• Nuclear Engineering and Technology
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• v.54 no.12
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• pp.4514-4521
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• 2022

In this study, the effects of heat and radiation on the degradation behaviour of fluoroelastomer under simulated normal operation and a severe accident environment were investigated using sequential testing of gamma irradiation and thermal degradation. Tensile properties and Shore A hardness were measured, and thermogravimetric analysis was used to evaluate the degradation behaviour of fluoroelastomer. Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy were used to characterize the structural changes of the fluoroelastomer. Heat and radiation generated in nuclear power plant break and deform the chemical bonds, and fluoroelastomer exposed to these environments have decreased C-H and functional groups that contain oxygen and double bonds such as C-O, C=O and C=C were generated. These functional groups were formed by auto oxidation by reacting free radicals generated from the cleaved bond with oxygen in the atmosphere. In this auto oxidation reaction, crosslinks were generated where bonded to each other, and the mobility of molecules was decreased, and as a result, the fluoroelastomer was hardened. This hardening behaviour occurred more significantly in the severe accident environment than in the normal operation condition, and it was found that thermal stability decreased with the generation of unstable structures by crosslinking.

• Korean Journal of Environmental Agriculture
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• v.31 no.1
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• pp.37-44
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• 2012

BACKGROUND: Many edible mushrooms are known to accumulate high levels of heavy metals. This research was focused on health risk assessment to investigate the mushrooms in Korea, arsenic (As), cadmium (Cd), lead (Pb) and mercury (Hg) contaminations in edible mushrooms in cultivated areas were investigated, and health risk was assessed through dietary intake of mushrooms. METHODS AND RESULTS: The heavy metals in mushrooms were analyzed by ICP/MS after acid digestion. Probabilistic health risk were estimated by Monte-Carlo simulation techniques. The average contents of As, Cd, Pb, and Hg were $0.035{\pm}0.042$ mg/kg, $0.017{\pm}0.020$ mg/kg, $0.043{\pm}0.013$ mg/kg, and $0.004{\pm}0.004$ mg/kg, respectively. The results showed that contents of Cd and Pb did not exceed maximum residual levels established by European Uion regulation (Cd 0.20 mg/kg and Pb 0.30 mg/kg). For health risk assessment, estimated intakes in all age populations did not exceed the provisional tolerable daily intake of As and Hg, provisional tolerable monthly intake of Cd, provisional tolerable weekly intake of Pb. The Hazard Index (HI) were ranged from $0.03{\times}10^{-4}{\sim}0.01{\times}10^{-3}$ for As, $0.02{\times}10^{-3}{\sim}0.81{\times}10^{-3}$ for Cd, $0.06{\times}10^{-3}{\sim}0.38{\times}10^{-3}$ for Pb, and $0.08{\times}10^{-4}{\sim}0.14{\times}10^{-3}$ for Hg at general population. CONCLUSION: The HI from the ratio analysis between daily exposure and safety level values was less than 1.0. This results demonstrated that human exposure to heavy metals through dietary intake of mushrooms might not cause adverse effect.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.55 no.6
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• pp.836-843
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• 2022

In the present study, exposure to heavy metals by consumption of edible seaweeds (green laver, laver, hijiki, sea tangle, and sea mustard) was assessed based on their concentrations of lead (Pb), cadmium (Cd), arsenic (As), and mercury (Hg). The mean of heavy metal concentrations were 0.006-0.023 mg/kg for Pb, 0.037-0.156 mg/kg for Cd, 1.117-15.928 mg/kg for As, and 0.008-0.021 mg/kg for Hg. In multivariate analysis, the correlations were high between Pb levels in sea mustard, Cb levels in laver, and As and Hg level in Hijiki. However, the estimated daily intake and target hazard quotient (THQ) of the heavy metals in edible seaweeds were below their approved limits suggesting no health risks associated with seaweed consumption by Koreans.

• Journal of the Korean Institute of Gas
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• v.4 no.4 s.12
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• pp.50-57
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• 2000

Past accidents have shown that vapor cloud explosions are the predominant cause of the largest losses in the chemical and petrochemical industries due to the generation of significant overpressures. Prediction of such overpressure is of great concern and a knowledge of the likely overpressure is needed for the design of equipment, safety cases and emergency planning. For these reasons, risk assessment for vapor cloud explosion is crucial and this assessment can be carried out using the different models including TNT-Equivalency, TNO Hemispherical, TNO Multi-Energy and CFD models. Accordingly, in this paper, the published VCE prediction models are reviewed to provide a critical comparison of the different models used for the quantification of explosion hazards, in terms of the fundamental assumptions employed, and their predictive accuracy

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2004.04a
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• pp.189-195
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• 2004

Recently, bridge design and／or construction works on marine traffic route are undertaking in Korean waters. Naturally the ship-handling difficulty and hazardous to navigation should be increased when the bridge is constructed on the shipping route. Unfortunately, however, it is impossible or not desirable to secure wide enough bridge span width due to geographical condition or economic point of view. Therefore this study aims to propose the consideration factors during the bridge design process, and the traffic volume control, speed limit and other alternative measures to secure traffic safety using marine traffic flow simulation technique.

• Journal of the Korean Society of Safety
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• v.22 no.3 s.81
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• pp.57-64
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• 2007

Recently, the corrosion of concrete structures has received great attention related with the deterioration of sea-side structures, such as new airport, bridges, and nuclear power plants. In this regards, many studies have been done on the chloride attack in concrete structures. However, those studies were confined mostly to the single deterioration due to chloride only, although actual environment is rather of combined type. The purpose of the present study is, therefore, to explore the influences of carbonation and freezing-thawing action to chloride attack in concrete structures. The test results indicate that the chloride penetration is more pronounced than the case of single chloride attack when the carbonation process is combined with the chloride attack. It is supposed that the chloride ion concentration of carbonation region is higher than the sound region because of the separation of fixed salts. Though the use of fly ash pronounces the chloride ion concentration in surface, amounts of chloride ion penetration into deep region decreases with the use of fly ash. The small reduction of relative dynamic elastic modulus induced from freezing-thawing increases the chloride ion penetration depths much. The present study allows more realistic assessment of durability for such concrete structures which are subjected to combined attacks of both chlorides and carbonation or freezing-thawing but the future studies for combined environment will assure the precise assessment.

• Steel and Composite Structures
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• v.9 no.5
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• pp.457-471
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• 2009

This study investigates the role of accidental torsion in seismic reliability assessment. The analyzed structures are regular 6-story and 20-story steel office buildings. The eccentricity in a floor plan was simulated by shifting the mass from the centroid by 5% of the dimension normal to earthquake shaking. The eccentricity along building heights was replicated by Latin hypercube sampling. The fragilities for immediate occupancy and life safety were evaluated using 0.7% and 2.5% inter-story drift limits. Two limit-state probabilities and the corresponding earthquake intensities were compared. The effect of ignoring accidental torsion and the use of code accidental eccentricity were also assessed. The results show that accidental torsion may influence differently the structural reliability and limit-state PGAs. In terms of structural reliability, significant differences in the probability of failure are obtained depending on whether accidental torsion is considered or not. In terms of limit-state PGAs, accidental torsion does not have a significant effect. In detail, ignoring accidental torsion leads to underestimates in low-rise buildings and at small drift limits. On the other hand, the use of code accidental eccentricity gives conservative estimates, especially in high-rise buildings at small drift limits.

• Journal of Dairy Science and Biotechnology
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• v.29 no.2
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• pp.59-68
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• 2011

In Korea, there are a couple of risk assessment organizations: The Animal Plant and Fisheries Quarantine and Inspection Agency(QIA) and the Korea Food and Drug Administration (KFDA). The major food laws include the Food Sanitation Act (FSA), the Livestock Product Processing Act (LPPA), and the Agricultural Products Quality Control Act (APQCA). Milk and dairy products are mostly controlled by the Food Sanitation Act and the Livestock Product Processing Act. This study was carried out to estimate the current standard methods of foodborne pathogens for dairy products, comparing the Livestock Products Processing Act with the Food Sanitation Act. The standard methods of foodborne pathogens for dairy products are composed by growth culture, isolation culture, and identification, however, standard methods of QIA and KFDA are different at the using of medium and inspection stage. Therefore, consolidation of risk management and risk assessment methods are regarded important to provide safe dairy products to consumer.

• Journal of the Korean Society of Marine Environment & Safety
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• v.15 no.4
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• pp.345-354
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• 2009

The review of statements and coastal development characteristics in South Korea were diagnosed by the consultation on the coastal area utilization in Korea. The occupation and the use of public water were dominated by installation of coastal structure and seawater supply and drainage whereas the reclamation areas were predominantly utilized for developing industrial complex, harbor, fishing port and road. The occupation and the use were dominant in western coast, but reclamation was dominant in southern coast of Korea. The number of utilization cases was particularly greater in Jeonnam, Gyeongnam, and Gyeonggi Province including Incheon. The number of the statements reviews increased by more than 200 cases in 2008 compared with 2007, and most of them were the simple statements. The statements related to ocean disposal of dredged sediment, reclamation, dredging sediment, seawater supply and drainage, and marine sand mining were submitted for review. Coastal utilization was especially active in the regions of seawater quality criteria I and II. In particular, special management sea areas designated under the relevant marine regulations were utilized mostly by reclamation for developing harbor, fishing port and coastal structure. Development activities in national parks comprised primarily structure installation and coastal maintenance. In the fisheries resources protection areas, 40% of the total cases accounted for coastal maintenance, 31% for structure installation, and 16% for seawater supply and drainage. In addition, alternative plans for the improvement in policies and system of marine environmental impact assessment were suggested to enhance the function and confidence of the consultation on the coastal area utilization in Korea.

• Journal of the Korean Society of Marine Environment & Safety
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• v.21 no.2
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• pp.130-139
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• 2015

To assess the noise stress of shrimp farms reasonably, we need a noise observation data underneath the waters first. But, it did not collect yet and airborne noise transfers to water noise wave using transition calculation. In case of construction of solar energy without noise stress protection wall, the threshold values (140 dB) from circumstance of underwater noise exceed within 17m at $S_2$ (15m away from source) and $S_3$ (15m away from source). Considering additional way to decrease the construction noise, all cases including minimum mode(Case A), general mode(Case B), and maximum mode(Case C) meet the guideline of underwater noise for fish farms. In case of the underwater noise could affect the fish farm, it is necessary to understand about farming species such as shrimp, monitoring of present states, and protection way under the construction.