiffness. Therefore I think persimmon juice dyeing is a very useful textile finishing and ex-pect a wide application of the technique in fu-ture.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.43 no.3
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• pp.88-97
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• 2011

We carried out cationization of Dak pulp (paper mulberry bast fiber pulp) which is raw material of Hanji (Traditional Korean Paper) using a (3-chloro-2-hydroxypropyl) trimethyl ammonium chloride to improve dyeability during a dyeing of Hanji with Gardenia (Gardenia jasminoides) and smoke tree (Cotinus coggygria). Fiber specific charge densities were determined using polyelectrolyte titration method and K/S values of dyed Hanji was calculated by Kubelka-Munk equation. As the result, fiber specific charge density increased with degree of cationization. Colors of Hanji dyed with Gardenia did not vary significantly with degree of cationization, but cationized Hanji dyed with smoke tree showed a large increase of a* value and reddish yellow color. After-mordanting did not decrease K/S value of dyes with cationized Hanji. K/S values of dyed Hanji decreased with increasing dyeing temperature. For smoke tree, the cationization impair lightfastness of dyed Hanji without mordant. After-mordanting with copper acetate or iron chloride improved lightfastness of dyed Hanji.