• Title/Summary/Keyword: Natural $^{15}N$

Search Result 595, Processing Time 0.026 seconds

Nitrate Concentration and ${\delta}^{15}N$ Value of the Groundwater in the Miyakojima Island, Okinawa Prefecture, Japan (일본(日本) 궁고도(宮古島)의 지하수중(地下水中)의 $NO_3-N$${\delta}^{15}N$치(値))

  • Park, Kwang-Lai;Kikuo, Kumazawa.
    • Korean Journal of Environmental Agriculture
    • /
    • v.14 no.1
    • /
    • pp.97-108
    • /
    • 1995
  • Nitrate concentration and ${\delta}^{15}N$ value in the groundwater in Miyakojima Island, Okinawa, were measured during 1992-1993. Water from the shallow and the deep wells at the ten separate sites were sampled. Mineral contents and natural nitrogen isotope abundance(${\delta}^{15}N$) were analyzed using a liquid chromatography and a mass spectrometry (Finnigan MAT 252). Except for waters which were directly influenced by sea water invasion, most of the groundwater showed small variations among their mineral contents and ${\delta}^{15}N$ values. The average nitrate nitrogen concentrations were $1.4{\sim}11.5mgL^{-1}$ and average ${\delta}^{15}N$ values were +4.3${\sim}$+9.7$%_o$. From the nitrate concentration and ${\delta}^{15}N$ value observed, the types of the groundwater could be categorized into four groups, such as high ${\delta}^{15}N$ and high nitrate, high ${\delta}^{15}N$ and medium nitrate, low ${\delta}^{15}N$ and medium nitrate, and low ${\delta}^{15}N$ and low nitrate, reflecting the main source of nitrate contamination, such as animal and domestic waste, animal waste and soil organic matter, soil organic matter and chemical fertilizer, and chemical fertilizer, respectively. It was discussed that the lowest ${\delta}^{15}N$ value was higher than the ${\delta}^{15}N$ value of the chemical fertilizers used in this island(-3.9${\sim}$-1.4$%_o$), then considerable amounts of nitrogen must be lost by ammonium evaporation or denitrification after fertilization.

  • PDF

Estimation of bioluminescence intensity of the dinoflagellates Noctiluca scintillans, Polykrikos kofoidii, and Alexandrium mediterraneum populations in Korean waters using cell abundance and water temperature

  • Sang Ah Park;Hae Jin Jeong;Jin Hee Ok;Hee Chang Kang;Ji Hyun You;Se Hee Eom;Yeong Du Yoo;Moo Joon Lee
    • ALGAE
    • /
    • v.39 no.1
    • /
    • pp.1-16
    • /
    • 2024
  • Many dinoflagellates produce bioluminescence. To estimate the intensity of bioluminescence produced by populations of the heterotrophic dinoflagellates Noctiluca scintillans and Polykrikos kofoidii and autotrophic dinoflagellate Alexandrium mediterraneum in Korean waters, we measured cellular bioluminescence intensity as a function of water temperature and calculated population bioluminescence intensity with cell abundances and water temperature. The mean 200-second-integrated bioluminescence intensity per cell (BLcell) of N. scintillans satiated with the chlorophyte Dunaliella salina decreased continuously with increasing water temperature from 5 to 25℃. However, the BLcell of P. kofoidii satiated with the mixotrophic dinoflagellate Alexandrium minutum continuously increased from 5 to 15℃ but decreased at temperatures exceeding this (to 30℃). Similarly, the BLcell of A. mediterraneum continuously increased from 10 to 20℃ but decreased between 20 and 30℃. The difference between highest and lowest BLcell of N. scintillans, P. kofoidii, and A. mediterraneum at the tested water temperatures was 3.5, 11.8, and 21.0 times, respectively, indicating that water temperature clearly affected BLcell. The highest estimated population bioluminescence intensity (BLpopul) of N. scintillans in Korean waters in 1998-2022 was 4.22 × 1013 relative light unit per liter (RLU L-1), which was 1,850 and 554,000 times greater than that of P. kofoidii and A. mediterraneum, respectively. This indicates that N. scintillans populations produced much brighter bioluminescence in Korean waters than the populations of P. kofoidii or A. mediterraneum.

Use of Bentonite and Organobentonite as Alternatives of Partial Substitution of Cement in Concrete Manufacturing

  • Lima-Guerra, D.J.;Mello, I.;Resende, R.;Silva, R.
    • International Journal of Concrete Structures and Materials
    • /
    • v.8 no.1
    • /
    • pp.15-26
    • /
    • 2014
  • In order to study the capacities of a new occurrence of Brazilian clay samples as partial replacements of cement, a bentonite sample was selected for utilization in the natural and modified forms for present study. The natural bentonite (BBT) was modified by anchorament of 3-aminopropyltrietoxisilane ($BBT_{APS}$) and 3,2-aminoethylaminopropyltrimetoxisilane (BBTAEAPS) in the surface of component minerals of bentonite sample. The original and organo-bentonite samples were characterized by elemental analysis, scanning electron microscopic and textural analyses. The values of micropore area were varying from $7.2m^2g^{-1}$ for the BBT to $12.3m^2g^{-1}$ for the $BBT_{AEAPS}$. The bentonite samples were characterized by the main variable proportion of bentonite in the natural and intercalated forms (2, 5, 10, 15, 20, 25, 30, and 35 % by weight of cement) in the replacement mode whiles the amount of cementations material. The workability, density of fresh concrete, and absorption of water decreased as the substitution of ordinary Portland cement by perceptual of natural and modified bentonite increased. The results reveal that workability decreased with decrease of the amount of natural bentonite in the concrete, same behavior is observed for bentonite functionalized, varying from 49 to 28 mm. The energetic influence of the interaction of calcium nitrate in the structure of blends was determined through the calorimetric titration procedure.

Structural Durability Analysis According to the Thickness of Bicycle Frame Tube (자전거 프레임 튜브 두께에 따른 구조적 내구성 해석)

  • Cho, Jae-Ung;Han, Moon-Sik
    • Journal of the Korean Society of Manufacturing Process Engineers
    • /
    • v.11 no.3
    • /
    • pp.122-129
    • /
    • 2012
  • This study investigates structural and vibration analyses according to the thickness of bicycle frame tube. The model of bicycle frame has the dimension as length of 862mm, width of 100mm and hight of 402.5mm. There are 3 kinds of models with tubes of top, down and seat at bicycle frame as thicknesses of 10, 15 and 20mm. The maximum displacement and stress occur at the center part of seat stay and at the installation part of rear wheel respectively. Maximum displacements become 0.031936, 0.029159 and 0.027984mm in cases of thicknesses of 10, 15 and 20mm respectively. In case of thickness of 20mm among 3 cases, maximum displacement becomes lowest. But maximum stresses become 10.019, 8.5492 and 9.2511MPa in cases of thicknesses of 10, 15 and 20mm respectively. In case of thickness of 15mm among 3 cases, maximum stress becomes lowest. There is no resonance at practical driving conditions and natural frequency remains almost unchanged along the change of thickness. In case of the displacement due to vibration mode, the displacement difference at thickness between 15mm and 20mm becomes 1/2 times than that between 10mm and 15mm. Design at bicycle frame tube becomes most economical and durable effectively in case of thickness of 15mm among 3 cases.

Syntheses and Characterization of Cr(III)-Hydrogensalicylato and -Hydroxonitrophenolato Tetraaza Macrocyclic Complexes

  • Byun, Jong-Chul;Yoon, Chang-Hoon;Mun, Dae-Hun;Kim, Ki-Ju;Park, Yu-Chul
    • Bulletin of the Korean Chemical Society
    • /
    • v.27 no.5
    • /
    • pp.687-693
    • /
    • 2006
  • Chromium(III) complexes, cis-[Cr([14]-decane)$(HOC _6H _4COO) _2$]$ClO _4$ I and cis-[Cr([14]-decane)(OH) $(OC _6H _4NO _2)$]$ClO _4{\cdot}H _2O$ II ([14]-decane = rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-teraazacyclotetradecane) are synthesized and structurally characterized by a combination of elemental analysis, conductivity, IR and VIS spectroscopy, and X-ray crystallography. The complexes crystallizes in the monoclinic space groups, $C2 _1$/a in I and $P2 _1$/n in II. Analysis of the crystal structure of complex I reveals that central chromium(III) ion has a distorted octahedral coordination environment and two hydrogensalicylato ligands are unidentate to the chromium(III) ion via the carboxyl groups in the cis-position. For monomeric complex I the hydrogensalicylato coordination geometry is as follows: Cr-O(average) = 1.984(3) $\AA$;Cr-N range = 2.105(3)-2.141(4) $\AA$;C(24)-O(4) = 1.286(5) $\AA$;N(2)-Cr-N(4) (equatorial position) = 96.97(15)${^{\circ}}$; N(1)-Cr-N(3) (axial position) = 168.27(15)${^{\circ}}$; O(1)-Cr-O(4) = 85.70(13)${^{\circ}}$. The crystal structure of II has indicated that chromium(III) ion is six-coordinated by four secondary amines of the macrocycle, hydroxide anion and nitrophenolate anion.

Studies on the Chromosomes of Fossaria truncatula (Muller) (Gastropoda : Lymnaeidae) (긴 애기물달팽이 (복족강 : 물달팽이과)의 염색체에 관한 연구)

  • Park, Gab-Man;Kim, Jae-Jin
    • The Korean Journal of Malacology
    • /
    • v.12 no.2
    • /
    • pp.141-145
    • /
    • 1996
  • 1996년 8월 춘천 의암호에서 채집한 긴애기물달팽이(Fossaria truncatula)를 재료로 공기건조법을 이용하여 통상적인 방법으로 염색체를 관찰하고 핵형을 분석하였다. 그 결과 긴애기물달팽이의 염색체 수는 2n=31, 32이었으며 15쌍의 배수체와 1개의 성염색체를 가지고 있었다. 핵형은 3쌍의 metacentric과 13쌍의 submetacentric 염색체로 구성되어 있었다.

  • PDF

CONVERGENCE OF PARALLEL MULTISPLITTING METHODS USING ILU FACTORIZATIONS

  • Yun, Jae-Heon;Oh, Se-Young;Kim, Eun-Heui
    • Journal of applied mathematics & informatics
    • /
    • v.15 no.1_2
    • /
    • pp.77-90
    • /
    • 2004
  • In this paper, we study the convergence of both relaxed multisplitting method and nonstationary two-stage multisplitting method associated with a multisplitting which is obtained from the ILU factorizations for solving a linear system whose coefficient matrix is an H-matrix. Also, parallel performance results of nonstaionary two-stage multisplitting method using ILU factorizations as inner splittings on the IBM p690 supercomputer are provided to analyze theoretical results.

Complexation of Pyridino-Azacrown Ethers with Alkali Metal Ions in N,N-Dimethylformamide (N,N-디메틸포롬아미드 용액에서의 알칼리금속이온과 피리디노-아자크라운에테르와의 착물화 반응)

  • Kim, Dong Won;Shin Young-Kook;Kim Chang Suk;Oh Je Jik;Jeon Young Shin;Kim, Tae Seung
    • Journal of the Korean Chemical Society
    • /
    • v.36 no.5
    • /
    • pp.669-673
    • /
    • 1992
  • The stability constants, K for the complexation of alkali metal cations(Li^+, Na^+, K^+, Rb^+, and Cs^+) with both 4,5: 13,14-dibenzo-6,9,12-triaza-bicyclo [15,3,1] heneicosa-1 (21),7,19-trioxa-2,16-dione (DBPDA) and 6,9,12-trioxa-3,15,21-triaza bicyclo [15,3,1] heneicosa-1 (21),17,19-triene-2,16-dione (PDA) in N,N-Dimethylformamide (DMF) were determined conductomatically at various temperatures. At all the experiment temperatures, the K value sequences of the alkali metal ions with DBPDA and PDA are Cs^+ > K^+ > Rb^+ > Li^+ > Na^+ and Cs^+ > K^+ > Rb^+ > Li^+ > Na+, respectively. The K values for DBPDA are larger those of PDA for alkali metal ions. The widely recounted "hole-size-selectivity" principle is not applicable to these complexation systems. From the K values obtained at different temperatures, {\delta}H and T{\delta}S for these complexation reactions were determined. The enthalpy change plays principal important role in the complex formation by DBPDA. However, in the case of PDA, the entropy change also contributes to its complex formation.

  • PDF

Seroprevalence of antibodies to Neospora caninum in dairy cattle raised in Kangwon province (강원도 사육 젖소의 네오스포라포자충(Neospora caninum)에 대한 항체양성률 조사)

  • Hwang, Eui-Kyung
    • Korean Journal of Veterinary Research
    • /
    • v.50 no.1
    • /
    • pp.19-24
    • /
    • 2010
  • This survey was carried out to investigate the seroprevalence of antibodies to Neospora (N.) caninum in dairy cattle raised in Kangwon province in Korea. A total of 349 sera collected from dairy cattle were tested for N. caninum antibodies using an indirect immunofluorescent antibody test (IFAT). Ninety six (27.5%) dairy cattle were positive by IFAT. Seroprevalence of cows was 28.9% (91/315) and seroprevalence of boars was 14.7% (5/34). The seroprevalences of cows were increased according to the ages from 19.6% in cows less than 2 year-old to 50.0% in cows more than 7 year-old. Among the seroprevalences of cattle according to the raised areas, five counties or cities, Wheongsung was 34.6% (27/78), Wonju was 29.3% (46/157), Hongcheon was 28.9% (13/45), Chuncheon was 15.0% (3/20) and Cheolwon was 13.3% (2/15). It was proved that dairy cattle raised in Kangwon provinces exposed extensively and seriously to N. caninum.

Effects of compound traditional Astragalus and Salvia Miltiorrhiza extract on acute and chronic hepatic injury

  • Zhang, Xiaoxiang;Yang, Yan;Liu, Xin;Wu, Chao;Chen, Minzhu
    • CELLMED
    • /
    • v.3 no.2
    • /
    • pp.15.1-15.5
    • /
    • 2013
  • Previous reports showed that Compound Astragalus and Salvia miltiorrhiza extract (CASE), which was mainly composed of astragalosides, astragalus polysaccharide and salvianolic acids, inhibited hepatic fibrosis by mediating transforming growth factor-${\beta}$ (TGF-${\beta}$)/Smad signaling. Our aim was to examine the effects of CASE on D-galactosamine (D-GalN) treated liver injury in mice and carbon tetrachloride ($CCl_4$)-induced liver fibrosis in rats. CASE was administered to mice with D-GalN-induced liver injury and to rats with $CCl_4$-induced liver fibrosis, respectively. Liver injury was routinely evaluated by relative liver weight, serum levels of ALT, AST, hyaluronic acid (HA), hepatic malondialdehyde (MDA) content, superoxide dismutase (SOD) activity, hydroxyproline (HYP) and histopathologic changes. Treatment of mice with CASE (60, 120, and 240 mg/kg, ig) significantly lowered ALT, relative liver weight, and MDA levels when compared with D-GalN treated mice. CASE (120, 240 mg/kg) significantly lowered ALT, AST, HA, HYP, and MDA levels against $CCl_4$ treated rats. Decreased SOD level was reversed with CASE treatment. Upon histopathological examination, CASE treatment had significantly inhibitory effect on the progression of hepatic fibrosis in rats. These results indicate that CASE might be effective in treatment and prevention of acute and chronic hepatic injury due to its antioxidant activity.