• 제목/요약/키워드: Naphthylene Central Unit

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Synthesis and Mesomorphic Properties of Banana-Shaped Mesogens with All-Ester Linking Group

  • Choi, E-Joon;Cui, Xin;Zin, Wang-Choel;Ohk, Chang-Woo;Lim, Tong-Kun;Lee, Ji-Hoon;Kim, Young-Chul;Paek, Sang-Hyon
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권1호
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    • pp.197-199
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    • 2007
  • Four banana-shaped compounds have beene synthesized introducing ester linking group into mesogenic unit, varying the central core with 1,6-, 1,7-, 2,3-, and 2,7-naphthylene units, and introducing the dodecyloxy group as the terminal flexible unit. All obtained compounds except one with 1,7-naphthylene unit were reversibly thermotropically liquid crystalline. The compound with 1,7-naphthylene unit could not form the mesophase due to its asymmetrical and sharp substitution angle. The compounds with 1,6- and 2,3-naphthylene units showed an antiferroelectric switchable smectic phase, which has been designated B2 phase. Interestingly, the compound with the 2,3-naphthylene unit showed the two mesophases of B2 and nematic phase.

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Biaxial Nematic Phase Derived From Banana-Shaped Molecules Containing Naphthylene Central Unit

  • Seo, Young-Ho;Choi, E-Joon;Park, Sang-Byung;Zin, Wang-Cheol
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.330-332
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    • 2008
  • Banana-shaped molecules were synthesized introducing ester linking group into mesogenic unit, varying the central unit with 1,6-, 2,3-naphthylenes, and introducing the hexyloxy group as the terminal flexible unit. The properties of the compounds were characterized by FT-IR, NMR spectroscopy, DSC, polarizing optical microscopy, and X-ray diffractometry.

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Synthesis and Properties of Polyesters with Bent-Shaped Mesogens Containing Naphthalene Central Unit

  • Seo, Young-Ho;Choi, E-Joon
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.633-636
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    • 2009
  • New polyesters with bent-shaped mesogens were synthesized varying the central unit with 1,6- and 2,3- naphthylenes, and introducing the dodecamethylene flexible spacer. The mesogenic properties of the polymers were characterized by FT-IR spectroscopy, DSC, polarizing optical microscopy.

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Chiral Mesophase Derived from Achiral Polymers with Banana-Shaped Mesogens and Their Model Compounds

  • Choi, E-Joon;Kim, Eun-Chul;Kwon, Myung-Hun;Zin, Wang-Cheol;Kim, Young-Chul;Paek, Sang-Hyon
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.242-243
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    • 2006
  • In this work, we report the synthesis and characterization of azomethineester polymers that consist of banana-shaped mesogen in their backbone. Two parts of the key structure of five-ring bent-core mesogen were modified by connecting different angle of central unit (Ar), and introducing lateral substituent into the outer ring (X). The synthetic details includes (1) placing the dioxydodecamethylene unit as a flexible spacer, (2) possessing 2,3- or 2,7-naphthylene, or 1,2-phenylene connection on the central unit, and (3) introducing fluorine or chlorine substituent (X = F or Cl) into the outer phenylene unit.

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Synthesis and Mesomorphism of Polymers with Banana-Shaped Mesogens in the Main Chain

  • Choi, E-Joon;Zin, Wang-Cheol;Kim, Young-Chul;Paek, Sang-Hyon;Chien, Liang-Chy;Samulski, Edward T.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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    • pp.171-174
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    • 2006
  • In this work, we report the synthesis and characterization of azomethine-ester polymers that consist of banana-shaped mesogen in their backbone. Two parts of the key structure of five-ring bent-core mesogen were modified by connecting different angle of central unit (Ar), and introducing lateral substituent into the outer ring (X). The synthetic details includes (1) placing the dioxydodecamethylene unit as a flexible spacer, (2) possessing 2,3- or 2,7-naphthylene, or 1,2-phenylene connection on the central unit, and (3) introducing fluorine or chlorine substituent (X = F or Cl) into the outer phenylene unit.

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