• Title/Summary/Keyword: Nano-material

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Improvement of Transmittance and Surface Integrity of Glass Mold for light-hardening polymer Using MR Polishing (HR polishing에 의한 광경화성수지 성형용 글래스 몰드의 투과율 및 표면품위 향상)

  • Lee, J.W.;Kim, D.W.;Cho, M.W.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2009.05a
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    • pp.78-83
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    • 2009
  • In general, Light-hardening polymer was used UV nanoimprint technology. A light-hardening polymer was had the problem of poor hardness, durability. In order to overcome the problem of polymer, inter change optical glass. However glass is very manufacture and a lowering of standars transmittance. In order to glass recover was necessary polishing process. The process is magnetorheological fluids polishing. MR polishing has been developed as a new precision finishing technique to obtain a fine surface. Hence, Magnetorheological fluids has been used for micro polishing to get micro parts. This polishing process guarantees high polishing quality by controlling the fluid density electrically. The applied material in experiments is fused silica glass. Fused silica glass is widely used in the optical field because of high degree of purity. For MR polishing experiments, MR fluid was composed with DI-water, carbonyl iron and nano slurry ceria. The wheel speed and electric current were chosen as the variables for analyzing the characteristics of MR polishing process. Outstanding surface roughness of Ra=1.58nm was obtained on the fused silica glass specimen. And originally glass transmittance was recover on the fused silica glass.

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A Study on Finite Element Analysis and Aging Test for Automotive Grommet (자동차 그로멧의 유한요소해석 및 노화시험에 대한 연구)

  • Lee, Seong-Beom;Yeom, Sang-Hoon;Han, Chang-Yong;Woo, Chang-Su
    • Elastomers and Composites
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    • v.47 no.3
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    • pp.201-209
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    • 2012
  • Grommet is one of the Automotive rubber components and is made from EPDM(Ethylene Propylene Diene monomer M-class) rubber and the nonlinear hyperelastic material properties of rubber are important to predict the behavior of rubber product. In this study, the stable stress-strain relations were obtained from the uni-axial tension test and the equi-biaxial tension test. Finite element analysis for grommet was carried out and heat aging test for the lifetime prediction of grommet was introduced.

Multiphase Simulation of Rubber and Air in the Cavity of Mold

  • Woo, Jeong Woo;Yang, Kyung Mi;Lyu, Min-Young
    • Elastomers and Composites
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    • v.51 no.4
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    • pp.263-268
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    • 2016
  • In the polymer shaping process that uses molds, the quality of the molded products is determined not only by the flow of the (molten) polymer but also by the air venting in the cavity. Inadequate air venting in the cavity can cause defects in the product, such as voids, short shot, or black streaks. As it is critical to consider the location and size of the vents for proper venting of the air in the cavity, a method that predicts the flow of air and material is required. The venting of air by the flow of rubber inside the cavity was simulated by using a multi-phase computational fluid dynamics method. Through computer simulation, the interface of rubber and air over time was predicted. Then, the velocity and pressure distribution of the venting air were observed. Our research proposes a fundamental method for analyzing the multi-phase flow of polymer materials and air inside the cavity of a mold.

Synthesis of Nano-size Aluminum Nitride Powders by Chemical Vapor Process (화학기상공정을 이용한 나노질화알루미늄 분말 합성)

  • Pee, Jae-Hwan;Park, Jong-Chul;Kim, Yoo-Jin;Hwang, Kwang-Taek;Kim, So-Ryong
    • Journal of Powder Materials
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    • v.15 no.6
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    • pp.496-502
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    • 2008
  • Aluminum nitride (AlN) powders were prepared by the chemical vapor synthesis (CVS) process in the $AlCl_{3}-NH_{3}-N_{2}$ system. Aluminum chloride ($AlCl_3$) as the starting material was gasified in the heating chamber of $300^{\circ}C$. Aluminum chloride gas transported to the furnace in $NH_{3}-N_{2}$ atmosphere at the gas flow rate of 200-400ml/min. For samples synthesized between 700 and $1200^{\circ}C$, the XRD peaks corresponding to AlN were comparatively sharp and also showed an improvement of crystallinity with increasing the reaction temperature. In additions, the average particle size of the AlN powders decreased from 250 to 40 nm, as the reaction temperature increased.

The evolution characteristics of incipient soot particles in ethylene/air inverse diffusion flame (에틸렌/공기 역확산 화염에서의 초기 매연 입자의 성장 특성)

  • Oh, Kwang-Chul;Lee, Uen-Do;Shin, Hyun-Dong;Lee, Eui-Ju
    • Journal of the Korean Society of Combustion
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    • v.9 no.2
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    • pp.38-44
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    • 2004
  • The evolution of incipient soot particles has been examined by high resolution electron microscopy (HRTEM) and elemental analyzer in ethylene-air inverse diffusion flames. Laser Induced Incandescence(LII) and laser scattering methods were introduced for examining the soot volume fraction and morphological properties in combustion generated soot qualitatively. Soot particles, collected by thermophoretic sampling, were analyzed by using HRTEM to examine the nano structure of precursor particles. HRTEM micrographs apparently reveal a transformation of condensed phase of semitransparent tar-like material into precursor particles with relatively distinct boundary and crystalline which looks like regular layer structures. During this evolution histories, C/H analysis was also performed to estimate the chemical evolution of precursor particles. The changes of C/H ratio of soot particles with respect to residence time can be divided into two parts: one is a very slowly increasing regime where tar-like materials are transformed into precursor particles (inception process) the other is an increasing region with constant rate where surface growth affects the increase of C/H ratio dominantly (surface growth process). These results provide a clear picture of a transition to mature soot from precursor materials.

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Fabrication and Characterization of an OTFT-Based Biosensor Using a Biotinylated F8T2 Polymer

  • Lim, Sang-Chul;Yang, Yong-Suk;Kim, Seong-Hyun;Kim, Zin-Sig;Youn, Doo-Hyeb;Zyung, Tae-Hyoung;Kwon, Ji-Young;Hwang, Do-Hoon;Kim, Do-Jin
    • ETRI Journal
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    • v.31 no.6
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    • pp.647-652
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    • 2009
  • Solution-processable organic semiconductors have been investigated not only for flexible and large-area electronics but also in the field of biotechnology. In this paper, we report the design and fabrication of biosensors based on completely organic thin-film transistors (OTFTs). The active material of the OTFTs is poly(9,9-dioctylfluorene-co-bithiophene) (F8T2) polymer functionalized with biotin hydrazide. The relationship between the chemoresistive change and the binding of avidin-biotin moieties in the polymer is observed in the output and on/off characteristics of the OTFTs. The exposure of the OTFTs to avidin causes a lowering of ID at $V_D$ = -40 V and $V_G$ = -40 V of nearly five orders of magnitude.

Effect of $Al_2O_3/Fe$ Ratio on Characteristics of Carbon Nanotubes Prepared by Catalytic Chemical Vapor Deposition

  • Jung, Sung-Sil;Lee, Dae-Yeol;Chung, Won-Sub;Park, Ik-Min
    • Carbon letters
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    • v.5 no.2
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    • pp.81-87
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    • 2004
  • The effect of compositions of $Al_2O_3$ in the mixed $Fe/Al_2O_3$ catalysts on the synthetic behaviors of carbon nanotubes (CNTs) by catalytic chemical vapor deposition (CCVD) process was investigated in wide range of the mixture ratios of support materials. CNTs were synthesized with $Fe/Al_2O_3$ catalysis under the condition of 40 min in synthetic time, and 923 K of synthetic temperature using $C_2H_4$ and $H_2$ as synthetic and carrier gas, respectively. The carbon yield with the content of $Al_2O_3$ showed in a parabolic curve and the maximum carbon yield was 40 wt.% of $Al_2O_3$. As the mixture ratio of $Al_2O_3$ increased, decreasing tendency was observed in the diameter of CNTs. Specific surface areas of CNTs were increased with the increase of the mixture ratio of $Al_2O_3$.

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Inhibition of Hydrogen Formation with Calcium Hydroxide on Zinc Electrode of Film-type Manganese Battery

  • Yun, Je-Jung;Kim, Nam-In;Hong, Chang Kook;Park, Kyung Hee
    • Transactions on Electrical and Electronic Materials
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    • v.16 no.3
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    • pp.135-138
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    • 2015
  • A manganese dioxide (MnO2) layer and zinc (Zn) layer are used as the cathode and the anode to develop filmtype manganese battery, in which a stack of a MnO2 layer, gel electrolyte, and Zn layer are sandwiched between two plastic layers. This paper describes the chemical equation of swelling control upon the film-type manganese battery. We examined the reduction of hydrogen formation, by using calcium hydroxide Ca(OH)2 as an additive in the electrolyte of film-type manganese battery. The phenomena or an effect of reduced hydrogen gas was proven by cyclic voltammogram, X-ray photoelectron spectra (XPS), and volume of hydrogen formation. The amount of H2 gas generation in the presence of Ca2+ ion was reduced from 4.81 to 4.15 cc/g-zinc (14%), and the corrosion of zinc electrode in the electrolyte was strongly inhibited as time passed.

Buckling analysis of embedded laminated plates with agglomerated CNT-reinforced composite layers using FSDT and DQM

  • Shokravi, Maryam
    • Geomechanics and Engineering
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    • v.12 no.2
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    • pp.327-346
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    • 2017
  • Laminated plates have many applications in different industrials. Buckling analysis of these structures with the nano-scale reinforcement has not investigated yet. However, buckling analysis of embedded laminated plates with nanocomposite layers is studied in this paper. Considering the single-walled carbon nanotubes (SWCNTs) as reinforcement of layers, SWCNTs agglomeration effects and nonlinear analysis using numerical method are the main contributions of this paper. Mori-Tanaka model is applied for obtaining the equivalent material properties of structure and considering agglomeration effects. The elastic medium is simulated by spring and shear constants. Based on first order shear deformation theory (FSDT), the governing equations are derived based on energy method and Hamilton's principle. Differential quadrature method (DQM) is used for calculating the buckling load of system. The effects of different parameters such as the volume percent of SWCNTs, SWCNTs agglomeration, number of layers, orientation angle of layers, elastic medium, boundary conditions and axial mode number of plate on the buckling of the structure are shown. Results indicate that increasing volume percent of SWCNTs increases the buckling load of the plate. Furthermore, considering agglomeration effects decreases the buckling load of system. In addition, it is found that the present results have good agreement with other works.

Comparison of different cylindrical shell theories for stability of nanocomposite piezoelectric separators containing rotating fluid considering structural damping

  • Pour, H. Rahimi;Arani, A. Ghorbanpour;Sheikhzadeh, G.A.
    • Steel and Composite Structures
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    • v.23 no.6
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    • pp.691-714
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    • 2017
  • Rotating fluid induced vibration and instability of embedded piezoelectric nano-composite separators subjected to magnetic and electric fields is the main contribution of present work. The separator is modeled with cylindrical shell element and the structural damping effects are considered by Kelvin-Voigt model. Single-walled carbon nanotubes (SWCNTs) are used as reinforcement and effective material properties are obtained by mixture rule. The perturbation velocity potential in conjunction with the linearized Bernoulli formula is used for describing the rotating fluid motion. The orthotropic surrounding elastic medium is considered by spring, damper and shear constants. The governing equations are derived on the bases of classical shell theory (CST), first order shear deformation theory (FSDT) and sinusoidal shear deformation theory (SSDT). The nonlinear frequency and critical angular fluid velocity are calculated by differential quadrature method (DQM). The detailed parametric study is conducted, focusing on the combined effects of the external voltage, magnetic field, visco-Pasternak foundation, structural damping and volume percent of SWCNTs on the stability of structure. The numerical results are validated with other published works as well as comparing results obtained by three theories. Numerical results indicate that with increasing volume fraction of SWCNTs, the frequency and critical angular fluid velocity are increased.