• 한국전기전자재료학회논문지
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• 제29권9호
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• pp.565-570
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• 2016

In this work, the complex permittivity of epoxy resins is measured. Epoxy resins, epoxy with micro size fillers and epoxy with micro+nano alumina composites have been evaluated for dielectric properties according to frequency variation. The dielectric spectroscopy measurement and analyses are carried out in the frequency range of $10^{-2}Hz$ to 1MHz and constant to room temperature. The results of dielectric loss suggest that significant improvement in the electrical performance can be expected by using samples containing nano and micro fillers mixture when compared to materials containing only microfillers. As the result, we verified the specific characteristics of dielectric permittivity and dielectric loss namely, relative permittivity become low with improving dispersibility of nano+micro mixture composites and become rise with agglomerate of nano particles.

• 대한화학회지
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• 제60권5호
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• pp.299-309
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• 2016

In this study, the physicochemical and electrochemical properties of carbon nanomaterials and synthesized nano-carbon/Si composites were studied. The nano-carbon/Si composites were ball-milled to a nano size and coated with pyrolytic carbon using Chemical Vapor Deposition (CVD). They were then finely mixed with respective nano-carbon materials. The physicochemical properties of samples were analyzed using Scanning Electron Microscopy (SEM), Energy Dispersive X-ray Spectroscopy (EDS), Raman spectroscopy, X-ray Diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS), and surface area analyzer. The electrochemical characteristics were investigated using the galvanostatic charge-discharge and cyclic voltammetry (CV) measurements. Three-electrode cells were fabricated using the carbon nanomaterials and nano-carbon/Si composites as anode materials and LiPF₆ and LiClO₄ as electrolytes of Li secondary batteries. Reversibility using LiClO₄ as an electrolyte was superior to that of LiPF₆ as the electrolyte. The initial discharge capacities of nano-carbon/Si composites were increased compared to the initial discharge capacities of nano-carbon materials.

• Transactions on Electrical and Electronic Materials
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• 제13권1호
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• pp.31-34
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• 2012

The addition of nano/micro silica into unsaturated polyester resin (UPR) results in the improvement of the electrical properties of Silica-UPR composites. The surface, volume resistivity, dielectric strength, dissipation factor and dry arc resistivity of nano silica-UPR composites were found to improve significantly. The effects of the nano and micro fillers in UPR have been evaluated. They are presented in this paper. To evaluate the electrical properties of the nano & micro composites, all the measurements were done as per the prescribed methods in ASTM. It was observed that the addition of nano silica improves the electrical properties as compared to micro silica. The better dispersion of silica particles in unsaturated polyester resin enhances the electrical properties of silica-UPR composites.

• 한국항공우주학회지
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• 제30권5호
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• pp.88-93
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• 2002

본 연구의 목적은 epoxy를 기지로 하고 $Fe_2O_3$ 나노 입자 포함하는 나노 복합재료의 특성에 미치는 나노입자의 영향을 알아보는데 있다. 이를 위하여 다음과 같은 연구가 이루어졌다. 나노 입자의 수지 내에서 최적 분산 기법, 나노 입자가 수지의 점성에 미치는 영향, 나노 입자의 조성비에 대한 나노 복합재료의 기계적 특성 변화 및 나노 복합재료의 다기능성에 대하여 조사를 하였다. 나노 입자의 분산을 위하여 초음파 가진을 사용하였으며 최적 분산을 위한 최적 초음파 가진 시간이 존재하며 초음파 외에도 기계적 교반이 필요함을 알 수 있었다. 첨가된 나노입자의 양에 따른 기계적 물성치의 변화를 알아보았다.

• 한국분말재료학회지
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• 제13권2호
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• pp.144-149
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• 2006

In this research we tried to make nano-sized TiNx by using planetary milling, and we made the composites double layered of titanium and nano-sized TiNx by using spark plasma sintering apparatus after mixing with the different ratio of pure titanium powder, and they were heat treated at $850^{\circ}C$ for 30 minutes. The crystal structures of nano-sized TiNx powders and the composites were analyzed by X-ray diffraction (XRD). The microstructures of the powders were analyzed by using scanning electron microscopy (FESEM) and the 40-50 nm size of nano-sized TiNx particle on the surface of agglomerated particles was investigated. With increasing the ratio of nano-sized TiNx of the composites, the microvickers hardness of the composites was increased.

• 한국분말재료학회지
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• 제8권3호
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• pp.210-213
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• 2001

$Si_3N_4$/TiN nano/nano-type composites were successfully fabricated by the combination of a mechano-chemical grinding (MCG) method and a short time sintering process, and their wear resistance was evaluated. Powder mixtures of $\alpha-Si_3N_4$and Ti were prepared using mechano-chemical grinding process and the resulting nanocomposite powder mixtures were consolidated using pulsed electric current sintering (PECS). TEM observation showed that the nano/nano-type composites consisted of homogeneous and very fine matrix grains with the size less than 100 nm. The obtained $Si_3N_4$-based nano/nano-type showed high wear resistance and electric discharge machinability.

• 한국정밀공학회지
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• 제22권10호
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• pp.121-128
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• 2005

The research on electromagnetic shielding has been advanced for military applications as well as for commercial products. Utilizing the reflective properties and absorptive properties of shielding material, the replied signal measured at the rear surface or at the signal source can be minimized. The shielding effect was obtained from materials having special absorptive properties and structural characteristics such as stacking sequence. Recently researchers studied the electromagnetic properties of nano size particles. In this research {glass fiber}/{epoxy}/{nano particle} composites(GFR-Nano composites) was fabricated using various nano particles, and their properties in electromagnetic shielding were compared. For the visual observation of the nano composite materials, SEM(Scanning Electron Microscope) and TEM(Transmission Electron Microscope) were used. For the measurement of electromagnetic shielding, HP8719ES S-parameter Vector Network Analyser System was used on the frequency range of 8 GHz${\~}$12GHz. Among the nano particles, carbon black and Multi-Walled Carbon Nano-Tube (MWCNT) revealed outstanding electromagnetic shielding. Although silver nano particles (flake and powder) were expected to have effective electromagnetic shielding due to their excellent electric conductivities, test results showed little shielding characteristics.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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• pp.465-467
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• 2004

We presented a systematic investigation on the growth of CNTs including SWNTs on nano-catalyst-embedded particles by PECVD. For CNTs growth, the mixture of $C_2H_2$ and $NH_3$ was used. The total pressure and temperature were kept at 3.25 Torr and 650 $^{\circ}C$, respectively. Finally, we measured the field emission property from CNTs grown from nano-catalyst embedded zeolite particles in vacuum chamber (<$10^{-7}$ Torr).

• 대한기계학회논문집A
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• 제28권10호
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• pp.1534-1540
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• 2004

This study aims to obtain fundamental understandings involving the manufacturing processes of nano-composites with chemically surface-modified multi-walled carbon nanotubes(MWCNTs), and explore the role of functionalized MWCNTs in the epoxy/MWCNT composites. For this purpose, MWCNTs were purified by the thermo-chemical oxidation process, and incorporated into an epoxy matrix by in situ polymerization process, the surface of MWCNTs were functionalized with carboxyl functions which were demonstrated by an infrared spectroscopy. The mechanical properties of epoxy/MWCNT nano-composites were measured to investigate the role of a chemically functionalized carbon nanotubes. To improve the dispersion quality of MWCNTs in the epoxy matrix, methanol and acetone were exploited as dispersion media with sonification. The epoxy/MWCNT nano-composites with 1 or 2 wt.％ addition of functionalized carbon nanotubes show an improved tensile strength and wear resistance in comparison with pure epoxy, which shows the mechanical load transfer improves through chemical bonds between epoxy and functionalized MWCNTs. The tensile strength with 7 wt.％ functionalized MWCNTs increases by 28％ and the wear resistance is dramatically improved by 100 times.

• 대한금속재료학회지
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• 제50권2호
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• pp.93-99
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• 2012

The mechanical properties of nano composites were evaluated for structural performance in order to enhance their applicability to the car and machine industrial fields. Carbon fiber reinforced plastics (CFRP) and GFRP were manufactured by vacuum-assisted resin transfer molding (VARTM) process with good mechanical properties. Tensile test was conducted to obtain the process factor of each composite. Also, carbon nano fiber (CNF) was dispersed in the composites and the relationship between the mechanical property and the CNF fraction was compared. The tensile strength and stiffness of 0/90 laminated CFRP were the best. CFRP/CNF (0.5 wt.%) was confirmed to be an excellent material for its elasticity and tensile strength.