• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
• /
• pp.801-804
• /
• 2002

Electrochemical capacitors are becoming attractive energy storage systems particularly for applications involving high power requirements such as hybrid systems consisting of batteries and electrochemical capacitors for electric vehicle propulsion. Both of amorphous cobalt oxide and manganese dioxide were prepared by sol-gel process reported in our previous work. Nanostructured supramolecular oligomer of 1,5-diaminoanthraquinone(DAAQ) coated metal oxides were successfully prepared by electrochemical oxidation from an acidic non-aqueous medium. We established process parameters of the technique for the formation of nano-structured materials. Furthermore, improved the capacitive properties of the nano structured metal oxide electrodes using controlled solution chemistry. $CoO_2$ and $MnO_2$-based composite electrode showed relatively good electrochemical behaviors in acidic electrolyte system with respect to specific capacity and scan rate dependency.

• Journal of Electrochemical Science and Technology
• /
• 제7권1호
• /
• pp.1-12
• /
• 2016

The production of oxygen and hydrogen from solar water splitting has been considered to be an ultimate solution for energy and environmental issues, and over the past few years, nano-sized semiconducting metal oxides alone and with graphene have been shown to have great promise for use in photocatalytic water splitting. It is challenging to find ideal materials for photoelectrochemical water splitting, and these have limited commercial applicability due to critical factors, including their physico-chemical properties, the rate of charge-carrier recombination and limited light absorption. This review article discusses these main features, and recent research progress and major factors affect the performance of the water splitting reaction. The mechanism behind these interactions in transition metal oxides and graphene based nano-structured semiconductors upon illumination has been discussed in detail, and such characteristics are relevant to the design of materials with a superior photocatalytic response towards UV and visible light.

• 한국정밀공학회지
• /
• 제21권10호
• /
• pp.7-13
• /
• 2004

• 산업식품공학
• /
• 제14권1호
• /
• pp.49-53
• /
• 2010

표면 플라즈몬 공명을 이용한 센서는 굴절계 기기의 일종으로서 높은 감도를 가질 뿐만 아니라 비표지 방식이라는 장점을 가지고 있다. 본 연구에서는 재래식 SPR 칩을 이용하여 시판 술 4종의 알코올 함량을 측정하였다. 또한, 재래식 SPR 칩의 감도를 개선하기 위하여 금 박막 위에 금으로 나노형상을 구축하여 나노형상 SPR 칩을 제조하여 모형 술에 대한 감도 개선 효과를 분석하였다. 재래식 SPR 칩을 이용하여 시판 술의 알코올 함량을 측정하기 위한 검량선을 개발하였을 때 시료를 전처리 하지 않고 그대로 측정하였을 때 가장 좋은 검량선을 얻을 수 있었다. 소주, 청주, 이과두주, 탁주 등 시판 술 4종에 대한 1차 회귀식의 검량식에서 결정계수는 각각 0.992, 0.933, 0.918, 그리고 0.984로 나타났다. 한편, 재래식 SPR 칩의 감도를 개선하기 위해 나노형상 SPR 칩을 제조하기 위하여 Langmuir-Blodgett(LB) 방법을 활용하였다. 본 연구에서는 수십 nm 두께의 금 박막을 바닥층으로 하여 그 위에 나노 크기의 실리카 입자를 단분자 층으로 덮어 형틀을 제조하고 다시 그 위에 금을 증착한 후 실리카 입자를 제거하는 방법으로 나노형상을 갖는 SPR 칩을 제조하였다. 나노형상 SPR 칩의 성능을 평가하였을 때 20% 알코올 함량을 가지는 모형 술에 대해서 바닥층의 두께가 50 nm, 나노형상에서 골의 깊이가 20 nm, 나노형상의 배열주기가 300 nm일 때 SPR의 감도가 가장 좋아서 95%의 감도 향상을 얻을 수 있었다. SPR의 감도는 칩과 관련된 인자, 시료의 종류 및 상태에 따라 다르게 나타날 수 있으므로 측정 목적에 알맞은 칩의 설계와 선택이 요구된다.

• 한국기계가공학회지
• /
• 제14권4호
• /
• pp.8-13
• /
• 2015

In this study, we fabricated and characterized a nanostructured surface based on a plastic injection molding with a local mold heating (LMH) system. A metal mold core with a closed packed nano convex array (CVA) was achieved by integrated engineering procedures: (1) master template fabrication by anodic aluminum oxidation (AAO), (2) nickel electroforming (NE) process, and (3) post-processing by precision machining. The nickel mold core was utilized to replicate a surface with a closed packed nano concave-array (CCA) based on injection molding using cyclic olefin copolymer (COC) as a plastic material. In particular, an LMH system was introduced to enhance transcription quality of the nano structures by delaying solidification of molten polymer near the surface of the mold core.

• 생태와환경
• /
• 제41권4호
• /
• pp.530-540
• /
• 2008

The temporal and spatial variations of size-structured phytoplankton dynamics in Youngsan Lake were investigated to explore potential mechanims controlling the dynamics in the Youngsan Lake. Field data were collected monthly from February to October, 2003 at 6 stations along the axis of Youngsan Lake. In this study, phytoplankton (chlorophyll $\alpha$) were categorized into three size classes: micro-size ($>20{\mu}m$), nano-size ($2{\sim}20{\mu}m$) and pico-size ($<20{\mu}m$). Water temperature, light attenuation coefficients, PAR (photosynthetically active radiation) and suspended solids were measured to analyze relationship between physical-chemical properties and size structure of phytoplankton. Phytoplankton blooms developed during March, July and October in the upper region of the main stem whereas small-scaled spring bloom was observed in the lower region. The scales of phytoplankton blooms were higher in the upper regions than the lower region and blooms were predominated by micro-size class in upper region but predominated by nano-size class in lower region. Growth of size-structured phytoplankton appeared to be controlled by rather light availability than temperature-dependant metabolisms in the system. Phytoplankton growth may be also supported by ambient nutrients available in the water column from analyses of chlorophyll $\alpha$ vs. nutrient concentrations including nitrite+nitrate and orthophosphate. Growth of nano-sized phytoplankton alone appeared to be supported by orthophosphate as well as nitrite+nitrate indicating that response of phytoplankton to nutrient inputs may be size-dependent.

• 한국표면공학회:학술대회논문집
• /
• 한국표면공학회 2006년도 춘계학술발표회 초록집
• /
• pp.21-21
• /
• 2006

• 한국반도체및디스플레이장비학회:학술대회논문집
• /
• 한국반도체및디스플레이장비학회 2007년도 춘계학술대회
• /
• pp.234-237
• /
• 2007

We fabricated nano-structures of the anodic aluminum oxides on sapphire substrates. Two processes of nano-structured sapphire surface have present: the one is the template mask and the other is the anodic oxidized aluminum deposited on sapphire substrate. The formation of nano-structures has investigated by FE-SEM measurement. The etched surface by the template showed periodic lattice but the deposited surface showed the randomly distributed phase of nanoholes instead of the periodic lattice.

• 대한용접접합학회:학술대회논문집
• /
• 대한용접접합학회 2004년도 춘계 학술발표대회 개요집
• /
• pp.311-313
• /
• 2004

WC-12-17%Co powders with nano- and micro-structures were deposited by cold spray process using nitrogen and helium gases. The results show that there is no detrimental phase transformation and/or decarburization of WC by cold spray deposition as expected. It is also observed that nano-sized WC in the feedstock powder is maintained in the cold spray deposition. It is demonstrated that it is possible to fabricate the nano-structured WC-Co coating with low porosity and very high hardness (-2050 HV) by cold spray deposition with reasonable powder preheating.

• 한국표면공학회:학술대회논문집
• /
• 한국표면공학회 2015년도 춘계학술대회 논문집
• /
• pp.66-66
• /
• 2015